• Title/Summary/Keyword: chemical balance study

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Potential of Torrified Tulip-tree for the Production of Solid Bio-fuels (백합나무의 반탄화 처리를 이용한 고체연료화 가능성 조사)

  • Ahn, Byoung Jun;Yang, In;Kim, Sang Tae;Park, Daehak
    • New & Renewable Energy
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    • v.9 no.4
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    • pp.40-50
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    • 2013
  • This study was performed to investigate the potential of torrefied tulip tree (TT) for the production of pellets. For this purpose, chemical composition and fuel characteristics of torrefied TT were examined. In addition, pellets were fabricated by using sawdust of torrefied TT chip, and durability of the pellet was measured. Lignin content of torrefied TT was higher than that of non-torrefied TT, and increased with the increases of torrefaction temperature and time. Fuel characteristics of torrefied TT were affected by torrefied conditions, and the characteristics were influenced more by torrefaction temperature than by torrefaction time. Higher heating value (HHV) and ash content (AC) of torrefied tulip tree increased with increasing torrefaction temperature, and the values were much higher than HHV and AC values of non-torrefied TT. Durability of pellets fabricated with $230^{\circ}C$- and $250^{\circ}C$-torrefied TT was higher than that of $270^{\circ}C$-torrefied TT, and the value exceeded the minimum requirement (-97.50%) of the 1st-grade pellet standard designated by Korea Forest Research Institute. Based on the results, torrefaction treatment of $250^{\circ}C/50min$ to TT might be a optimal condition for the production of TT pellets considering the mass balance and fuel characteristics of TT as well as the durability of the pellets. Thus, it is confirmed that torrefied TT can be used as a raw material for the production of bio-pellets.

The psychopharmacological activities of Vietnamese ginseng in mice: characterization of its psychomotor, sedative-hypnotic, antistress, anxiolytic, and cognitive effects

  • dela Pena, Irene Joy I.;Kim, Hee Jin;Botanas, Chrislean Jun;de la Pena, June Bryan;Van Le, Thi Hong;Nguyen, Minh Duc;Park, Jeong Hill;Cheong, Jae Hoon
    • Journal of Ginseng Research
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    • v.41 no.2
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    • pp.201-208
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    • 2017
  • Background: Panax vietnamensis Ha et Grushv. or Vietnamese ginseng (VG) is a recently discovered ginseng species. Studies on its chemical constituents have shown that VG is remarkably rich in ginseng saponins, particularly ocotillol saponins. However, the psychopharmacological effects of VG have not been characterized. Thus, in the present study we screened the psychopharmacological activities of VG in mice. Methods: VG extract (VGE) was orally administered to mice at various dosages to evaluate its psychomotor (open-field and rota-rod tests), sedative-hypnotic (pentobarbital-induced sleeping test), anti-stress (cold swimming test), anxiolytic (elevated plus-maze test), and cognitive (Y-maze and passive-avoidance tests) effects. Results: VGE treatment increased the spontaneous locomotor activity, enhanced the endurance to stress, reduced the anxiety-like behavior, and ameliorated the scopolamine-induced memory impairments in mice. In addition, VGE treatment did not alter the motor balance and coordination of mice and did not potentiate pentobarbital-induced sleep, indicating that VGE has no sedative-hypnotic effects. The effects of VGE were comparable to those of the Korean Red Ginseng extract. Conclusion: VG, like other ginseng products, has significant and potentially useful psychopharmacological effects. This includes, but is not limited to, psychomotor stimulation, anxiolytic, antistress, and memory enhancing effects.

Solvent Extraction Equilibria of Gd with PC88A from Chloride Solution (염산용액에서 PC88A에 의한 Gd 용매추출의 평형)

  • Lee Gwang-Seop;Lee Jin-Young;Kim Sung-Don;Kim Joon-Soo;Park Jang-Hyun;Lee Man-Seung
    • Resources Recycling
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    • v.13 no.2
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    • pp.24-32
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    • 2004
  • Solvent extraction equilibria of Gd with PC88A from chloride solutions were analyzed by considering chemical equilibria. phase equilibria, mass and charge balance equations. The following solvent extraction reaction and equilibrium constant were evaluated from the experimental data performed in this study. $Gd^{3+}$ $+2H_2$$A_2$,$or=GdA_3$HA.or+3 $H^{+}$ , K=3.3 A procedure was suggested to calculate the initial concentration of chloride ion from initial pH and initial concentration of Gd. By applying ionic equilibria, the distribution of Gd complexes with Gd and HCl concentration was obtained. The predicted distribution coefficients of Gd agreed well with the experimental results.

