• Title/Summary/Keyword: chemical factors

Search Result 2,760, Processing Time 0.049 seconds

Microwave Mediated Production of FAME from Waste Cooking Oil : Optimization of Process Parameters by RSM (마이크로웨이브를 이용한 폐식용유로부터 FAME의 제조 : RSM에 의한 공정변수 최적화)

  • Hong, In Kwon
    • Applied Chemistry for Engineering
    • /
    • v.31 no.2
    • /
    • pp.172-178
    • /
    • 2020
  • In this study, the optimization of the biodiesel production process from waste oil using microwave with response surface methodology (RSM) was conducted. The microwave irradiation time and power in addition to the alcohol/oil mole ratio were chosen as process parameters. Also the fatty acid methyl ester (FAME) content (over 96.5%) and kinematic viscosity (1.9~5.5 cSt) were selected as response values. From basic experiments, the range of quantitative factors were set as following; 4~6 min, 400~600 W, and 7~9 for the microwave irradiation time and power, and alcohol/oil molar ratio, respectively. The optimum conditions for the methanolysis were 5.0~5.1 min, 481.3~525.5 W, 7.9~8.4, and 2.0 or 3.0 mg KOH/g for the microwave irradiation time and power, methanol/oil molar ratio, and each acid value, respectively. The FAME content and kinematic viscosity were predicted as 97.49~96.34% and 4.01~4.12 cSt, respectively, under the condition above. Under the optimum experimental conditions, the results showed that the FAME content and kinematic viscosity of 97.82~96.42% and 4.07~4.16 cSt, respectively were measured and the mean error rates were 0.22% and 0.98%, respectively.

A Study on Numerical Analysis for Internal PEMFC Cooling of Power Pack for UPS (UPS 파워 팩 내부 연료전지의 냉각특성에 대한 수치 해석)

  • Song, Jun-Seok;Kim, Byeong-Heon
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.18 no.4
    • /
    • pp.527-535
    • /
    • 2017
  • Heat management is one of the most critical issues in Polymer Electrolyte Membrane Fuel Cells (PEMFCs) installed inside the fuel cell power pack of a fuel cell battery hybrid UPS. If the heat generated by the chemical reaction in the fuel cell is not rapidly removed, the durability and performance of the fuel cell may be affected, which may shorten its lifetime. Therefore, the objective of this study is to select and propose a proper cooling method for the fuel cells used in the fuel cell power pack of a UPS. In order to find the most appropriate cooling method, the various design factors affecting the cooling performance were studied. The numerical analysis was performed by a commercial program, i.e., COMSOL Multiphysics. Firstly, the surface temperature of the 1 kW class fuel cell stack with the cooling fans placed at the top was compared with the one with the cooling fans placed at the bottom. Various rotation speeds of the cooling fan, viz. 2,500, 3,000, 3,500, and 4,000 RPM, were tested to determine the proper cooling fan speed. In addition, the influence of the inhaled air flow rate was investigated by changing the porous area of the grille, which is the entrance of the air flowing from the outside to the inside of the power pack. As a result, it was found that for the operating conditions of the 1 kW class PEMFC to be acceptable, the cooling fan was required to have a minimum rotating speed of 3500 RPM to maintain the fuel cell surface temperature within an acceptable range. The results of this study can be effectively applied to the development of thermal management technology for the fuel cells inside the fuel cell power pack of a UPS.

Bone-Preserving Decompression Procedures Have a Minor Effect on the Flexibility of the Lumbar Spine

