• Title/Summary/Keyword: chemical protection properties

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Determination of Low-temperature Electrochemical Properties of Selected Cation-exchange Membranes for Cathodic Protection Analysis

  • Ko, Moon-Young;Kwon, Byeong-Min;Hong, Byung-Pyo;Byun, Hong-Sik
    • Korean Membrane Journal
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    • v.10 no.1
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    • pp.8-12
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    • 2008
  • The electrochemical properties of Nafion type membranes as a function of temperature to examine the key factors affecting the cathodic protection process at low temperatures was investigated in this study. Variable temperature experiments for AC impedance, DC resistance were conducted. The resistances of 3 Nafion membranes (N 324, N 450, N MAC) were measured in 30% KOH (aq) for a range of temperatures between $-30^{\circ}C$ and room temperature. Membrane resistance increases exponentially with decreasing temperature. This behaviour is most significant at operational temperatures below $0^{\circ}C$. These membranes are stable under the low temperature and caustic conditions of the heat exchange system, but they place a much higher restriction on the cathodic protection of the stainless heat exchange stack. N 450 has the lowest AC impedence and DC resistance at temperatures below $0^{\circ}C$ and consequently is most suitable membrane of the three, for low temperature applications.

Experimental Study of Bond Properties Using Coated Bars (도막재료에 따른 철근의 부착성능에 관한 실험적 고찰)

  • 김영진
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.211-216
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    • 2003
  • Coated bars are protecting reinforcing bars from corrosion and enhancing durabilities of reinforced concrete structures are tested to evaluate corrosion protection properties. Tests are performed based on the relevant standards of ACI and ASTM, such as chemical resistance, salt water spray, salt crack test and chloride permeability test with the main variable of the coating thickness. Three type materials are tested by Polyethylene, epoxy and bare bar. Test results show good chemical protection property and chloride permeability. Polyethylene coated bar is good coating material than any other materials.

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Novel Punch-through Diode Triggered SCR for Low Voltage ESD Protection Applications

  • Bouangeune, Daoheung;Vilathong, Sengchanh;Cho, Deok-Ho;Shim, Kyu-Hwan;Leem, See-Jong;Choi, Chel-Jong
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.14 no.6
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    • pp.797-801
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    • 2014
  • This research presented the concept of employing the punch-through diode triggered SCRs (PTTSCR) for low voltage ESD applications such as transient voltage suppression (TVS) devices. In order to demonstrate the better electrical properties, various traditional ESD protection devices, including a silicon controlled rectifier (SCR) and Zener diode, were simulated and analyzed by using the TCAD simulation software. The simulation result demonstrates that the novel PTTSCR device has better performance in responding to ESD properties, including DC dynamic resistance and capacitance, compared to SCR and Zener diode. Furthermore, the proposed PTTSCR device has a low reverse leakage current that is below $10^{-12}$ A, a low capacitance of $0.07fF/mm^2$, and low triggering voltage of 8.5 V at $5.6{\times}10^{-5}$ A. The typical properties couple with the holding voltage of 4.8 V, while the novel PTTSCR device is compatible for protecting the low voltage, high speed ESD protection applications. It proves to be good candidates as ultra-low capacitance TVS devices.

Investigation on the Dielectric, Physical and Chemical Properties of Palm Oil and Coconut Oil under Open Thermal Ageing Condition

  • Mohamad, Nur Aqilah;Azis, Norhafiz;Jasni, Jasronita;Kadir, Mohd Zainal Abidin Ab;Yunus, Robiah;Ishak, Mohd Taufiq;Yaakub, Zaini
    • Journal of Electrical Engineering and Technology
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    • v.11 no.3
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    • pp.690-698
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    • 2016
  • In this paper, a study is carried out to investigate the dielectric, physical and chemical properties of Palm Oil (PO) and Coconut Oil (CO) under open thermal ageing condition. The type of PO used in this study is Refined Bleached and Deodorized Palm Oil (RBDPO) Olein. The ageing experiment was carried out at 85 ℃ and 115 ℃ for 1, 3, 5, 7 and 14 days. Several parameters were measured such as AC breakdown voltage, dielectric dissipation factor, relative permittivity, resistivity, viscosity, moisture and acidity throughout the ageing duration. Based on the study, it is found that there are no significant changes on the AC breakdown voltages and relative permittivities for both RBDPO and CO. At ageing temperature of 115℃, there are clear reduction trends of dielectric dissipation factor for CO and resistivities for most of RBDPO. On the other hand, no clear trends are observed for viscosities, moisture and acidities of RBDPO and CO throughout the ageing duration.

