• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2007.04a
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• pp.87-90
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• 2007

Fuel cell power system was developed for high-endurance unmanned aerial vehicle (UAV). Liquid chemical hydride was selected as a fuel due to its high energy density. Liquid storage of the fuel is an ideal alternative solution of the existing compressed hydrogen storage. The fueling system that extracts hydrogen from chemical hydride consists of catalytic reactor, micro-pump, fuel cartridge, separator, and controller. The fuel cell power system including the fueling system and the fuel cell that generates electricity was integrated into a proposed UAV. The performance verification of the fuel cell power system was performed to use as a power plant of the UAV.

• Journal of Environmental Science International
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• v.7 no.2
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• pp.203-208
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• 1998

A simple on-line measurement system consisting of a conventional peristaltic pump, a HPLC-type heater, and a flow-through spectrophotometer is introduced for the determination of chemical oxygen demand(CODI. The system was configured such that the reaction mixture in the highly concentrated surffuric acrid medium flowing through the PTFE reaction tubing was heated at 150℃ and the absorbance of dichromate was continuously moutored at 445 m. The same addation principle as in the standard procedure was employed akcept the use of CoSO4 as a new effective catalyst. To test the system, potassium hydrogen phthalate was selected as a COD standard material. With suitably optimized reaction condition, the applicable concentration range depends on the concentration of potassium dichromate in the oxidizing reagent. With 2.0×10-3 M and 5.0×10-4M dichromate, the linear dynamic range was observed up to 400 ppm and 100 ppm, respectively. The standards in the Unear ranges were shown to be completely oxidized, which was confirmed with sodium oxalate or Mohr's salt. In all cases, the typical reproduclbility for betweenruns was 2% or less. The proposed measurement system provides the valuable in- formation for the further development of automated analysis system based on the present standard procedure.

• Clean Technology
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• v.7 no.4
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• pp.273-280
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• 2001

An absorber is a major component in the absorption refrigeration systems and its performance greatly affects the overall system performance. In this study, experimental analyses on heat transfer characteristics for removal of absorption heat in ammonia-water bubble mode absorber were performed. Heat transfer coefficients were estimated as the variations of input gas flow rate, solution flow rate, temperature, concentration, absorber diameter and height, and input flow direction. The increase of gas and solution flow rate affects positively in heat transfer. However, the increase of solution temperature and concentration affects negatively. Moreover, under the same Reynolds Numbers, countercurrent flow is superior to cocurrent flow in heat transfer performance. In addition, from these experimental data, empirical correlations which can explain easily the characteristics of heat transfer are derived.

• Journal of the Korean Electrochemical Society
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• v.10 no.4
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• pp.301-305
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• 2007

The performance of polymer electrolyte membrane fuel cell could be decreased due to coolant leaked from connection part. Micro pump was used to put small amount of coolant and investigate the effect on fuel cell. The stoichiometric ratio of hydrogen/air was 1.5/2.0, both side of gas was fully humidified, and current density of $400mA/cm^2$ was used as standard condition in this experiment. Constant current method was used to check performance recovery from coolant effect in 3 cell stack. The performance was recovered when coolant was injected in cathode side. On the other hand, the performance was not recovered when coolant was injected in anode side. Ethylene glycol could be converted to CO in oxidation process and cause poisoning effect on platinum catalyst or be adhered on GDL and cause gas diffusion block effect resulting performance decrease. Water with nitrogen gas was supplied in anode side to check performance recovery. Polarization curve, cyclic voltammetry, electrochemical impedance spectroscopy was used to check performance, and gas chromatography was used to check coolant concentration. Constant current method was not enough in full recovery of performance. However, water injection method was proved good method in full recovery of performance.

• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.841-855
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• 2018

The purpose of this study is to estimate the available potential heat source for heat pump in the district heating supply area in the city. Unused energy potentials were estimated and integrated based on open source based data. In particular, geographical spatial analysis of recoverable heat energy density and heat demand in the heat source area of large retailers and public sauna facilities in the DH network located in the southern part of the metropolitan area (Pyeongtaek-si) was conducted. As a result of the study, the DH network area had a total potential energy of 1,741.7 toe/year for the two heat sources of large retailers and public saunas. It is estimated that 1,006.9 toe/year, which is 57.8% of the total, can be linked to the district heating. The large retailers showed a positive correlation with the floor area and energy use of 0.4937. The recoverable energy intensity was estimated to be $0.0017toe/m^2$ per unit area and $0.0069tCO_2/m^2$ for greenhouse gas emissions. In addition, public saunas were analyzed by comparing the empirical case with the theoretical calculation, and it was estimated that energy conservation estimate of 80% was $0.0315toe/m^2$ per bath area and $0.1183tCO_2/m^2$ for greenhouse gas emissions. The total potential energy amount of this area was positively correlated with the heat demand of apartment house by administrative district, and it was confirmed that it had a relatively high potential energy especially in traffic and commercial center.

