• Korean Journal of Materials Research
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• v.32 no.3
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• pp.115-124
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• 2022

Porous basalt aggregate is commonly used in roadbed engineering, but its application in concrete has rarely been studied. This paper studies the application of porous basalt in concrete. Porous basalt aggregate is assessed for its effects on mechanical strength and durability of prepared C50 concrete; because it has a hole structure, porous basalt aggregate is known for its porosity, and porous basalt aggregates can be made full of water through changing the content of saturated basalt; after full-water condition is achieved in porous basalt aggregate mixture of C50 concrete, we discuss its mechanical properties and durability. The effects of C50 concrete prepared with basalt aggregate on the compressive strength, water absorption, and electric flux of concrete specimens of different ages were studied through experiments, and the effects of different replacement rates of saturated porous basalt aggregate on the properties of concrete were also studied. The results show that porous basalt aggregate can be prepared as C50 concrete. For early saturated porous basalt aggregate concrete, its compressive strength decreases with the increase of the replacement rate of saturated aggregate; this occurs up to concrete curing at 28 d, when the replacement rate of saturated basalt aggregate is greater than or equal to 40 %. The compressive strength of concrete increases with the increase of the replacement rate of saturated aggregate. The 28 d electric flux decreases with the increase of the replacement rate of saturated aggregate, indicating that saturated porous basalt aggregate can improve the chloride ion permeability resistance of concrete in later stages.

• Journal of the Korea Concrete Institute
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• v.29 no.4
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• pp.407-413
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• 2017

The fundamental property of magnesia phosphate cement (MPC) for concrete repair material was investigated in this research. For mechanical properties, setting time, compressive strength and tensile/flexural bond strength were measured, and hydration products were detected by X-ray diffraction. The specimens were manufactured with dead burnt magnesia and potassium dihydrogen phosphate was admixed to activate the hydration of magnesia and a borax was used as a retarder. To observe the pore structure and ionic permeability of MPC mortar, mercury intrusion porosimetry was performed together with rapid chloride penetration test (RCPT). As a result, time to set of Fresh MPC mortar was in range of 16 to 21 min depend on the M/P ratio. Borax helped delaying setting time of MPC to 68 min. The compressive strength of MPC with M/P of 4 was sharply developed to 30 MPa within 12 hours. The compressive strength of MPC mortar was in range of 11.0 to 30.0 MPa depend on the M/P ratio at 12 hours of curing. Both tensile and flexural bond strength of MPC to old substrate (i.e. MPC; New substrate to OPC; Old substrate) were even higher than ordinary Portland cement mortar (i.e. [OPC; New substrate] to [OPC; Old substrate]) does, accounting 19 and 17 MPa, respectively. The total pore volume of MPC mortar was lower than that of OPC mortar. MPC mortar had the entrained air void rather than capillary pore. The RCPT showed that total charge passed of OPC mortar had more than that of MPC mortar, which can be explained by the pore volume and pore distribution.

• Journal of the Korea Concrete Institute
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• v.18 no.1 s.91
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• pp.125-132
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• 2006

Recently, surface finishing and protection materials were developed to restore performance of the deteriorated concrete and inhibiting corrosion of the reinforcing-bar. For this purpose, surface protection agent as well as coatings are used. Coatings have the advantage of low Permeability of $CO_2,\;SO_2$ and water. However, for coatings such as epoxy, urethane and acryl, long-term adhesive strength is reduced and the formed membrane of those is blistered by various causes. Also when organic coatings are applied to the wet surface of concrete, those have a problem with adhesion. On the other hand, surface protection agent penetrates into pore structure in concrete through capillary and cm make a dense micro structure in concrete as a result of filling effect. Furthermore, the chemical reaction between silicate from surface protection agent and cement hydrates can also make a additional hydration product which is ideally compatible with concrete body. The aim of this study is to examine the effect of penetrative surface protection agent(SPA) by evaluating several concrete durability characteristics. The results show that the concrete penetrated surface protection agent exhibited higher durability characteristics for instance, carbonation velocity coefficient, resistance to chemical attack and chloride ion penetration than the plain concrete. These results due to formation of a discontinuous macro-pore system which inhibits deterioration factors of concrete by changed the pore structure(porosity and pore size distributions) of the concrete penetrated surface protection agent.

