• Title/Summary/Keyword: chromaticity coordinates

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White Organic Light-Emitting Diodes Using DCJTB-Doped 24MeSAlq as a New Hole-Blocking Layer (새로운 정공차폐 층 (Hole blocking layer)으로 DCJTB 도핑된 24MeSAlq를 이용한 백색유기발광다이오드)

  • Kim, Mi-Suk;Lim, Jong-Tae;Yeom, Geun-Young
    • Korean Journal of Materials Research
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    • v.16 no.4
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    • pp.231-234
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    • 2006
  • To obtain balanced white-emission and high efficiency of the organic light-emitting diodes (OLEDs), a deep blue emitter made of N,N'-diphenyl-N,N'-bis(1-naphthyl)- (1,1'-biphenyl)-4,4'-diamine (NPB) emitter and a new red emitter made of the Bis(2,4 -dimethyl-8-quinolinolato)(triphenylsilanolato)aluminum(III) (24MeSAlq) doped with red fluorescent 4-(dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H -pyran (DCJTB) were used and the device was tuned by varying the thickness of the DCJTB-doped 24MeSAlq and $Alq_3$. For the white OLED with 10 nm thickness DCJTB (0.5%) doped 24MeSAlq and 45 nm thick $Alq_3$, the maximum luminance of about 29,700 $Cd/m^2$ could be obtained at 14.8 V. Also, Commission Internationale d'Eclairage (CIE) chromaticity coordinates of (0.32, 0.28) at about 100 $Cd/m^2$, which is very close to white light equi-energy point (0.33, 0.33), could be obtained.

White Organic Light-emitting Diodes using the Tandem Structure Incorporating with Organic p/n Junction

  • Lee, Hyun-Koo;Kwon, Do-Sung;Lee, Chang-Hee
    • Journal of Information Display
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    • v.8 no.2
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    • pp.20-24
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    • 2007
  • Efficient white organic light-emitting diodes are fabricated with the blue and red electroluminescent (EL) units electrically connected in a stacked tandem structure by using a transparent doped organic p/n junction. The blue and red EL units consist of the light-emitting layer of 1,4-bis(2,2-diphenyl vinyl)benzene (DPVBi) and 4-dicyanomethylene-2-methyl-6-[2-(2,3,6,7-tetrahydro-1H,5H-benzo[i,j] quinolizin-8-yl)vinyl]-4H-pyran) (DCM2) doped tris(8-hydroxyquinoline) aluminum $(Alq_3)$, respectively. The organic p-n junction consists of ${\alpha}-NPD$ doped with $FeCl_3$ (15 % by weight ratio) and $Alq_3$ doped with Li (10 %). The EL spectra exhibit two peaks at 448 and 606 nm, resulting in white light-emission with the Commission Internationale d'Eclairage (CIE) chromaticity coordinates of (0.36, 0.24). The tandem device shows the quantum efficiency of about 2.2 % at a luminance of 100 $cd/m^2$, higher than individual blue and red EL devices.

Synthesis of NaCaLa(MoO4)3:Ho3+/Yb3+ Phosphors via Microwave Sol-Gel Route and Their Upconversion Photoluminescence Properties

  • Lim, Chang Sung
    • Korean Journal of Materials Research
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    • v.26 no.7
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    • pp.363-369
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    • 2016
  • $NaCaLa_{1-x}(MoO_4)_3:Ho^{3+}/Yb^{3+}$ ternary molybdates with proper doping concentrations of $Ho^{3+}$ and $Yb^{3+}$ (x = $Ho^{3+}+Yb^{3+}$, $Ho^{3+}$ = 0.05 and $Yb^{3+}$ = 0.35, 0.40, 0.45 and 0.50) were successfully synthesized by microwave sol-gel method. Well-crystallized particles formed after heat-treatment at $900^{\circ}C$ for 16 h showed a fine and homogeneous morphology with particle sizes of $3-5{\mu}m$. Under excitation at 980 nm, the UC intensities of the doped samples exhibited strong yellow emissions based on the combination of strong emission bands at 520-nm and 630-nm emission bands in the green and red spectral regions, respectively. The optimal $Yb^{3+}:Ho{3+}$ ratios were obtained at 9:1 and 10:1, as indicated by the composition-dependent quenching effect of the $Ho^{3+}$ ions. The pump power dependence of the upconversion emission intensity and the Commission Internationale de L'Eclairage chromaticity coordinates of the phosphors were evaluated in detail.

