• Title/Summary/Keyword: chemical image

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Some Applications of SAR Imagery to the Coastal Waters of Korea (한국 주변 해역에서의 SAR 영상 응용예)

  • 김태림
    • Korean Journal of Remote Sensing
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    • v.15 no.1
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    • pp.61-71
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    • 1999
  • Several physical phenomena on the sea surface are analyzed from SAR images of South Sea areas, Korea. Strong wave patterns propagating in southerly direction are seen in ERS-1 SAR image on October 11, 1994, and a wave directional spectrum is calculated from this image using the SAR modulation transfer function. RADARSAT SAR image of August 15, 1996 reveals internal waves in northern coastal waters of Cheju Island. Analysis indicates that the internal waves may have been generated by the tidal currents traveling over the shallow bottom of the stratified water in the summer during the tidal changeovers fro ebb to flood and shows patterns of trains of solitons. RADARSAT SAR image taken 3 days after the oil spill accident near Goeje Isalnd on April 3, 1997 detects distinct oil slicks from the accident area but also shows slicks near the coast caused by wind sheltering of coastal mountains and chemical-biological activities.

Practical Research for Quantitative Expression of Leakage Through Optical Gas Image (광학가스이미지에서 유출량의 정량표시 실험적 연구)

  • Park, Suri;Han, Sang-wook;Kim, Byung-jick
    • Journal of the Korean Institute of Gas
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    • v.21 no.5
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    • pp.16-26
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    • 2017
  • In chemical industry plants, the raw material, intermediate and final products can leak from unstable joints of flanges and valves as well as cracks of storage tanks. From the safety and economic standpoints, it is very important to understand whether leaks or not and leakage rate. The OGI(optical gas image) technique can tell gas leakages, but cannot give the leakage rate. Some special OGI devices can show the kind of gas in different color concentration in different darkness. Therefore the research on quantification of OGI is necessary. In this research, we have developed the practical method to quantify OGI of methane leakage. To estimate 3-dimensional gas leakages distribution from 2-dimensional OGI, the Monte Carlo Probability technique was applied. First the number of points in the area of width(2.54 cm) and length(2.54 cm) in OGI was counted. Total no of each experiment was compared with the measured flow rate. The correlation average between total points and measured flow rate was found to be 0.980. Reversely we estimated the leakage rate of OGI by use of the correlation table. The results showed good agreement between the estimation value and the measured value.

Fabrication of Polymer Thin Films on Solid Substrates (고체 기판에 고분자 박막의 고정화)

  • Kim, Min Sung;Jeong, Yeon Tae
    • Applied Chemistry for Engineering
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    • v.21 no.2
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    • pp.200-204
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    • 2010
  • Surface properties are important for determining the functions and uses of materials. So modification of materials with polymer thin films has emerged as an important method to control the physical and chemical properties of the surface layer. We report a simple and effective method to photochemically attach thin polymeric layers to solid surface without chemical derivatization of the substrate and/or the polymer. The system is based on a photoreactive poly(4-vinylpyridine) (P4VP) thin film which is formed on the $SiO_{2}$ surface via spin coating. This substrate is then covered with another polymer film that is reacted with the benzyl radical moieties by UV irradiation. As a result of photochemical reaction, a thin layer of the later polymer is covalently bound to the surface of P4VP. Unbounded polymer is removed by sonication. The thickness of the attached film is a function of the irradiation time and the molecular weight of the polymer. Spatially defined polymer thin films can be fabricated by way of photolithography.

Dimerization of Aquooxomolybdenum (V) ion in Acid Media (I). Dehydrogenation of Bridging Hydroxide of $Mo_2O_4(OH)_{2(aq)}^{4+}$ (산성용액에서 아쿠오옥소몰리브덴 (V) 이온의 이합화 반응 (I). 이합체 착물의 두다리인 히드록소의 탈수소화 반응)

  • Chang-Su Kim;Chann-Woo Kim;Chang-Yong Kwon;Moon-Pyoung Yi
    • Journal of the Korean Chemical Society
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    • v.29 no.5
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    • pp.510-515
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    • 1985
  • Color of $MoO_{(aq)}^{3+}$ in concentrated methanesulfonic acid (∼10M) changes dark green due to the formation of $Mo_2O_2(OH)_{2(aq)}^{4+}$ dimer. This color is similar to that shown by addition of water to that shown by addition of water to green $MoO_{(aq)}^{3+}$ solution in 15-16M methanesulfonic acid. The molar extinction coefficient of monomer in 15M methanesulfonic acid is about 20 at 415nm. Rate constants are independent on the aquomolybdenum (V) and hydrogen ion concentration under the condition of this experment. Bridging hydroxides of $Mo_2O_2(OH)_{2(aq)}^{4+}$ are dehydrogenated at the less concentration of ∼6 M for HPTS and ∼10M for $CH_3SO_3H$. The structure of both the yl-oxygens and the bridging oxygens of final product is identified to (*image)unit.

