• Title/Summary/Keyword: chemical pulp

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A Study on the Nutritive Value of Distributed Roughage in Domestic Market (국내 유통 조사료의 사료가치에 관한 연구)

  • 이형석;이인덕;박덕섭;박연진;김선균;금종수
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.21 no.3
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    • pp.109-114
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    • 2001
  • The object of this experiment was to evaluate nutritive value of roughage which was collected by Woosung Feed Co., Ltd. in Korea in 1999-2000. Nineteen kinds of roughage(l32 samples) were collected by Woosung Feed Co., Ltd. and their chemical composition, ADF, NDF, Ca and P. were analysed. In addition, their DMD, DMI, WV and hay grades were calculated based on analysed values. The CP content of roughage was ranged from 17.35%(alfalfa hay) to 4.00%(Italian ryegrass hay), and ten kinds of roughage under six percentages were observed. The NDF content of roughage was ranged from 47.50%(sugarcane leaf) to 78.84%(orchardgrass hay), and eight kinds of roughage above seventy percentages were observed. The DMD of roughage was ranged from 66.38%(beet pulp) to 50.95%(orchardgrass hay). The WV of roughage was ranged from 60.1 l(orchardgrass hay) to 125.07(sugarcane leaf). In hay grade of roughage, the first grade was assigned to sugarcane leaf only and the third grade and fourth grade were assigned to four kinds of roughage each. Bermudagrass straw received the fifth grade, and the nine kinds of roughage received the poor grades. As shown in the above results, nineteen kinds of roughage were mostly low in crude protein contents and dry matter digestibility, but they were high in fibrous contents. Futhermore, while only one kind of roughage was evaluated as obtaining the first grade, nine kinds of roughage were evaluated as the poor grade. Hence, we know that roughage which was collected in Korea was mostly low in their quality and that there was significant difference in their feed value among those roughage(P<0.05). Therefore, it is necessary to mark the hay quality for purpose of distributive circulation of roughage. (Key words : Roughages, Nutritive value, DMD. RFV. Hay grade)

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A Study on the Actual Status of Heat Transfer oils in Industries for Process Safety Management (공정안전관리 사업장의 열매체유 사용실태에 관한 연구)

  • Lee, Keun Won;Lee, Joo Yeob
    • Journal of the Korean Institute of Gas
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    • v.18 no.5
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    • pp.33-39
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    • 2014
  • Heat transfer oils are used in applications such as chemical plant heating systems, refinery heat exchange systems, certain gas processes, injection molding systems, and pulp and paper processing. These oils are extremely stable and resistant to thermal and oxidative degradation. In the event of a spill or accidental release of heat transfer oils, it can be ignited easily when there is an ignition source. This study discusses the status of safety management through the actual status of the heat transfer oils to prevent fire and explosion accidents in industries for process safety management. The actual status of the heat transfer oils in process system of industries surveyed by a questionnaire developed. The results of this study can be used to help establishment of safety management to prevent fire and explosion accidents, such as the management of heat transfer oils, safe operation and maintenance in heat transfer oil processes.

The Current Status and Recommendation of Work Environment Management in Small Scale Industry with less than 5 Workers (경인지역 일부 5인미만 사업장 근로자의 작업환경실태와 관리대책)

