• Title/Summary/Keyword: chemical and mechanical properties

Search Result 2,248, Processing Time 0.046 seconds

Chemical and Functional Characteristics of Mechanically Deboned Chicken Meat and its Utilization in Processed Meat -I. Chemical and Functional Characteristics of Mechanically Deboned Chicken Meat- (기계발골가금육(機械拔骨家禽肉)의 특성(特性) 및 이용(利用)에 관(關)한 연구(硏究) -제(第) 1 보(報) : 기계발골가금육(機械拔骨家禽肉)의 특성(特性)-)

  • Ahn, Byung-Yoon;Kim, Jong-Won;Lee, Yu-Bang
    • Korean Journal of Food Science and Technology
    • /
    • v.13 no.3
    • /
    • pp.171-175
    • /
    • 1981
  • Hand deboned and mechanically deboned chicken meat were produced from domestic broilers and spent layers. Meat yield, chemical composition, functional characteristics, storage stability and microbiogical properties were investigated. The results obtained were as follows: 1. 35% of carcass freight was recovered primarily as hand deboned chicken meat (HDM) and 45% secondarily as mechanically deboned chicken meat(MDM), total meat yield reaching 80% of carcass weight. 2. Moisture, protein, fat. ash and calcium content of MDM were 65, 12, 20, 1.7 and $0.2{\sim}0.4%$, respectively MDM was higher than HDM in fat, ash and calcium, but significantly lower in moisture and protein Total pigment content of MDM was 2.5 times higher than that of HDM, such high content being attributed to the increased inclusion of hemoglobin during the mechanical masceration of carcass in the deboning process. 3. The emulsifying capacity (ES) of MDM per g meat was only 70% that of HDM, but when ES was expressed on unit g of protein basis MDM showed even higher ES than HDM primarily due to the higher proportion of salt soluble protein fraction of MDM. 4. Since the TBA value of MDM increased rapidly after 4 weeks of frozen storage at $-20^{\circ}C$, the maximum possible storage period of MDM is estimated to be about 4 weeks. 5. Total microbial counts of MDM was approximately $1.8{\times}10\;cells/g$ showing no great difference from HDM or red meat.

  • PDF

A Comparison Study on Reinforcement Behaviors of Functional Fillers in Nitrile Rubber Composites

  • Seong, Yoonjae;Lee, Harim;Kim, Seonhong;Yun, Chang Hyun;Park, Changsin;Nah, Changwoon;Lee, Gi-Bbeum
    • Elastomers and Composites
    • /
    • v.55 no.4
    • /
    • pp.306-313
    • /
    • 2020
  • To investigate the reinforcing effects of functional fillers in nitrile rubber (NBR) materials, high-structure carbon black (HS45), coated calcium carbonate (C-CaCO3), silica (200MP), and multi-walled carbon nanotubes (MWCNTs) were used as functional filler, and carbon black (SRF) as a common filler were used for oil-resistant rubber. The curing and mechanical properties of HS45-, 200MP-, and MWCNT-filled NBR compounds were improved compared to those of the SRF-filled NBR compound. The reinforcing effect also increased with a decrease in the particle size of the fillers. The C-CaCO3-filled NBR compound exhibited no reinforcing effect with increasing filler concentration because of their large primary particle size (2 ㎛). The reinforcing behavior based on 100% modulus of the functional filler based NBR compounds was compared by using several predictive equation models. The reinforcing behavior of the C-CaCO3-filled NBR compound was in accordance with the Smallwood-Einstein equation whereas the 200MP- and MWCNT-filled NBR compounds fitted well with the modified Guth-Gold (m-Guth-Gold) equation. The SRF- and HS45-filled NBR compounds exhibited reinforcing behavior in accordance with the Guth-Gold and m-Guth-Gold equations, respectively, at a low filler content. However, the values of reinforcement parameter (100Mf/100Mu) of the SRF- and HS45-filled NBR compounds were higher than those determined by the predictive equation model at a high filler content. Because the chains of SRF composed of spherical filler particles are similarly changed to rod-like filler particles embedded in a rubber matrix and the reinforcement parameter rapidly increased with a high content of HS45, the higher-structured filler. The reinforcing effectiveness of the functional fillers was numerically evaluated on the basis of the effectiveness index (��SRF/��f) determined by the ratio of the volume fraction of the functional filler (��f) to that of the SRF filler (��SRF) at three unit of reinforcing parameter (100Mf/100Mu). On the basis of their effectiveness index, MWCNT-, 200MP-, and HS45-filled compounds showed higher reinforcing effectiveness of 420%, 70%, and 20% than that of SRF-filled compound, respectively whereas C-CaCO3-filled compound exhibited lower reinforcing effectiveness of -50% than that of SRF-filled compound.