Perforrmance Tests of Epoxy-coated Reinforcing Bars : Corrosion Protection Properties (에폭시 도막 철근의 내부식 성능에 관한 실험적 연구)

  • 신영수;홍기섭;최완철
    • Magazine of the Korea Concrete Institute
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    • v.6 no.6
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    • pp.173-179
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    • 1994
  • Epoxy coated bars protecting reinforcing bars from corrosion and enhancing durability of reinforced concrete structures are tested to evaluate corrosion protection properties. Tests are performed based on the relevant sta.ndards of KS and ASTM, such as chenical resistance, salt water spray, salt crock test and chloride ermeability test. with the main varlable of the coating thlckness. Test results show good chemical protection property and chloride permeability. The results of the salt water spray and the salt crock test show that epoxy coating well protects the reinforcing bars from corrosion, cornparing to the biack bars without epoxy coatmg. However, several spots on the coated bars are rusted at the pinholes or un the bars with coating thickness less thar $200{\mu}M$. Special cautions are required i n the process of blast cleanmg when applying the usion-bonded epoxy coating.

High Temperature Properties of Alumino Silicate Fire Protection Materials Using Fly ash (플라이애쉬 활용 Alumino silicate계 내화마감재의 고온특성)

  • Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu;Park, Nam-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.689-692
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    • 2008
  • HSC(High Strength Concrete) have superior properties well as improvement in durability compared with normal strength concrete. In spite of durability of HSC, explosive spalling of concrete is serious problem in structure safety. Therefore, Solving methods are required to control the explosive spalling. The properties of concrete are affected by changes of temperatures. Compressive strength and elasticity modulus were degraded depending on a rise of temperatures. Also, change in microstructure and dehydration of concrete subjected to high temperatures. This paper is concerned with change in microstructure and dehydration of the alumino silicate fire protection materials at high temperatures. The testing methods of fire protection materials in high temperature properties are make use of SEM, TG-DSC and XRD. From the experimental test results, influence of high temperatures on microstructure of alumino-silicate fire protection material was identified, including chemical dehydration of C-S-H and CH. The chemical dehydration of CH under various temperatures from to 450 to 600$^{\circ}$C has been measured using the TG-DSC. However, developed alumino silicate fire protection materials showed good stability in high Temperatures. Thus, the results indicate that it is possible to fireproof panels, fire protection of materials.

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High Performance ESD/Surge Protection Capability of Bidirectional Flip Chip Transient Voltage Suppression Diodes

  • Pharkphoumy, Sakhone;Khurelbaatar, Zagarzusem;Janardhanam, Valliedu;Choi, Chel-Jong;Shim, Kyu-Hwan;Daoheung, Daoheung;Bouangeun, Bouangeun;Choi, Sang-Sik;Cho, Deok-Ho
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.4
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    • pp.196-200
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    • 2016
  • We have developed new electrostatic discharge (ESD) protection devices with, bidirectional flip chip transient voltage suppression. The devices differ in their epitaxial (epi) layers, which were grown by reduced pressure chemical vapor deposition (RPCVD). Their ESD properties were characterized using current-voltage (I-V), capacitance-voltage (C-V) measurement, and ESD analysis, including IEC61000-4-2, surge, and transmission line pulse (TLP) methods. Two BD-FCTVS diodes consisting of either a thick (12 μm) or thin (6 μm), n-Si epi layer showed the same reverse voltage of 8 V, very small reverse current level, and symmetric I-V and C-V curves. The damage found near the corner of the metal pads indicates that the size and shape of the radius governs their failure modes. The BD-FCTVS device made with a thin n- epi layer showed better performance than that made with a thick one in terms of enhancement of the features of ESD robustness, reliability, and protection capability. Therefore, this works confirms that the optimization of device parameters in conjunction with the doping concentration and thickness of epi layers be used to achieve high performance ESD properties.

