• Title/Summary/Keyword: chemical-recycled

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Modified-stoichiometric Model for Describing Hydration of Alkali-Activated Slag (알칼리 활성 슬래그의 수화에 대한 개선된 화학양론적 모델)

  • Abate, Selamu Yihune;Park, Solmoi;Song, Keum-Il;Lee, Bang-Yeon;Kim, Hyeong-Ki
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.1
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    • pp.1-12
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    • 2021
  • The present study proposes the modified-stoichiometric model for describing hydration of sodium silicate-based alkaliactivated slag(AAS), and compares the results with the thermodynamic modelling-based calculations. The proposed model is based on Chen and Brouwers(2007a) model with updated database as reported in recent studies. In addition, the calculated results for AAS are compared to those for hydrated portland cement. The maximum difference between the proposed model and the thermodynamic calculation for AAS was at most 20%, and the effects of water-to-binder ratio and activator dosages were identically described by both approaches. In particular, the amount of non-evaporable water was within 10% difference, and was in excellent agreement with the experimental results. Nevertheless, notable deviation was observed for the chemical shrinkage, which is largely dependent on the volume of hydrates and pores.

An Experimental Study on Indoor Pollutant Reduction of Cementitious Composite Using Charcoal and Phytoncide (숯과 피톤치드를 사용한 시멘트계 복합재의 실내 오염물질 저감에 관한 실험적 연구)

  • Jeong, Hyeon-Woo;Jeong, We-Young;Jung, Yoong-Hoon;Han, Song-Yi;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.1
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    • pp.13-19
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    • 2021
  • In modern society, indoor activities time is increasing due to industrial development. Interest in indoor air quality is increasing as indoor activity time increases. The main causes of indoor air pollution are formaldehyde which a chemical cause, and fungi which a biological cause. Phytoncide effectively reduces Formaldehyde and Fungi. Charcoal which possess porous-structure has a good absorbance of pollutants. In this study, the authors manufactured functional cement matrix using by phytoncide and charcoal to remove formaldehyde and fungi. In this study, Functional cement matrix reduced formaldehyde and Fungi and effectively improve indoor air quality.

Investigation on the Characteristics of Interfacial Transition Zone (ITZ) of High-Strength Cement Mortar Incorporating Graphene Oxide (그래핀 옥사이드 혼입 고강도 시멘트 모르타르의 Interfacial Transition Zone (ITZ) 특성에 관한 연구)

  • Im, Su-Min;Cho, Seong-Min;Liu, Jun-Xing;Lim, Seungmin;Bae, Sung-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.343-350
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    • 2022
  • In recent years, nanomaterials, such as nano-silica, carbon nanotubes, and graphene oxide (GO), have been suggested to improve the properties of the interfacial transition zone (ITZ) between aggregates and cement pastes, which has most adversely affected the strength of quasi-brittle concrete. Among the nanomaterials, GO with superior dispersibility has been reported to be effective in improving the properties of ITZ of normal-strength concrete by forming interfacial chemical bonds with Ca2+ ions abundant in ITZ. In this study, the effect of GO on the properties of ITZ in the high-strength mortar was elucidated by calculating the change in hydration heat release, ITZ thickness, and the porosity around ISO sand, which was obtained with isothermal calorimetry tests and scanning electron microscope image analysis, respectively.

Experimental Study on the Setting Time and Compressive Strength of Nano-Micro Pozzolanic Binders as Cement Composites (포졸란 혼화재의 입자 크기 및 비표면적에 따른 응결시간 발현 및 압축강도 특성 평가)

  • Kim, Won-Woo;Yang, Keun-Hyeok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.269-275
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    • 2022
  • In this study, the setting time and compressive strength of cement paste composites applied with nano-micro pozzolanic binders were experimental analyzed. The pozzolanic binder was reduced initial and final setting time and the compressive strength was increased. Micro silica was effective in decrease the initial setting and final setting time and impressing the compressive strength. When two or more cement binders were used, the using of silica fume and a small amount of nano silica at reduced the setting time to 62-64 % to OPC cement and the compressive strength was increased to 117 %. A small amount of mixing the nano silica was effect to pore filling and pozzolanic activation. However, the addition of a chemical admixture should be considered when mixing table design because pozzolanic binders high specific surface area causes a decrease in cement composites flow.

Properties of Grout Material for Seawall Using Slags from Steel Making Industry (철강산업부산물을 사용한 방조제용 그라우트 재료 및 그 특성)

  • Ha-Seog, Kim;Kee-Seok, Kim;Bong-Hyun, Baek;Sim-Hoon, Yook
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.523-530
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    • 2022
  • The problem in the construction of seawall reinforcing the seawall where there is seawater flow is the outflow of materials. Gravity-type pouring of concrete is difficult to fill the voids smoothly, and the cement of concrete that has not hardened is likely to be dispersed in seawater. This phenomenon not only reduces the reliability of quality after concrete hardening, but can also adversely affect the surrounding environment. Therefore, there is a need for a gel-like injection material that can be injected, In this study, the initial strength and durability improvement effect of seawater immersion were evaluated by using electrofurnace reduction slag and blast furnace slag with acute properties. As a result of the experiment, it was possible to prepare a gel-like injection material having flowability through reaction with silica-based chemical liquid. The flowability of the gel is 105~143 mm depending on the formulation, and the on-site simulation test can fill the voids without external leakage, confirming its on-site applicability.

