• 제목/요약/키워드: chemical treatment

검색결과 7,413건 처리시간 0.032초

Modification of polyethersulfone hollow fiber membrane with different polymeric additives

  • Arahman, Nasrul;Mulyati, Sri;Lubis, Mirna Rahmah;Razi, Fachrul;Takagi, Ryosuke;Matsuyama, Hideto
    • Membrane and Water Treatment
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    • 제7권4호
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    • pp.355-365
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    • 2016
  • The improvement of fouling resistance of porous polymeric membrane is one of the most important targets in membrane preparation for water purification in many process like wastewater treatment. Membranes can be modified by various techniques, including the treatment of polymer material, blending of hydrophilic polymer into polymer solution, and post treatment of fabricated membrane. This research proposed the modifications of morphology and surface property of hydrophobic membrane by blending polyethersulfone (PES) with three polymeric additives, polyvinylpyrrolidone (PVP), Pluronic F127 (Plu), and Tetronic 1307 (Tet). PES hollow fiber membranes were fabricated via dry-wet spinning process by using a spinneret with inner and outer diameter of 0.7 and 1.0 mm, respectively. The morphology changes of PES blend membrane by those additives, as well as the change of performance in ultrafiltration module were comparatively observed. The surface structure of membranes was characterized by atomic force microscopy and Fourier transform infra red spectroscopy. The cross section morphology of PES blend hollow fiber membranes was investigated by scanning electron microscopy. The results showed that all polymeric additives blended in this system affected to improve the performances of PES membrane. The ultra-filtration experiment confirmed that PES-PVP membrane showed the best performance among the three membranes on the basis of filtration stability.

염기처리시간에 따른 지르코니아 현탁액의 분산성과 굴절율 변화 (Change of Dispersibility and Refractive Index of Zirconia Suspension Depending on Alkali Treatment Time)

  • 조충희;함동석;이재흥;류주환;이기윤;조성근
    • 한국재료학회지
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    • 제27권1호
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    • pp.1-7
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    • 2017
  • Zirconia nanoparticles were widely used as filler in order to get high refractive index layer. However, dispersion of nanoparticles is difficult due to their agglomeration in solvent. In this study, the dispersibility of the zirconia suspension is promoted by controlling the steric hindrance and electrostatic interactions through the adsorption of PEI according to alkali treatment time. Also, to induce improved dispersibility on suspension, we changed the dispersion conditions variously and fabricated an ink formulation method for the coating layer. Zirconia suspension was characterized by dynamic light scattering (DLS), Zeta potential measurement, Transmission Electron Microscope (TEM) and FT-IR. We were able to confirm that good dispersion of zirconia suspension by alkali treatment and PEI led to high refractive index.

Industrial wastewater treatment by using of membrane

  • Razavi, Seyed Mohammad Reza;Miri, Taghi;Barati, Abolfazl;Nazemian, Mahboobeh;Sepasi, Mohammad
    • Membrane and Water Treatment
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    • 제6권6호
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    • pp.489-499
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    • 2015
  • In this work, treatment of real hypersaline refinery wastewater by hollow fiber membrane bioreactor coupled with reverse osmosis unit was studied. The ability of HF-MBR and RO developed in this work, was evaluated through examination of the effluent properties under various operating conditions including hydraulic retention time and flux. Arak refinery wastewater was employed as influent of the bioreactor which consists of an immersed ultrafiltation membrane. The HF-MBR/RO was run for 6 months. Average elimination performance of chemical oxygen demand, biological oxygen demand, total suspended solids, volatile suspended solids, total dissolved soild and turbidity were obtained 82%, 89%, 98%, 99%, 99% and 98% respectively. Highly removal performance of oily contaminant, TDS and the complete retention of suspends solids implies good potential of the HF-MBR/RO system for wastewater refinement.

화학적 처리방법에 의한 효모의 세포벽 제거 (The Disruption Yeast Cell Wall by chemical Treatment)

  • 문정혜;김중균
    • 생명과학회지
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    • 제8권2호
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    • pp.197-202
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    • 1998
  • 효모를 먹이로 하는 filter-feeder들의 소화력을 높이고자, algae의 대용물로서 가치가 있는 Kluyveromuces fragilis효모를 화학적 처리방법에 의해 세포벽을 바괴시켰다. 화학적 처리방법의 최적조건은 0.2 M Tris-buffer에 용해시켜 만든 1M 의 $Na_2EDTA$와 0.3 M의 2-mercaptoethanol을 처리한 후 $30{\circ}C$배양기에서 1시간 배양하는 조건에서 얻어졌다. 이때, 약 30%의 protoplast yeast를 실시함으로써, 그 생성률을 약 2배이상 올릴 수 있었다.

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화학 소작술로 치료한 새성 기형 5례 (Treatment of 5 Branchial Cleft Fistulas with Chemical Cauterization)

  • 연제엽;정지성;이동욱
    • 대한기관식도과학회지
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    • 제9권2호
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    • pp.56-59
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    • 2003
  • Branchial cleft fistula is one of the most common congenital neck masses. Most of the branchial cleft fistula patients complain of reucrrent neck infection or abscesses even with appropriate previous treatment. The traditional treatment of these patients was agreed to be a complete surgical removal of whole fistula tract with infection control. However this surgical treatment has risks of injuring important major vessels o. nerves adjacent to the track and difficulties in dealing with previous recurrent infections and scars of previous procedures such as drainage or incomplete surgical excision. Today, obliteration of internal opening with chemical or electrical cauterization has been introduced as a new way of treating branchial anomaly with a less invasive procedure. In this article, we reports 5 cases of branchial anomalies treated with TCA(trichloroacetic acid) chemical cauterization.

