• 제목/요약/키워드: chemical oxide

검색결과 3,456건 처리시간 0.037초

Chemical Modification of Wood with Alkylene Oxides, Vinylpirrolidinone and Furans:Effects on Dimensional Stabilization

  • Guevara, R.;Moslemi, A.A.
    • Journal of the Korean Wood Science and Technology
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    • 제10권4호
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    • pp.38-52
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    • 1982
  • The effect of propylene oxide, butylene oxide, furan resin, and vinylpyrrolidinone in controlling wood dimensional stability have been examined. Wood in the green or ovendry condition was treated with various chemical treatments using a vacuum-pressure procedure, and treated specimens were tested for tangential sweelling, moisture gain, and changes in sorption hysteresis. Results' indicate that propylene oxide, and butylene oxide enhanced with the crosslin king agent trimethylol propane trimethacrylate and applied to ovendry wood were the most efficient chemical treatments in controlling tangential sweeling caused by liquid water or water vapor, and in reducing water vapor adsorption. The sorption behavior of treated wood as depicted by the ratios of sorption was "very favorable" in most instances. In the particular case of furan resin treatments, ratios of sorption were improved from 25 to 100 percent as compared to those of untreated wood.

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에어로졸 반응기에서 산화아연 입자의 응집 성장 (The growth of zinc oxide particles by coagulation in aerosol reactor)

  • 이종호;송신애;박승빈
    • 한국입자에어로졸학회지
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    • 제4권2호
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    • pp.69-75
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    • 2008
  • Nanosize ZnO particles were prepared by oxidation of zinc vapor and the particle growth was modeled by a coagulation model by assuming that the characteristic time for reaction was much shorter than coagulation time and residence time (${\tau}_{reaction}{\ll}{\tau}_{coagulation}{\ll}{\tau}_{residence}$). Experimental measurement of zinc oxide particles diameter was consistent with the predicted result from the coagulation model. For practical purpose of predicting zinc oxide size in areosol reactor, the constant kernel solution is concluded to be sufficient, Uniqueness of nano-scale property of zinc oxide was confirmed by the higher photocatalytic activity of zinc oxide than nanosize titania particles.

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Cu Oxide와 Silicon Tip 사이의 나노트라이볼러지 작용 (Nanotribological Behavior of Cu Oxide and Silicon Tip)

  • 김태곤;김인권;박진구
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.364-365
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    • 2005
  • This paper report nanotribological behavior between Si tip and Cu wafer surfaces which was treated various concentration of $H_2O_2$. This experimental approach has proven atomic level insight into Cu CMP. It has been used to study interfacial friction and adhesion force between Si tip and Cu wafer surfaces in air by atomic force microscopy (AFM). Adhesion force of Cu surfaces which was pre-cleaned in diluted HF solution was lager than Cu oxide surfaces. Adhesion force of Cu oxide surface was saturated around 7 nN. Slope of normal force vs lateral signal was increased as increasing concentration of $H_2O_2$ and it was saturated around 24. Friction force of Cu oxide was lager than Cu.

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Graphene Oxide-based Direct Measurement of DNase I Activity with Single Stranded DNA

  • Gang, Jongback
    • Bulletin of the Korean Chemical Society
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    • 제35권9호
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    • pp.2749-2752
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    • 2014
  • Recent studies have shown that single-stranded DNA adsorbed onto graphene oxide is protected from DNase I cleavage. However, double-stranded DNA bound to graphene oxide and could be digested by DNase I. To elucidate whether single-stranded DNA is protect from DNase I in the presence of graphene oxide, this study conducted DNase I digestion using single-stranded DNA and single-stranded DNA containing the duplex region in the presence of graphene oxide. Addition of DNase I resulted in restoration of the fluorescence emission that had been quenched when DNA was adsorbed to graphene oxide. It indicates that DNase I cleaved the adsorbed single-stranded DNA onto graphene oxide, which was sufficient for the detection of DNase I activity.

