• Title/Summary/Keyword: chemical-recycled

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Development of Low-activation Cement for Decreasing the Activated Waste in Nuclear Power Plant (원전 방사화 폐기물 저감을 위한 저방사화 시멘트의 개발)

  • Lee, Binna;Lee, Jong-Suk;Min, Jiyoung;Lee, Jang-Hwa
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.3
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    • pp.223-229
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    • 2017
  • When concrete is exposed to neutron rays for a long time, the concrete tends to become activated. If activated, it is classified as middle or low level radioactive waste. However, the great amount of the activated concrete is hard to dispose. In this study, low-activation cement was developed for decreasing the activated waste from shielding concrete around nuclear reactor. Furthermore, the manufactured low-activation was analyzed with activation nuclide Eu, Co. The low-activation cement showed great advantage for low-activation with detecting none of Eu and 3.75ppm of Co while ordinary portland cement showed 0.4~0.9ppm of Eu, 5.5~19.8ppm of Co content. As the results of physical properties of the low-activation cement, it is similar to type 1 ordinary portland cement and accords with type 4 low heat portland cement. Meanwhile, as for the chemical properties of the cement, it accords wite type 1 and 4 at the same time.

Evaluation of TDF ash as a Mineral Filler in Asphalt Concrete (TDF ash를 채움재로 사용한 아스팔트 콘크리트 물성 평가)

  • Choi, MinJu;Lee, JaeJun;Kim, HyeokJung
    • International Journal of Highway Engineering
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    • v.18 no.4
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    • pp.29-35
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    • 2016
  • PURPOSES : The new waste management policy of South Korea encourages the recycling of waste materials. One material being recycled currently is tire-derived fuel (TDF) ash. TDF is composed of shredded scrap tires and is used as fuel in power plants and industrials plants, resulting in TDF ash, which has a chemical composition similar to that of the fly ash produced from coal. The purpose of this study was to evaluate the properties of an asphalt concrete mix that used TDF ash as the mineral filler. METHODS : The properties of the asphalt concrete were evaluated for different mineral filler types and contents using various measurement techniques. The fundamental physical properties of the asphalt concrete specimens such as their gradation and antistripping characteristics were measured in accordance with the KS F 3501 standard. The Marshall stability test was performed to measure the maximum load that could be supported by the specimens. The wheel tracking test was used to evaluate the rutting resistance. To investigate the moisture susceptibility of the specimens, dynamic immersion and tensile strength ratio (TSR) measurements were performed. RESULTS : The test results showed that the asphalt concrete containing TDF ash satisfied all the criteria listed in the Guide for Production and Construction of Asphalt Mixtures (Ministry of Land, Infrastructure and Transport, South Korea). In addition, TDF ash exhibited better performance than that of portland cement. The Marshall stability of the asphalt concrete with TDF ash was higher than 7500 N. Further, its dynamic stability was also higher than that listed in the guide. The results of the dynamic water immersion and the TSR showed that TDF ash shows better moisture resistance than does portland cement. CONCLUSIONS : TDF ash can be effectively recycled by being used as a mineral filler in asphalt, as it exhibits desirable physical properties. The optimal TDF ash content in asphalt concrete based on this study was determined to be 5%. In future works, the research team will compare the characteristics of asphalt concrete as function of the mineral filler types.

Engineering Property of Basalt Fiber as a Reinforcing Fiber (보강 섬유로서 현무암 섬유의 공학적 특성)

  • Choi, Jeong-Il;Jang, Yu-Hyun;Lee, Jae-Won;Lee, Bang-Yeon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.1
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    • pp.84-89
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    • 2015
  • Basalt fiber has many advantages as a reinforcing fiber such as high tensile strength and similar density to concrete. This study investigated the bonding property and the effect of fiber orientation on tensile strength of basalt fiber. Single fiber pullout tests for basalt and polyvinyl alcohol (PVA) fibers were performed to evaluate the bonding property between basalt fiber and mortar. And then tensile strength of basalt, PVA, and polyethylene (PE) fibers according to fiber orientation were measured. From the test results, it was exhibited that the chemical bond, frictional bond, and slip-hardening coefficient of basalt fiber were 1.88, 1.03, 0.24 times of PVA fibers, respectively. And the strength reduction coefficient of basalt fiber was 9 times of PVA fiber and 3 times of PE fiber.

