• Title/Summary/Keyword: clean elements

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Effects of Sulfuric Acid Concentration and Alloying Elements on the Corrosion Resistance of Cu-bearing low Alloy Steels

  • Kim, Ki Tae;Kim, Young Sik
    • Corrosion Science and Technology
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    • v.17 no.4
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    • pp.154-165
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    • 2018
  • During the process of sulfur dioxide removal, flue gas desulfurization equipment provides a serious internal corrosion environment in creating sulfuric acid dew point corrosion. Therefore, the utilities must use the excellent corrosion resistance of steel desulfurization facilities in the atmosphere. Until now, the trend in developing anti-sulfuric acid steels was essentially the addition of Cu, in order to improve the corrosion resistance. The experimental alloy used in this study is Fe-0.03C-1.0Mn-0.3Si-0.15Ni-0.31Cu alloys to which Ru, Zn and Ta were added. In order to investigate the effect of $H_2SO_4$ concentration and the alloying elements, chemical and electrochemical corrosion tests were performed. In a low concentration of $H_2SO_4$ solution, the major factor affecting the corrosion rate of low alloy steels was the exchange current density for $H^+/H_2$ reaction, while in a high concentration of $H_2SO_4$ solution, the major factors were the thin and dense passive film and resulting passivation behavior. The alloying elements reducing the exchange current density in low concentration of $H_2SO_4$, and the alloying elements decreasing the passive current density in high concentration of $H_2SO_4$, together play an important role in determining the corrosion rate of Cu-bearing low alloy steels in a wide range of $H_2SO_4$ solution.

Elemental Analysis of Coal by Inductively Coupled Plasma Mass Spectrometry (誘導結合플라스마 質量分析法에 의한 石炭의 元素 分析)

  • 이용근;고인형;이동수
    • Journal of Korean Society for Atmospheric Environment
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    • v.8 no.3
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    • pp.155-161
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    • 1992
  • A simple, fast yet sensitive method is described for the determination of fifty elements in coal by inductively coupled plasma mass spectrometry. The method involves complete dissolution of coal with mixed acid $(HNO_3, HF, HClO_4)$ in hish pressure Teflon bomb and subsequent inductively coupled plasma mass spectrometric(ICP-MS) measurement. The accuracy of the method, being evaluated by the analysis of NIST SRMs (1632a, 1632b) is better than 20% RSD for most elements. The limits of detection defined by two times $\sigma$ (standard deviation of operational blank) are in order of sub-ppm to ppm, which are low enough to quantitate most elements. However, the determiantions for few elements such as V, As, Se are severely interfered by molecular ions such that their accurate determiantions are not possible. Analytical results for twentyon coals from eight countries including six ones world major coal producing, Korea, Japan, China, I.C.S., U.S.A., Canada, Australia, and South Africa are presented. While the results for major elements agree well with the existing ones, those for a few trace elements disagree considerably. The existing values are considerably higher. It is not possible to judge which are more accurate. However, the exisisting values are more likely to be errorous inasmuch as they are obtained without using high purity reagents and clean laboratory techniques.

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Hydraulic Modal Analysis of High-Pressure Common-rail Fuel Injection System for Passenger Vehicle (승용 CR 연료분사시스템에 대한 유압 Modal 분석)

  • Sung, Gisu;Kim, Sangmyeong;Kim, Jinsu;Lee, Jinwook
    • Journal of ILASS-Korea
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    • v.20 no.1
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    • pp.14-19
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    • 2015
  • Recently, R&D demand for environmental friendly vehicle has rapidly increased due to its global environmental issues such as global warming, energy and economic crisis. Under this situation, the most realistic alternative way for environmental friendly vehicle is a clean diesel vehicle. The common-rail fuel injection system, as key technology of clean diesel vehicle, consists of a high pressure pump, common-rail, high pressure fuel line and electronic control injector. In common-rail high-pressure fuel injection system, high pressure wave of injection system and geometry of injector elements have a major effects on high-pressure fuel spray. Therefore, in this study, the numerical model was developed for analysis about the common-rail fuel pressure pulsation by using AMESim code. We could secure stability of common-rail high-pressure fuel injection system through optimal design of fuel line.

