• Title/Summary/Keyword: chloride ion penetration

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Evaluation of Durability of Cement Matrix Replaced with Limestone Powder (석회석 미분말을 혼합한 시멘트 경화체의 내구성능 평가)

  • Woo-Sik Jang;Kwang-Pil Park
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.1
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    • pp.102-109
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    • 2024
  • In order to use limestone powder as a material for concrete, the mechanical and durability characteristics of cement matrices manufactured by varying the substitution rate were evaluated. In general, limestone powder did not contribute to the cement hydration reaction, so as a result of the compressive strength test of cement mortar using it, the compressive strength decreased as the substitution rate increased. However, as a result of evaluating the durability performance of cement mortar using limestone powder, such as chloride ion penetration resistance, carbonation resistance, and chemical attack resistance, small particles of limestone powder showed superior results compared to the unsubstituted control mortar due to the micro-filler effect of filling the fine pores inside the cement matrix. Therefore, limestone powder is expected to be used as an effective method for improving the durability of concrete. In this study, the durability was evaluated by changing the mixing amount of limestone powder to 0 %, 5 %, 10 %, and 15 %, but it is judged that it is necessary to study in more detail the effect on the durability by changing the end and mixing amount of limestone powder to various levels in the future.

Interaction Experiment on Chloride Ion Adsorption Behavior of C-S-H Phases (C-S-H 상의 염소이온 흡착 메커니즘 규명을 위한 반응 작용 실험)

  • Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.29 no.1
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    • pp.65-75
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    • 2017
  • C-S-H phase is the most abundant reaction product, occupying about 50~60% of cement paste volume. The phase is also responsible for most of engineering properties of cement paste. This is not because it is intrinsically strong or stable, but because it forms a continuous layer that binds together the original cement particles into a cohesive whole. The binding ability of C-S-H phase arises from its nanometer-level structure. In terms of chloride penetration in concrete, C-S-H phase is known to adsorb chloride ions, however, its mechanism is very complicated and still not clear. The purpose of this study is to examine the interaction between chloride ions and C-S-H phase with various Ca/Si ratios and identify the adsorption mechanism. C-S-H phase can absorb chloride ions with 3 steps. In the C-S-H phase with low Ca/Si ratios, momentary physical adsorption could not be expected. Physical adsorption is strongly dependent on electro-kinetic interaction between surface area of C-S-H phase and chloride ions. For C-S-H phase with high Ca/Si ratio, electrical kinetic interaction was strongly activated and the amount of surface complexation increased. However, chemical adsorption could not be activated for C-S-H phase with high Ca/Si ratio. The reason can be explained in such a speculation that chloride ions cannot be penetrated and adsorbed chemically. Thus, the maximum chloride adsorption capacity was obtained from the C-S-H phase with a 1.50 Ca/Si ratio.

Evaluations of Corrosion Resistance of Coated Steel Using Polymer Cement Slurry (폴리머 시멘트 슬러리로 코팅한 도장철근의 내식성 평가)

  • Jo, Young-Kug;Kim, Young-Jib;Soh, Yang-Seob
    • Journal of the Korea Concrete Institute
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    • v.15 no.1
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    • pp.117-124
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    • 2003
  • Reinforced concrete structures under sever conditions such as marine structures, bridges and structures constructed with aggregates(dredged from sea), can be deteriorated from corrosion of the reinforcing bars. The purpose of this study is to evaluate the anti-corrosive performance of coated steel using polymer cement slurry. Polymer cement slurry with various polymer dispersions and corrosion inhibiting agent were coated to the surface of bars, and tested for accelerated corrosion tests. Tests include immersion in NaCl 10% solution, chloride ion spray, autoclave cure, autoclave cure after carbonation, penetration of NaCl 10 % solution, carbonation after penetration of NaCl 10% solution. Test results, show that the anti-corrosive performace is considerably improved by using polymer cement slurry at surface of steel. And this trend is marked by adding of corrosion inhibiting agent. This difference of the anti-corrosive properties is hardly recognized according to types of polymer dispersions. The coated steel using polymer cement slurry will be improved to a great extent compared to those of plain steel when increasing content of chloride ion in cement concrete.