Theoretical approach on the heating and cooling system design for an effective operation of Li-ion batteries for electric vehicles (전기구동 자동차용 리튬이온 배터리의 고효율 운전을 위한 냉방 및 난방 시스템 설계에 대한 이론적 접근법)

  • Kim, Dae-Wan;Lee, Moo-Yeon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.5
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    • pp.2545-2552
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    • 2014
  • This study is aiming to suggest the effective thermal management system design technologies for the high voltage and capacity battery system of the electricity driven vehicles and introduce the theoretical designing methods. In order to investigate the effective operation of the battery system for the electricity driven vehicles, the heat generation model for Li-ion battery system using the chemical reaction while charging and discharging was suggested and the thermal loads of the heat sources (air or liquid) for cooling and heating were calculated using energy balance. Especially, the design methods for the cooling and heating of the battery system for maintaining the optimum operation temperature were investigated under heating, cooling and generated heat (during charging and discharging) conditions. The battery thermal management system for the effective battery operation of the electricity driven vehicles was suggested reasonably depending on the variation of the season and operation conditions. In addition, at the same conditions under summer season, the cooling method using the liquid and active cooling technique showed a relatively high capacity, while cooling method using the passive cooling technique showed a relatively low capacity.

Identification of Vestibular Organ Originated Information on Spatial Memory in Mice (마우스 공간지각과 기억 형성에 미치는 전정 유래 정보의 규명)

  • Han, Gyu Cheol;Kim, Minbum;Kim, Mi Joo
    • Research in Vestibular Science
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    • v.17 no.4
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    • pp.134-141
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    • 2018
  • Objectives: We aimed to study the role of vestibular input on spatial memory performance in mice that had undergone bilateral surgical labyrinthectomy, semicircular canal (SCC) occlusion and 4G hypergravity exposure. Methods: Twelve to 16 weeks old ICR mice (n=30) were used for the experiment. The experimental group divided into 3 groups. One group had undergone bilateral chemical labyrinthectomy, and the other group had performed SCC occlusion surgery, and the last group was exposed to 4G hypergravity for 2 weeks. The movement of mice was recorded using camera in Y maze which had 3 radial arms (35 cm long, 7 cm high, 10 cm wide). We counted the number of visiting arms and analyzed the information of arm selection using program we developed before and after procedure. Results: The bilateral labyrinthectomy group which semicircular canal and otolithic function was impaired showed low behavioral performance and spacial memory. The semicircular canal occlusion with $CO_2$ laser group which only semicircular canal function was impaired showed no difference in performance activity and spatial memory. However the hypergravity exposure group in which only otolithic function impaired showed spatial memory function was affected but the behavioral performance was spared. The impairment of spatial memory recovered after a few days after exposure in hypergravity group. Conclusions: This spatial memory function was affected by bilateral vestibular loss. Space-related information processing seems to be determined by otolithic organ information rather than semicircular canals. Due to otolithic function impairment, spatial learning was impaired after exposure to gravity changes in animals and this impaired performance was compensated after normal gravity exposure.

Structure analysis, and magnetic study of a new Gd-metal-organic framework single crystal grown by the slow-evaporation method (증발법으로 합성된 신규 가돌리늄 금속-유기골격체의 단결정 구조 분석 및 자성학적 특성 연구)

  • Song, Jeong Hwa
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.5
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    • pp.199-204
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    • 2022
  • A new three-dimensional Gd-MOF, [Gd(p-XBP4)4(H2O)]·W(CN)8; (1; p-XBP4 = N,N'-p-phenylenedimethylenbis (pyridin-4-one)) has been synthesized by slow-evaporation and its crystal structure was characterized by single-crystal X-ray diffraction (SCXRD) analysis. For each GdIII ion, there are seven coordination sites, which are occupied by six oxygen atoms of six p-XBP4 ligands and one oxygen atom from the water molecule. The [W(CN)8]3- anion exists for charge balance with cationic framework. The GdII ions are interconnected by the p-XBP4 ligand to form the three-dimensional structure. Considering the magnetic property of lanthanide ions, magnetic studies of Gd-MOF were investigated by direct-current (DC) magnetic susceptibilities measurements.