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Influence of Surface Treatment of Polyimide Film on Adhesion Enhancement between Polyimide and Metal Films

  • Park, Soo-Jin;Lee, Eun-Jung;Kwon, Soo-Han
    • Bulletin of the Korean Chemical Society
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    • 제28권2호
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    • pp.188-192
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    • 2007
  • In this work, the effects of chemical treatment of polyimide films were studied by FT-IR, X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and contact angles. The adhesion characteristics of the films were also investigated in the peel strengths of polyimide/aluminum films. The increases of surface functional groups of KOH-treated polyimide films were greatly correlated with the polar component of surface free energy. The peel strength of polyimides to metal substrate was also greatly enhanced by increasing the KOH treatment time, which can be attributed to the formation of polar functional groups on the polyimide surfaces, resulting in enhancement of the work of adhesion between polymer film and metal plate.

Heat Treatment Effect on Anti-Tacking Properties of an Zn-stearate/TEA-stearate/Water Emulsion System

  • Qin, Pei;Lee, JinBae;Ha, KiRyong;Ahn, WonSool
    • Elastomers and Composites
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    • 제54권3호
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    • pp.241-246
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    • 2019
  • Carbon master batch (CMB) rubber sheets, which are stored in stacks, are difficult to separate during reuse because of the adhesion between sheets caused by the stacked weight over time. To solve this problem, in the actual rubber product manufacturing process, various anti-tacking agents (solid powder or liquid surfactants) are applied to the sheet surface. In this study, the emulsion samples of zinc (Zn)-stearate/triethanolamine (TEA)-stearate mixtures were prepared using TEA-stearate as a surfactant, prepared using an industrially manufactured Zn-stearate powder, and their basic anti-tacking properties were studied. During the process of manufacturing emulsion, a heat treatment process and an auxiliary surfactant were introduced to improve the dispersion stability. Results showed that the heat-treated sample exhibited a significant improvement in terms of sedimentation, storage stability, and anti-tacking characteristics since the Zn-stearate particles were reduced to a smaller size by the heat-treatment than that of the original Zn-stearate powder.

열플라즈마를 이용한 재료의 표면개질 (Surface modification of materials by thermal plasma)

  • 강성표;이한준;김태희
    • 한국표면공학회지
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    • 제55권6호
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    • pp.308-318
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    • 2022
  • The surface modification and treatment using thermal plasma were reviewed in academic fields. In general, thermal plasma is generated by direct current (DC) and radiofrequency (RF) power sources. Thermal spray coating, a typical commercial process using thermal plasma, is performed by DC thermal plasma, whereas other promising surface modifications have been reported and developed using RF thermal plasma. Beyond the thermal spray coating, physical and chemical surface modifications were attempted widely. Superhydrophobic surface treatment has a very high industrial demand particularly. Besides, RF thermal plasma system for large-area film surface treatment is being developed. Thermal plasma is especially suitable for the surface modification of low-dimensional nanomaterial (e.g., nanotubes) by utilizing high temperature and rapid quenching. It is able to synthesize and modify nanomaterials simultaneously in a one-pot process.

Effect of Chemical Treatment with Citric Acid or Ozonated Water on Microbial Growth and Polyphenoloxidase Activity in Lettuce and Cabbage

  • Youm, Hyoung-Jun;Jang, Jae-Won;Kim, Kyu-Ri;Kim, Hyo--Jjung;Jeon, Eun-Hee;Park, Eun-Kyoung;Kim, Mee-Ree;Song, Kyung-Bin
    • Preventive Nutrition and Food Science
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    • 제9권2호
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    • pp.121-125
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    • 2004
  • Effects of chemical treatment with a citric acid solution or ozonated water on microbiological changes in lettuce and cabbage during storage were studied. Fresh lettuce and cabbage samples were cut into small pieces and treated by soaking in either ozonated water or a citric acid solution. After treatment, populations of total bacteria, yeast and mold, and E. coli were determined. Numbers of microorganisms increased during storage, but ozonated water and citric acid treatments retarded the increase in microbial growth. Among treatments, 1 % citric acid treatment was the most effective in terms of microbiological change and inhibition of polyphenoloxidase (PPO). For lettuce, citric acid treatment decreased the microbial growth overall by 1.5 log CFU/g and inhibited the PPO activity by 80%. These results indicate that chemical-treated lettuce and cabbage retained a better quality than those of the control during storage.

Optimized O2 Plasma Surface Treatment for Uniform Sphere Lithography on Hydrophobic Photoresist Surfaces

  • Yebin Ahn;Jongchul Lee;Hanseok Kwon;Jungbin Hong;Han-Don Um
    • 한국전기전자재료학회논문지
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    • 제37권2호
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    • pp.188-194
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    • 2024
  • This paper introduces an optimized oxygen (O2) plasma surface treatment technique to enhance sphere lithography on hydrophobic photoresist surfaces. The focus is on semiconductor manufacturing, particularly the creation of finer structures beyond the capabilities of traditional photolithography. The key breakthrough is a method that makes substrate surfaces hydrophilic without altering photoresist patterns. This is achieved by meticulously controlling the O2 plasma treatment duration. The result is the consistent formation of nano and microscale patterns across large areas. From an academic perspective, the study deepens our understanding of surface treatments in pattern formation. Industrially, it heralds significant progress in semiconductor and precision manufacturing sectors, promising enhanced capabilities and efficiency.