  • Costa, Francesco;Ottardi, Claudia;Volkheimer, David;Ortolina, Alessandro;Bassani, Tito;Wilke, Hans-Joachim;Galbusera, Fabio
    • Journal of Korean Neurosurgical Society
    • /
    • v.61 no.6
    • /
    • pp.680-688
    • /
    • 2018
  • Objective : To mitigate the risk of iatrogenic instability, new posterior decompression techniques able to preserve musculoskeletal structures have been introduced but never extensively investigated from a biomechanical point of view. This study was aimed to investigate the impact on spinal flexibility caused by a unilateral laminotomy for bilateral decompression, in comparison to the intact condition and a laminectomy with preservation of a bony bridge at the vertebral arch. Secondary aims were to investigate the biomechanical effects of two-level decompression and the quantification of the restoration of stability after posterior fixation. Methods : A universal spine tester was used to measure the flexibility of six L2-L5 human spine specimens in intact conditions and after decompression and fixation surgeries. An incremental damage protocol was applied : 1) unilateral laminotomy for bilateral decompression at L3-L4; 2) on three specimens, the unilateral laminotomy was extended to L4-L5; 3) laminectomy with preservation of a bony bridge at the vertebral arch (at L3-L4 in the first three specimens and at L4-L5 in the rest); and 4) pedicle screw fixation at the involved levels. Results : Unilateral laminotomy for bilateral decompression had a minor influence on the lumbar flexibility. In flexion-extension, the median range of motion increased by 8%. The bone-preserving laminectomy did not cause major changes in spinal flexibility. Two-level decompression approximately induced a twofold destabilization compared to the single-level treatment, with greater effect on the lower level. Posterior fixation reduced the flexibility to values lower than in the intact conditions in all cases. Conclusion : In vitro testing of human lumbar specimens revealed that unilateral laminotomy for bilateral decompression and bone-preserving laminectomy induced a minor destabilization at the operated level. In absence of other pathological factors (e.g., clinical instability, spondylolisthesis), both techniques appear to be safe from a biomechanical point of view.

Phytophthora Blight of Pepper and Genetic Control of the Disease (고추 역병과 그 유전적 방제)

  • Kim, Byung-Soo
    • Current Research on Agriculture and Life Sciences
    • /
    • v.32 no.3
    • /
    • pp.111-117
    • /
    • 2014
  • Phytophthora blight caused by Phytophthora capsici Leonian is a dangerous disease threatening pepper growers worldwide. The efficacy of chemical control is generally low as the pathogen is soil-borne and rapidly spread by zoospores during the rainy season. Thus, based on the demand for resistant varieties, various good resistant sources, such as CM334, AC2258, and PI201234, have been reported and their inheritance of resistance studied by many different authorities. However, the mode of inheritance remains unclear, as 1 or 2 independent dominant genes, 3 genes, or multiple genes have all been reported as responsible for resistance. Recently, QTL mappings of the gene factors for resistance have been reported, and molecular markers for resistance used in breeding programs. With the release of many resistant commercial hybrid cultivars, differentiation of pathotypes of the pathogen is attracting interest among breeders and plant pathologists. Various authorities have already classified the pathogen strains into different races according to the inter-action between resistant host plants, including the source of resistance, such as CM334 and PI201234, and resistant commercial varieties and P. capsici isolates. However, no standard differential host sets have yet been established, so the results are good only for the pathogen strains used in the experiments. Thus, for breeding varieties with durable resist-ance, it is important to introduce resistance from different sources and use diverse local pathogen strains collected in the target area for distribution in a breeding program.

Selection of Culture Media Applied to Gymnocalycium mihanovichii 'Huhong' for Export (수출용 접목 선인장 '후홍'의 재배에 적합한 대체 배지 선발)

  • Kim, Yoo Sun;Ryu, Byung Yeol;Heo, Young Min;Cho, Yun Sung
    • FLOWER RESEARCH JOURNAL
    • /
    • v.18 no.4
    • /
    • pp.225-230
    • /
    • 2010
  • This study was conducted to increase the income of cactus farm by selecting cheaper and better media than the peat moss using for Gymnocalycium mihanovichii 'Huhong'. We cultivated Gymnocalycium mihanovichii 'Huhong' on 10 kinds of media (peat moss, culture medium, coco peat, sphagnum moss, hydro ton, hydro cray, hydro bal, hugato, vermiculite, perlite) and analyzed media's physiochemical factors and growth, betacyanin. The results were as follows: In case of media's physical condition planting Gymnocalycium mihanovichii 'Huhong' after 90 days, an approximate value with peat moss is culture medium and coco peat. Also, coco peat has no change in chemical media. The rate of growth and development is high in Coco peat while overall culture medium and coco peat was seen lower growth. The level of betacyanin in subirrigation is higher than overhead irrigation. Meanwhile, hugato among 10 kinds of media has high value in both of overhead irrigation and bottom watering. Thus, culture medium and coco peat is proper for alternation of peat moss due to similar value with peat moss. And coco peat is favorable to media, growth condition, pigment.

