• Bulletin of the Korean Chemical Society
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• v.24 no.12
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• pp.1775-1780
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• 2003

A continuous flow system has been developed to determine trace Cu(II), Mn(II), Ni(II) and Zn(II) in a large volume of water samples by a solvent sublation technique. The mixed solution of 1,10-phenanthroline(phen) and thiocyanate ion was used as ligands for the formation of their ternary complexes. The continuous system was constructed in this laboratory with a peristaltic pump, a mini shaker, three mixing bottles and a flotation cell by connecting each part with a polyethylene tube. The flotation conditions such as the flow rate of sample solution and the injection rates of ligand, buffer and surfactant solutions have been investigated to obtain the best sublation efficiencies. Each solution flowed into the flotation cell through each polyethylene tube by the peristaltic pumps. The ternary complexes were floated and extracted into MIBK in a flotation cell of 2 L by bubbling a nitrogen gas. The absorbances of extracted analytes in MIBK were directly measured by graphite furnace-AAS. The concentrations of 1,10-phenanthroline and thiocyanate ion were $2.6\;{\times}\;10^{-3}$ M and $2.3\;{\times}\;10^{-2}$ M in the mixed solution, respectively. The pH of sample solution was adjusted to 5.0 with a buffer solution and 1%(m/v) sodium lauryl sulphate solution was added as a surfactant to support the effective flotation of the complexes. The $N_2$ gas was bubbled at 30 mL/min for 90 minutes for 20 L of sample. Reproducible results of less than 10% RSD and recoveries of 80-120% could be obtained in real samples.

• Membrane Journal
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• v.34 no.2
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• pp.114-123
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• 2024

Hydrogen isotopes can be categorized into light hydrogen, heavy hydrogen, and tritium based on the number of neutrons, each of which is used in specific fields. Specifically, deuterium is of interest in the electronics industry, nuclear energy industry, analytical technology industry, pharmaceutical industry, and telecommunications industry. Conventional methods such as cold distillation, thermal cycling absorption processes, Girdler sulfide processes, and water electrolysis have their own advantages and disadvantages, leading to the need for alternative technologies with high separation and energy efficiency. In this context, membrane-based hydrogen isotope separation is one of the promising solutions to reduce energy consumption. In this review, we will present the state-of-the-art in hydrogen isotope separation using membranes and their operating principles. The technology for separating hydrogen isotopes using membranes is just beginning to be conceptualized, and many challenges remain to be overcome. However, if achieved, the economic benefits are expected to be significant. We will discuss future research directions for this purpose.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2136-2141
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• 2007

The Loop Heat Pipe(LHP) system uses capillary forces so as to pump the working fluid from heat acquisition to heat rejecting systems. The performance of the LHP systems depends mainly upon the operating performance of the wick structure. The capillary pressure increases with decreasing the pore size of the wick structure. By the way, the wick structure's permeability decreases with decreasing the pore size and the porosity. To obtain an ideal wick, the wick structure should possess several characteristics such as the small pore size, high porosity and chemical compatibility with working fluid. Sintered metal wicks have been mainly used as the capillary wick structure mounted in LHP because of the fact that the sintered metal wick has some advantages like convenient selection of wick material, smaller pore size and so on as well as high reliability. In this study, sintered metal wicks were developed to meet required several parameters to design the high performance LHP systems for obtaining even more effective cooling technologies.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.4
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• pp.486-492
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• 2004

CMP (Chemical mechanical polishing) is inevitable process to overcome $0.2{\mu}m$ wire thickness in semiconductor industry. In this study, effect of pressure to separate used CMP slurry into solid and liquid for recycle and reuse by ultrafiltration was investigated. Also, water quality after the ultrafiltration such as turbidity and TDS was evaluated. The material of membrane used in the study was PVDF. The used CMP contained 0.5% of solid content and then concentrated up to 18% by weight. The used CMP can not be concentrated higher than 18% because of viscosity and abrasion of pump. The tested feed pressures were 22.1, 29.4 and 36.8 psi. The results have shown that operating at 36.8 psi has advantages on operation time and total flux. The specific flux showed some variation at 1 to 15 of concentration factor but no difference after 15 of concentration factor. Mass balance of solid at initial stage of the operation showed some unbalance because of deposition of solid on the membrane, which was main reason to reduce flux. Turbidity was very stable at lower than 0.2NTU for 22.1 and 36.8 psi of feed pressure.

