• 제목/요약/키워드: chemical defense

검색결과 395건 처리시간 0.022초

온도와 질량유속이 불화중수소 화학 레이저 성능에 미치는 영향 (Effects of Temperature and Mass Flux on Deuterium Fluoride Chemical Laser Performance)

  • 박병서;이정환
    • 한국군사과학기술학회지
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    • 제7권4호
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    • pp.100-106
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    • 2004
  • The effects of adiabatic flame temperature and mass flux on deuterium fluoride(DF) chemical laser performance were investigated. The power flux and specific power, which are important parameters containing the information of scaling effects of laser device magnitude, and chemical efficiency were selected as a judging parameter of DF laser performance. For the specific power, it was decreased by the increase of power flux of DF laser. Higher the adiabatic flame temperature of atomic fluorine generator, higher the chemical efficiency of DF laser was changed. It seems that the mass flux effect on the chemical efficiency is not remarkable.

Roles of Nickel Layer Deposition on Surface and Electric Properties of Carbon Fibers

  • Kim, Byung-Joo;Choi, Woong-Ki;Bae, Kyong-Min;Moon, Cheol-Whan;Song, Heung-Sub;Park, Jong-Kyoo;Lee, Jae-Yeol;Im, Seung-Soon;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • 제32권5호
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    • pp.1630-1634
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    • 2011
  • Electroless plating of metallic nickel on carbon fiber surfaces was carried out to control specific electric resistivity of the fibers, and the effects of the nickel content and coating thickness on the electric properties were studied. The structural and surface properties of the carbon fibers were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The specific resistivity of the fibers was measured using a four-point probe testing method. From the XPS results, the oxygen and Ni atomic ratio of the fibers was greatly enhanced as the plating time increased. Additionally, it was observed that the specific electric resistivity decreased considerably in the presence of metallic nickel particles and with the formation of nickel layers on carbon fibers.

수동형 FTIR 원격화학 탐지기를 이용한 SF6 오염운의 실시간 탐지 (Passive Remote Chemical Detection of SF6 Clouds in the Atmosphere by FTIR)

  • 정유진;박병황;김주현
    • 한국군사과학기술학회지
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    • 제17권1호
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    • pp.8-14
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    • 2014
  • Brightness temperature spectra acquired from FTIR(Fourier Transform Infrared)-SCADS (Standoff Chemical Agent Detection System) could be available for detection and identification of the chemical agents and pollutants from different background. IR spectrum range of 770 to 1350 $cm^{-1}$ is corresponding to "atmospheric window". A 2-dimensional(2D) brightness temperature spectrum was drawn from combining each data point through automatic continuous scanning of FTIR along with altitude and azimuth. At higher altitude, temperature of background was decreased but scattering effect of atmospheric gases was increased. Increase in temperature difference between background and blackbody in SCADS at higher temperature causes to increases in peak intensity of $SF_6$. This approach shows us a possibility that 2D visual information is acquired from scanning data with a single FTIR-SCADS.

150 kJ Compact Capacitive Pulsed Power System for an Electrothermal Chemical Gun

  • Lee, Byung-Ha;Kim, Jin-Sung;Kim, Seong-Ho;Lee, Young-Hyun;Yang, Kyung-Seung
    • Journal of Electrical Engineering and Technology
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    • 제7권6호
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    • pp.971-976
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    • 2012
  • A 150 kJ compact capacitive pulsed power system (CCPPS) capable of delivering electrical energy into an electrothermal chemical (ETC) gun on a vehicle has been studied. The CCPPS provides pulsed electrical energy into a capillary plasma injector which generates plasma of tens of thousands $^{\circ}K$ in temperature and has a nonlinear resistance depending on the current. The design requirements of the CCPPS are as follows: the maximum power of 250 MW, the pulse width of about 0.6 ms, the volume of no more than 0.5 cubic meter, the efficiency of energy transfer over 80 % and the repetition rate of 4~5 times per minute. The constructed CCPPS is composed of four 37.5 kJ capacitor bank modules in parallel to make a trapezoid pulse shape and to satisfy the design requirements. Each module is designed to achieve high reliability, safety, efficiency and energy density to endure severe operating conditions. The results of the performance test on the CCPPS using a 120 mm ETC gun are described.