A Study on the Repair of Fatigue Damage at Large Cast Iron structure using Cold Joint Method (냉간체결방법을 이용한 대형 주철 구조물의 피로손상수리방법에 대한 연구)

  • Lee, Sung-Riong;Lee, Dong Jun;Cho, Seok Swoo
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.20 no.10
    • /
    • pp.140-148
    • /
    • 2019
  • Large cast iron structures are used in casings and pipes in shipsand chemical plants. Broken parts in the casings and pipescan result in failures even when stresses are below the yield strength of the part's materials. Fatigue failure of a large cast iron structure is inevitable due to the design constraints and low reliability of the material strength. A small structure can be repaired by welding, but a large structure cannot because it cannot be preheated slowly and uniformly. This study shows that a large structure can be repaired by a cold joint method using a crack repair screw. Large cast iron structures were manufactured by GC 300, and their design stress is below 3.5 MPa. The tensile strength on notched specimens repaired by crack repair screws was 8.2 MPa. Therefore, the safety factors of structures repaired by crack repair screws have a value above 2.3 and are considered to be high values.

Effects of Food Quality and Temperature on life History Traits of Moina macrocopa Reared in Laboratory

  • Yoon, Seong Myeong;Lee, Jung Sup;Jung, Suk Hun;Baek, Kyoung Hwan;Chang, Cheon Young;Lee, Sung Kyu;Kim, Won
    • Animal cells and systems
    • /
    • v.4 no.4
    • /
    • pp.329-336
    • /
    • 2000
  • Life table experiments were performed in order to examine the effects of food quality on Moina macrocopa fed with four kinds of algal foods, Botryococcus sp., Scenedesmus subspicatus, Selenastrum capricornutum, and Chlorella sp., at $20^{\circ}C$ . The temperature effects on M. macrocopa were also assessed, feeding Chlorella at $17^{\circ}C$,$20^{\circ}C$,$25^{\circ}C$, and a combination of $28^{\circ}C$ (light) and $25^{\circ}C$ (dark). The cartilaginous Botryococcs cells were Inappropriate food for Moina. Among the foods tested, Chlorella was the food of the best quality in all accounts of life history traits. Moina grown on Chlorella showed higher net reproductive rate ($R_0$), longer mean and maximum longevities, earlier mean age at maturity, longer mean carapace length at maturity, larger mean clutch size, and shorter mean time interval between clutch productions than those grown on Selenastrum and Scenedesmus. An optimal temperature for Moina was $20^{\circ}C$ . When Moina were grown on Chlorella at $20^{\circ}C$, they showed the highest r, the highest $R_0$, the shortest T, the longest mean longevity, the earliest mean age at maturity, the longest mean carapace length at maturity, and the largest mean clutch size. The results of life table experiments showed that the individual and population growth patterns were much more affected by low temperature $17^{\circ}C$, than by high temperature ($\geq 20^{\circ}C$). In the optimal condition, the r value was very high, 5.1 in $d^{-1}$. In conclusion, the food quality and the temperature are the most important factors to govern the size and continuity of Moina population, by which the individual growth rates and reproductivity of members in the population can be controlled to survive in their environment such as small and temporary water bodies in nature.

  • PDF

Soil Survey and Land Evaluation for Establishing the Demonstration Farm in the Oudomxai Province, Laos (농업투자용 시범농장 조성 후보지 선정을 위한 라오스 우돔싸이주(州)의 토양조사 및 토지특성 평가)