ReaxFF and Density Functional Theory Studies of Structural and Electronic Properties of Copper Oxide Clusters

  • Baek, Joo-Hyeon;Bae, Gyun-Tack
    • 대한화학회지
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    • 제64권2호
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    • pp.61-66
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    • 2020
  • In this study, we investigate the structural and electronic properties of copper oxide clusters, CunOn (n = 9 - 15). To find the lowest energy structures of copper oxide clusters, we use ReaxFF and density functional theory calculations. We calculate many initial copper oxide clusters using ReaxFF quickly. Then we calculate the lowest energy structures of copper oxide clusters using B3LYP/LANL2DZ model chemistry. We examine the atomization energies per atom, average bond angles, Bader charges, ionization potentials, and electronic affinities of copper oxide clusters. In addition, the second difference in energies is investigated for relative energies of copper oxide clusters.

Propylene Oxide와 Cyclohexene Oxide와 CO2의 삼원 공중합체의 합성 (Synthesis of the Terpolymers of Propylene Oxide, Cyclohexene Oxide, and Carbon dioxide)

  • 이윤배;성언경;박희경
    • 한국산학기술학회논문지
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    • 제12권2호
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    • pp.1027-1031
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    • 2011
  • 온실가스 가운데 하나인 이산화탄소를 활용하기 위한 연구의 일환으로 프로필렌옥사이드와 사이클로헥신옥사이드, 그리고 이산화탄소를 원료로 하고 zinc glutarate를 촉매로 하여 여러가지 조성의 삼원공중합체가 합성되었다. 이고분자는 FT-IR, $^1H$-NMR, DSC을 이용하여 분석되었고, 이들의 유리전이온도는 poly(alkylene carbonate)의 두성분의 질량비와 일정한 관계를 가지며 Fox식과 비교적 일치함을 확인하였다.

Electrochemical Fabrication of CdS/CO Nanowrite Arrays in Porous Aluminum Oxide Templates

  • Yoon, Cheon-Ho;Suh, Jung-Sang
    • Bulletin of the Korean Chemical Society
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    • 제23권11호
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    • pp.1519-1523
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    • 2002
  • A procedure for preparing semiconductor/metal nanowire arrays is described, based on a template method which entails electrochemical deposition into nanometer-wide parallel pores of anodic aluminum oxide films on aluminum. Aligned CdS/Co heterostructured nanowires have been prepared by ac electrodeposition in the anodic aluminum oxide templates. By varying the preparation conditions, a variety of CdS/Co nanowire arrays were fabricated, whose dimensional properties could be adjusted.

화학적 박리법으로 제조된 산화그래핀 분말의 건조방법에 따른 물성 비교 (Effect of Drying Methods on the Production of Graphenes Oxide Powder Prepared by Chemical Exfoliation)

  • 노상균;노경훈;엄성훈;허승현;임형미
    • 한국재료학회지
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    • 제23권10호
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    • pp.592-598
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    • 2013
  • Graphene oxide powders prepared by two different drying processes, freeze drying and spray drying, were studied to compare the effect of the drying method on the physical properties of graphene oxide powder. The graphene oxide dispersion was prepared from graphite by chemical delamination with the aid of sulfuric acid and permanganic acid, and the dispersion was further washed and re-dispersed in a mixed solvent of water and isopropyl alcohol. A freeze drying method can feasibly minimize damage to the sample, but it requires a long process time. In contrast, spray drying is able to remove a solvent in a relatively short time, though this process requires exposure to a high temperature for a rapid evaporation of the solvent. The powders prepared by freeze drying and spray drying were characterized and compared by Raman spectroscopy, X-ray diffraction, field-emission scanning electron microscopy, transmission electron microscopy, and by an elemental analysis. The graphene oxide powders showed similar chemical compositions; however, the morphologies of the powders differed in that the graphene oxide prepared by spray drying had a winkled morphology and a higher apparent density compared to the powder prepared by freeze drying. The graphene oxide powders were reduced at $900^{\circ}C$ in an atmosphere of $N_2$. The effect of the drying process on the properties of the reduced graphene oxide was examined by SEM, TEM and Raman spectroscopy.