Effect of Solcoseryl in Corneal Alkali Burn Rat Model

  • Kim, Hoon;Kim, Hong-Bee;Seo, Jae-Hwi;Lee, Dong Cho;Cho, Kyong Jin
    • Medical Lasers
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    • v.10 no.1
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    • pp.22-30
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    • 2021
  • Background and Objectives Ocular alkali burns cause severe damage to the ocular tissues and vision loss. Solcoseryl is a standardized calf blood extract that normalizes the metabolic disturbance and aids in maintaining the chemical and hormonal balance and has been used to treat burns in various tissues. This study examined the effects of Solcoseryl on a rat corneal alkali burn model. Materials and Methods Twenty rats were assigned randomly to four equal groups, including alkali burn, hyaluronic acid, Solcoseryl eyedrop, and Solcoseryl gel. A corneal alkali burn was induced by a NaOH-soaked paper disc. The treatments were given twice a day, every day. The wound area was measured after 24 and 48 hours, and the degree of neovascularization and corneal opacity were scored every week. The rats were sacrificed after three weeks for immunohistochemistry (IHC) to compare the level of inflammatory cytokines, IL-1β, IL-6, and TNF-α. The thickness of the retinal layers was compared to observe any changes in the retina. Results The use of Solcoseryl on corneal alkali burn accelerated wound healing with less neovascularization, greater opacity, and less cataract. IHC showed that the inflammation of the cornea was controlled by both the hyaluronic acid and Solcoseryl treatments. On the other hand, the inflammation had spread to the retina. When the dosage forms were compared, eyedrops were more effective on corneal inflammation, while the gel-type had a greater effect on retinal inflammation. Conclusion Solcoseryl was effective in accelerating the wound healing rate on a corneal alkali burn but could not prevent the spread of inflammation from the cornea to the retina. Eyedrops were more effective on inflammation in the cornea, and the gel was more effective in the retina.

Determination of Application Rate of Composted Pig Manure for Wetland Rice (논토양에서 돈분톱밥퇴비 시용량 결정에 관한 연구)

  • Lee, Sang-Min;Ryu, In-Soo;Lee, Choon-Soo;Park, Yang-Ho;Um, Myung-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.32 no.2
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    • pp.182-191
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    • 1999
  • A study was conducted for the determination of application rate of pig-dung composted with sawdust (referred as pig manure hereafter) for wetland rice. The study involved the field experiments with the cultivation of rice under different rates of application of pig manure in combination of different rates of chemical fertilizers, in a wetland rice soil. The field experiment involved following treatments : (I) Without fertilizer, (II) Standard rate of chemical fertilizers based on soil testing($98-73-71kg\;ha^{-1}$ as $N-P_2O_5-K_2O$), (III) $2.1Mg\;ha^{-1}$ of pig manure $>+80-37kg\;ha^{-1}$ of $N- K_2O$ as chemical fertilizer(Less $N-P_2O_5-K_2O$ contained in the compost), (IV) $4.2Mg\;ha^{-1}$ of pig manure+ $62-3kg\;ha^{-1}$ of $N-K_2O$as chemical fertilizer(Less $N-P_2O_5-K_2O$ contained in the compost), (V) $10Mg\;ha^{-1}$ of pig manure+ Treatment(II), (VI) $20Mg\;ha^{-1}$ of pig manure +Treatment(II). Number of tillers in treatment (I) were higher than other treatments in tillering and panicle formation stage. After heading stage, treatments (V) and (VI) have higher number of tillers, but treatment (III) and (IV) have fewer number of tillers during all growing stage. Uptake of NPK in rice plants was higher in treatment (VI), but the efficiency of N, P and K was higher in treatment (I), (III) and (IV). The yield of unhulled rice were in order of tretments (VI)>(V)>(IV)>(II)>(III), although the difference was not statistically significant. Inorganic nitrogen, available P and exchangable K contents in soil were highest at tillering stage in all treatments and became low from panicle formation to harvest stage. Available P in soil was increased by the application of pig manure upto 20 cm depth. Exchangeable cation contents in 40 to 60 cm soil depth was much higher in treatment (VI) than in other treatments. Treatment (V) and (VI) showed much higher losses of N. $P_2O_5 $ and $K_2O$ than other treatment. Though treatment (VI) tended yield higher than in other treatments, showed lodging and occurrence of leaf and neck blast in this treatment. Yield of unhulled rice in treatment (IV) was not significant statistically and reduced nutritional losses. It is conclude that treatment (IV) seems to be the most reasonable one for the application of pig manure in combination of chemical fertilizers.

