• Proceedings of the Korean Institute of Building Construction Conference
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• 2009.11a
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• pp.127-131
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• 2009

The purpose of this study is to provide fundamental data on chloride diffusion from lightweight aggregate concrete by utilizing crushed stone-powder. Accordingly, the study performed experiments using concrete aggregates of Crushed Aggregate (CG), Single-sized Lightweight Aggregate (SLG), Continuous Graded Lightweight Aggregate (CLG), and using water-binder ratio of 0.4, 0.5, 0.6, and using binder of FA and BFS. The chloride diffusion coefficient is calculated after experiment based on NT BUILD 492. Diffusion coefficient of SLG and CLG were little bit higher than CG Concrete, but the difference is meaningless. Also, chloride diffusion coefficient indicates that it is highly affected by water-binder ratio, and it decreases with the decrease in water-binder ratio. The admixture substitution indicates decrease only with water-binder ratio of 0.4 for FA15% case, but admixture substitution indicates decrease with all levels of ratio for FA10 + BFS20% which means more appropriate. According to the analysis result of chloride diffusion from lightweight aggregate concrete, crushed stone-powder utilized lightweight aggregate concrete indicates higher chloride diffusion coefficient than CG concrete, which is not a significant difference, and can improve resistance through water-binder ratio and admixture substitution.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.793-796
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• 2001

Physical properties of concrete, Such as, compressive strength, permeable pore and penetration depth of chloride ion were investigated. And to investigate the effect of containing GGBF in concrete, the diffusion coefficient of chloride was measured through an electro- migration test. The diffusion coefficient of chloride was decreased with increase of replacement ratios of GGBF when compared to OPC. Relation coefficients between physical properties of concrete and diffusion coefficient of chloride were more than 0.9.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.673-678
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• 2002

There are various methods for the electrochemical techniques to estimate diffusion coefficient of chloride ions in concrete, such as ASTM C 1202 test method, Andrade's method, Dhir's method, Tang's method, and etc. In the case of estimating diffusion coefficient of chloride ions in concrete by using these methods, applied voltage and resistivity nay exercise some influence on the characteristics of chloride ions diffusion. Thus. in this study, effect of applied voltage and resistivity on the characteristics of chloride ions diffusion in concrete were researched by applying voltage in 12V, 30V, and 60V, and by using resistivity in 0.2Ω and 1.0Ω, respectively. It can be concluded that diffusion coefficient of chloride ions are found to be increasing as the individual applied voltage and resistivity decrease, when water-cement ratio is constant.

• Journal of the Korea Concrete Institute
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• v.12 no.1
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• pp.33-44
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• 2000

Since the mechanism of chloride diffusion and its ratio in concrete depend on structural conditions and concrete as a micro-structure, if these are analyzed quantitatively, the long-term ageing of structures can be predicted. Although, a quantitative analysis of concrete micro-structure, in which the results are affected by various parameters, is very difficult, this can be done indirectly by the durability test of concrete. In this study, the compressive strength, void ratio and air permeability of concrete. In this study, the compressive strength, void ratio and air permeability of concrete are chosen as the parameters in concrete durability test, and these effects on test results are analysed according to changes of mixing properties. The relationships between parameters and chloride diffusion velocity is used for prediction models of chloride diffusion. The developed prediction models for the chloride diffusion according to mixing and physical properties, can be used to estimate the service life and corrosion initiation of reinforcing bars in marine structures.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.489-492
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• 2006

A chloride is an important deteriorating factor which governs the durability of the reinforced-concrete structures under marine environments. Also, the main penetration mechanism of chloride ion into concrete is a diffusion phenomenon and numerous methods have been proposed to determine the diffusion coefficient of chloride ion quickly. In this study, electrically accelerated experiments were carried out in order to evaluate diffusion coefficient of the chloride ion into concrete. The methods were diffusion cell test method in which the voltage of 15V(DC) was applied. The type of cement is blended cement in which the admixtures of blast-furnace slag and fly ash were used. In conclusion, the diffusion coefficient of chloride ion is much affected according to mineral admixtures and the diffusion coefficient of ternary blended cement showed very low values. it is presumably said that this result is due to highly densified pore structures by the aid of slag substitution and pozzolanic activity of fly ash.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.10a
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• pp.747-750
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• 1999