Simulation on the Alternation of Limestone for Portland Cement Raw Material by Steel By-products Containing CaO (CaO 함유 철강 부산물을 활용한 시멘트 원료 석회석 대체 시뮬레이션)

  • Jae-Won Choi;Byoung-Know You;Min-Cheol Han
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.1-8
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    • 2023
  • In this study, to reduce CO2 emission in the cement manufacturing process, we evaluated the limestone that is used as a raw material for cement, substituted with steel slag by the various substituted levels. Based on the chemical composition of each raw materials including limestone, and blast furnace slow cooling slag, converter slag, and KR slag as an alternative raw material, we simulated the optimal cement raw mixture by the substitution levels of limestone. Test results indicated that the steel slags contain a certain level of CaO that can be used as alternative decarbonated raw materials, and it has enough to partially reduce the amount of limestonem. And we estimated the maximum usable levels of each raw material. In particular, it was confirmed that by using a mixture of these raw materials rather than using them one by one, the effect of reducing limestone was increased and CO2 emission from the cement manufacturing process could be reduced.

Performance Evaluation of Eco-friendly Permeable Block Using Basalt Waste Rock (현무암 폐석을 이용한 친환경 투수블록의 성능평가)

  • Sang-Soo Lee;Hyeong-Soon Kwon;Jae-Hwan Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.299-306
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    • 2023
  • Environmental pollution problems are occurring due to the negative treatment of basalt waste in Jeju Island. This study identifies the characteristics of permeable block with basalt with physical and chemical adsorption mechanisms and examines their applicability and functionality as building materials. This experiment is basic data for evaluating the functionality of the permeable block by analyzing flexural strength, compressive strength, permeability coefficient, carbon dioxide, and fine dust adsorption rate by producing a permeable block using a basalt waste rock. As the basalt waste stone replacement rate increased, the flexural strength and compressive strength tended to decrease, and as the replacement rate increased, the water permeability coefficient, absorption rate, carbon dioxide, and fine dust adsorption rate tended to increase. Therefore, it is judged that the permeable block using the basalt waste rock is superior to the existing permeable block.

Experimental Study on the Use of High-Volume Fly Ash and Basalt Fiber as Emergency Repair Materials for Slope Stabilization: An Analysis of Basic Quality Characteristics (비탈면 긴급 복구를 위한 하이볼륨 플라이애시 및 현무암 섬유 보강 보수재료의 기초 품질 특성에 대한 실험적 연구)

  • Doo-Won Lee;Il-Young Jang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.2
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    • pp.111-120
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    • 2024
  • This paper presents a study aimed at developing repair materials for emergency slope stabilization after disasters such as floods. The research assessed how different mix ratios of fly ash and reinforcement with basalt fibers affect the basic quality properties of mortars. Optimal amounts of fly ash were selected based on these properties, and appropriate amounts of chemical admixtures and thickeners were determined to enhance the quality attributed to the basalt fiber mixture. Notably, high-volume fly ash reduced the need for high-performance water reducers and improved workability, known benefits that also helped mitigate fiber ball issues in conjunction with the effects of thickeners. The experimental results indicated that the developed repair materials could potentially be used for emergency repairs, with a focus on initial age strength. This research aims to provide foundational data for repair materials used in future emergency slope stabilizations.

Evaluation of Durability of Cement Matrix Replaced with Limestone Powder (석회석 미분말을 혼합한 시멘트 경화체의 내구성능 평가)

  • Woo-Sik Jang;Kwang-Pil Park
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.1
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    • pp.102-109
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    • 2024
  • In order to use limestone powder as a material for concrete, the mechanical and durability characteristics of cement matrices manufactured by varying the substitution rate were evaluated. In general, limestone powder did not contribute to the cement hydration reaction, so as a result of the compressive strength test of cement mortar using it, the compressive strength decreased as the substitution rate increased. However, as a result of evaluating the durability performance of cement mortar using limestone powder, such as chloride ion penetration resistance, carbonation resistance, and chemical attack resistance, small particles of limestone powder showed superior results compared to the unsubstituted control mortar due to the micro-filler effect of filling the fine pores inside the cement matrix. Therefore, limestone powder is expected to be used as an effective method for improving the durability of concrete. In this study, the durability was evaluated by changing the mixing amount of limestone powder to 0 %, 5 %, 10 %, and 15 %, but it is judged that it is necessary to study in more detail the effect on the durability by changing the end and mixing amount of limestone powder to various levels in the future.

Exploration of retention system for papermaking system closure (제지공정의 무방류화를 위한 보류시스템 탐색)

  • 이학래;함충현;이지영;황남선;이상길;김종민
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.2
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    • pp.1-7
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    • 2001
  • Use of high yield pulp and recycled fiber as raw materials and water system closure result in higher fines content and buildup of organic and inorganic contaminants in white water. These are detrimental for the effectiveness of chemical additives including retention aids. Thus it is imperative to employ a retention systems that maintains its efficiency in closed papermaking system for reducing fresh water consumption. The performance of four different microparticle retention systems including cationic polyacrylamide (C-PAM)/bentonite, highly charged cationic starch (HCS)/silica, C-PAM/micropolymer, cationic guar gum (CGG)/silica was evaluated and compared at three different levels of papermaking system closure. Buildup of detrimental substances in a closed white water system increased cationic demand and finally reduced the performance of retention systems. Cationic starch and guar gums maintained their effectiveness in retention in closed white water systems contaminated with anionic trashes because of their structural rigidity and hydrogen bonding ability. Particularly, cationic guar gums, due its stiffness of molecular structure, appeared perform better than catinonic starch.

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