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Study of Alkaline Peroxide Mechanical Pulp Made from Pinus densiflora (국내산 소나무로 제조된 APMP 특성 연구)

  • Lee, Ji-Young;Nam, Hyegeong;Kim, Chul-Hwan;Kwon, Sol;Park, Dong-Hun;Joo, Su-Yeon;Lee, Min-Seok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.100-110
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    • 2016
  • Alkaline Peroxide Mechanical Pulping (APMP) of Pinus densiflora harvested from domestic mountains was explored. APMP contributes to various advantages including pulp quality, elimination of the need for a bleaching process, and energy savings. Sequential treatment of impregnation of bleaching chemicals and refining not only overcome the concern of alkaline darkening of wood chips during chemical impregnation, but it also brightens the chips to the desired brightness levels suitable for writing and printing papers. APMP pulping from Pinus densiflora was greatly influenced by the dosage levels of hydrogen peroxide and sodium hydroxide. Alkaline peroxide treatment was carried out by applying one of three levels of hydrogen peroxide (1.5, 3, and 4.5% based on the oven-dried weight of the wood chips) and one of three levels of sodium hydroxide (1.5, 3, and 4.5% based on the oven-dried weight of the wood chips). Other chemicals including a peroxide stabilizers and metal chelation were constantly added for all treatments. Chemical treatment with a liquor-to-wood ration of 9:1 was carried out in a laboratory digestor. Compared to BTMP, APMP pulping displayed outstanding characteristics including the less requirement of refining energy, the better improvement of tensile strength, the more reduction of shives, and the greater increase of pulp brightness. In particular, when 4.5% of hydrogen peroxide with impregnation during 90 minutes was used, the brightness of APMP reached 64.9% ISO. Even though bulk of APMP was decreased with the increase of sodium hydroxide, a better and improved balance could be achieved between optical and strength properties. The spent liquor obtained from the discharge of the impregnation process at the dosage level of 4.5% hydrogen peroxide exhibited an equal level of residual peroxide with BTMP. In conclusion, APMP pulping showed successful results with Pinus densiflora due to its better response to the development of optical and physical properties compared to TMP pulping.

Material and Heat Balances of Bioethanol Production Process by Concentrated Acid Saccharification Process from Lignocellulosic Biomass (목질계 Biomass로부터 강산 당화 공정에 의한 Bioethanol 생산 공정의 물질 및 열수지)

  • Kim, Hee-Young;Lee, Eui-Soo;Kim, Won-Seok;Suh, Dong-Jin;Ahn, Byoung-Sung
    • Clean Technology
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    • v.17 no.2
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    • pp.156-165
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    • 2011
  • The process for bioethanol production from lignocellulosic biomass was studied through process simulation using PRO/II. Process integration was conducted with concentrated acid pretreatment, hydrolysis process, SMB (simulated moving bed chromatography) process and pervaporation process. Energy consumption could be minimized by the heat recovery process. In addition, material and energy balance were calculated based on the results from the simulation and literature data. A net production yield of 4.07 kg-biomass and energy consumption value of 3,572 kcal per 1 kg ethanol were calculated, which is indicating that 26% yield increase and 30% energy saving compared to the bioethanol production process with dilute-acid hydrolysis (SRI report). In order to make it possible, sugar conversion yield of cellulose and hemi-cellulose is to be reached up to 90% and fermentation of xylose needs to be developed. In order to reduce the energy consumption up to 30%, the concentration of acid solution after being separated by 5MB should exceed 20%. If acid/sugar separation by SMB process is to be practical, the bioethanol process designed in this study can be commercially feasible.