Chloride ions are considered to be the major cause of steel corrosion in concrete structures exposed to seashore environments. Thus, estimating chloride ion concentrations by ages is needed to predict service life of seashore structures. Experimentally measured chloride profiles were used in this study for estimating chloride diffusion coefficients, and a relationship between mixing properties and chloride diffusion coefficients is proposed for predicting chloride penetrations.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.699-704
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• 2003

Corrosion of reforcement is the main cause of damage and early failure of reinforced concrete structures. The corrosion is mainly progressed by the chloride ingress. In this paper, an experimental study is executed to investigate the effect of concrete properties and testing method on the coefficient of chloride diffusion. Also, it is compared that the relationship between total chloride and free chloride in concrete. According to this experiment results, w/c ratio and testing method effect on chloride diffusion coefficient of concrete. As w/c ratio is increased, diffusion coefficient in concrete is also increased. Diffusion coefficient obtained by each testing method show the different value, respectively. Also, the content of free chloride in 7days curing concrete is increased as w/c ratio is increased.

• Computers and Concrete
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• v.3 no.6
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• pp.401-422
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• 2006

A multi-species model based on the Nernst-Planck equation has been developed by using a finite volume method. The model makes it possible to simulate transport due to an electrical field or by diffusion and to predict chloride penetration through water saturated concrete. The model is used in this paper to assess and analyse chloride diffusion coefficients and chloride binding isotherms. The experimental assessment of the effective chloride diffusion coefficient consists in measuring the chloride penetration depth by using a colorimetric method. The effective diffusion coefficient determined numerically allows to correctly reproduce the chloride penetration depth measured experimentally. Then, a new approach for the determination of chloride binding, based on non-steady state diffusion tests, is proposed. The binding isotherm is identified by a numerical inverse method from a single experimental total chloride concentration profile obtained at a given exposure time and from Freundlich's formula. In order to determine the initial pore solution composition (required as initial conditions for the model), the method of Taylor that describes the release of alkalis from cement and alkali sorption by the hydration products is used here. Finally, with these input data, prediction of total and water-soluble chloride concentration profiles has been performed. The method is validated by comparing the results of numerical simulations to experimental results obtained on various types of concretes and under different exposure conditions.

• Journal of The Korean Society of Agricultural Engineers
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• v.50 no.4
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• pp.27-37
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• 2008

It is most serious problem which is various occurs from the agricultural concrete structure and off shore concrete structure the problem which it comes to think is deterioration of the concrete which is caused with the corrosion of the reinforcing steel which is caused by with permeation of the water and the sea water. Specially the off shore concrete structure has been deteriorated by the steel reinforcement corrosion. The latex modified concrete(LMC) was adds latex in the plain concrete as the latex has increase the durability of concrete. This study were accomplished to the estimate the diffusion coefficient of LMC, and the time dependent constants of diffusion. The average chloride diffusion coefficient was estimated. Also, the average chloride diffusion coefficient was compared with diffusion coefficient test results of 28 curing days. The test results indicated that the average chloride diffusion coefficient could closely estimate the test results of the diffusion coefficient test results of 28 curing days.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.225-228
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• 2004

In order to estimate the chloride ion penetration, the model, which considers diffusion and sorption, is proposed on the basis of Finite Element Method (FEM). The FEM program provides the estimation of chloride concentration according to cyclic humidity and sorption. After the humidity diffusion analysis is carried out, the chloride ion diffusion and sorption analysis are conducted on the basis of the preestimated humidity data in each element. Each element has different analysis variables at different ages and locations. At early ages and constant outer humidity, the difference between inner and outer relative humidity causes the chloride ion penetration by sorption. As the humidity diffusion reduces the difference with age, the effect of sorption on the chloride ion penetration decreases. By the way, the cyclic humidity increases the effect of sorption on the chloride ion penetration at early ages, and the quantity of chloride ion around steel at later ages. Therefore, the in-situ analysis of chloride ion penetration for marine concrete structures must be performed considering the cyclic humidity condition and the long term sorption.