A Study on the Residual Expansibility of Electric Arc Furnace Slag Aggregate (전기로슬래그 골재의 잔류팽창성에 대한 고찰)

  • Yoo, Jung-Hoon;Choi, Jae-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.1
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    • pp.128-135
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    • 2006
  • Steel slag (divided into electric arc furnace slag and convener slag) is being produced by millions of tons per every year in many industrial countries. About 6.5 million tonnes of steel slag is produced yearly as an industrial by-product in Korea. Generally natural aggregate is relatively stable and does not enter into complex chemical reactions with water. Unfortunately, however. steel slag aggregate contains a small amount of free lime. The hydration of free lime makes steel slag aggregate unstable and liable to expand. In this paper, firstly, several aging methods are used in order to decrease the volume expansion of electric arc furnace slag, that is stabilization. The volume expansion of electric arc furnace slag is formulated from the experiment. From the formula, the residual expansibility is predicted with immersion expansion. Compressive strength of concrete with electric arc furnace slag has relation with the residual expansibility in slag aggregate.

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Review: Utilization of Coal Bottom Ash for Concrete and Mortar (총설: 콘크리트 및 모르타르를 위한 석탄 바텀애시의 활용)

  • Kim, Hyeong-Ki
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.333-348
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    • 2020
  • The present review dealt with the state-of-art on utilization of coal bottom ash in cement-based concrete and mortar. Two types of bottom ashes generated from pulverized coal combustion and circulating fluidized-bed combustion systems have been considered. The production process, chemical and physical characteristics of both ashes, and the methodology of utilization in various cement composites are summarized. The effect of bottom ash on various properties of concrete, such as workability, strength, and durability, were reviewed from the literature. In addition, the environmental and economic aspects of utilizing bottom ash in concrete are analyzed to explore the perspectives of bottom ash utilization, and through this, the future of the utilization was considered. The effect of bottom ash on the performance of concrete and mortar was greatly depended on the condition, pretreatment, and processing of the ash. Additional processing such as crushing might contribute to stimulating the utilization in this field. In particular, if economic support is possible in terms of policy, utilization rate is expected to be improved.

Effect of Calcium Sulfate Dihydrate (Gypsum) on the Fundamental Properties of Slag-based Mortar (이수석고가 고로슬래그 미분말 베이스 무시멘트 모르타르의 기초물성에 미치는 영향)

  • Baek, Byung Hoon;Han, Cheon Goo
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.3
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    • pp.252-258
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    • 2014
  • With the vision of 'a low carbon green develop' various industrial by-products were used as replacement of cement, in order to reduce $CO_2$ emissions from the manufacturing process of cement. Blast furnace slag is one of the industrial by-products. Due to the similar chemical compositions to ordinary Portland cement, blast furnace slag have been widely used in concrete with minimum side effects. Hence, in recent years, alkali activated slag-based composites are extensively studied by many researchers. However, the alkali activator can cause a number of problems in practice. Therefore, in this study, an alternative way of activating the slag was investigated. To activate the slag without using an alkali activator, calcium sulfate dihydrate was chosen and mixed with natural recycled fine aggregate. Fundamental properties of the slag-based mortar were tested to evaluate the effect of calcium sulfate dihydrate.

A Feasibility Study on the Application of Ferrosilicon By-Product in Concrete to Replace Silica Fume (콘크리트 내 실리카퓸을 대체하기 위한 페로실리콘 산업부산물의 활용 적절성에 대한 연구)

  • Kim, Hansol;Cho, Won Jung;Ann, Ki Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.413-422
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    • 2019
  • A ferrosilicon (FS) by-product was applied into a cementitious binder in concrete substituting the ordinary Portland cement (OPC). The original material characteristic of FS is very identical to silica fume (SF) regarding chemical composition and physical properties such as specific surface area and specific gravity. Therefore, the FS and SF concrete or mortal of which 10% of the material was replaced to total binder weight were fabricated to evaluate the feasibility of using F S as a binder, and the comparative information of OPC, FS and SF concrete was given. The hydration characteristic of FS concrete was analyzed using X-ray diffraction analysis. The FS concrete was beneficial in compressive strength, resistivity against chloride ingress and reducing porosity considering performance of OPC concrete but the advantage was less than using SF. A possibility of alkali-silica expansion was found out from the FS concrete due to the agglomerated size of the silica particles.