Microstructure Analysis of Rabbit and Chicken Femurs by Light Microscopy and Transmission Electron Microscopy (광학현미경과 투과전자현미경을 이용한 토끼와 닭 대퇴골의 미세구조 분석)

  • Kim, Chang-Yeon;Kim, Eun-Kyung;Jeon, Tae-Hoon;Nam, Seung-Won;Kim, Youn-Joong
    • Applied Microscopy
    • /
    • v.40 no.3
    • /
    • pp.155-162
    • /
    • 2010
  • Bone is a hierarchically structured composite material which has been well studied by the materials engineering community because of its unique structure and mechanical properties. Bone is a laminated organic-inorganic composite composed of primarily hydroxyapatite, collagen and water. The main mineral that gives bone's hardness is calcium phosphate, which is also known as hydroxyapatite. Light microscopy (LM) and transmission electron microscopy (TEM) were used to study the structure of femurs from chicken and rabbit. The elemental analysis was used to search variation in the distribution of calcium, potassium and oxygen in the femur. Current investigation focused on two structural scales: micro scale (arrangement of compact bone) and nano scale (collagen fibril and apatite crystals). At micro scale, distinct difference was found in microstructures of chicken femur and rabbit femur. At nano scale, we analyzed the shape and size of apatite crystals and the arrangement of collagen fibril. Consequently, femurs of chicken and rabbit had very similar chemical property and structures at nano scale despite of their different species.

Thermomechanical Characteristics of Poly(vinyl alcohol)/Chitosan Films and Its Blend Hydrogels (폴리(비닐 알코올)/키토산 블렌드와 블렌드 수화젤의 열특성)

  • Park Jun Seo;Park Jang Woo;Kim Byung Ho
    • Polymer(Korea)
    • /
    • v.29 no.2
    • /
    • pp.183-189
    • /
    • 2005
  • Films of poly(vinyl alcohol)(PVA)/chitosan blends and its blend hydrogels were prepared by the solution casting method. The state of miscibility of the blends and blend hydrogels were examined over the entire composition range by differential scanning carorimetry (DSC), thermogravimetry (TGA), and dynamic mechanical analysis (DMA). DSC analysis shows the depression of melting point of PVA in the blends and the decrease of crystallization temperature of PVA in the blends were observed with increasing chitosan content in the blends. TGA analysis indicates that chitosan was thermally more stable than PVA and the thermal stability of PVA in the blends was higher than that of pure PVA, due to some interactions between two component polymers in the blend. The glass transition temperature $(T_g)$ of the chitosan and of PVA, measured by DMA, were at 160 and $90^{\circ}C$, respectively. The $T_g$ of the blends was changed with the content of chitosan in the blends. The results of thermal and viscoelastic analysis indicate some miscibility between component polymers in the blend exists. Moisture and cross linking in the blend and blend hydrogel, which strongly change thermal and physical properties of hydrophilic polymers, affected the miscibility of chitosan and PVA to a small extent.