• Tunnel and Underground Space
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• v.17 no.4
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• pp.266-284
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• 2007

Recently, many efforts have been made to construct the first unlined tunnel, without in-situ concrete lining, in Korea. However, the lack of reliability in the performance of shotcrete as permanent tunnel support prevented from its realization. Shotcrete has been regarded to have significant problems in field application and long term performance because of unsatisfactory strength level and durability compared to those of European countries. In this study, the high strength shotcrete satisfying compressive strength over 40 MPa and flexural strength over 4.5 MPa was developed from optimized mix design. The type of accelerators and the amount of silica fume were selected as the main factors in mixing process and the analyses were carried out up to the elapsed time of 2 years. In order to evaluate the short term durability of shotcrete, an array of laboratory test consisting of freeze-thaw, carbonation chloride penetration and permeability test was performed. For long-term durability tests, specimens have been put in an operated highway tunnel to expose them to the similar environment when they are actually used as an unlined tunnel support. From the strength and durability tests, it was found that only alkali-free based accelerator satisfied the target strength of this study and also, the developed shotcrete showed very high performance in its durability.

• International Journal of Highway Engineering
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• v.4 no.2 s.12
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• pp.1-8
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• 2002

Latex modified concrete(LMC) became to be applied as a new material for newly constructed bridge deck overlays in Korea due to its excellent bond strength, flexural strength and impermeability against water and chloride. However, it could not be adopted at repair job site because of its long curing time required. Thus, a research on latex modified concrete with rapid-setting cement(RSLMC) is necessary if it could develope the sufficient strength for early opening to traffic. This study focused on the durability of latex modified concrete with rapid-setting cement mainly on water permeable resistance and freeze-thaw resistance. The main experimental variables were latex contents(0, 5, 10, 15 and 20%) and antifoamer contents (0, 1.6, 3.2, 4.8 and 6.4%). Test results show that the permeability of RSLMC is very low indicating below 100 coulombs at 15% of latex contents at all antifoamer contents. The freeze-thaw resistance of RSLMC maintains above 90% of relative dynamic modulus at 3.2% of antifoamer content until 300 freezing-thawing cycles.

• Journal of the Korea Concrete Institute
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• v.28 no.3
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• pp.317-328
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• 2016

This research intends to understand the impact of super-absorbent polymer (SAP) as an internal curing agent in Ultra-High Performance Concrete (UHPC). Two different types of SAPs of acrylic acid (SAP_AA) and acrylic acid-co-acrylamide (SAP_AM) were examined with UHPC formulation. Isothermal calorimetry and x-ray diffraction experiments revealed the impact of polymers with the different chemical bonds on cement hydration. To test its feasibility as a shrinkage reducing admixture for UHPC, a series of experiments including flowability, compressive strength, rapid chloride permeability and autogenous shrinkage profile was performed. While both SAPs showed a reduction in autogenous shrinkage, it has been concluded that the SAP size and chemical form significantly affect the performance as an internal curing agent in UHPC by controlling cement hydration and porosity modification. Between the tested SAPs, SAP_AM which absorbs more water in UHPC than SAP_AA, shows better mechanical and durability performance.

• International Journal of Highway Engineering
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• v.10 no.4
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• pp.189-198
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• 2008

Generally, UFF A(Ultra Fine Fly Ash) has merit that advances a greater concrete workability and activates a greater pozzolanic reaction than common fly ash due to its ultra fine particle size. These properties enhance concrete durability by reducing permeability and increasing resistance of alkali silica reaction(ASR) and sulfate attack, etc. Due to these reasons, UFFA can be used in a rapid setting concrete. The purpose of this study is to develop and evaluate the rapid setting concrete with UFF A as a repair material for early-opening-to-traffic. In previous studies, if only UFFA is added to the rapid setting concrete mixture, pozzolanic reaction doesn't happen actively. Therefore, in this study, the chemical and physical tests were performed for rapid setting concrete with UFFA including calcium hydroxide and the activity of pozzolanic reaction was evaluated. Finally, the effectiveness of this mixture on enhancing concrete durability was investigated. As results, adding UFF A decreased the water/cement ratio of concrete, and compensated the reduced portion of the early strength of concrete. Also, rapid setting concrete with UFFA including calcium hydroxide activated a greater pozzolanic reaction than normal-UFF A concrete. As calcium hydroxide increases, electrical indication of concrete's ability to resist chloride ion penetration is promoted significantly.

