• Title/Summary/Keyword: chemical vapor curing

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Densification of Cf/SiC Composite Using PIP with Adding of Cyclohexene (Cyclohexene을 첨가한 PIP 공정 사용 Cf/SiC 복합재의 고밀도화)

  • Bae, Jin-Cheol;Cho, Kwang-Youn;Kim, Jun-Il;Im, Dong-Won;Park, Jong-Kyu;Lee, Man-Young;Lee, Jae-Yeol
    • Composites Research
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    • v.26 no.5
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    • pp.322-327
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    • 2013
  • Carbon fiber-reinforced SiC matrix composites have good oxidation resistance and thermal shock resistance. These properties have allowed the composites to be applied to high-temperature structures. In this study, $C_f/SiC$ composites were fabricated via precursor infiltration and pyrolysis (PIP) process, including liquid phase infiltration and chemical vapor curing using cyclohexene. The final $C_f/SiC$ composites, which have gone through the PIP process five times, showed a density of $1.79g/cm^3$, as compared to a density of $0.43g/cm^3$ for pre-densified bare carbon fiber preform. As for the oxidation resistance characteristics, the weight of $C_f/SiC$ composite was maintained at 81% at $1400^{\circ}C$ in air for 6 hours. Chemical vapor curing (CVC) using cyclohexene has shown to be an effective method to achieve high densification, leading to increased oxidation resistance.

Development of Polymer-derived Silicon Carbide Fiber with Low Oxygen Content Using a Cyclohexene Vapor Process (싸이클로헥센 증기 공정에 의한 산소량이 적은 실리콘카바이드 섬유의 개발)

  • Yoon, Byungil;Choi, Woo Chul;Kim, Myeong Ju;Kim, Jae Sung;Kim, Jung il;Kang, Hong Gu
    • Journal of the Korea Institute of Military Science and Technology
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    • v.20 no.5
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    • pp.620-632
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    • 2017
  • A chemical vapor curing method(CVC) was developed to cure polycarbosilane(PCS) fibers by using cyclohexene vapour as a non-oxygen active reactant, instead of air in oder to prepare the silicon carbide(SiC) fiber with low oxygen content. A cross-linked PCS fibers by cyclohexene vapor showed a completely different variation in IR spectra in comparison to the air-cured PCS fiber. CVC method resulted in less than 3 wt% in oxygen content. In this experiment conditions, The average tensile strength and modulus of SiC fiber obtained by CVC had 1995 MPa and 183 GPa respectively, which is higher than that of SiC fiber prepared by air-curing process.

INFECTION CONTROL OF LIGHT CURING UNITS (광중합기 사용 시의 감염 조절)

  • Chang, Hoon-Sang
    • Restorative Dentistry and Endodontics
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    • v.35 no.4
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    • pp.235-237
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    • 2010
  • When curing the composite restorations with light curing units, the light guides are often in direct contact with oral tissues, therefore contamination of light guides is inevitable. Curing light guides fall into the "semicritical" instrument category according to the Centers for Disease Control and Prevention (CDC) and must be heat or vapor-sterilized or at a minimum, these semicritical instruments must be sterilized in a liquid chemical agent. Currently, most common methods of maintaining sterility of the light guides are wiping the guide with a disinfectant, such as glutaraldehyde, after each patient use; using autoclavable guides; using presterilized, single-use plastic guides; and using translucent disposable barriers to cover the guide.

The capacitance characteristics of polyimide thin films by VDP Method (진공 증착 중합법에 의해 제작된 폴리이미드박막의 유전특성)

  • Kim, H.G.;Kim, J.S.;Kim, D.S.;Park, B.K.;Kim, D.Y.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1995.07c
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    • pp.1171-1173
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    • 1995
  • Polyimide thin films were fabricated through the vapor deposition polymerization method, and the structure and capacitance characteristics of them were investigated in detail. It was found that the chemical structure and uniformity of the film could be stabilized with curing. The peaks of $720cm^{-l},\;1380cm^{-1}\;and\;1780cm^{-1}$ show C=O stretch mode, C-N stretch mode and carbonyl stretch mode, and those of polyimide which cured over $300^{\circ}C$ were fixed. It was found that capacitance was changed in proportion to temperature.