Study of Cresol-Novolac Epoxy Systems on Fusion Bonded Epoxy Coatings for Pipeline Protection

  • Chung, Chi Wook;Lee, Sang Sun;Chai, Soo Gyum;Lim, Jong Chan
    • Corrosion Science and Technology
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    • v.2 no.4
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    • pp.202-206
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    • 2003
  • Fusion Bonded Epoxy(FBE) systems have been widely used to protect pipelines for over 30 years. Numerous attempts have so far been made to improve the properties of FBE coatings such as chemical resistance, adhesion, water resistance, cathodic disbondment resistance, impact resistance, and flexibility to protect pipelines at a wet and a high temperature condition. But these attempts have not been successful in reducing some weakness, for instance, in pipeline operating at high temperature due to poor hot water resistance and cathodic protection. The purpose here is to build a basis for getting better corrosion resistance of FBE systems. Cresol-novolac epoxy coating systems were studied compared to bisphenol A type epoxy systems. After the immersion of the film in water at a high temperature for a long period, good adhesion to metal substrate and excellent cathodic disbond resistance were observed in the cresol-novolac epoxy resin systems. It is well known that the adhesion of organic coatings to metal substrate might be decreased due to the disruption of a chemical bond across the film and metal interface induced by water molecules. A high crosslinking density might decrease water permeability and improve cathodic disbonding protection in the coatings. Other factors are studied to understand anti-corrosion mechanism of Cresol-novolac epoxy coatings. In addition, the water absorption rate and the effect of cure temperature on the adhesion and cathodic disbonding resistance ofthe films were studied in different epoxy coatings and the effect of substrate was evaluated. The results of field application are proved that the Cresol-novolac epoxy coating system developed recently is one of the most suitable coatings for protection of pipelines.

Development of Hybrid Sol-Gel Coating to Prevent Corrosion of Magnesium Alloys (마그네슘 합금의 방청을 위한 하이브리드 졸-겔 코팅제의 개발)

  • Lee, Dong Uk;Kim, Young Hoon;Moon, Myung Jun
    • Corrosion Science and Technology
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    • v.17 no.1
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    • pp.30-36
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    • 2018
  • The high rate of corrosion of magnesium alloys makes it limited for industrial applications. Therefore, surface treatment is required to enhance their corrosion resistance. In our study, a chemical conversion coating for protecting the corrosion of the magnesium alloy, AZ31B, was prepared by using a phosphate-permanganate solution. The chemical conversion coating had a limited protection ability due to defects arising from cracks and pores in the coating layer. The sol-gel coating was prepared by using trimethoxymethylsilane (MTMS) and 3-glycidoxypropyltrimethoxysilane (GPTMS) as precursors, and aluminum acetyl acetonate as a ring opening agent. The corrosion protection properties of sol-gel and conversion coatings in 0.35wt% NaCl solution were measured by the electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization test. The EIS results indicated that the resistance of the chemical conversion coating with the sol-gel coating was significantly improved through the sol-gel sealed phosphate-permanganate conversion coating. The results of the potentiodynamic polarization test revealed that the sol-gel coating decreased the corrosion current density ($I_{corr}$). The SEM image showed that the sol-gel coating sealed conversion coating and improved corrosion protection.

Properties of Paint Protection Film Containing Poly(urea-urethane)-based Self-Recovery Coating Layer (Poly(urea-urethane) 자기복원 코팅층을 가진 도장 보호필름 물성 연구)

  • Minseok Song
    • Journal of Adhesion and Interface
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    • v.24 no.2
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    • pp.69-75
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    • 2023
  • Recently, the application of paint protection films (PPFs) for automobiles having a self-recovery coating layer has been grown up. In this study, we report the evaluation results on the basic physical properties of a poly(vinyl chloride)- based PPF containing poly(urea-urethane) hybrid self-recovery coating layer. Depending on the main chemical composition and the thickness of poly(urea-urethane)-based coating layer for PPF, the self-recovery performance by an optical microscope and the stain resistance through color difference value are measured. To improve the surface properties and show its easy-cleaning effect against the polluted things, silicone-modified polyacrylate is introduced to the self-recovery coating composition. The contact angle of water on the coated surface is confirmed to show its hydrophobic surface. Finally, accelerated weathering test of paint protection film with poly(urea-urethane) hybrid coating layer is performed to check the possibility of discoloration and deformation due to long-term exposure on harsh condition.