• 제목/요약/키워드: chemical cracking

검색결과 232건 처리시간 0.023초

복합재 원통구조물의 열-점탄성적 잔류음력 및 열좌굴 해석 (Analysis of Thermo-Viscoelastic Residual Stresses and Thermal Buckling of Composite Cylinders)

  • 김철;김영국;최웅
    • 대한기계학회논문집A
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    • 제26권8호
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    • pp.1653-1665
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    • 2002
  • One of the most significant problems in the processing of composite materials is residual stresses. The residual stresses may be high enough to cause cracking in the matrix even before external loads are applied and can degrade the integrity of composite structures. In this study, thermo-viscoelastic residual stresses occurred in the polymeric composite cylinder are investigated. This type of structure is used for the launch vehicle fuselage. The time and degree of cure dependent thermo-viscoelastic constitutive equations are developed and coupled with a thermo-chemical process model. These equations are solved with the finite element method to predict the residual stresses in the composite structures during cure. A launch vehicle experiences high thermal loads during flight and re-entry due to aerodynamic heating or propulsion heat, and the thermal loads may cause thermal buckling on the structure. In this study the thermal buckling analysis of composite cylinders are performed. Two boundary conditions such as all clamped and all simply supported are used for the analysis. The effects of laminates stacking sequences, shapes and residual stresses on the critical buckling temperatures of composite cylinders are investigated. The thermal buckling analysis is performed using ABAQUS.

바이트 가변 연산기능을 가진 블록 암호시스템 설계에 관한 연구 (A Study on the Block Cryptosystem Design with Variable Byte Operation)

  • 이선근
    • 한국산학기술학회논문지
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    • 제12권5호
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    • pp.2311-2316
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    • 2011
  • 정보통신과 네트워크의 발전으로 인하여 정보에 대한 보안의 중요성이 날이 갈수록 심화되고 있다. 이러한 시점에서 암호시스템들이 발전하고 있으나 비례적으로 크랙 및 해킹의 기술도 발전되고 있다. 그러므로 본 논문에서는 바이트 가변연산을 이용하여 블록암호시스템을 설계하였다. 설계된 바이트 기반 블록암호시스템은 고정된 DC 및 LC를 발생시키지 않으므로 이러한 공격방법으로부터 안전하다는 장점을 가진다. 또한 기존 대칭형 암호시스템이 가지고 있던 처리속도와 비대칭 암호시스템이 가지고 있던 인증기능을 모두 포함함으로서 네트워크 기반에서의 정보통신발달에 많은 도움을 주리라 사료된다.

A Numerical Model for the Freeze-Thaw Damages in Concrete Structures

  • Cho Tae-Jun
    • 콘크리트학회논문집
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    • 제17권5호
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    • pp.857-868
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    • 2005
  • This paper deals with the accumulated damage in concrete structures due to the cyclic freeze-thaw as an environmental load. The cyclic ice body nucleation and growth processes in porous systems are affected by the thermo-physical and mass transport properties, and gradients of temperature and chemical potentials. Furthermore, the diffusivity of deicing chemicals shows significantly higher value under cyclic freeze-thaw conditions. Consequently, the disintegration of concrete structures is aggravated at marine environments, higher altitudes, and northern areas. However, the properties of cyclic freeze-thaw with crack growth and diffusion of chloride ion effects are hard to be identified in tests, and there has been no analytic model for the combined degradations. The main objective is to determine the driving force and evaluate the reduced strength and stiffness by freeze-thaw. For the development of computational model of those coupled deterioration, micro-pore structure characterization, pore pressure based on the thermodynamic equilibrium, time and temperature dependent super-cooling with or without deicing salts, nonlinear-fracture constitutive relation for the evaluation of internal damage, and the effect of entrained air pores (EA) has been modeled numerically. As a result, the amount of ice volume with temperature dependent surface tensions, freezing pressure and resulting deformations, and cycle and temperature dependent pore volume has been calculated and compared with available test results. The developed computational program can be combined with DuCOM, which can calculate the early aged strength, heat of hydration, micro-pore volume, shrinkage, transportation of free water in concrete. Therefore, the developed model can be applied to evaluate those various practical degradation cases as well.