Performance Evaluation of Bio-Composites Composed of Acetylated Kenaf Fibers and Poly(lactic acid) (PLA) (아세틸화 케나프 섬유와 폴리락트산으로 구성된 바이오복합재료의 물성 평가)

  • Chung, T.J.;Lee, B.H.;Lee, H.J.;Kwon, H.J.;Jang, W.B.;Kim, H.J.;Eom, Y.G.
    • Elastomers and Composites
    • /
    • v.46 no.3
    • /
    • pp.195-203
    • /
    • 2011
  • Eco-friendly materials or bio-composites were made with poly(lactic acid) (PLA) as matrix polymer and kenaf fibers as filler. Also, acetylated kenaf fibers and compatibilizer were adopted in order to improve the interfacial adhesion between fiber and polymer. In this study, the effect of chemical modification and compatibilizer on the mechanical-viscoelastic and morphology properties of the bio-composites was discussed. The hydrophobic fibers by acetylation were known to show better interfacial bonding with the matrix polymer and resulted in improved performance and morphology. Viscoelastic property and glass transition temperature, however, were not nearly enhanced.

Fabrication and characterization of glass with E-glass fiber composition by using silica-alumina refused coal ore (사암계 석탄폐석을 활용한 E-glass fiber 조성의 유리 제조 및 특성)

  • Lee, Ji-Sun;Lim, Tae-Young;Lee, Mi-Jai;Hwang, Jonghee;Kim, Jin-Ho;Hyun, Soong-Keun
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.23 no.4
    • /
    • pp.180-188
    • /
    • 2013
  • The glass of E-glass fiber composition was fabricated by using refused coal ore which is obtained as by-product from Dogye coal mine in Samcheok. We used silica-alumina refused coal ore which has low carbon content relatively, and the amount of refused coal ore has been changed from 0 to 35 % in batch composition. E-glass was fabricated by the melting of mixed batch materials at $1550^{\circ}C$ for 2 hrs with different refused coal ore composition of 0~35 %. We obtained a transparent and clear glass with high visible light transmittance value of 81~84%, thermal expansion coefficient of $5.39{\sim}5.61{\times}10^{-6}/^{\circ}C$ and softening point of $851{\sim}860^{\circ}C$. The glass fiber samples were also obtained through fiberizing equipment at $1150^{\circ}C$, and tested chemical resistance and tensile strength to evaluate the mechanical property as a reinforced glass fiber of composite material. As the result, we identified the properties of E-glass fiber by using refused coal ore are plenty good enough compare to that of normal E-glass without refused coal ore, and confirmed the possibility of refused coal ore as for the raw material of E-glass fiber.

The study on Comparison Evaluation of Shear Bond Strength of Co-Cr Based Alloy using for Porcelain Fused Metal (도재용착주조관용 Co-Cr계 비귀금속 합금의 전단결합강도 비교평가에 관한 연구)