• Corrosion Science and Technology
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• v.4 no.2
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• pp.45-50
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• 2005

A 3% NaCl solution of 1 $dm^3$ circulated with 1.5 $dm^3/min$ by a pump for 24 h in the presence of magnetic field. An iron plate immersed in a $100cm^3$ of test solution for 24 h. The rest potential and pH on surface fixed after 3 h. Containing 0~120 ppm of Fe(II) ion, the dissolution in the magnetically treated solution rose comparing with that in the non-magnetically treated solution. The dissolution amount reached to maximum at 50 ppm, then fixed in the non-magnetically treated solution. When Fe(II) ion existed in the magnetically treated solution, dissolution accelerated a little. In the non-magnetic treated solution containing 10~125 ppm of Fe(III) ion existed, the dissolution accelerated. The dissolution amounts reached to maximum at 50 ppm, then decreased from maximum value. In the magnetically treated solution, the dissolution amounts reached to minimum until 50 ppm, then increased from minimum value. The dissolution amounts affected larger with increasing of magnetic flux density. Fe(II), Fe(III) ions and magnetic treatment affected to formation of $Fe(OH)_2$ and/or $Fe_3O_4$ films. The magnetically treated effects memorized about one month.

• Bulletin of the Korean Chemical Society
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• v.33 no.10
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• pp.3298-3302
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• 2012

Although offline enrichment of phosphorylated peptides is widely used, enrichment for phosphopeptides using $TiO_2$ is often performed manually, which is labor-intensive and can lead to irreproducible results. To address the problems associated with offline enrichment and to improve the effectiveness of phosphopeptide detection, we developed an automated online enrichment system for phosphopeptide analysis. A standard protein mixture comprising BSA, fetuin, crystalline, ${\alpha}$-casein and ${\beta}$-casein, and ovalbumin was assessed using our new system. Our multidimensional system has four main parts: a sample pump, a 20-mm $TiO_2$-based column, a weak anion-exchange, and a strong cation-exchange (2:1 WAX:SCX) separation column with LC/MS. Phosphorylated peptides were successfully detected using the $TiO_2$-based online system with little interference from nonphosphorylated peptides. Our results confirmed that our online enrichment system is a simple and efficient method for detecting phosphorylated peptides.

• Bulletin of the Korean Chemical Society
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• v.31 no.7
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• pp.1869-1874
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• 2010

By reducing PVP with $H_2NOH$.HCl and NaOH 2:2:1 mass ratios in aqueous ethanol, poly-N-vinyl pyrrolidone oxime [PVPO] was prepared with 92% yield. Applying the sol-gel concept, orthosilicic acid [OSA] was made by hydrolyzing TEOS with ethanol in 1:0.5 molar ratios using 1 N KOH aqueous solution as a catalyst. The OSA + PVPO + $_L$-Valine ($\alpha$-amino acid) were mixed with pure ethanolic medium in 1:2:2 mass ratios and refluxed at $78^{\circ}C$ and 6 pH for 6.5 h. A white residue of poly-N-vinyl pyrrolidone oximo-L-valyl-siliconate [POVS] appeared after 5 h. The heating of reaction mixture was stopped and the contents were brought to NTP. The residue formation of POVS was intensified with lowering a temperature and completely solidified within 5 h, was filtered using a vacuum pump with Whatmann filter paper no. 42. The residue of POVS was washed several times with 20% aqueous cold ethanolic solution and dried in vacuum chamber at $25^{\circ}C$ for 24 h. The MP was noted above $350^{\circ}C$. Structural and internal morphology were analyzed with IR and $^1H$-NMR, and SEM respectively. A drug loading and transporting ability of the POVS in water and at pH = 5 and 8 was determined chromatographically.

• Applied Science and Convergence Technology
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• v.24 no.4
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• pp.111-116
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• 2015

The graphene oxide (GO) and graphene oxide quantum dots (GOQDs), which have gained research interest as new types of light-emitting materials, were synthesized by the modified Hummers method for oxidation of graphite flake and graphite nanoparticle. The optical properties of GO and GOQDs have been compared by mean of photoluminescence (PL), PL excitation (PLE), UV-vis absorbance, and time-resolved PL. The GO have an absorption peak at 229 nm and shoulder part at 310 nm, whereas the GOQDs show broad absorption with a gradual change up without any absorption peaks. The PL emission of GOQDs and GO showed the green color at 520 nm and the red color at 690 nm, respectively. The red emission of GO showed faster PL decay time than the green emission of GOQDs. In particular, the temporal PL profile of the GO showed redshift from 560 nm to 660 nm after the pump event.

• Journal of Sensor Science and Technology
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• v.23 no.1
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• pp.58-65
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• 2014

We developed a low-cost automatic diagnosis system for water quality in cooling towers to measure the concentrations of key ingredients such as $Ca^{2+}$, $Cl^-$, $PO{_4}^{3-}$, and $Fe^{2+}$. $Ca^{2+}$, and $Cl^-$ are the main factors that cause the generation of scale, corrosion, and sludge in water pipes. $PO{_4}^{3-}$ prevents corrosion, sludge and scale by inhibiting the ions (i.e., $Ca^{2+}$, $Cl^-$) from sticking to the pipes. $Fe^{2+}$ is an indicator of pipe corrosion. The proposed system consists of a microprocessor, a specimen container and heater, a precision pump, relays and valves, LED optical sources, and photo detectors. It automatically collects water samples and carries out pretreatment for determining the concentration of each chemical, and then estimates the concentration of each ion using low-cost LED optical sources and detectors. Experimental results showed that the accuracy of the proposed system is sufficiently high for water quality diagnosis and management of cooling towers, demonstrating the possibility of the proposed system's wide usage in real environments.