  • Kim, Dea Sic;Roh, Youngman;Kim, Hyun Wook;Jeong, Chun Hwa;You, Ki ho
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.11 no.3
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    • pp.179-189
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    • 2001
  • This study was performed to identify the current status of work environment management and to provide appropriate recommendations for small scale industry with less than 5 workers from September, 2000 to October, 2000 in Seoul city and Gyoung-gi province. The 211 companies were surveyed by checklist included the elements of management of work environment, hazardous chemicals, MSDS, personal protective equipment, and ventilation system. The proportion of metal products manufacturing and printing industries are 25.6 % and 22.3%, respectively. The daily working hours in printing industry is longer than others. The industries that produce potentially hazardous agents, such as noise, dust, metal, organic solvents, radiation and chemical material are pulp, plating, machinery, and printing, respectively. In above industries, only 2.8 % of those recognised and had MSDS. The proportion of companies providing fire extinguishers, safety showers are found to be 13.3 %, 7.1 %, respectively. Only 24.2 % of companies provided personal protective equipment to the workers. The ventilation system was operated in most of companies. But local exhaust ventilation system is provided to 22.3 % of those, also had not been annually inspected. This study showed that the current status of occupational safety and health was not appropriate for workers in small scale industries. It is suggested that annual physical examination have to be performed, MSDS usage must become widespread, and employer and emplyees in small scale industry should be educated for the treatment and storage of hazardous chemicals to improve the occupational safety and health of the working environment. also, regulatory standard has to be applied to local exhaust ventilation system in small scale industry to improve the working condition.

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Studies on the Sequestering Agents to Replace Silicate in Peroxide Bleaching System (과산화수소 보존표백시 Silicate 대체 약품에 관한 연구)

  • Kim, Sung-Kwon;Choung, Sung Wook;Michalowski, R.J.
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.754-757
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    • 1998
  • This study was carried out to investigate the effect of replacing silicate by Versenate PS peroxide stabilizer in a peroxide bleaching system of deinked pulp process. To evaluate the possibility of replacement, optimization of pretreatment and caustic in bleaching for stock treated with silicate and Versenate PS were performed. After these performance, residual peroxide content and brightness were measured. Results obtained form this study were summarized as follows : 1. Caustic concentration in bleaching system treated with silicate was optimized at 2.5~3.0%. 2. Caustic concentration in bleaching system treated with Versenate PS was optimized at 1.0~1.5%. 3. Versenate PS alone did not provide satisfying bleaching effect. 4. Bleaching system treated with Versenate PS had potential to reduce silicate. 5. DTPA pretreatment provided higher bleaching efficiency.

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Effect of Biological and Liquid Hot Water Pretreatments on Ethanol Yield from Mengkuang (Pandanus artocarpus Griff)

  • Yanti, Hikma;Syafii, Wasrin;Wistara, Nyoman J;Febrianto, Fauzi;Kim, Nam Hun
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.2
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    • pp.145-162
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    • 2019
  • This study aimed to increase the sugar and ethanol yield from the mengkuang plant biomass through biological and liquid hot water (LHW) pretreatment and their combination. The results showed that biological pretreatments with 5% inoculum of the fungus Trametes versicolor resulted in the highest alpha cellulose content incubated for 30 days, and 10% inoculum resulted in the lowest lignin content. LHW pretreatment decreased the hemicellulose content of pulps from 10.17% to 9.99%. T. versicolor altered the structure of the mengkuang pulp by degrading the lignin and lignocellulose matrix. The resulting delignification and cellulose degradation facilitate the hydrolysis of cellulose into sugars. The alpha cellulose content after biological-LHW pretreatment was higher (78.99%) compared to LHW-biological pretreatment (76.85%). Scanning electron microscopy analysis showed that biological-LHW combinated treatment degrades the cell wall structures. The ethanol yield for biological-LHW pretreated sample was observed 43.86% (13.11 g/L ethanol by weight of the substrate, which is much higher than that of LHW-biological pretreatment (34.02%; 9.097 g/L). The highest reducing sugar content about 45.10% was observed with a resulting ethanol content of 15.5 g/L at LHW pretreatment temperature of $180^{\circ}C$ for 30 min.

