• Title/Summary/Keyword: chemical cleaning

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Time-elapes Change of Oil-polluted Taean Coastal Area by the Hebei Spirit Oil Spill Incident - Focusing on the Field Surveying(Vision and Photos) - (허베이스피리트호 원유유출사고로 오염된 태안연안의 경시변화 -현장관측(육안 및 사진분석)을 중심으로-)

  • Jung, Jae-Sung;Cheong, Cheong-Jo
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.3
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    • pp.111-123
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    • 2009
  • The purpose of this study is to investigate the time-elapse change of oil-polluted Taean coastal area with by Herbei Spirit oil spill incident. From Mandae of Iwonmeyon to Padori beach of Sowonmeyon, field monitering was conducted at eleven surveying points surveying. The specific conclusions from this study are as follows. The residual oil was not founded at ten surveying points, but the crude oil remained under the ground at the Groompo beach one year passed since the oil spill. Because the efforts of volunteers over millionaires and inhabitants for cleaning and reciprocating actions of waves, the oil-polluted coastal area by Herbei Spirit oil spill incident. It is guessed that a part of stranded oil spilled from the incident was degraded by physical, chemical, and biological weathering and the residue was dispersed in tidal and subtidal zone with oil-minerals aggregates(OMA).

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Dyeing Properties and Storage Stability of Leaf Powder Prepared from Dyer's Knotweed(II) - by Hot Air and Room Temperature Drying Methods - (생쪽잎분말의 염색성 및 저장성(II) - 열풍 및 상온건조방법 -)

  • Shin, Youn-Sook;Son, Kyung-Hee;Yoo, Dong-II
    • Textile Coloration and Finishing
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    • v.21 no.4
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    • pp.23-32
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    • 2009
  • The objective of this study is to investigate the efficacy of leaf powder colorants as substitutes for traditional indigo dyeing. Leaf powder colorants were prepared by hot air($50^{\circ}C$) and room temperanrre($25^{\circ}C$) drying methods from fresh leaves. The presence of indigo in the leaf powder colorants was confirmed by UV/Visible absorption spectra. All the powder colorants showed broad absorption at 602 nm as same as synthetic indigo. Dyeing was done by reduction method with sodium hydrosulfite and sodium hydroxide. Leaf powder colorants produced blue color on silk fabrics, showing similar color to the one dyed traditionally with fresh juice extract. The powder colorants prepared at room temperature drying were more stable for long term storage than that prepared by hot air drying. Thus, the powder colorants prepared by room temperature drying was reduced and dyed in one-step process without sodium hydroxide in the dyebath for further investigate dyeing properties. K/S value of the fabric dyed without sodium hydroxide was much higher than one dyed with sodium hydroxide. Regardless of the addition of sodium hydroxide, rubbing fastness was fairly good showing above 4 rating. Fastness to dry cleaning and light of the fabrics dyed without sodium hydroxide were mote higher than that dyed in alkaline condition.

Removal of Hydrophobic Contaminant using Amphiphilic Block Copolymer (양친성 블록공중합체를 이용한 소수성 오염원제거)

  • Lee, Junhyup;Shim, Jaeyoul;Kim, Younguk
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.3
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    • pp.15-19
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    • 2014
  • Spilling pollutants and its contamination to the ground have serious impact to public resulting in various research about remediation techniques. In this study, the use of amphiphilic block copolymer for remediation was investigated with a series of laboratory tests on removal of hydrophobic contaminant in soil. Four types of amphiphilic block copolymer were developed and the efficiency of the cleaning was compared with surfactant using arbitrary diesel-contaminated soils. The results of the study show that the use of amphiphilic polymer in the soil washing process significantly enhanced the remediation of the contaminated soil and a potential of new methodology of eco-friendly remediation.

Investigation of N2O Emission and Reduction Effect from MSW Incineration Plant (도시고형폐기물 소각시설에서 발생하는 N2O 발생량 조사 및 저감효과에 관한 연구)

  • Song, Hyun-Ok;Ko, Jae-Churl;Choi, Sang-Hyun;Kim, Duk-Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.12
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    • pp.672-678
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    • 2017
  • In this study, municipal solid waste (MSW) has collected 3 times and physico-chemical analysis has done. Nitrous oxide emissions from MSW incineration plant were measured continuously by EPA Method 18 and it was compared with the emission by calculation using the emission factor. The $N_2O$ emission of MSW incineration plant was more than twice as large as the emission by calculation. It was found that the installation of abatement facilities in MSW incineration plant is effective in achieving the greenhouse reduction targets and it can be ensure economical efficiency through emission trading system.