  • Kim, Hee-Jin;Kim, Bu-Sob
    • Journal of Technologic Dentistry
    • /
    • v.32 no.3
    • /
    • pp.195-207
    • /
    • 2010
  • Purpose: The purpose of this study was to observe the microstructural changes of surface in the specimens, performing the shear bond strength testing. The currently most used non-precious alloys are nickel-chromium based alloys with or without beryllium. However, their biocompatibility has been questioned concerning possible damages to the health of the patient and professionals involved in the fabrication of prosthesis caused by long exposure to Ni and Be. An option to nickel-chromium alloys is the cobalt-chromium alloy, an alternative that does not sacrifice the physical properties of the metal porcelain systems. Studies in the animals substantially show that the cobalt-chromium alloys are relatively well tolerated, being therefore more biocompatible than the nickel-chromium alloys. Methods: Non-addition Be to nickel-chromium based alloy(Bellabond plus) and cobalt-chromium alloy which has been widely used(Wirobond C) fused with ZEO light porcelain classified control group and cobalt-chromium alloy which is developing alloy of Alphadent company in Korea(Alphadent alloy) fused with ZEO light porcelain classified experimental group. The specimens of $4mm{\times}4mm{\times}0.5mm$ were prepared as-cast and as-opaque to cast body to analyze the mechanical characteristic change, the microstructure of alloy surface. The phase change was used to observe through XRD analysis and OM/SEM was used to observe the surface of specimens as-cast and as-opaque to cast body. Chemical formation of their elements was measured with EDS. Then hardness was measured with Micro Vicker's hardness tester. Shear bond strength test thirty specimens of $10mm{\times}10mm{\times}2mm$ was prepared, veneered, 3mm high and 3mm in diameter, over the alloy specimens. The shear bond strength test was performed in a universal testing machine(UTM) with a cross head speed of 0.5mm/min. Ultimate shear bond strength data were analyzed with one-way ANOVA and the Scheffe's test (P<0.05). Within the limits of this study, the following conclusions were drawn: The X-ray diffraction analysis results for the as-cast and as-opaque specimens showed that the major relative intensity of Bellabond plus alloy were changed smaller than Wirobond C and Alphadent Co-Cr based alloys. Results: Microstructural analysis results for the opaque specimens showed all the alloys increased carbides and precipitation(PPT). Alphadent Co-Cr based alloy showed the carbides of lamellar type. The Vickers hardness results for the opaque specimens showed Wirobond C and Alphadent Co-Cr based alloys were increaser than before ascast, but Bellabond plus alloy relatively decreased. The mean shear bond strengths (MPa) were: 33.11 for Wirobond C/ZEO light; 25.00 for Alphadent Co-Cr alloy/ZEO light; 18.02 for Bellabond plus/ZEO light. Conclusion: The mean shear bond strengths for Co-Cr and Ni-Cr based alloy were significantly different. But the all groups showed metal-metal oxide modes in shear bond strengths test at the interface.

Preparation and characteristics of $HfO_2$ and $CeO_2$ doped 3Y-TZP block for dental ceramic block ($HfO_2$$CeO_2$가 첨가된 3Y-TZP 치과용 블록의 제조 및 특성 평가)

  • Ji, Sang-Yong;Ji, Hyung-Bin;Park, Hong-Chae;Yoon, Seog-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.19 no.6
    • /
    • pp.311-317
    • /
    • 2009
  • 3Y-TZP block doped with $HfO_2$ and $CeO_2$ for dental ceramic block to the proliferation of CAD/CAM systems was prepared by heating at $800{\sim}1100^{\circ}C$ and then sintering at $1450^{\circ}C$. The influences of heating temperature and addition of $HfO_2$ and $CeO_2$ on the mechanical and chemical properties of 3Y-TZP block were investigated. Using the EDS mapping images, $HfO_2$ and $CeO_2$ was well dispersed in the 3Y-TZP matrix. 3 wt% $HfO_2$ doped block showed the optimum biaxial strength (1 GPa), while 3 wt% $CeO_2$ doped block enhanced the stability of $t-ZrO_2$ under hydrothermal atmosphere.

Recycling of Plant Fiber Resources: Enhanced Hydration of Newspaper Stock for Decrease of Deinking Reject (식물유래 섬유자원의 재활용: 탈묵 수율 개선을 위한 신문 지료의 수화 촉진 방안)