Estimating illuminant color using the light locus for camera and highlight on the image (카메라의 조명궤적과 광휘점을 이용한 조명색 추정)

  • Park, Du-Sik;Kim, Chang-Yeong;Seo, Yang-Seock
    • Journal of the Korean Institute of Telematics and Electronics S
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    • v.36S no.10
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    • pp.94-102
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    • 1999
  • In this paper, an algorithm for estimating the scene-illuminant color directly from an image is proposed. To determine the scene-illuminant color in the image. the intersection point between the light locus of camera (CCD) reponses and an approximated lines for the cluster of pixels in a highlight area on chromaticity coordinates is used. By using the predetermined characteristics of the used camera for some illuminants, this algorithm allows us to obtain more accurate estimation of the scene-illuminatnt color from a captured image than that the previous methods provide.

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Highly Efficient Red Phosphorescent OLEDs Based on Ir(III) Complexes with Fluorine-substituted Benzoylphenylpyridine Ligand

  • Kang, Hyun-Ju;Lee, Kum-Hee;Lee, Suk-Jae;Seo, Ji-Hyun;Kim, Young-Kwan;Yoon, Seung-Soo
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3711-3717
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    • 2010
  • Four orange-red phosphorescent Ir(III) complexes were designed and synthesized based on the benzoylphenylpyridine ligand with a fluorine substituent. Multilayered OLEDs with the device structure, ITO/2-TNATA/NPB/CBP : 8% Ir(III) complexes/BCP/Liq/Al, were fabricated using these complexes as dopant materials. All the devices exhibited orange-red electroluminescence and their electroluminescent properties were quite sensitive to the structural features of the dopants in the emitting layers. Among these, the maximum luminance ($14700\;cd/m^2$ at 14.0 V) was observed in the device containing Ir(III) complex 1 as the dopant. In addition, its luminous, power and quantum efficiency were 11.7 cd/A, 3.88 lm/W and 9.58% at $20\;mA/cm^2$, respectively. The peak wavelength of electroluminescence was 606 nm with CIE coordinates of (0.61, 0.38) at 12.0 V. The device also showed stable color chromaticity with various voltages.

Electroluminescence Characteristics of a New Green-Emitting Phenylphenothiazine Derivative with Phenylbenzimidazole Substituent

  • Ahn, Yeonseon;Jang, Da Eun;Cha, Yong-Bum;Kim, Mansu;Ahn, Kwang-Hyun;Kim, Young Chul
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.107-111
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    • 2013
  • A new green-emitting material with donor-acceptor architecture, 3,7-bis(1'-phenylbenzimidazole-2'-yl)-10-phenylphenothiazine (BBPP) was synthesized and its thermal, optical, and electroluminescent characteristics were investigated. Organic light-emitting diodes (OLEDs) with four different multilayer structures were prepared using BBPP as an emitting layer. The optimized device with the structure of [ITO/2-TNATA (40 nm)/BBPP (30 nm)/TPBi (30 nm)/Alq3 (10 nm)/LiF (1 nm)/Al (100 nm)] exhibited efficient green emission. Enhanced charge carrier balance and electron mobility in the organic layers enabled the device to demonstrate a maximum luminance of 31,300 cd/$m^2$, a luminous efficiency of 6.83 cd/A, and an external quantum efficiency of 1.62% with the CIE 1931 chromaticity coordinates of (0.21, 0.53) at a current density of 100 mA/$cm^2$.

Photoluminescence Characteristic of Gallate-Based Red Emitting Phosphors with High Color Purity (색순도가 우수한 갈륨 산화물계 적색 형광체의 광발광 특성)

  • Kim, Kyoung-Un;Choi, Sung-Ho;Jung, Ha-Kyun;Nahm, Sahn
    • Korean Journal of Materials Research
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    • v.18 no.3
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    • pp.159-162
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    • 2008
  • $Eu^{3+}$-activated $R_3GaO_6$ (R = Y, Gd) phosphors were prepared in a conventional solid-state reaction and their optical properties were investigated. These compounds exhibit strong red emission under light excitation at 254 nm. The emission spectra are dominated by peaks appearing around 610-630 nm that are induced by the electric dipole transition of $^5D_0\;{\rightarrow}\;^7F_2$ of $Eu^{3+}$. In addition, the appropriate CIE (Commission Internationale de l'clairage) chromaticity coordinates, (x = 0.656, y = 0.336) for $Y_3GaO_6$ and (x = 0.655, y = 0.334) for $Gd_3GaO_6$, become closer to the NTSC (National Television System Committee) standard values. With the optimized activator concentrations, the maximum emission brightness is approximately 80% of $Y_2O_3$:$Eu^{3+}$ typical red-emitting phosphor with improved color purity under an excitation condition of 254 nm.