Research Trends of Scheduling Techniques for Domestic Major Industries (국내 주요 산업별 스케줄링 기법의 연구동향)

  • Lee, Jae-yong;Shin, Moonsoo
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.41 no.1
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    • pp.59-69
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    • 2018
  • The up-to-date business environment for Korean manufacturers is very complex and rapidly changing. Especially, the companies have faced with various changes derived from small quantity batch production, diversification of customer demands, and short life cycles of products. Consequently, the Korean manufacturing companies are in need of more efficient production planning and scheduling techniques. In this paper, the research trend of scheduling techniques is investigated to provide relevant information to researchers in this field. Furthermore, some implications for future researches are presented regarding literatures published in Korea over the last 10 years. This paper presents an entire investigation into Korean research works on scheduling (2,569 papers) that are published from 2007 to 2016. Especially, detailed analysis was carried out in the following three industry : 1) semiconductor, 2) shipbuilding and 3) automobile. In this paper, approaches to scheduling presented in the literature are categorized into the following three categories : 1) application, 2) algorithm, and 3) simulation modeling. First, in the semiconductor industry, scheduling techniques related to semiconductor cleaning processes, photolithography processes, chemical processes, transport and transport equipment have been found to be dominant. Second, the shipbuilding industry is focused on assembly processes, transporter, crane and various existing production management system. On the other hand, the scheduling research of the automobile industry is mainly focused on the vehicle movement routing and procurement supply-chain planning algorithm in terms of logistics. The conclusion of this study are expected to provide many implications for various types of academic and practical follow-up studies related to scheduling in consideration of main characteristics of semiconductor, shipbuilding and automobile industries.

Tafel Characteristics by Electrochemical Reaction of SnAgCu Pb-Free Solder (SnAgCu계 무연솔더의 전기화학적 반응에 따른 타펠 특성)

  • Hong Won Sik;Kim Kwang-Bae
    • Korean Journal of Materials Research
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    • v.15 no.8
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    • pp.536-542
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    • 2005
  • Recently European Council(EU) published the RoHS(restriction of the use of certain hazardous substances in electrical and electronic equipment) which is prohibit the use of Pb, Hg, Cd, $Cr^{+6}$, PBB or PBDE in the electrical and electronic equipments. So EU member States shall ensure that, from 1 July 2006, new electrical and electronic equipment put on the market does not contain 6 hazardous substances. The one of the most important in electronics manufacturing process is soldering. Soldering process use the chemical substances which are applied in fluxing and cleaning processes and it can generate the malfunction of electronics caused by corrosion in the fields conditions. Therefore this study researched on the polarization and Tafel properties of Sn40Pb and Sn3.0Ag0.5Cu(SAC) solder based on the electrochemical theory. We prepared SnPb specimens which was aged in $150^{\circ}C,\;180^{\circ}C$ for 15 minutes ana Sn3.0Ag0.5Cu specimens that was aged in $180^{\circ}C,\;220^{\circ}C$ for 10 minutes. Experimental polarization curves were measured in distilled ionized water and $3.5 wt\%$, 1 mole NaCl electrolyte of $40^{\circ}C$, pH 7.5. Ag/AgCl and graphite were utilized by reference and counter electrode, respectively. To observe the electrochemical reaction, polarization test was conducted from -250 mV to +250 mV. From the polarization curves that were composed of anodic and cathodic curves, we obtained Tafel slop, reversible electrode potential(Ecorr) and exchange current density(Icorr). In these results, corrosion rate for two specimen were compared Sn3.0Ag0.5Cu with SnPb solders

Conservation and Analysis of Inner Materials of a Stoneware Bottle from Incheon Ongjingun Yeongheungdo Shipwreck (인천 옹진군 영흥도선 출수 도기병의 보존처리와 내용물 분석)

  • Kim, Hyoyun;Kim, Seojin
    • Journal of Conservation Science
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    • v.32 no.4
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    • pp.449-457
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    • 2016
  • A stoneware bottle was recovered from the Incheon Yeongheungdo Shipwreck in 2013. Primary observations showed that this object had a sealed opening and was covered with a foreign material. After it was cleaned via mechanical and chemical methods, wave patterns were observed on the outer surface of the bottle and a yellowish-brown transparent material was found within. In this paper, the process of conserving the stoneware bottle and the analysis conducted on the unknown material found within is explained. The conservation process included steps such as cleaning, desalination and restoration. After of the missing area located at the rim, the original shape of the bottle was made clear. In addition, the unknown inner material was analyzed using FT-IR and GC-MS. Results showed that the material is similar to golden lacquer. It is speculated that the Yeongheungdo Ship had wrecked during the Unified Silla period while carrying a bottle loaded with golden lacquer.