Binary CDMA 시스템에 적용 가능한 PBS-AES 코릴레이터 설계에 관한 연구 (A Study on PBS-AES Correlator Design adapted in Binary CDMA System)

  • 이선근
    • 한국산학기술학회논문지
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    • 제12권6호
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    • pp.2713-2717
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    • 2011
  • 수처리 기간산업 등의 산재된 센서들로부터 데이터를 전송하기 위해서 사용되는 Binary-CDMA 시스템은 자체적으로 안전성을 내포하고 있다. 그러나 급변하는 다양한 방식의 해킹 및 크래킹에 대한 방어기재로서 Binary-CDMA는 환경변화에 매우 민감하게 반응할 필요성이 대두되고 있다. 그러므로 본 논문은 이러한 문제점을 해결하기 위하여 Binary-CDMA에서 병목현상이 발생되는 코릴레이터에 안전성 확보 및 쉬운 업데이트를 위하여 보안 암호알고리즘을 추가하였다. 추가된 암호알고리즘은 대칭형 기반 암호알고리즘으로 센서들에 대한 1:1 대응을 수행함으로서 안전하지 않은 채널에서 안전한 정보를 통신할 수 있도록 한다.

우슬(Achyranthes Root) 탕제 후 얻어진 폐한약재 부산물의 열분해 (Pyrolysis of Waste Oriental Medicine Byproduct Obtained from the Decoction Process of Achyranthes Root)

  • 박지희;정재훈;이지영;김영민;박영권
    • 공업화학
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    • 제29권4호
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    • pp.474-478
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    • 2018
  • Thermal decomposition of waste Achyranthes Root (WAR) emitted from its decoction process was investigated using a TG analyzer and a fixed-bed reactor. The WAR had the larger C and fixed carbon content than fresh AR (FAR) due to the extraction of hemicelluloses from FAR during decoction process. Thermogravimetric (TG) analysis results also revealed the elimination of hemicellulose by its decoction. Relatively high contents of the cellulose and lignin made high contents of their typical pyrolyzates, such as acids, ketones, furans, and phenols, in the pyrolysis of WAR using the fixed-bed reactor. The increase of pyrolysis temperature from 400 to $500^{\circ}C$ increased yields of oil and gas due to the more effective cracking efficiency of WAR at a higher temperature. The chemical composition of product oil was also changed by applying the higher pyrolysis temperature, which increased the selectivity to furans and phenols.

내(耐)Sour 라인파이프 강재의 개발동향 및 용접부 Sour특성 (Development Trend of Sour Resistant Linepipe Steel and its Sour Characteristics in Welded Joints)

  • 김영훈;송우현;고성웅
    • Journal of Welding and Joining
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    • 제32권5호
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    • pp.21-25
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    • 2014
  • Oil and gas fields were left unexploited which deemed too deep and sour. New developing markets are emerging in this part and pipe manufacturers need demanding requirements in the combination of sour service requirements with heavier wall thickness required to cope with increasing water depths. Whilst, the strength and fracture toughness needed to meet the strict requirements In order to deliver the optimum sour properties in the final pipe, attention needs to be paid to each stage throughout the process from steel making. The main key during steel making is strengthening, securing mechanical properties and suppression of center segregation by adding proper chemical elements and controlling water cooling and plate rolling. Additionally in welding, it is required to prevent HAZ softening by high heat input during welding of heavy thick pipes and hydrogen assisted cracking in high strength steels with hard phases. In this paper, we introduce markets of sour resistant linepipe steels and in response to this, have a look in the development trend of sour resistant linepipe steels and its sour characteristics in welded joints.