• Journal of ILASS-Korea
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• v.1 no.3
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• pp.20-28
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• 1996

It is well known that drag reduction in single phase liquid flow is affected by polymer material, molecular weight, polymer concentration, pipe diameter, and flow velocity. Drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, pool and boiling flow, and to present cavitation which occurs in pump impellers. But the research of drag reduction in two phase flow is not sufficient. The purpose of the present work is to evaluate the drag reduction by measuring pressure drop, void fraction whether polymer is added in the horizontal two phase system or not. Experiment has been conducted in a test section with 24 m of the inner diameter and 1,500 mm of the length. The used polymer materials are two kinds of polyacrylamide[PAAM] and co-polymer[A611P]. The polymer concentration was varied with 50, 100 and 200 ppm under the same experimental conditions. Experimental results were shown that the drag is higher reduced by co-polymer rather than polyanylamide.

• Journal of the Korean GEO-environmental Society
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• v.5 no.4
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• pp.5-11
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• 2004

When settled sediments in natural condition for long time were dredged by dredging process, it is natural that bulking change between sediments and dredged soils is affected by chemical injection; coagulant. Dredged sediments used in this study were sampled in the lagoon "Young rang lake" located at the east coast Sokcho city and the bulking change of dredged soils is quantitatively analysed by changing of the clay content and the amount of the flocculant and coagulant. From the experimental results, the bulking of dredged soils increased 1.69 times on the average bulking of settled sediments in natural condition in the case of the optimum chemicals addition.

• The KSFM Journal of Fluid Machinery
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• v.16 no.3
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• pp.32-38
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• 2013

This paper deals with the study on the rotordynamic and experimental analysis of turbine-generator system connected with a magnetic coupling. Although magnetic coupling has been used to torque transmission of chemical processing pump rotating at under 3,600rpm, magnetic coupling in this study is applied to high-speed turbine-generator system using a working fluid that is refrigerant such as ammonia or R-124a. Results of rotordynamic design analysis are as follows. The first, shaft diameter nearest to outer hub of magnetic coupling has a big effect on the $1^{st}$ critical speed of generator rotor. The second, if the $1^{st}$ critical speeds of turbine rotor and generator rotor have enough to separation margin in comparison to rated speed, the $1^{st}$ critical speed of turbine-magnetic coupling-generator rotor train has enough to separation margin regardless of connection stiffness of magnetic coupling. The analytical FE model is guaranteed by impact test on the prototype and condition monitoring such as measurements of vibration and bearing temperature is also performed.

• Journal of Environmental Health Sciences
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• v.32 no.1 s.88
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• pp.60-66
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• 2006

Bisphenol A(BPA) was known as an endocrine disrupting chemical. This study was conducted to assess the effect of BPA, weaker estrogen, on the preneoplastic and neoplastic lesions induced by diethylnitrosamine (DEN). One hundred male F344 rats were divided into four groups which were treated with DEN followed by BPA. To make liver tumor early, we conducted that DEN containing osmotic pump implanted into rat abdominal cavity. Then diet containing BPA were fed to the rats. All animals were sacrificed at 10 and 18 weeks. Body weights were significantly decreased in 4000ppm at 18 weeks. Relative Liver weights of 4000 ppm BPA treated group were significantly increased compared to that of DEN alone group at 18 weeks. There were no significant differences of liver tumor incidences. Sum area of GST-P positive foci and BrdU labeling indices of BPA treated group were not significantly different compared to those of control group. These results suggest that BPA have no effects in preneoplastic and neoplastic lesions on DEN-induced hepatocarcinogenesis.

• Journal of the Korean Applied Science and Technology
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• v.32 no.3
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• pp.497-504
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• 2015

Apart from hydrates, asphaltenes, and inorganic minerals, paraffinic waxes are also very important in flow assurance area. Evaluation of wax gel behavior has been important as off-shore oil recovery becomes more popular in oil production. Restart after either planned or emergency shutdown requires pump operation in high pressure since a waxy oil forms troublesome gel. In this paper, vane method is introduced to determine wax gel strength by determining yield stress. Prediction of gel strength are discussed in qualitative and quantitative manners.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.8 no.2
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• pp.198-207
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• 1996

It is well known that drag reduction in single phase liquid flow is affected by polymer material, molecular weight, polymer concentration, pipe diameter, and flow velocity. Drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, pool and boiling flow, and to present cavitation which occurs in pump impellers. But the research of drag reduction in two phase flow is not sufficient. The purpose of the present work is to evaluate the drag reduction by measuring pressure drop, void fraction, mean liquid velocity, and turbulent intensity whether polymer is added in the horizontal two phase system or not. Experiment has been conducted in a test section with the inner diameter of 24mm and the length of 1,500mm. The polymer materials used are two kinds of polyacrylamide[PAAM] and co-polymer[A611P]. The polymer concentration was varied with 50, 100 and 200 ppm under the same experimental conditions. Experimental results showed that the drag reduction of co-polymer is higher than that of polyacrylamide. Mean liquid velocities increased as polymer was added, and turbulent intensity decreased inversely near the pipe wall.