The SPM Study on the Change of Titanium Surface Roughness following Airpowder Abrasive and Application Time of Citric Acid (공기-분말 연마와 구연산의 적용시간에 따른 임프란트 표면 거칠기의 변화에 관한 주사탐침현미경적 연구)

  • Park, Min-Seo;Chung, Chin-Hyung;Lim, Sung-Bin
    • Journal of Periodontal and Implant Science
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    • v.30 no.4
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    • pp.821-836
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    • 2000
  • The Peri-implantitis causes inflammation of periodontal tissue and bone loss. It contaminates surface of implants. Therefore, guided bone regeneration has been used for the treatment of this disease. For the reosseointegration of the exposed surface, various mechanical and chemical methods have been used for cleaning and detoxication of implant surface. Among these methods, air-powder abrasive and oversaturated citrate are known to be most effective. However, these treatments may deform implant surface. In this research, changes of surface roughness they were examined. 10 experimental machined titanium cylinder models were fabricated to be used for control groups. Each of them was air powder abraded for 1 minute and they were named group 1. And then, group 1 were burnished with cotton pellets soaked with citrate for 30 seconds(Group 2), 1 minute(Group 3), 3 minutes(Group 4), and 5 minutes(Group 5) burnishing were applied for grouping respectively. Each group were examined with SPM, and their surface roughness were measured and analyzed. 1. Surface roughness of titanium decreased when it was air-powder abraded for 1 minute. It was statistically significant. 2. When Air-powder abraded titanium were treated with citrate for 3 minutes, Their surface roughness was the lowest. Titanium treated for 1 minute was the second lowest and 30 seconds was the third and titanium burnished for 5 minutes was the highest. 3. Surface roughness of titanium which was treated with citrate was decreased till 3 minutes, which was statistically significant. There was no statistical significance from 30 seconds to 1 minute and from 1 minute to 3 minutes, and there was statistical significance from 30 seconds to 3 minutes. 4. Oxide layer was formed when titanium is exposed to air, and it was removed when air-powder abraded. It was made when treated with citrate. It is thought that citrate treatment is necessary after the air-powder abrasion, and 1 minute is clinically and qualitatively adequate for burnishing time of citrate.

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A Study on Etching Characteristics of SnO2 Thin Films Using High Density Plasma (고밀도 플라즈마를 이용한 SnO2 박막의 건식 식각 특성)

  • Kim, Hwan-Jun;Joo, Young-Hee;Kim, Seung-Han;Woo, Jong-Chang;Kim, Chang-Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.11
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    • pp.826-830
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    • 2013
  • In this paper, we carried out the investigations of both etch characteristics and mechanisms for the $SnO_2$ thin films in $O_2/BCl_3/Ar$ plasma. The dry etching characteristics of the $SnO_2$ thin films was studied by varying the $O_2/BCl_3/Ar$ gas mixing ratio. We determined the optimized process conditions that were as follows: a RF power of 700 W, a DC-bias voltage of - 150 V, and a process pressure of 2 Pa. The maximum etch rate was 509.9 nm/min in $O_2/BCl_3/Ar$=(3:4:16 sccm) plasma. From XPS analysis, the etch mechanism of the $SnO_2$ thin films in the $O_2/BCl_3/Ar$ plasma can be identified as the ion-assisted chemical reaction while the role of ion bombardment includes the destruction of the metal-oxide bonds as well as the cleaning of the etched surface form the reaction products.

Human Risk Assessment of Perchloroethylene Considering Multi-media Exposure (다매체 노출을 고려한 Perchloroethylene의 인체위해성평가연구)

  • Seo, Jungkwan;Kim, Taksoo;Jo, Areum;Kim, Pilje;Choi, Kyunghee
    • Journal of Environmental Health Sciences
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    • v.40 no.5
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    • pp.397-406
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    • 2014
  • Objectives: Perchloroethylene (PCE) is a volatile chemical widely used as a solvent in the dry-cleaning and textile processing industries. It was evaluated as Group 2 "probably carcinogenic to humans" by the Integrated Risk Information System (IRIS) of the United State Environmental Protection Agency (U.S. EPA) in 2012. In order to provide a scientific basis for establishing risk management measures for chemicals on the national priority substances list, aggregate risk assessment was conducted for PCE, included in the top-10 substances. Methods: We conducted the investigation and monitoring of PCE exposure (e.g., exposure scenario, detection levels, and exposure factors, etc.) and assessed its multi-media (e.g., outdoor air, indoor air, and ground water) exposure risk with a deterministic and probabilistic approach. Results: In human risk assessment (HRA), the level of human exposure was higher in the younger age group. The exposure level through inhalation at home was the highest among the exposure routes. Outdoor air or uptake of drinking water represented less than 1% of total contributions to PCE exposure. These findings suggested that the level of risk was negligible since the Hazard Index (HI) induced by HRA was below one among all age groups, with a maximum HI value of 0.17 when reasonable maximum exposure was applied. Conclusion: In conclusion, it was suggested that despite low exposure risk, further studies are needed considering main sources, including occupational exposure.