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Synthesis and Characterization of Crosslinked Hole Transporting Polymers for Organic Light Emitting Diodes

  • Jang, Do-Young;Lim, Youn-Hee;Kim, Joo-Hyun;Kim, Jang-Joo;Shin, Jung-Hyu;Yoon, Do-Y.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.235-235
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    • 2006
  • Triphenylamine derivatives play important roles as hole transporting materials in organic light emitting devices. However, low molecular weight triphenylamine derivatives show low glass transition temperature and aggregation behavior, and the vapor deposition step of low molecular weight materials is incompatible with large area display fabrication. Conventional polymer PEDOT-PSS HTL has serious drawbacks such as the ITO anode corrosion, poor surface energy match with aromatic EMLs. To solve these problems, we introduced crosslinkable units to triphenylamine-based polymers to make insoluble HTL by thermal curing following spin-coating. Electrochemical and optical properties of the new hole transporting materials were investigated. In addition, the device characteristics obtained with new hole transporting polymers were investigated in details.

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Design and fabrication of the $1.3/1.55\mum$ WDM coupler with the PSG waveguide films (PSG 광도파박막을 이용한 $1.3/1.55\mum$ WDM coupler의 설계 및 제작)

  • 전영윤;김한수;이용태;이형종
    • Korean Journal of Optics and Photonics
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    • v.6 no.4
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    • pp.310-316
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    • 1995
  • We designed the $1.3/1.55\mum$ WDM directional coupler and its coupling length was calculated with the variation of the two waveguide's core separation and other variables by the Fourier transformed scalar wave equation. We deposited the PSG films for optical waveguide by low pressure chemical vapor deposition and fabricated the WDM coupler using the laser lithography and $CF_4/O_2$ reactive ion etching process. A V -groove which was made to support and fix the optical fiber is fabricated on Si substrate by chemical etching. The WDM coupler and the V-groove are connected using UV curing epoxy. We found that propagation mode of each port of WDM coupler is single mode and maximum extinction ratio between two out ports is 6 dB for $1.3.\mum$, and 12 dB for $1.55\mum$. /TEX>.

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DLC Structure Layer for Piezoelectric MEMS Switch (압전 MEMS 스위치 구현을 위한 DLC 구조층에 관한 연구)

  • Hwang, Hyun-Suk;Lee, Kyong-Gun;Yu, Young-Sik;Lim, Yun-Sik;Song, Woo-Chang
    • Journal of Satellite, Information and Communications
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    • v.6 no.1
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    • pp.28-31
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    • 2011
  • In this paper, a new set of structural and sacrificial material that is diamond like carbon (DLC)/photoresist for high performance piezoelectric RF-MEMS switches which are actuated in d33 mode is suggested. To avoid curing problem of photoresist sacrificial layer, DLC structure layer is deposited at room temperature by radio frequency plasma enhanced chemical vapor deposition (RF-PECVD) method. And lead zirconate titanate (PZT) piezoelectric layer is deposited on structure layer directly at room temperature by rf magnetron sputtering system and crystallized by rapid thermal annealing (RTA) equipment. Particular attention is paid to the annealing of PZT film in order to crystallize into perovskite and the variation of mechanical properties of DLC layer as a function of annealing temperature. The DLC layer shows good performance for structure layer in aspect to Young's modulus and hardness. The fabrication becomes much simpler and cheaper with use of a photoresist.

Effect of few-walled carbon nanotube crystallinity on electron field emission property

  • Jeong, Hae-Deuk;Lee, Jong-Hyeok;Lee, Byung-Gap;Jeong, Hee-Jin;Lee, Geon-Woong;Bang, Dae-Suk;Cho, Dong-Hwan;Park, Young-Bin;Jhee, Kwang-Hwan
    • Carbon letters
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    • v.12 no.4
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    • pp.207-217
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    • 2011
  • We discuss the influence of few-walled carbon nanotubes (FWCNTs) treated with nitric acid and/or sulfuric acid on field emission characteristics. FWCNTs/tetraethyl orthosilicate (TEOS) thin film field emitters were fabricated by a spray method using FWCNTs/TEOS sol one-component solution onto indium tin oxide (ITO) glass. After thermal curing, they were found tightly adhered to the ITO glass, and after an activation process by a taping method, numerous FWCNTs were aligned preferentially in the vertical direction. Pristine FWCNT/TEOS-based field emitters revealed higher current density, lower turn-on field, and a higher field enhancement factor than the oxidized FWCNTs-based field emitters. However, the unstable dispersion of pristine FWCNT in TEOS/N,N-dimethylformamide solution was not applicable to the field emitter fabrication using a spray method. Although the field emitter of nitric acid-treated FWCNT showed slightly lower field emission characteristics, this could be improved by the introduction of metal nanoparticles or resistive layer coating. Thus, we can conclude that our spray method using nitric acid-treated FWCNT could be useful for fabricating a field emitter and offers several advantages compared to previously reported techniques such as chemical vapor deposition and screen printing.