Laboratory Evaluation of Polysulfide Epoxy Overlay Material for Bridge Deck (교면포장용 폴리설파이드 에폭시재료의 실내물성 평가)

  • Kim, Jun-Hyung;Suh, Young-Chan
    • International Journal of Highway Engineering
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    • v.13 no.2
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    • pp.159-166
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    • 2011
  • This research was performed to evaluate physical properties of polysulfide epoxy overlay material for bridge deck as part of a review for possibility of domestic application of polymer concrete for bridge deck pavement. In order to evaluate strength characteristics, compressive strength, flexural strength and bond strength were tested, and, for durability characteristics, chloride ion penetration resistance and freeze/thaw resistance were tested along with ultraviolet rays impact evaluation. The tests showed that the results met the criteria suggested by the American Concrete Institute in terms of compressive strength, flexural strength and bond strength. However, in terms of the strengths measured at various test temperatures, it was found that the epoxy material was highly dependent on temperature, and, therefore, this should be considered at the time of domestic application of the epoxy material later. Deflection characteristics was checked through flexural strength test and it was found that bridge deck pavement using the epoxy material was excellent compared to bridge deck pavement using asphalt. Furthermore, the results of chloride ion penetration resistance test and freeze/thaw resistance test were also excellent. In the evaluation of ultraviolet rays impact on epoxy slurry mixture, reduction of strain was noticed with increased strength, but the deflection characteristics after exposure to ultraviolet rays was better than the existing acryl polymer concrete. Therefore, it is concluded from the research that the polysulfide epoxy overlay material has the physical properties that are appropriate to pavement of bridge deck.

The Properties of Strength and Durability of Concrete Using Early-Strength Poly Carbonic Acid Admixture (폴리카르본산계 조강혼화제 혼합 콘크리트의 강도 및 내구 특성)

  • Lee, Sang-Ho;Hong, Kyung-Sun;Moon, Han-Young
    • Journal of the Korea Concrete Institute
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    • v.19 no.2
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    • pp.217-224
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    • 2007
  • This study reports the properties of high early strength & durability of concrete using PC admixture. To apply these data to construction site, we did the lab tests. The target of this study is to accomplish early strength of concrete (5.0 Mpa/18 hr), and we did the durability tests such as length change test, chloride ion penetration test, fleeting and thawing test, adiabatic test, etc. And we tested the porperties of concrete by the different factors, such as the type of admixtures, curing temperature, the amount of binder, etc. Through the test of concrete using the different type of admixture, PC type was more excellent than PNS type admixture. As a result, we made a concrete of high early strength concrete, and excellent durable concrete. According to these tests, we concluded that we can apply this type of PC admixture to the civil & construction site, and we can reduce the term of works and finally we will accomplish the economical construction.

Durability and Bioassay of a Sulfur Polymer Surface Protecting Agent for Concrete Structures (콘크리트 구조물용 유황폴리머 표면보호재의 내구성능 및 생물독성)

  • Seok, Byoung-Yoon;Lee, Byung-Jae;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.6
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    • pp.29-36
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    • 2015
  • In this study, to examine the use of sulfur polymer as a coating agent for concrete, durability and hazard evaluations were performed. The result of the evaluation indicated that the chemical resistance of the coating agent for concrete was outstanding against acidic, base, and alkaline solutions. The evaluation of the bond strength after an accelerated weathering test depending on the mixing condition indicated that the most outstanding strength characteristic was obtained when silica powder and fly ash were mixed at the same time. The bond strength exceeded 1 MPa in every mixing condition even after the repeated hot and cold treatment of the coating agent specimen for concrete, and the SFS mix proportion showed the highest bond strength. The examination of the accelerated carbonation and chloride ion penetration resistance of the concrete coated with the coating agent indicated that the specimen coated with the coating agent using silica powder as a filler showed the most outstanding durability. When a fish toxicity test was performed to examine the hazard of the use of the functional polymer as a coating agent for concrete, the functional polymer was found to have no effect on the organisms. When the chemical resistance, freezing and thawing resistance, carbonation, and chloride ion penetration resistance of the coating agent were considered, substituting silica powder and fly ash as the fillers of the functional polymer by 20%, respectively, was the optimal level in the range of this study.