전기화학적 환원법에 의한 $Hg_{l-x}Cd_xTe$ 재료의 표면특성 개선에 관한 연구 (A Study of Improvement the Surface Properties of $Hg_{l-x}Cd_xTe$ material by using Electro-Chemical Reduction)

  • 이상돈;김봉흡;강형부;최경구;정용택;박희숙;김흥국
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 C
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    • pp.1280-1282
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    • 1994
  • The method of passivation for protecting the $Hg_{l-x}Cd_xTe$ surface is important device fabrication process, because the surface components are highly reactive leading to its chemical and electrical instability. Especially, the material of which composition is x=0.2 or 0.3, is narrow bandgap semiconductor and used as detector of infrared radiation. The device performance of narrow bandgap semiconductors are largely governed by the properties of the semiconductor surface. The electro-chemical processing of $Hg_{l-x}Cd_xTe$ allows rigorous control of the surface chemistry and provides an in-situ monitor of surface reaction. So electro-chemical reduction at specific potential can selectively eliminate the undesirable species on the surface and manipulated to reproducibly attain the desired stoichiometry. This method shows to assess the quality or chemically treated $Hg_{l-x}Cd_xTe$ good surface.

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Preparation and Characterization of Highly Conductive Nickel-coated Glass Fibers

  • Kim, Byung-Joo;Choi, Woong-Ki;Song, Heung-Sub;Park, Jong-Kyoo;Lee, Jae-Yeol;Park, Soo-Jin
    • Carbon letters
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    • 제9권2호
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    • pp.105-107
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    • 2008
  • In this work, we employed an electroless nickel plating on glass fibers in order to enhance the electric conductivity of fibers. And the effects of metal content and plating time on the conductivity of fibers were investigated. From the results, island-like metal clusters were found on the fiber surfaces in initial plating state, and perfect metallic layers were observed after 10 min of plating time. The thickness of metallic layers on fiber surfaces was proportion to plating time, and the electric conductivity showed similar trends. The nickel cluster sizes on fibers decreased with increasing plating time, indicating that surface energetics of the fibers could become more homogeneous and make well-packed metallic layers, resulting in the high conductivity of Ni/glass fibers.

Optimization of Neural Networks Architecture for Impact Sensitivity of Energetic Molecules

  • Cho, Soo-Gyeong;No, Kyoung-Tai;Goh, Eun-Mee;Kim, Jeong-Kook;Shin, Jae-Hong;Joo, Young-Dae;Seong, See-Yearl
    • Bulletin of the Korean Chemical Society
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    • 제26권3호
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    • pp.399-408
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    • 2005
  • We have utilized neural network (NN) studies to predict impact sensitivities of various types of explosive molecules. Two hundreds and thirty four explosive molecules have been taken from a single database, and thirty nine molecular descriptors were computed for each explosive molecule. Optimization of NN architecture has been carried out by examining seven different sets of molecular descriptors and varying the number of hidden neurons. For the optimized NN architecture, we have utilized 17 molecular descriptors which were composed of compositional and topological descriptors in an input layer, and 2 hidden neurons in a hidden layer.

Hydroiminoacylation of $\alpha,\omega$-diene with Aldimine by Rh(Ⅰ) and Isomerization of the Terminal Olefin to the Internal Olefin

  • Jun, Chul-Ho;Kang, Jung-Bu;Lim, Yeong-Gweon
    • Bulletin of the Korean Chemical Society
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    • 제14권2호
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    • pp.287-291
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    • 1993
  • Catalytic iminohydroacylation has been achieved by the reaction of aldimine 1 and 1,5-hexadiene (2a) with Wilkinson's complex as catalyst. Compounds 7a, 8a and 9a were obtained as final product after hydrolysis of the resulting iminohydroacylation products 4a, 5a and 6a. Depending on the reactant ratio (2/1), the ratio of products were changed dramatically : As the 2/1 ratio was increased, 7a is the major product after hydrolysis while 8a is the major with an 1/1 ratio of 2/1. The mechanism of the formation of 5a is determined by the reaction of 1 and 2b under the identical reaction conditions. Considering that 5a may not be formed from the hydroiminoacylation of 14a since 5b cannot be formed from that of conjugate diene 14b generated from isomerization of 2b, 5a must be formed from the reaction of 4a and 10 by addition-elimination mechanism.