Emission Factors of Chemical Substances and the Abatement Policies in Korea Industries (화학물질 배출량 변동 요인과 배출저감 정책의 조합)

  • Rhee, Hae-Chun
    • Environmental and Resource Economics Review
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    • v.18 no.4
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    • pp.653-693
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    • 2009
  • Using the Korean environmental input output analysis, this paper provides the emission intensities of the chemicals, especially, the toxic and carcinogenic substances, by linking the structure of demand, and the policy mix to abate these substances emissions. Acording to the results, Industries with the highest total emission intensities(TEI) of toxic substances are ranked : Printing and reproduction of recorded media(21), Other transportation equipment(26), Pulp and paper(11), Leather and fur products(9), Fiber yarn and fabrics(7). And the highest TEI of carcinogenic substances are Wood and wooden products(10), Motor vehicles and parts(25), Plastic and rubber products(15), Audio, video and communications equipment(23), etc.. The economic factors of changing these emissions are emission intensities and final demands. The effective combinations of policy instruments to abate these emissions are varied by the industries and substances. For example, Government need to execute the effective TEI management in the Fiber yarn and fabrics(7) sector, and, in furniture(27) sector, the reduction of final demand is more effective.

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Depolymerization of Kraft Lignin over a Ru-Mg-Al-oxide Catalyst (Ru-Mg-Al-oxide 촉매 상에서 크라프트 리그닌의 저분자화 연구)

  • Kim, Han Ung;Limarta, Susan Olivia;Jae, Jungho
    • Clean Technology
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    • v.27 no.2
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    • pp.190-197
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    • 2021
  • Kraft lignin is a by-product of the pulp and paper industry, obtained as a black liquor after the extraction of cellulose from wood through the Kraft pulping process. Right now, kraft lignin is utilized as a low-grade boiler fuel to provide heat and power but can be converted into high-calorific biofuels or high-value chemicals once the efficient catalytic depolymerization process is developed. In this work, the multi-functional catalyst of Ru-Mg-Al-oxide, which contains hydrogenation metals, acid, and base sites for the effective depolymerization of kraft lignin are prepared, and its lignin depolymerization efficiency is evaluated. In order to understand the role of different active sites in the lignin depolymerization, the three different catalysts of MgO, Mg-Al-oxide, and Ru-Mg-Al-oxide were synthesized, and their lignin depolymerization activity was compared in terms of the yield and the average molecular weight of bio-oil, as well as the yield of phenolic monomers contained in the bio-oil. Among the catalysts tested, the Ru-Mg-Al-oxide catalyst exhibited the highest yield of bio-oil and phenolic monomers due to the synergy between active sites. Furthermore, in order to maximize the extent of lignin depolymerization over the Ru-Mg-Al-oxide, the effects of reaction conditions (i.e., temperature, time, and catalyst loading amount) on the lignin depolymerization were investigated. Overall, the highest bio-oil yield of 72% and the 3.5 times higher yield of phenolic monomers than that without a catalyst were successfully achieved at 350 ℃ and 10% catalyst loading after 4 h reaction time.

Chemical Components Composition on Different Parts of Fruit in Schisandra chinensis Baillon (오미자 열매 부위별 이화학적 특성)

  • Lee, Ka Soon;Lee, Bo Hee;Seong, Bong Jae;Kim, Sun Ick;Han, Seung Ho;Kim, Gwan Hou;Park, Saet Byeol;Kim, Hyun Ho;Choi, Taek Yong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.45 no.6
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    • pp.851-858
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    • 2016
  • The effective components of Schisandra chinensis are lignans (schizandrins and gomisins), which have various physiological functionalities such as anti-cancer, anti-inflammatory, and antioxidant activities. This study was carried out to determine the different parts of fruits in Schisandra chinensis to elevate their usefulness. Schisandra chinensis was separated into skin (epicarp), pulp (mesocarp), and seeds, and raw Omija and hot-dried Omija (HDO) were used as control. The most abundant component was nitrogen free extract (6.88~56.70%) followed by crude lipids (1.65~19.04%). The main mineral was K (383.10~2,024.10 mg/100 g), except in seeds where P was the main mineral. The main lignan in all parts of fruit was schizandrin, and the highest content of schizandrin was 9.46 mg/g in dried seeds. Total lignan content was 25.97 mg/g and 14.97 mg/g in dried seeds and HDO, respectively. A total of 17 components of fatty acids in seeds and HDO were detected, of which linoleic acid (72.66~73.78%), oleic acid (14.78~17.39%), palmitic acid (2.88~3.54%), and capric acid (1.70~4.93%) were determined as the major components. Main lignans and fatty acids of Schisandra chinensis fruit contain mainly seeds. Therefore, it is more efficient to use seeds than pulp and extract of fruit itself to use the components of Omija.

