• Title/Summary/Keyword: chondrite

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Geochemical Relationship Between Shore Sediments and Land Geology in Keum River Area, West Coast of Korea (한반도 서해안 금강하구 연안퇴적물과 육상지질과의 지화학적 상관관계)

  • 지정만;장윤호;오재경;이연희
    • Economic and Environmental Geology
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    • v.33 no.6
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    • pp.447-467
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    • 2000
  • This study was carried out geochemically and mineralogically to define how Kunsan shore sediments are related to their terrestrial source rocks in the region of Keum River Basin, western Korea. As a whole the chemical composition for major elements, trace elements and rare earth elements analysis from shore sediments and river bed sediments doesn't show the big difference, and especially rare earth elements chondrite normalized patterns are almost same. Heavy minerals of shore sediments are identified as hornblende, epidote, ilmenite, garnet, hematite, magnetite, sphene and rutile. Compared with Taean Area of Seo et al. (1998) and Byeonsan Area of Kwon et al. (1999), Kunsan shore sediments of this study area were origined mostly from Keum River Basin.

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Applications of the Fast Grain Boundary Model to Cosmochemistry (빠른 입계 확산 수치 모델의 우주화학에의 적용)

  • Changkun Park
    • Korean Journal of Mineralogy and Petrology
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    • v.36 no.3
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    • pp.199-212
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    • 2023
  • Diffusion is a powerful tool to understand geological processes recorded in terrestrial rocks as well as extraterrestrial materials. Since the diffusive exchange of elements or isotopes may have occurred differently in the solar nebula (high temperature and rapid cooling) and on the parent bodies (fluid-assisted thermal metamorphism at relatively low temperature), it is particularly important to model elemental or isotopic diffusion profiles within the mineral grains to better understand the evolution of the early solar system. A numerical model with the finite difference method for the fast grain boundary diffusion was established for the exchange of elements or isotopes between constituent minerals in a closed system. The fast grain boundary diffusion numerical model was applied to 1) 26Mg variation in plagioclase of an amoeboid olivine aggregate (AOA) from a CH chondrite and 2) Fe-Mg interdiffusion between chondrules, AOA, and matrix minerals in a CO chondrite. Equilibrium isotopic fractionation and equilibrium partitioning were also included in the numerical model, based on the assumption that equilibrium can be reached at the interfaces of mineral crystals. The numerical model showed that diffusion profiles observed in chondrite samples likely resulted from the diffusive exchange of elements or isotopes between the constituent minerals. This study also showed that the closure temperature is determined not only by the mineral with the slowest diffusivity in the system, but also strongly depends on the constituent mineral abundances.

Abundane of Rare Earth Element in Duwon Meteorite and Its Geochchemical Significance (두원운석의 희토류원소 존재도 및 지구화학적 의의)

  • Lee Seung-Gu;Kim Kun-Han;Choi Byeon-Gak
    • The Journal of the Petrological Society of Korea
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    • v.13 no.4
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    • pp.238-243
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    • 2004
  • Duwon meteorite was fallen on 23 November 1943 in Duwonmyeon, Goheung, Jeolanam-Do. We measured rare earth element abundance of Duwon meteorite by isotope dilution thermal ion mass spectrometry (ID-TIMS) and ICP-MS. As a result, except La and Ce, abundance of other rare earth element show a correspondence within 10% of error range. However, La and Ce show more than 70% in abundance, which is considered due to 1) experimental procedure or 2) inhomogeneity of sample. Leedey meteorite was fallen on 25 November 1943 in Dewey County, Oklahoma, USA. which suggested that fallen difference between Leedey and Duwon meteorites is only 2 days. Leedey and Duwon meteorites are classified as ordinary chondrite of L6 type. In Leedey chondrite-normalized REE pattern, Duwon meteorite shows nearly flattened, which suggests close relationship between Leedey and Duwon meteorites meteoritically or cosmochemically.

Geochemistry and Petrogenesis of Pliocene Alkaline Volcanic Rocks of Dok Island, Korea

  • Wee, Soo Meen
    • Journal of the Korean earth science society
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    • v.36 no.5
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    • pp.447-459
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    • 2015
  • Dok island comprises Pliocene volcanic products such as a series of volcanoclastic rocks and lavas ranging in composition from alkali basalts, and trachyandesites to trachytes. Compositional variation of the basaltic rocks can be attributed to fractional crystallization of olivine, clinopyroxene, plagioclase, and magnetite. Chemical variations among the trachyandesites are caused by fractionation of clinopyroxene, plagioclase, and magnetite with minor amphibole, while trachytes are controlled mainly by feldspar fractionation. Incompatible element abundance ratios and chondrite normalized LREE/HREE ratios (e.g., (La/Yb)c: 24.8 to 32.8 for basalts, 15.6 to 31.2 for trachyandesites) suggest that the origins of the basalts and trachyandesites involve both different degrees of partial melting and subsequent fractional crystallization processes. Trace element ratios of the basalts from Dok island are characterized by high Ba/Nb, La/Nb, Ba/Th and Th/U and isotopic ratios (Tasumoto and Nakamura, 1991) that are similar to the EM 1 type of oceanic island basalts such as Gough and Tristan da Cunha basalts.

