• Food Science and Biotechnology
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• v.14 no.1
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• pp.112-116
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• 2005

Composite films were prepared with soy protein isolate (SPI) and various clay minerals by casting from polymer and clay water suspension. Effects of clay minerals on film thickness, moisture content (MC), tensile strength (TS), elongation at break (E), water vapor permeability (WVP), and water solubility (WS) were tested. Properties including thickness, surface smoothness, and homogeneity of films prepared with organically modified montmorillonite (O-MMT), Wamok clay (W-clay), bentonite, talc powder, and zeolite were comparable to those of control SPI films. TS increased significantly (p<0.05) in films prepared with O-MMT and bentonite, while WVP decreased significantly (p<0.05) in bentonite-added films. WS of most nanocomposite films decreased significantly (p<0.05).

• Journal of the Mineralogical Society of Korea
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• v.28 no.2
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• pp.109-126
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• 2015

Because fault gouge developed at the center of fault is recognized as one of the most important weak sites, it is evident that clay mineralogy and physical properties greatly affect the rock stability. The purpose of this study is to establish the relationship of mineralogy and physical factors that control rock stability in fault zones. We analyzed a total of 51 samples from 16 main faults which were selected from a Korea fracture map, using XRD, SEM, and physical analyses like unit weight, friction and cohesion properties. Though it is considered that the most common clay minerals comprising fault gouge are kaolinite, illite and smectite, clay mineralogy slightly varies depending on lithology: illite > smectite > kaolinite and chlorite in volcanic rocks, kaolinite and chlorite > illite > smectite in sedimentary rocks, and illite > smectite > kaolinite and chlorite in abundance, respectively. Friction angle decreases with increasing clay content. Cohesion increases with increasing clay content below the 45 % region while it decreases with increasing clay content at the region higher than 45%, with some scatters in the data. It is likely that these results are ascribed to the physical heterogeneity of fault gouges with varying content of different clay minerals.

• Journal of the Korean Geotechnical Society
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• v.29 no.12
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• pp.45-56
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• 2013

Abrams equation could be effectively applied to predict strength of cement-admixed clay and clay-water content to cement content ratio is a fundamental parameter for governing strength. This paper analyses unconfined compression strength varying with $w_c/C$ and curing time using laboratory test results. An attempt is made to identify strength of composite soil of cement and clay according to variation of Abrams coefficients and curing time. The value B, which was considered to be constant value in past researches, needs to be considered as parameter variable with curing time. From Abrams equation a correlation was formed for unconfined compression strength with mixing conditions by $w_c/C$ and curing time as dependent variable. Regression results in this paper could be used to predict strength of cement-admixed clay at various mixing conditions.

• Geotechnical Engineering
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• v.10 no.4
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• pp.153-166
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• 1994

In this paper, the experimental study on the behavior of the dredged clay was performed by introducing the consolidation teat method using continuous loading. Also a new testing method was examined and the strength of the dredged clay using thin plate was evaluated. The rheological characteristics of the dredged clay are described by the gingham model. The static and rheologic thin plate penetration test is proposed for the shear strength testing method. It is found that both of testing methods are reasonable and have a practicability. Especially, the strength increases for a water content which is less than two times of liquid limit in case of silty soil and clayey soil. About plasticity index, the strength increases rapidly for a value less than 10 for silt, 5 for clay which a water content is normalized by plasticity index of silty soil rather than clayey soil.

• Geomechanics and Engineering
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• v.16 no.4
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• pp.375-384
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• 2018

Unconfined compressive strength (UCS) of high plasticity clayey soil mixed with 5 and 10 % of Portland cement and four chemical agents such as sodium hexametaphosphate, aluminum sulfate, sodium carbonate, and sodium silicate with 0, 5, 10, and 20% concentrations was comparatively evaluated. The individual and combined effects of the cement and chemical agents on the UCS of the soil mixture were investigated. The strength of the soil-cement mixture generally increases with increasing the cement content. However, if the chemical agent is added to the mixture, the strength of the cement-chemical agent-soil mixture tends to vary depending on the type and the amount of the chemical agent. At low concentrations of 5% of aluminum sulfate and 5% and 10% of sodium carbonate, the average UCS of the cement-chemical agent-soil mixture slightly increased compared to pure clay due to increasing the flocculation of the clay in the mixture. However, at high concentrations (20%) of all chemical agents, the UCS significantly decreased compared to the pure clay and clay-cement mixtures. In the case of high cement content, the rate of UCS reduction is the highest among all cement-chemical agent-soil mixtures, which is more than three times higher in comparison to the soil-chemical agent mixtures without cement. Therefore, in the mixture with high cement (> 10%), the reduction of the USC is very sensitive when the chemical agent is added.