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Adsorption Characteristics of PES-BSA Affinity Membrane Prepared by Electrospinning (전기방사로 제조된 PES-BSA 친화막의 흡착특성)

  • Byun, Hong-Sik;Hong, Byung-Pyo
    • Membrane Journal
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    • v.18 no.4
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    • pp.306-316
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    • 2008
  • The adsorption characteristics of L-tryptophan of PES-BSA affinity membranes prepared by using electro-spinning were investigated. It was found that the fiber diameters could be controlled by the comparisons of fiber diameters prepared by various spinning conditions through FESEM and Image Analyzer. Darcy's permeability constants, mechanical properties and hydrophobic properties were enhanced since micro-fibers increased by increasing the composition ratio of HFB and BSA. The elution capacity of L-tryptophan in borate-DMSO buffer solution was higher than that in tris-HCl buffer solution, while the elution capacity of A 7906 type BSA was higher than A 8022 type BSA. This is due to the characteristics of BSA type, i. e. higher purity and uniform molecular weight and better pH stability of A 7906 type BSA than those of A 8022 type BSA.

Recombinant Human Epidermal Growth Factor (rhEGF)-loaded Solid Lipid Nanoparticles: Fabrication and Their Skin Accumulation Properties for Topical rhEGF Delivery

  • Hwang, Hee-Jin;Han, Sunhui;Jeon, Sangok;Seo, Joeun;Oh, Dongho;Cho, Seong-Wan;Choi, Young Wook;Lee, Sangkil
    • Bulletin of the Korean Chemical Society
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    • v.35 no.8
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    • pp.2290-2294
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    • 2014
  • For the present study, rhEGF was encapsulated into solid lipid nanoparticles (SLNs). The SLNs were prepared by the $W_1/O/W_2$ double emulsification method combined with the high pressure homogenization method and the physical properties such as particle size, zeta-potential and encapsulation efficiency were measured. The overall particle morphology of SLNs was investigated using a transmission electron microscopy (TEM). The percutaneous skin permeation and accumulation property of rhEGF was evaluated using Franz diffusion cell system along with confocal laser scanning microscopy (CLSM). The mean particle size of rhEGF-loaded SLNs was $104.00{\pm}3.99nm$ and the zeta-potential value was in the range of -$36.99{\pm}0.54mV$, providing a good colloidal stability. The TEM image revealed a spherical shape of SLNs about 100 nm and the encapsulation efficiency was $18.47{\pm}0.22%$. The skin accumulation of rhEGF was enhanced by SLNs. CLSM image analysis provided that the rhEGF rat skin accumulation is facilitated by an entry of SLNs through the pores of skin.

Investigation of the Scanning Tunneling Microscopy Image, the Stacking Pattern and the Bias-voltage Dependent Structural Instability of 2,2'-Bipyridine Molecules Adsorbed on Au(111) in Terms of Electronic Structure Calculations

  • Suh, Young-Sun;Park, Sung-Soo;Kang, Jin-Hee;Hwang, Yong-Gyoo;Jung, D.;Kim, Dong-Hee;Lee, Kee-Hag;Whangbo, M.-H.
    • Bulletin of the Korean Chemical Society
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    • v.29 no.2
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    • pp.438-444
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    • 2008
  • A self-assembled monolayer of 2,2'-bipyridine (22BPY) molecules on Au(111) underwent a structural phase transition when the polarity of a bias voltage was switched in scanning tunneling microscopy (STM) experiments. The nature of two bright spots representing each 22BPY molecule on Au(111) in the high-resolution STM images was identified by calculating the partial density plots for a monolayer of 22BPY molecules adsorbed on Au(111) using tight-binding electronic structure calculations. The stacking pattern of the chains of 22BPY molecules on Au(111) was explained by examining the intermolecular interactions between the 22BPY molecules based on first principles electronic structure calculations for a 22BPY dimer, (22BPY)2. The structural instability of the 22BPY molecule arrangement caused by a change in the bias voltage switch was investigated by estimating the adsorbate-surface interaction energy using a point-charge approximation for Au(111).