  • Chung, Sung-Hyun;Kim, Joong-Ho;Joo, Jong-Hun;Bang, Jae-Wook
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
    • /
    • 2011.10a
    • /
    • pp.39-41
    • /
    • 2011
  • The recycling rate of recovered paper in Korea is the highest in the world, 92%, but remanufacturing yield is low due to the extremely poor quality of the paper. The poor quality, in turn, influences to the reject amount in deinking process. To increase the yield of old newspaper recycling process, hydrophobic degree of inorganic pigments of deinking stock must be reduced. To determine the hydrophobicity, Pitch Potential Deposit Tester (PDT) was newly designed and applied with respect to the SB latex property of various quality used in Korea; its hydrophobic degree according to Tg, gel content, charge and particle size of latex and optimum designing condition of SB latex. And below are the conclusions: 1. The reason of excessive reject from old newspaper deinking process for total amount of printed ink is loss of inorganic pigments. When lipase, a biochemical catalyst, was applied with the purpose of preventing inorganic pigments loss about more than 70% of total reject weight and promoting hydration of pulp for deinking, deinking process yield of pre flotation secondary stage increased remarkably without any changes of deinking efficiency. 2. Lipase improved deinking stock by cutting ester linkage on surface of hydrophobic materials to promote its hydration. From this, it reached the conclusion that hydration degree of stock exercises significant effect on flotation deinking process yield. 3. Inorganic alkali promotes hydration of deinking stock. But there have been needs for more fundamental measures other than inorganic alkali of promoting hydration for yield improvement. For this, this study intended to find out reasons of chemical properties change on surface of hydrophobic material by change of pH. 4. Pitch Deposit Test (PDT) was performed for understanding principle of why surface of coating flake from OMG is hydrophobic and why it becomes hydrophilic when pH of stock is alkaline. As a result of this test, it is determined that swelling property by change of pH of latex film, which were used as coating adhesive is the reason for hydrophobic change. 5. Hydrophilicity of coating flake increased with hydrophilic pigments. And as more of SB Latex adhesive was used and higher of calcium hardness of stock became, its hydrophilicity decreased. SB Latex adhesive film is reformed by mechanical friction. For having hydrophilicity under neutral pH, strong bruising action such as kneading is required. 6. Because swelling of adhesive film decreases as Tg of SB latex gets lower and mean diameter gets smaller, it shows hydrophobicity under neutral pH. This lowers hydrophilicity of coating flake, which leads to easy elimination with flotation reject on DIP process. Therefore, for improving future flotation yield, it is necessary to develop to use eco-friendly clean SB latex by raising Tg and increasing mean diameter for recycling, and as a result, to reduce excessive loss of coating flake as a reject from deinking process.

  • PDF

Fabrication of Field Emitter Arrays by Transferring Filtered Carbon Nanotubes onto Conducting Substrates

  • Jang, Eun-Soo;Goak, Jung-Choon;Lee, Han-Sung;Lee, Seung-Ho;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2009.06a
    • /
    • pp.311-311
    • /
    • 2009
  • Carbon nanotubes (CNTs) belong to an ideal material for field emitters because of their superior electrical, mechanical, and chemical properties together with unique geometric features. Several applications of CNTs to field emitters have been demonstrated in electron emission devices such as field emission display (FED), backlight unit (BLU), X-ray source, etc. In this study, we fabricated a CNT cathode by using filtration processes. First, an aqueous CNT solution was prepared by ultrasonically dispersing purified single-walled CNTs (SWCNTs) in deionized water with sodium dodecyl sulfate (SDS). The aqueous CNT solution in a milliliter or even several tens of micro-litters was filtered by an alumina membrane through the vacuum filtration, and an ultra-thin CNT film was formed onto the alumina membrane. Thereafter, the alumina membrane was solvated by acetone, and the floating CNT film was easily transferred to indium-tin-oxide (ITO) glass substrate in an area defined as 1 cm with a film mask. The CNT film was subjected to an activation process with an adhesive roller, erecting the CNTs up to serve as electron emitters. In order to measure their luminance characteristics, an ITO-coated glass substrate having phosphor was employed as an anode plate. Our field emitter array (FEA) was fairly transparent unlike conventional FEAs, which enabled light to emit not only through the anode frontside but also through the cathode backside, where luminace on the cathode backside was higher than that on the anode frontside. Futhermore, we added a reflecting metal layer to cathode or anode side to enhance the luminance of light passing through the other side. In one case, the metal layer was formed onto the bottom face of the cathode substrate and reflected the light back so that light passed only through the anode substrate. In the other case, the reflecting layer coated on the anode substrate made all light go only through the cathode substrate. Among the two cases, the latter showed higher luminance than the former. This study will discuss the morphologies and field emission characteristics of CNT emitters according to the experimental parameters in fabricating the lamps emitting light on the both sides or only on the either side.

  • PDF