The study of nondestructive method for measuring the acidity of the recent record paper in Hanji by using FT-NIR spectroscopy and Integrating sphere (푸리에 변환 근적외선 분광분석기(FT-NIR)와 적분구를 이용한 근대 한지 기록물의 산성도 비파괴 평가방법에 대한 연구)

  • Shin, Yong-Min;Park, Soung-Be;Kim, Chan-Bong;Lee, Seong-Uk;Cho, Won-Bo;Kim, Hyo-Jin
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.10a
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    • pp.255-269
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    • 2011
  • The purpose of study has to analyze with non destructive method for researching the tool that could be measured with the status of record written on Hanji speedily. Because the original record should be destructed for analyzing with previous method in the case of the paper record, it was to develop the tool based on non destructive method for overcoming such limit. The study was used with FT NIR (Fourier transform NIR) for analyzing the Hanji for being written and preserved. The FT NIR spectrometer that of NIR spectrometer has the better performance of precision and accuracy than dispersive NIR spectrometer was used. Also the wavelength of FT-NIR was measured with 12,500 to 4,000 $cm^{-1}$, and the integrating sphere as diffuse reflectance type was used for analyzing Hanji. The moisture and acidity (pH) of chemical factors as quality evaluated factor of Hanji was studied for the correlation of NIR spectrum. And then The NIR spectrum was pretreated for showing the coefficients of optimum correlation. MSC and First derivative of Savitzky - Golay was used as pretreated method, and the coefficients of optimum correlation were shown by PLSR(Partial least square regression). And the coefficients of optimum correlation were calculated by PLSR(Partial least square regression). The correlation coefficients of acidity had 0.92 on NIR spectra without pretreatment. Also the SEP of acidity was 0.24. And then The NIR spectra with pretreatment would have more good correlation coefficients ($R^2=0.98$) and more good SEP(=019) on acidity. Therefore the data of correlation coefficients ($R^2$) and SEP with pretreatment was shown to be superior. And NIR spectra data of first derivative had best linearity on the correlation coefficients ($R^2=0.99$) and also SEP(=0.45) was superior. Therefore the correlation coefficients and SEP of first derivative had better than those of NIR spectra of no pretreatment. As such result, it was possible to evaluate the record status of Hanji speedily with integrated sphere and NIR analyzer as non destructive method.

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Decomposition and Leaching of Bastnasite by Sulfation and Recovery of Cerium Hydroxide from Leached Solution (황산화반응에 의한 불탄산염 희토류광(Bastnasite)의 분해, 침출 및 세륨수산화물의 회수)

  • Yoon, Ho-Sung;Kim, Sung-Don;Kim, Chul-Joo;Kim, Jun-Soo;Han, Choon
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.407-412
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    • 1998
  • This study was carried out to investigate the optimum leaching conditions for the sulfation and water leaching, and separation of cerium from rare earth elements in leached solution by acid-adjusting method. The optimum conditions for the sulfation and water leaching from bastnasite concentrates are that the equivalent ration of sulfuric acid to concentrates is 2.5, calcination temperature and time are $600^{\circ}C$ and 2 hrs respectively, and the pulp density in the water leaching is 9.1%. The yield of rare earth oxide is about 93% at the above condition. The process of recovery of cerium hydroxide from leached solution by acid-adjusting method was carried out as following steps. The first step is the oxidation of the solution at pH 5 by using twice the equivalent of $H_2O_2$ solution as an oxidant. The second step is the precipitation to obtain cerium complex salt and cerium hydroxide after lowering the solution to pH 2. The last step is the oxidation-precipitation by using equivalent of $H_2O_2$ solution. From these results, it was possible to prepare cerium hydroxide with the yield of 60% and the quality of 80%.

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