Strength Development and Durability of High-Strength High-Volume GGBFS Concrete (고강도 고함량 고로슬래그 콘크리트의 강도 발현 특성 및 내구성)

  • Kim, Joo-Hyung;Jeong, Ji-Yong;Jang, Seung-Yup;Jung, Sang-Hwa;Kim, Sung-Il
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.3
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    • pp.261-267
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    • 2015
  • To develop high-strength high-volume ground granulated blast-furnace slag (GGBFS) concrete, this study investigated the characteristics of strength development and durability of concrete with the water-to-binder ratio of 23% and the GGBFS replacement ratio of up to 65%. The results show that the compressive strength of GGBFS blended concrete is lower than that of ordinary Portland cement (OPC) concrete up to 3-day age, but the becomes higher after 7-day age. Together with strength increase, the pore structure becomes tighter, and thus the resistance to chloride ion penetration increases. Therefore, the GGBFS blended concrete has high resistance to freezing and thawing without additional air-entraining, and high resistance to carbonation despite low amount of calcium hydroxide ($Ca(OH)_2$). On the other hand, if silica fume (SF) is blended with GGBFS, the strength becomes lower than that of the concrete blended with GGBFS only, and the resistance to chloride ion penetration deceases. Therefore, it needs further studies on the reaction of SF in high-strength high-volume GGBFS concrete.

Analysis of Chloride Ion Penetration Properties into Concrete on Road Facilities Depending on the Deterioration Environments (국도 상 도로시설물 대상 열화환경 조건 별 콘크리트 염화물 침투 특성 분석)

  • Min, Jiyoung;Lee, Jong-Suk;Lee, Tack-gon;Cha, Ki-Hyuk
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.5
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    • pp.102-113
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    • 2021
  • The deterioration environments caused by de-icing salt and airborne chlorides in the seashore, evaluated in the "Detailed guideline for safety and management practice of facilities (performance evaluation)", were reviewed in terms of penetrated chlorides into concrete on various road facilities. Target concrete structures, in this study, were 4 concrete barriers in Gangwon area, 3 concrete barriers and 1 retaining wall in Busan area, and 4 bridges in Gangwon-do, Seoul, Gyeonggi-do, and Busan. The deterioration environments were classified into three categories: direct and indirect de-icing salt attack, and airborne salt attack depending on the distance to seashore and the height of pier, and the penetrated chlorides in to concrete were analyzed. The results showed that (1) the regional deterioration environments were clearly classified by de-icing salt sprayed days (snowfall days), (2) the penetrated chlorides increased significantly when leakage occurred through slabs or expansion joints, and (3) the airborne chlorides affected to a height of 20 m concrete in the seashore, Busan. From these, it could be confirmed that the chloride ion penetration properties depend on the exposed aging environment, member location and height, and deterioration status, even on the same structure, so the selection of target members and location is very important in the inspection and maintenance. If the database of penetrated chlorides properties in various deterioration environments is constructed, it is expected that the proactive durability management on concrete structures will be possible in the field.

Property Analysis of Waterproofing and Corrosion-Resistant Performance in Concrete Water Supply Facilities (상수도시설 콘크리트 수조구조물에서의 염화이온 침투저항 특성분석)

  • Kwak, Kyu-Sung;Ma, Seung-Jae;Choi, Sung-Min;Oh, Sang-Keun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.2
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    • pp.122-131
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    • 2015
  • The purpose of this study is to understand the necessity for waterproofing and corrosion-resistant technique application on concrete water tank used in water supply. Relevant research materials and regulation were collected, reviewing for the case studies of sample structures aged over 20 years, and experimental studies on chloride conduction for the high performance concrete and penetration properties of water repellency of liquid type materials. The result is that the concrete water tank in the water supply is needed for waterproofing and corrosion-resistant material coating to maintain long term durability due to the constant environmentally induced degradation deterioration often caused by chloride attack.

Reliability Analysis of Chloride Ion Penetration based on Level II Method for Marine Concrete Structure (해양 콘크리트 구조물에 대한 Level II 수준에서의 염소이온침투 신뢰성 해석)

  • Han, Sang-Hun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.12 no.6
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    • pp.129-139
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    • 2008
  • Due to uncertainty of numerous variables in durability model, a probalistic approach is increasing. Monte Carlo simulation (Level III method) is an easily accessible method, but requires a lot of repeated operations. This paper evaluated the effectiveness of First Order Second Moment method (Level II method), which is more convenient and time saving method than MCS, to predict the corrosion initiation in harbor concrete structure. Mean Value First Order Second Moment method (MV FOSM) and Advanced First Order Second Moment method (AFOSM) are applied to the error function solution of Fick's second law modeling chloride diffusion. Reliability index and failure probability based on MV FOSM and AFOSM are compared with the results by MCS. The comparison showed that AFOSM and MCS predict the similar reliability index and MV FOSM underestimates the probability of corrosion initiation by chloride attack. Also, the sensitivity of variables in durability model to corrosion initiation probability was evaluated on the basis of AFOSM. The results showed that AFOSM is a simple and efficient method to estimate the probability of corrosion initiation in harbor structures.