• Clean Technology
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• v.8 no.3
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• pp.119-128
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• 2002

In the present study the membrane filtration characteristics of a commercially available synthetic water-based cutting oil through two kinds of ultrafiltration membranes (HF1-45-CM50 and HF1-43-CM100) with molecular weight cut-offs of 50,000 and 100,000, respectively, have been investigated in detail. Among these membranes, the hydrophilic one (HF1-45-CM50) was found to show a satisfactory result for both the permeate flux and the permeability of oil components, whereas the permeate flux obtained with the hydrophobic membrane (HF1-43-CM100) appears to be significantly low, indicating that synthetic cutting oil was easily wetted on the hydrophobic membrane surface and induced more membrane fouling. The effect of material characteristics of the membrane on the filtration characteristics was found to be much more significant compared with the mean pore size of the membrane. Backflushing by nitrogen gas was applied to reduce the formation of a gel layer and membrane fouling. With the hydrophilic membrane, the backflushing was found to increase the permeate flux, whereas the backflushing resulted in a decrease in flux for the hydrophobic membrane. The flux recovery was observed to be highest when the membranes fouled with waste synthetic cutting oil were immersed into a cleaning solution for more than 72 hours and then backflushed by nitrogen gas.

• Membrane Journal
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• v.25 no.5
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• pp.398-405
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• 2015

Facilitated transport is considered to be a possible solution to simultaneously improve permeability and selectivity, which is challenging in normal polymeric membranes based on solution-diffusion transport only. We investigated the effect of adding mesoporous $TiO_2$ ($m-TiO_2$) upon the separation performance of facilitated olefin transport membranes comprising poly(vinyl pyrrolidone), Ag nanoparticles, and 7,7,8,8-tetracyanoquinodimethane as the polymer matrix, olefin carrier, and electron acceptor, respectively. In particular, $m-TiO_2$ was prepared by means of a facile, mass-producible method using poly(vinyl chloride)-g-poly(oxyethylene methacrylate) graft copolymer as the template. The crystal phase of $m-TiO_2$ consisted of an anatase/rutile mixture, of crystallite size approximately 16 nm as determined by X-ray diffraction. The introduction of $m-TiO_2$ increased the membrane diffusivity, thereby increasing the mixed-gas permeance from 1.6 to 16.0 GPU ($1GPU=10^{-6}cm^3$(STP)/($s{\times}cm^2{\times}cmHg$), and slightly decreased the propylene/propane selectivity from 45 to 37. However, both the mixed-gas permeance and selectivity of the membrane containing $m-TiO_2$ rapidly decreased over time, whereas the membrane without $m-TiO_2$ had more stable long-term performance. This difference might be attributed to specific chemical interactions between $TiO_2$ and Ag nanoparticles, causing Ag to lose activity as an olefin carrier.

• Applied Chemistry for Engineering
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• v.7 no.5
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• pp.877-887
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• 1996

The ideal membranes for membrane-covered oxygen probes system should be selectively permeable for oxygen and chemically inert, and have good mechanical strength. Polysulfone(PSf) was selected to develop the membrane for membrane-covered oxygen electrodes system. PSf membranes have properties such as good reproducibility, good mechanical strength, chemical inertness, and high heat resistance. PSf membranes were cast from polymer solution on the glass plate at constant temperature, and casting solvents used were tetrahydrofuran(THF), methylene chloride, and N-methyl-2-pyrrolidone(NMP). Tricresyl phosphate(TCP) as plasicizer was added to PSf to increase the softness of membrane. The permeation characteristics were observed for pure oxygen and nitrogen through pure PSf membranes by variable volume method and membrane-covered electrode system. The permeability coefficients of oxygen and nitrogen measured by variable volume method were slightly decreased with increasing of upstream pressure. The permeation properties of PSf membrane using methylene choride as casting solvent were not affected by the PSf amount of polymer solution. The permeability coefficients of oxygen and nitrogen for PSf membrane containing TCP were very slightly lower than those for pure PSf membrane, but ideal separation factors were slightly higher. The flexibility of PSf membrane containing 2wt% TCP was better than that of pure PSf membrane. It was expected that this increase in flexibility would solve the difficulty of fixing the membrane to the cathode. The membrane-covered oxygen probes system was composed of anode, cathode and electrolyte. The type of the anode was Ag/AgCl half-cell, that of cathode was Ag, and the electrolyte was 4N KCl solution. The result of sampled current voltametry for PSf membrane showed the plateu region at -0.3V~-1.0V. The correlation coefficient of oxygen partial pressure versus current for PSf membrane was relatively high, 0.99949. It was concluded that PSf membrane was the good candidate for the membrane-covered oxygen probes system.