Factors Effecting the Strength & Durability of Geopolymer Binder: A Review (지오폴리머의 강도와 내구성에 영향을 미치는 요인에 대한 고찰)

  • On, Jeong-Kwon;Kim, Gyu-Yong;Sasui, Sasui;Lee, Yae-Chan;Eu, Ha-Min
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.460-468
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    • 2021
  • Owing to the production of conventional concrete/cement, the climate crises is increasing and is mainly caused greenhouse gas (GHG) emission into the environment by industrial process. To reduce the emission of GHG, and excessive consumption of energy, research on geopolymer binder is increasing as it is environmentally friendly compared to the conventional binders such as Portland cement. The research on improving the strength and durability of geopolymer cement becomes one of the trending researches. Generally, the strength and durability of geopolymer binders are improved by altering alkaline solution & its concentration, the precursor materials and curing temperature & time, which significantly influence the chemical composition and microstructure of geopolymer to which the strength and durability of geopolymers relies. This paper included the detailed discussion on the factors affecting the mechanical properties and durability of geopolymer binder and the influence of reaction mechanism on the strength and durability of geopolymer is also discussed in this paper.

Undrained shear strength and microstructural characterization of treated soft soil with recycled materials

  • Al-Bared, Mohammed A.M.;Harahap, Indra S.H.;Marto, Aminaton;Abad, Seyed Vahid Alavi Nezhad Khalil;Ali, Montasir O.A.
    • Geomechanics and Engineering
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    • v.18 no.4
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    • pp.427-437
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    • 2019
  • Waste materials are being produced in huge quantities globally, and the usual practice is to dump them into legal or illegal landfills. Recycled tiles (RT) are being used in soil stabilisation which is considered as sustainable solution to reduce the amount of waste and solve the geotechnical problems. Although the stabilisation of soil using RT improved the soil properties, it could not achieve the standard values required for construction. Thus, this study uses 20% RT together with low cement content (2%) to stabilise soft soil. Series of consolidated undrained triaxial compression tests were conducted on untreated and RT-cement treated samples. Each test was performed at 7, 14, and 28 days curing period and 50, 100, and 200 kPa confining pressures. The results revealed an improvement in the undrained shear strength parameters (cohesion and internal frication angle) of treated specimens compared to the untreated ones. The cohesion and friction angle of the treated samples were increased with the increase in curing time and confining pressure. The peak deviator stress of treated samples increases with the increment of either the effective confining pressures or the curing period. Microstructural and chemical tests were performed on both untreated and RT-cement treated samples, which included field emission scanning electron microscopic (FESEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and energy dispersive X-ray spectrometer (EDX). The results indicated the formation of cementation compounds such as calcium aluminium hydrate (C-A-H) within the treated samples. Consequently, the newly formed compounds were responsible for the improvement observed in the results of the triaxial tests. This research promotes the utilisation of RT to reduce the amount of cement used in soil stabilisation for cleaner planet and sustainable environment.

Quantitative Analysis of Rietveld Method Minerals by Sintering Temperature of Cement Clinkers with Fly Ash (리트벨트법에 의한 석탄재를 적용한 시멘트 클링커의 소성 온도별 광물 정량분석)

  • Yoo, Dong-Woo;Im, Young-Jin;Park, Tae-Gyun;Lee, Chang-Hyun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.514-519
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    • 2020
  • In this study, cement clinkers were sintered at each temperature by replacing some of the clay components of cement clinkers with coal materials. The mineral phase change of sintered cement clinker was quantitatively analyzed by XRD-Rietveld method. As the sintering temperature of cement clinker increased, the amount of belite decreased, the amount of alite increased, and the amount of free-CaO decreased. The form of alite and belite could be distinguished at sintering temperature of 1450℃ or higher. The crystal size was greatly increased at 1500℃ sintering. It was confirmed that the excessive sintering was progressed. Free-CaO decreased with the increase of sintering temperature. At 1450 ℃ or higher, it was less than 0.5%. In 1450℃ or greater, it is determined that enough sintering is included. Therefore, the application of fly ash as a raw material of cement clinker was judged to be usable as a source of chemical components of alumina and iron raw materials.