세라믹/금속 이종재료 계면의 기계적 특성에 관한 연구 (A Study on Mechanical Characteristics of Interface of Ceramic/Metal Composites)

  • 서도원;김학근;송준희;임재규;박찬경
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2000년도 춘계학술대회논문집A
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    • pp.121-126
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    • 2000
  • Metal/Ceramic structures have many attractive properties, with great potential for applications that demand high stiffness, as well as chemical and biological stability, thermal and electrical insulation. They are currently in use for mechanical and thermal protection in cutting tool and engine parts. With all their great advantage, ceramics suffer from one major problem they are brittle, and are especially susceptible to cracking from surface contacts. Delamination at the interfaces with adjacent layers is a particularly disturbing problem, and can cause premature failure of a composite system. so determination of adhesive properties of coating is one of the most important problems for the extension of the use of coated materials. In this work, mechanical characteristics of Interface of ceramic/Metal composites are evaluated by means of hardness test, indentation test apparent interfacial toughness and bonding strength test. The interface indentation test provides a relation between the applied load(P) and the length of the crack(a) created at the interface between the coating and the substrate.

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섬유의 종류, 형상 및 치환율에 따른 HPFRCC의 공학적 특성에 관한 실험적 연구 (An Experimental Study on the Engineering Properties of HPFRCC According to Kinds, Shapes and Volume Fraction of Fibers)

  • 김영덕;조봉석;김재환;김규용;최경렬;김무한
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2003년도 학술.기술논문 발표회
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    • pp.59-62
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    • 2003
  • Kinds, shapes and fraction ratios of fibers have influence on properties of HPFRCC(High-Performance Fiver Reinforced Cementitious Concrete) like bending strength, strain capacity and fracture toughness. For example, hydrophilic fibers have different chemical bond strength from hydrophobic fibers, fiber shapes influence on fiber pull-out and rupture, and fiber volume fraction influence on bending strength. In this study, to estimate influences of kinds, shapes and fraction ratios of fibers, we make HFRCC with 3 kind of fiber in various volume fraction of fiber and compare cracking, bending strength and fracture toughness. As the results, bending strength of HPFRCC was increased as fiber volume fraction was increase and fiber tensile strength was increase, and strain capacity and fracture toughness of HFRCC was higher in fiber pull-out fracture than in fiber rupture fracture. And HFRCC showing pseudo strain hardening has higher fiber reinforce efficiency than others.

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Cu-Zn 황동에서 수소가 탈아연 부식에 미치는 영향 (Effect of Hydrogen on Dezincification of Cu-Zn Brass)

  • 최병학;이범규;장현수;전우일;박용성;임재균;이진희;박찬성;김진표
    • 한국재료학회지
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    • 제27권3호
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    • pp.172-178
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    • 2017
  • The aim of this study is to consider the effect hydrogen on dezincification behavior of Cu-Zn alloys. The investigations include microstructural observations with scanning electron microscope and chemical composition analysis with energy dispersive spectrometer. The dezincification layer was found to occur in high pressure hydrogen atmosphere, not in air atmosphere. In addition, the layers penetrated into the inner side along the grain boundaries in the case of hydrogen condition. The shape of the dezincification layers was porous because of Zn dissolution from the ${\alpha}$ or ${\beta}$ phase. In the case of stress corrosion cracks formed in the Cu-Zn microstructure, the dezincification phenomenon with porous voids was also accompanied by grain boundary cracking.

Plasma Corrosion in Oxalic Acid Anodized Coatings Depending on Tartaric Acid Content

  • Shin, Jae-Soo;Song, Je-Boem;Choi, Sin-Ho;Kim, Jin-Tae;Oh, Seong-Geun;Yun, Ju-Young
    • Applied Science and Convergence Technology
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    • 제25권1호
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    • pp.15-18
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    • 2016
  • Study investigated the optimal anodizing conditions for fabricating an oxide film that produces less contamination in a corrosive plasma environment, using oxalic acid and tartaric acid. Oxide films were produced using sulfuric acid, oxalic acid, and tartaric acid electrolyte mixtures with various mole ratios. The oxide film made by adding 0.05M tartaric acid to 0.3M oxalic acid showed higher breakdown voltage and lower leakage current. Additionally, contamination particles were reduced during plasma etching, thus demonstrates that this mixture presented optimal conditions. However, higher tartaric acid content (0.1 M, 0.15 M) led to lower breakdown voltages and higher leakage currents. Also, it resulted in more cracking during thermal shock tests as well as the generation of more contamination particles during plasma processing.