  • Park, Moo-Eon;Park, Ki-Wook;Cho, Il-Hwan
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.43 no.6
    • /
    • pp.1024-1034
    • /
    • 2010
  • In order to select the demonstration farm site for agricultural investment by Korean fund, 14 sites were investigated by soil morphological characteristics and were evaluated by rating method in the Oudomxai province of Laos. Land evaluation was carried out by using eight factors, such as site accessibility, soil erosion susceptibility, easiness of farm mechanization, irrigation water obtainability, suitability of soil physical and chemical properties for crop growth, cost for establishment of farm foundation and land obtainability. In addition, one site to have been highly ranked was soil physico-chemically studied for farm planning. The site of heavy clayey soil has hydraulic conductivity of 26.27~40.64 cm $day^{-1}$, organic content of lower than 14 g $kg^{-1}$, available phosphate content of lower than 3 mg $kg^{-1}$, exchangeable cations of lower than 0.38, 11 and 3.1 cmolc $kg^{-1}$ in K, Ca and Mg, respectively. Major important limitations for establishment of demonstration farm were concluded as heavy soil-texture, high soil erodibility, low organic matter and phosphate contents, and insufficient irrigation water in the Oudomxai province of Laos.

Quality Change of Packaged Pears in PLA Tray for Export due to Vibration Stress by Simulated Transport Environment (PLA 트레이 포장 수출용 배의 수송 모의환경 진동 스트레스에 의한 품질변화)

  • Choi, Dong-Soo;Son, Jae-Yong;Kim, Jin-Se;Kim, Yong-Hoon;Park, Chun-Wan;Hwang, Sung-Wook;Park, Jong-Min;Jung, Hyun-Mo
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
    • /
    • v.27 no.2
    • /
    • pp.109-114
    • /
    • 2021
  • The characteristics of vibrational stress (shock and vibration) during transport and the possibility of damage to the packaged pears by functional PLA tray were investigated. And this study was conducted to analyze how environmental conditions by simulated transport environment affect quality factors such as weight loss (%) and soluble solid content (SSC, %), and firmness (bioyield strength, kPa) of packaged pears by PLA tray and Expanded PET foam pad (Group 1), EPE cushion cup pad and net (Group 2) for exporting. Pears with or without vibration stress were stored for 30 days at low temperatures (5 ± 0.8℃, 80 ± 5% relative humidity). There was the statistically significant difference (p ≤ 0.05) between pears with and without vibration stress for weight loss, soluble solid content, and firmness (bioyield strength) after 30 days storage. Vibration stress accelerated pear quality deterioration during storage, resulting in increased weight loss, soluble solids content, and reduced hardness. The firmness (bioyield strength) and weight changes of pears with PLA trays were smaller than those of conventional packaging box systems. It was determined that the firmness of agricultural products was a quality factor closely related to the storage period and that PLA could be applied.

Relationship between Polyphenol Oxidase Activity and Color of White Salted Noodles Prepared from Korean Wheat Cultivar (국산밀의 폴리페놀 산화 효소 활성과 국수 색과의 관계)

  • Kang, Chon-Sik;Kim, Kyeong-Hoon;Park, Jong-Chul;Kim, Kyung-Ho;Park, Kwang-Geun;Cheong, Young-Keun;Yoon, Sung-Joong;Park, Chul Soo
    • Korean Journal of Breeding Science
    • /
    • v.43 no.5
    • /
    • pp.470-478
    • /
    • 2011
  • This study was carried out to find major factors affecting the color of wheat flour and noodles and develop simple analysis method for the breeding of wheat cultivars suitable for producing flour and noodles with bright color which are preferred by consumers. Customers who buy white noodle or flour prefer bright-colored food to dark-colored products. We evaluated grains of 25 Korean wheat cultivars for chemical composition, grain characteristics, and color change of noodle dough sheets during storage. Polyphenol oxidase (PPO) has been connected to discoloration of white salted noodles and other wheat end products. The grain PPO activity was reduced as the 1,000 grain weight, grain ash content, and protein content decreased. The grain PPO activity was positively correlated with the total polyphenol content ($r=0.609^{**}$) and iron content ($r=0.655^{**}$). Lightness, protein, polyphenol and Fe content of flour were positively correlated with PPO activity of grain. Cultivars with higher grain PPO activity showed darker noodles and were more easily discolored during the storage (from 2 hr to 48 hr). Thus, PPO activity can be used as a selection index in a breeding program for wheat cultivars of bright-colored flour.