Preparation of Gold Coated Liposomes for CT Contrast Medium (CT 조영을 위한 금 코팅 리포솜의 제조)

  • Wee, Tae In;Jeon, Ye Won;Cho, Young Jae;Cho, Sung Keun;Ha, Jeung;Lee, Jeong Won;Cho, Sun Hang;Han, Hee Dong;Shin, Byung Cheol
    • Journal of the Korean Chemical Society
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    • v.57 no.5
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    • pp.634-639
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    • 2013
  • The use of medical imaging has been increased for diagnosis of cancer or vessel disease. Among the medical imaging, computed tomography (CT) is one of the popular methods, however, which should need administration of contrast medium. Therefore, we developed gold coated liposomes (GCL) as a contrast medium. To coat gold on the liposomal surface, positive charged liposomes was prepared and then negative $Au^-$ can coat on the liposomal surface by electronic interaction. The size of GCL was $154.8{\pm}9.2$ nm and surface charge was $27{\pm}3.2$ mV, respectively. The morphology of GCL was confirmed by electron microscopy (SEM) and transmission electron microscopy (TEM). The coating efficiency of gold was 18%. Chemical procedure for gold coating on liposomal surface was not toxic for cell cytotoxicity by MTT assay. Finally, we demonstrated attractive CT image for GCL. Taken together, the GCL would be useful for various vessel related disease as a contrast medium.

An Enzyme-linked Immunosorbent Assay Strip Sensor for the Detection of Legionella Pneumophila (Legionella Pneumophila 검출을 위한 효소면역측정 스트립 센서)

  • Kim, Young-Kee;Park, Sojung
    • Applied Chemistry for Engineering
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    • v.25 no.5
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    • pp.544-547
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    • 2014
  • In this study, an enzyme-linked immunosorbent assay (ELISA) and immuno-chromatographic technique were combined to fabricate immuno-strip sensors for the detection of Legionella pneumophila. The immuno-strip sensor was manufactured with four different membranes. A nitrocellulose membrane was used to immobilize capture antibody and generate signals due to the high affinity to antibodies, and glass fiber membranes were used as a conjugate release pad and a sample application pad. A cellulose membrane was used as an absorption pad to induce sample flow by the capillarity. Colorimetric signals produced by sandwich immuno-reaction and enzyme reaction could be analyzed qualitatively and quantitatively within 30 min. Under the given experimental conditions, sensor signals with L. pneumophila samples were observed qualitatively by naked eyes and measured quantitatively in a range of $1.3{\times}10^3-1.3{\times}10^6CFU/mL$ with a digital camera and home-made image analysis software.

Cleanliness Test by Spray-Type Cleaning Agent for Electronic and Semiconductor Equipment (전자·반도체용 스프레이 분사형 세정제에 대한 청정도 평가)

  • Heo, Hyo Jung;Row, Kyung Ho
    • Korean Chemical Engineering Research
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    • v.47 no.6
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    • pp.688-694
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    • 2009
  • A spray-type cleaning agent in utilizing dust-remover on PCB was chosen to study the cleanliness test and efficiency. In order to choose alternative environmental-friendly cleaning agents, it is important that the systematic selection procedures should be introduced and applied through the evaluation of their cleaning ability, environmental characteristics, and economical factors, and that the objective and effective evaluation methods of cleanliness should be established for the industry. A novel cleaning evaluation method with scanning electron microscopy/energy-dispersive X-ray analysis of surface observation evaluation method and an infra-red thermography camera(THERMOVISION A20 model) was studied in this work. The sound card(CT-2770 model) cut by $2{\times}2cm$ size was used as a part, and before and after the spray cleaning, the cleanliness was observed by the image analyzer of SEM and further the removal efficiency of dust was quantitatively evaluated by the component analysis of EDX. For the parts of P4TE model motherboard and IPC-A-36 PCB plate, before and after the spray cleaning, temperature differences were measured and compared at room temperature and 50 oven temperature by an infra-red thermography camera in the contaminants of dust and iron powder.