Variation of ordinary chondrite textures by thermal/shock metamorphisms and weathering ; a study using scanning electron microscopy (주사전자 현미경으로 관찰한 열변성, 충격변성 및 풍화작용에 따른 오디너리 콘드라이트 조직의 변화)

  • Park Gwon-Tae;Choe Byeon-Gak
    • 한국지구과학회:학술대회논문집
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    • 2006.02a
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    • pp.230-234
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    • 2006
  • 본 연구에서는 미분화 운석 중 오디너리 콘드라이트를 주사전자 현미경으로 관찰하여 열변성, 충격 변성 정도, 지구상에서의 풍화 정도에 따라서 그 구성 성분과 조직이 어떤 변화를 보이는지 알아보았다. 이를 위해 15개의 오디너리 콘드라이트에 대해 각각 연마편 및 연마박편을 준비하였으며, 주사전자 현미경 사진을 이용하여 열변성 단계별로 콘드률과 기질의 경계를 비교하였다. 열변성이 증가할수록 콘드률과 기질의 경계는 점차 모호해 진다. 충격변성을 받았는지의 유무는 감람석을 관찰하여 비교적 쉽게 인지할 수 있다. 충격변성을 받지 않은 콘드률 내의 감람석은 완전 소광과 불규칙적인 깨짐을 보이지만 충격변성을 받은 경우 파동소광과 규칙적인 깨짐을 보인다. 지구상에서 풍화를 받은 경우 철-니켈 금속의 산화가 가장 먼저 진행된다. 풍화에 의한 철산화물은 맥상으로 나타나거나 기존의 철-니켈 금속을 치환하여 나타난다. 철산화물에 의해 풍화를 받은 콘드라이트는 전체적으로 갈색을 띄게 된다.

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K-Ar ages and geochemistry of granitic rocks in the northeastern geongsang basin (북동부 경상분지의 화강암류에 대한 지구화학 및 K-Ar 연대)

  • 김상중
    • Economic and Environmental Geology
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    • v.32 no.2
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    • pp.141-150
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    • 1999
  • The granitic rocks are distributed in the northeastern Gyeongsang basin, and are subdivided into the Youngduk, Younghae, Jangsadong and Onjeong granite. Based on the chondrite normalized patterns of REE by primitive mantle, the Jangsadong granite is more negative Eu anomaly than other granites. On the patterns of trace and rare earcth elements normalized by primitive mantle, Sr, P, Nd, Sm and Ti contents of t도 Youngduk and Younghae granites are higher than those of Jangsadong and Onjeong granites. Based on K-Ar ages, the Youngduk granite is 166.5 Ma for biotite, Younghae granite is 158.7 to 178.0 Ma for hornblende, Jangsadong granite is 113.8 to 118.4 Ma for K-feldspar and hornblende, and Onjeong granite is 67.4 Ma for biotite. Thus, geochemical and geochronological results suggest two plutonic episodes :the Youngduk-Younghae granites and Jangsadong-Onjeong granites suggest two plutonic episodes : the Youngduk-Younghae granites and Jangsadong-Onjeong granites. Jurassic plutonism cooled faster than Cretacous plutonism in the study area.

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Petrochemical Study On the Kwangju Granite Body (광주화강암체에 대한 암석화학적 연구)

  • Kim, Yong-Jun;Oh, Min-Su;Park, Jay-Bong
    • Economic and Environmental Geology
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    • v.26 no.1
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    • pp.83-96
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    • 1993
  • Kwangju granite body located in vicinity of Kwangju city consist of three rock bodies-Kwangju rock body, Jangsung rock body and Youngkwang rock body. Petrochemistry of Kwangju granite is as follows: Kwangju granite body is igneous complex which compose of a series of differential products of a magma. Kwangju granites are divided into four rock facies based on the geologic age, mineralogical and chemical constituents and texture: Triassic hornblende-biotite granodiorite and biotite granite, and Jurassic porphyritic granite and two mica granite. Harker and other variation diagrams of Kwangju granites plot on trend of calc-alkali rock series and range of peraluminous granite. Parental magma type of Kwangju granites correspond to I-type, Syn-Collision type in compressive stress field by collision movement between both rock block. In chondrite normalized REE patterns of Kwangju grnites, LREE enriched than HREE in REE amount and have more steep negative slope with slightly (-) Eu anormaly.