Triangular Grid Homogenization Using Local Improvement Method (국소개선기법을 이용한 삼각격자 균질화)

  • Choi, Hyung-Il;Jun, Sang-Wook;Lee, Dong-Ho;Lee, Do-Hyung
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.33 no.8
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    • pp.1-7
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    • 2005
  • This paper proposes a local improvement method that combines extended topological clean up and optimization-based smoothing for homogenizing triangular grid system. First extended topological clean up procedures are applied to improve the connectivities of grid elements. Then, local optimization-based smoothing is performed for maximizing the distortion metric that measures grid quality. Using the local improvement strategy, we implement the grid homogenizations for two triangular grid examples. It is shown that the suggested algorithm improves the quality of the triangular grids to a great degree in an efficient manner and also can be easily applied to the remeshing algorithm in adaptive mesh refinement technique.

Clean techniques for trace metal analysis in natural waters (자연수 중의 미량금속 분석을 위한 청결기술)

  • Kim, Kyung-Tae;Kim, Eun-Soo;Cho, Sung-Rok;Park, Jun-Kun;Moon, Deok-Soo;Kim, Hyeon-Ju
    • Proceedings of KOSOMES biannual meeting
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    • 2007.11a
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    • pp.43-49
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    • 2007
  • The metals we are familiar with(Al, Ag, Au, Cu, Cd, Co, Fe, Ni, Pb, Zn, etc) are common elements and conservative pollutants. Although metals are often vital constituents of the metabolism of living organisms(trace elements}, a number of them are toxic if their concentration exceeds a certain threshold. It has long been recognized that measurements of trace metals in natural waters are often subject to large errors in terms of precision and accuracy. Since 1975 in US and European countries, seawater concentration of many trace metals have been shown to be factors of 10-1,000 lower than those previously accepted. Vertical profiles have been found to be consistent with known biological, physical and/or geochemical processes. These are resulted from major advances in analytical instrumentation and methodology for trace elements, and greater attention has been given to assuring the elimination of contamination during sampling, storage, and analysis.

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The brief review on Coal origin and distribution of rare earth elements in various Coal Ash Samples

  • Ramakrishna, Chilakala;Thenepalli, Thriveni;Nam, Seong Young;Kim, Chunsik;Ahn, Ji Whan
    • Journal of Energy Engineering
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    • v.27 no.2
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    • pp.61-69
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    • 2018
  • Rare earth elements together with Y and Sc (REEs) are essential in the development of technology for clean and efficient use of energy. In recent years coal deposits have much attention and attracted as a promising alternative raw sources for rare earth elements, not only because the REEs concentrations in many coals or coal ashes are equal to or higher than those found in conventional types of REEs ores but also because of the world wide demand for REEs in recent years has been greater than supply. In the coal ashes, REEs are mainly associated with carbonates, silicates and aluminosilicates in ashes at 800 and $1100^{\circ}C$. These elements are known to be powerful environmental tracers in natural biogeochemical compartments. In this study, to reviewed the REEs originating and distribution patterns in coal ash samples from the bedrock and/or soil weathering that were entrapped by lichens and mosses was investigated. The REEs patterns of different organisms species allowed minor influence of the species to be highlighted compared to the regional lithology.

