• 공업화학
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• 제30권1호
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• pp.43-48
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• 2019

본 연구는 매체순환연소공정용 산소전달입자로서 $CaSnO_3$ 입자의 타당성을 조사하기 위해 수행하였다. $CaSnO_3$은 페롭스카이트 구조를 가지고, 반복되는 환원-산화 반응 후에도 구조적안정성을 보였다. 산소전달량은 환원 반응 시 결정구조 변화를 통해 계산된 이론 수치와 거의 동일한 15.4 wt%를 가졌다. 10번의 환원과 산화 반응 후에, 산소전달량과 산소전달속도는 작동 온도에서 일정하게 유지되었다. 결론적으로, $CaSnO_3$ 입자는 CLC의 산소 운반체로서 좋은 대체 물질이 될 수 있다고 판단하였다.

• Journal of Ceramic Processing Research
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• 제19권5호
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• pp.372-377
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• 2018

MgO or gadolinium-doped ceria (GDC, $Ce_{0.9}Gd_{0.1}O_{2-{\delta}}$) was added as a promoter to improve the oxygen transfer kinetics of $MgMnO_3$ oxygen carrier material for chemical looping combustion. Neither MgO nor GDC reacted with $MgMnO_3$, even at the high temperature of $1100^{\circ}C$. The average oxygen transfer capacities of $MgMnO_3$, 5 wt% $MgO-MgMnO_3$, and 5 wt% $GDC-MgMnO_3$ were 8.74, 8.35, and 8.13 wt%, respectively. Although the addition of MgO or GDC decreased the oxygen transfer capacity, no further degradation was observed during their use in 5 redox cycles. The addition of GDC significantly improved the conversion rate for the reduction reaction of $MgMnO_3$ compared to the use of MgO due to an increase in the surface adsorption process of $CH_4$ via oxygen vacancies formed on the surface of GDC. On the other hand, the conversion rates for the oxidation reaction followed the order 5 wt% $GDC-MgMnO_3$ > 5 wt% $MgO-MgMnO_3$ >> $MgMnO_3$ due to morphological change. MgO or GDC particles suppressed the grain growth of the reduced $MgMnO_3$ (i.e., (Mg,Mn)O) and increased the specific surface area, thereby increasing the number of active reaction sites.

• 한국수소및신에너지학회논문집
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• 제33권4호
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• pp.419-429
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• 2022

Effects of operating variables on temperature profile and performance of 3 MWth chemical looping combustion system were estimated by mass and energy balance analysis based on configuration and dimension of the system determined by design tool. Air reactor gas velocity, fuel reactor gas velocity, solid circulation rate, and solid input percentage to fluidized bed heat exchanger were considered as representative operating variables. Overall heat output and oxygen concentration in the exhaust gas from the air reactor increased but temperature difference decreased as air reactor gas velocity increased. Overall heat output, required solid circulation rate, and temperature difference increased as fuel reactor gas velocity increased. However, overall heat output and temperature difference decreased as solid circulation rate increased. Temperature difference decreased as solid circulation rate through the fluidized bed heat exchanger increased. Effect of each variables on temperature profile and performance can be determined and these results will be helpful to determine operating range of each variable.

• 에너지공학
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• 제12권4호
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• pp.289-301
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• 2003

매체순환식 가스연소기의 개발을 위해 산화반응기와 환원반응기가 연계된 2탑 가압순환유동층 조건의 50kWth 매체순환식 가스연소기에 대해 물질수지와 에너지수지를 통한 개념설계를 수행하였다. 매체순환식 가스연소기의 물질수지를 통해 산화반응기는 상승관 형태의 고속유동층 조건으로, 환원반응기는 기포유동층 조건으로 반응기 형태를 결정하였다. 물질수지와 에너지수지에 의해 계산된 층내 고체량, 고체순환량 및 반응기 크기는 장치제작 및 실제조업에 적당한 범위의 값을 나타내었으며 산소공여입자의 반응속도는 만족할 만한 수준에 도달하는 것으로 확인되었다. 본 연구의 개념설계 결과에 의하면 매체순환식 가스연소기의 조업조건은 상용 순환유동층의 조업조건과 유사하였으며 실제공정에 적용하기에 무리가 없는 것으로 사료되었다. 본 연구에서 개발된 설계 tool을 이용하여 시스템의 용량, 조업압력, 산소공여입자 중의금속산화물의 함량, 수증기 주입량, 기체유속 및 고체층 높이 등의 변화에 따른 설계 값의 변화를 해석하였으며 이를 통해 조업조건 변화에 따른 시스템의 성능변화를 예측할 수 있었다.