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The Geochemical and Zircon Trace Element Characteristics of A-type Granitoids in Boziguoer, Baicheng County, Xinjiang (중국 신장 위그루자치구 바이청현 보즈구얼의 A형화강암류의 지화학 및 지르콘 미량원소특징에 대한 연구)

  • Yin, Jingwu;Liu, Chunhua;Park, Jung Hyun;Shao, Xingkun;Yang, Haitao;Xu, Haiming;Wang, Jun
    • Economic and Environmental Geology
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    • v.46 no.2
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    • pp.179-198
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    • 2013
  • The Boziguoer A-type granitoids in Baicheng County, Xinjiang, belong to the northern margin of the Tarim platform as well as the neighboring EW-oriented alkaline intrusive rocks. The rocks comprise an aegirine or arfvedsonite quartz alkali feldspar syenite, an aegirine or arfvedsonite alkali feldspar granite, and a biotite alkali feldspar syenite. The major rock-forming minerals are albite, K-feldspar, quartz, arfvedsonite, aegirine, and siderophyllite. The accessory minerals are mainly zircon, pyrochlore, thorite, fluorite, monazite, bastnaesite, xenotime, and astrophyllite. The chemical composition of the alkaline granitoids show that $SiO_2$ varies from 64.55% to 72.29% with a mean value of 67.32%, $Na_2O+K_2O$ is high (9.85~11.87%) with a mean of 11.14%, $K_2O$ is 2.39%~5.47% (mean = 4.73%), the $K_2O/Na_2O$ ratios are 0.31~0.96, $Al_2O_3$ ranges from 12.58% to 15.44%, and total $FeO^T$ is between 2.35% and 5.65%. CaO, MgO, MnO, and $TiO_2$ are low. The REE content is high and the total ${\sum}REE$ is $(263{\sim}1219){\times}10^{-6}$ (mean = $776{\times}10^{-6}$), showing LREE enrichment HREE depletion with strong negative Eu anomalies. In addition, the chondrite-normalized REE patterns of the alkaline granitoids belong to the "seagull" pattern of the right-type. The Zr content is $(113{\sim}1246){\times}10^{-6}$ (mean = $594{\times}10^{-6}$), Zr+Nb+Ce+Y is between $(478{\sim}2203){\times}10^{-6}$ with a mean of $1362{\times}10^{-6}$. Furthermore, the alkaline granitoids have high HFSE (Ga, Nb, Ta, Zr, and Hf) content and low LILE (Ba, K, and Sr) content. The Nb/Ta ratio varies from 7.23 to 32.59 (mean = 16.59) and the Zr/Hf ratio is 16.69~58.04 (mean = 36.80). The zircons are depleted in LREE and enriched in HREE. The chondrite-normalized REE patterns of the zircons are of the "seagull" pattern of the left-inclined type with strong negative Eu anomaly and without a Ce anomaly. The Boziguoer A-type granitoids share similar features with A1-type granites. The average temperature of the granitic magma was estimated at $832{\sim}839^{\circ}C$. The Boziguoer A-type granitoids show crust-mantle mixing and may have formed in an anorogenic intraplate tectonic setting under high-temperature, anhydrous, and low oxygen fugacity conditions.

Preliminary Study on the Ultramafic Rocks from the Chungnam Province, Korea (충남지역에 분포하는 초염기성암의 기원규명을 위한 기초연구)

  • Wee, Soo-Meen;Choi, Seon-Gyu;So, Chil-Sup
    • Economic and Environmental Geology
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    • v.27 no.2
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    • pp.171-180
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    • 1994
  • Several ultramafic bodies and ultramafic origin talc deposits are distributed in Chungnam province near the contact zone with Ogchun fold belt They occur as discontinued belt form with northeast trending, and most of them are more or less sepentinized. Major, trace, and rare earth elements analyses were made of the ultramafics from the study area to constrain their origin and genetic relationships. Compared to the primitive mantle estimates of privious workers, the correlations defined by the studied rock samples indicate similar Ni but very lower $Al_{2}O_{3}$, CaO and $TiO_{2}$ contents. It is inferred that source material of the studied rocks might be residual mantle which had undergone a large degree of partial melting event. The REE patterns show relatively flat to enriched in LREE (chondrite normalized La/Yb and Sm/Yb ratios are 1.1-5.2 and 1.2-1.6). Several alternative explaination are possible for LREE enrichment patterns in the studied ultramafic rocks such as 1) enrichment due to late stage alteration, 2) enriched pre-melting composition, and 3) mixing of two components. Based on the result, the LREE enrichment characteristic of the studied rocks might be result from the mixture of two geochemically distinct components; one is depleted residual mantle and the other component which determine the abundances of incompatible elements and responsible for the LREE enrichment.

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