Effect of design elements of Block Stripe Pattern on Sensibility (블록 스트라이프 패턴의 디자인 요소가 감성에 미치는 영향)

  • 이영진;정혜진;박희주;이주현;조길수
    • Science of Emotion and Sensibility
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    • v.5 no.3
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    • pp.21-28
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    • 2002
  • In order to reflect emotion and sensibility of consumers to textile pattern design, the effect of design elements of block stripe pattern on sensitivity was investigated. The stimuli were manipulated with 4 design elements of value difference (3 levels), arrangement (2 levels), width (2 levels) and interval (3 levels). Among the 36 combinations, 27 stimuli, which showed independent sensibility results in the pretest, were adopted as final stimuli. Male and female university students (n=30) evaluated each sensibility subjectively using a questionnaire developed for this study. The effect of design elements on 12 sensibility dimensions drawn by factor analysis and the relationships between the physical quantities of each stimulus and the sensibilities were investigated. As the results of ANOVA for the effect of design elements on sensibility, there were more significant differences in sensibility in the orders of value difference, interval, width, and arrangement. The value difference showed the highest explanatory power. Looking at the sensibility differences according to the level of design elements, the narrower the width of the stripe, the more 'humble', 'clean', 'modern', 'simple', and 'comfortable', and the narrower the interval between stripes, the more 'impressive' and 'conservative' The smaller the value difference, the more 'luxurious', 'modern', 'humble', 'simple', 'soft', and 'clean'. Regression models to predict the 12 sensibilities showed higher values of goodness of fit except 'conservative', 'casual' and 'modern', which were all over 0.6. Based on these results, 2 design prototypes reflecting consumer's sensibility were presented.

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Influence of Interior Design Elements on Spatial Satisfaction and Preference for Coffeeshop Space (커피전문점의 실내디자인 요소 변화에 따른 공간 만족도 분석)

  • Choi, You-Jin;Lee, Ji-Hyun;Kim, Soo-Young
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.24 no.4
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    • pp.364-375
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    • 2012
  • This study investigates the effects of interior design elements on the satisfaction and preference for space. Field measurements and surveys were conducted in three coffeeshops where various interior design elements were applied. Results indicate that movable tables and chairs for two people were preferred in the space. They need to be placed flexibly according to the visitors' needs to improve satisfaction for convenience. To improve spatial satisfaction, the brightness of color applied to wall surfaces was recommended to be lower than that of color used for floor surfaces. The surfaces of space and interior design elements such as furniture also need to be kept clean. Lamps with lower color temperature were effective to enhance spatial satisfaction. Light sources should be shielded when a pendant lighting system with general diffuse type was used in space. Natural daylight through window was also required for better satisfaction level. Multiple linear regression implied that the cozy feeling by electric light, existence of daylight, flexible layouts for tables and chairs, color and quality of material for tables and floor were significant contributors to overall spatial satisfaction.

Trace Element in the Indian Ocean: Current Research Trends and Future Needs (인도양에서 미량원소 연구 동향 및 향후 연구 방향)

  • Kim, Intae
    • Ocean and Polar Research
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    • v.43 no.4
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    • pp.335-352
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    • 2021
  • Trace elements in the ocean have been known as essential micronutrients for the primary production of phytoplankton and the growth of marine organisms. The GEOTRACES program beginning in the mid-2000 provided a new understanding of the distribution, origin and behavior of trace elements in the ocean, together with the establishment of both clean seawater sampling and trace element analysis techniques. The Indian Ocean, one of the major oceans, is relatively the least explored area, despite playing an important role in global climate variability. Although trace element observations have recently been conducted in the Indian Ocean by Japanese-and Indian scientists, relatively not much study has been done compared to the Atlantic, Pacific and Polar Regions. Recently, together with the launch of R/V Isabu, a 5,000-ton grade large- and comprehensive research vessel, the observations of trace elements has been conducted in the Indian Ocean for the first time in Korea since 2018. In this paper, we introduce the key results of currently conducted GEOTRACES expedition in the Indian Ocean to present future trace element research directions in the Indian Ocean, and also reviewed the preliminary results in the Indian Ocean studies from Korea. In the 2020s, new Indian Ocean GEOTRACES projects are planned around European countries, and it is time for Korea to prepare for the next phase of the trace element study in the Indian Ocean in line with these international trends.