• Journal of The Korean Society of Agricultural Engineers
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• v.58 no.6
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• pp.39-45
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• 2016

In this paper, analyzes the characteristics of self-weight consolidation on the dredged clay according to the fines content and falling height. Research was performed with the dredged clay sampled by Sae-mangeum field site. Classification of fines content was performed by sieve analysis test. After adjusting the fine content, self-weight consolidation tests were carried out focussing on the variation of fines content and falling heights. From the test results of the self-weight consolidation test, samples with high fines content had reached sedimentation completion more later than ones with less fine content samples. In other words, the start of self-weight consolidation was slowing down with increasing of fines content. Also, from the test results of calculating the coefficient of sedimentation consolidation, the coefficient value were increased with the fines content increases. In addition, the change of sedimentation ratio and volume ratio showed more higher changed value as the fine content increases. Thus, it is important to consider the fines content when estimate the settlement time of dredged soil in field dredge work.

• Membrane Journal
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• v.15 no.2
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• pp.165-174
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• 2005

Sulfonated poly(styrene-ethylene-butadiene-styrene) (SSEBS)-clay hybrid membranes were prepared by solution method. In the preparation of hybrid membrane, the amount of clay content was fixed to 5 phr and montmorillonite (MMT) was fully exfoliated by the SEBS and it was confirmed by X-ray diffraction method. D-spacing of the characteristic peak from MMT plate in WAXD was fully diminished. Gas permeability, mechanical properties and thermal properties of the SSEBS-clay hybrid membranes were investigated. Gas permeability through the SSEBS-clay hybrid membranes decreased due to increased tortuosity made by exfoliation of clay in SEBS.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2001.10a
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• pp.125-128
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• 2001

In this wort, the $Na^+-MMT$ has organically modified with silane intercalant to prepare the polymer/clay nanocomposites. The pH. X-ray diffraction (XRD), and contact angles were used to analyze the surface properties of clay and the exfoliation phenomenon of clay interlayer, The mechanical interfacial properties of epoxy/clay nanocomposites were investigated by three-point bending test. From the experimental results. the surface modification made by silane intercalant on clay surface leads to an increase of distance of silicate layers, surface acid value. and electron acceptor parameter of organoclay. The treatments are also necessary and useful for epoxy to intercalate into the interlayer by interacting of electron donor-accepter between basic epoxy and clay surface. The mechanical interfacial properties of the nanocomposites was improved by the presence of dispersed clay nanolayer containing low content of organoclay in comparison with the conventional, which increase the interfacial adhesion between dispersed clay and epoxy resins.

• Magazine of the Korean Society of Agricultural Engineers
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• v.36 no.3
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• pp.90-99
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• 1994

To investigate the undrained shear strength characteristics of marine soils with high water content, high compressibility and weak bearing capacity, a series of undrained triaxial tests with pore pressure measurements on undisturbed and disturbed Banwol marine clay in normally consolidated and overconsolidated states is carried out. The results and main conclusions of this study are summarized as follows : 1 . When the consolidation pressure is increased, the maximum deviator stress of disturbed and undistubed clay in normally consolidated state is increased. Pore pressure parameters and internal friction angle of undisturbed clay are greater than those of disturbed clay. 2. The relationship between pore pressure and axial strain of undisturbed clay in normally consolidated state can be expressed as a hyperbolic function like stress-strain relation proposed by Kondner. 3. In the pore pressure-axial strain relation of disturbed clay in normally consolidated state, failure ratio R'f is greatly deviated in the range of 0.7~0.9 proposed by Christian and Desai. 4. For overconsolided clay, when overconsolidation ratio (OCR) is increased, normalized maximum deviator stress is increased and maximum pore pressure is decreased gradually. 5. Cohesion of overconsolidated clay is greater than that of nomally consolidated clay and internal friction angle slightly is decreased. 6. Pore pressure parameter at failure (Af) of overconsolidated clay is varied with OCR, Af becomes negative values with increment in OCR

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.1
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• pp.19-23
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• 2019

The PMMA (polymethyl methacrylate)/clay nanocomposites were synthesized by in situ radical polymerizations with different clay contents (3 and 7 wt%) using microwave heating. The nanostructure, optical, and thermal properties of the synthesized PMMA/clay nanocomposites were measured by XRD, TEM, AFM, UV-vis, and TGA. It was found that the intercalated- or exfoliated structure of PMMA/clay nanocomposites was strongly dependent on the content of clay. Thus, the imposition of microwave-assisted polymerization facilitated a delamination process of layered silicates to achieve exfoliation state of interlayer distance. The PMMA/3 wt% C10A nanocomposite with well-dispersed and exfoliated clay nano-layers showed the good optical transparency similar to pure PMMA in this study. The thermal decomposition rates of the PMMA/clay nanocomposites become to be lower compared to that of the pure PMMA, indicating the intercalated- or exfoliated inorganic silicate has high thermal stability. A possible reason is that the thermally segmental motion of PMMA polymer into inorganic silicate interlayer spacing has increased the thermal stability of the PMMA/clay nanocomposites.