• Korean Chemical Engineering Research
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• 제46권6호
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• pp.1057-1062
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• 2008

기존 2탑 유동층 공정의 단점을 극복하기 위해 두 개의 기포유동층, 고체분사노즐, 상승관 및 고체재순환관으로 구성된 신개념 2탑 유동층 공정을 적용한 3 kW 매체순환식 가스연소기를 개발하였다. 본 연구에서는 3 kW급 매체순환식 가스연소기에서 고체순환속도에 미치는 고체분사노즐 유속, 유동화속도, 고체층 높이, 고체유입구의 단면적, 층 온도 등의 영향을 고찰하였다. 고체순환속도는 고체층 높이가 증가하고 고체유입구의 단면적이 증가할수록 증가하는 경향을 나타내었으며 유동화속도와 온도의 영향은 크지 않았다. 장기연속운전 가능성을 검토하기 위해 50시간까지 고체순환 장기연속운전을 실증하였다. 두 유동층과 고체재순환관의 압력강하 값이 안정적으로 유지되어 고체순환이 원활하고 안정적으로 유지되는 것을 확인하였다.

• 한국수소및신에너지학회논문집
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• 제29권1호
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• pp.90-96
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• 2018

Reaction characteristics and kinetics of a oxygen carrier (OCN717-R1SU) for chemical looping combustion (CLC) have been investigated using TGA by changing gas concentration (10-30 vol.% $CH_4$) and reaction temperature ($825-900^{\circ}C$). Reaction rate of OCN717-R1SU increased as temperature increased and it was found that reaction is delayed at the initial reaction regime. Johnson-Mehl-Avrami (JMA) model was adopted to explain the reaction phenomenon. The activation energy (E) determined by JMA model in reduction reaction of OCN717-R1SU is $151.7{\pm}2.03kJ/mol$ and pre-exponential factor and JMA exponent were also obtained. The parameters calculated in this study will be applied in design of the reactor and operation conditions for CLC process.

• 한국수소및신에너지학회논문집
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• 제20권3호
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• pp.245-255
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• 2009

Effect of CO$_2$ concentration on reduction reactivity of oxygen carrier particles for chemical-looping combustor were investigated. Four particles, NiO/bentonite, OCN601-650, OCN702-1100, OCN702-1250, were used as oxygen carrier particles and two kinds of gases (CH$_4$, 5%, N$_2$ balance and CH$_4$ 5%, CO$_2$ balance) were used as reactants for reduction. For all oxygen carrier particles, higher maximum conversion, reduction rate, oxygen transfer capacity, and oxygen transfer rate were achieved when we used N$_2$ balance gas. OCN601-650 particle showed higher oxygen transfer rate for all gases than other particles, and therefore we selected OCN601-650 particle as the best candidate. For all particles, lower carbon depositions were observed when we used CO$_2$ balance gas.

• 한국수소및신에너지학회논문집
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• 제28권5호
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• pp.554-560
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• 2017

Reduction reactivity of new oxygen carriers for chemical looping combustion system were investigated using $CH_4$ as a reduction gas in a bubbling fluidized bed reactor and compared with that of former SDN70 oxygen carrier. New oxygen carriers showed good reduction reactivity at different $CH_4$ concentration. N018-R2 particle represented better reactivity than SDN70 at high $CH_4$ concentration. N018-R2 particle showed higher fuel conversion and $CO_2$ selectivity than those of SDN70 particle within the temperature range of $750-900^{\circ}C$. Moreover, attrition loss of N018-R2 particle was almost same with that of SDN70 particle. Consequently, we could select N018-R2 particle as the best oxygen carrier.

• 한국수소및신에너지학회논문집
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• 제27권2호
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• pp.211-219
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• 2016

To develop an ash separator for the solid fuel chemical looping combustion system, effects of operating variables such as solid injection nozzle velocity, diameter of solid injection nozzle, gap between solid injection line and vent line, vent line inside diameter, and solid intake height on solid separation rate and solid separation efficiency were measured and discussed using heavy and coarse particle and light and fine particles mixture as bed material in an acrylic fluidized bed apparatus. The solid separation rate increased as the solid injection nozzle velocity and the diameter of solid injection nozzle increased. However, the solid separation rate decreased as the gap between solid injection line and vent line, the vent line inside diameter, and the solid intake height increased. The solid separation efficiency was in inverse proportion to the solid separation rate. In this study, we could get high solid separation rate up to 2.39 kg/hr with 91.6% of solid separation efficiency.

• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 2004년도 춘계 학술발표회 논문집
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• pp.347-352
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• 2004