Comparison of the Properties and Extracting Conditions of Juice Preperation from Schizandra nigra (흑오미자 즙액의 추출조건과 추출물의 특성)

  • Park, Moon-Su;Rim, Yo-Sup;Shin, Soo-Cheol
    • Journal of Korean Society of Forest Science
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    • v.95 no.4
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    • pp.453-458
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    • 2006
  • To determine the properties for juice preperation of Black Omija (Schizandra nigra MAXIM.) and Omija (Schizandra chinensis BAILL.), yield of extraction, chromaticity and lightness, pH and soluble solid of the extract were investigated. When Schizandra nigra was extracted for 3 hr at $80^{\circ}C$ using 20% aqueous ethanol, the yield of extracts was highest. For the desirable chromaticity coordinates, the optimum extraction time and temperature of Schizandra nigra were 3 hr at $80^{\circ}C$. The lightness of the extract was low of the value when extraction time and temperature was long and high. The sugar content of the extract of Schizandra nigra was ranged between 2.0 and 2.6% Brix, which is lower than that of Schizandra chinensis. Although the pH of the extract from Schizandra nigra was a low in comparison with that of water extract the pH range was proper to maintain the stability of color of extract from the Schizandra chinensis.

The properties and extracting conditions of juice preperation from Schizandra nigra Max. (흑오미자(Schizandra nigra Max) 즙액의 추출조건과 추출물의 특성)

  • 신수철;강성구;장미정
    • Korean Journal of Plant Resources
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    • v.16 no.3
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    • pp.187-193
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    • 2003
  • To determine the properties for juice preperation of Black Omija (Schizandra nigra Max.) and Omija (Schizandra chinensis), yield of extraction, chromaticity and lightness, pH and soluble solid of the extract were investigated. The rate of extract yield from Schizandra nigra was highest when extracted for 3 hours at 80$^{\circ}C$ in 20% ethanol solution. For the desirable chromaticity coordinates, the optimum extraction time and temperature of Schizandra nigra extract were 3 hours at 80$^{\circ}C$. The lightness of the extract was low of the value when extraction time and temperature was long and high. The sugar content of the extract of S. nigra was 2.0­2.6% Brix, lower than that of S. chinensis, but the difference was insignificant. The pH of the extract from S. nigra was 0.1­0.2 higher than that of S. chinensis. Although the pH of the extract from S. nigra was a little low when extracted by water, the pH range was enough to maintain the stability of color of extract from the S. chinensis.

Photoluminescence Properties of BiNbO4:RE3+ (RE = Dy, Eu, Sm, Tb) Phosphors (BiNbO4:RE3+ (RE = Dy, Eu, Sm, Tb) 형광체의 광학 특성)

  • Lee, Sangwoon;Cho, Shinho
    • Journal of the Korean institute of surface engineering
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    • v.50 no.3
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    • pp.206-211
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    • 2017
  • $BiNbO_4:RE^{3+}$ (RE = Dy, Eu, Sm, Tb) phosphors were prepared by solid-state reaction at $1100^{\circ}C$ and their structural, photoluminescent, and morphological properties were investigated. XRD patterns exhibited that all the synthesized phosphors exhibited a triclinic system with a dominant (210) diffraction peak, irrespective of the type of activator ions. The surface morphologies of rare-earth-ion-doped $BiNbO_4$ phosphors were found to depend strongly on the type of activator ions. The $Eu^{3+}$ and $Dy^{3+}$ doped $BiNbO_4$ phosphors revealed a strong red (613 nm) emission resulting from the $^5D_0{\rightarrow}^7F_2$ transition of $Eu^{3+}$ and a dominant yellow (575 nm) emission originating from the $^4F_{9/2}{\rightarrow}^6H_{13/2}$ transition of $Dy^{3+}$ respectively, which were the electric dipole transitions, indicating that the activator ions occupy sites of non-inversion symmetry in the $BiNbO_4$ phosphor. The main reddish-orange emission spectra of $Sm^{3+}$-doped $BiNbO_4$ phosphors were due to the $^4G_{5/2}{\rightarrow}^6H_{7/2}$ (607 nm) magnetic dipole transition, indicating that the $Sm^{3+}$ ions were located at inversion symmetry sites in the $BiNbO_4$ host lattice. As for $Tb^{3+}$-doped phosphors, green emission was obtained under excitation at 353 nm and its CIE chromaticity coordinates were (0.274, 0.376). These results suggest that multicolor emission can be achieved by changing the type of activator ions incorporated into the $BiNbO_4$ host crystal.