• Title/Summary/Keyword: chemical analysis tests

Search Result 414, Processing Time 0.025 seconds

The Effect of Improved Crosslink Density on the Properties of Waterborne Polyurethanes Using Sol-Gel Process (졸-겔 법을 통한 수분산형 폴리우레탄 합성 및 가교밀도 개선에 따른 성능 연구)

  • Kim, Young Ryul;Park, Jin Hwan
    • Corrosion Science and Technology
    • /
    • v.15 no.6
    • /
    • pp.297-302
    • /
    • 2016
  • Water-based systems are dominating the coating market because of worldwide VOCs regulations. Research is focusing especially on waterborne polyurethane (WPU) because of its unique mechanical and chemical properties. However, commercial WPU consists of linear thermoplastic polymers with polar groups on the main chain, which do not perform as well as solvent-borne PU in a two-pack system. In this study, APTES were used as a chain crosslink agent to overcome commercial WPU's limited performance. WPUs synthesized by using a sol-gel process were evaluated with FT-IR, particle analysis, TGA, tensile tests, pull-off tests, SEM, and EIS. The results showed that WPUs with added APTES had better thermal stability, mechanical properties, and water resistance than did WPUs without added APTES. Consequently, the sol-gel process increased the crosslink density of WPUs and modified the WPU's own properties.

Effect of the PC, diatomite and zeolite on the performance of concrete composites

  • Kocak, Yilmaz;Savas, Muhsin
    • Computers and Concrete
    • /
    • v.17 no.6
    • /
    • pp.815-829
    • /
    • 2016
  • This study has been carried out to investigate the effect of the surface properties of Portland cement, diatomite and zeolite on the performance of concrete composites. In this context, to describe the materials used in this study and determine the properties of them, chemical, physical, mineralogical, molecular, thermal, and zeta potential analysis have been applied. In the study, reference (Portland cement), 10%-20% diatomite, 10%-20% zeolite, 5+5%-10+10% diatomite and zeolite were substituted for Portland cement, a total of 7 different cements were obtained. Ultrasonic pulse velocity, capillary water absorption and compressive strength tests were performed on the hardened concrete specimens. Hardened concrete tests have been done on seven different types of concrete, for 28, 56 and 90 days. As a result of experiments it has been identified that both the zeolite and diatomite substitution has a positive effect on the performance of concrete.

Environmental Characteristics of Waste Tire for Use as Soil Reinforcement (지반보강재로서 폐타이어 사용에 따른 환경영향 분석)

  • Cho, Jinwoo;Lee, Yongsoo
    • Journal of the Korean GEO-environmental Society
    • /
    • v.14 no.1
    • /
    • pp.61-68
    • /
    • 2013
  • This paper presents an experimental results on the environmental characteristics of waste tire. Experimental program includes a set of laboratory leaching tests and field pilot test for leachate analysis. Laboratory tests were conducted to illustrate how properties such as TOC, pH, turbidity and Zn change with tire sizes and drain conditions. In field pilot test, water samples were collected form a drainage system installed below the tire-reinforced retaining wall and analyzed for chemical quality. Laboratory leaching tests performed on various particle sizes of waste tire indicated that as tire size is increased, the concentration of leachate is decreased. In continuous flow column tests, the concentration of leachate decreased with the number of exposure periods or pore volumes flushed through the waste tire. However, during pause flow column tests, the concentration of leachates were increased with time. Field monitoring of effluent indicated that no significant adverse effects on ground water quality had occurred over a period of 12 months.

Comparison of Digital PCR and Quantitative PCR with Various SARS-CoV-2 Primer-Probe Sets

  • Park, Changwoo;Lee, Jina;Hassan, Zohaib ul;Ku, Keun Bon;Kim, Seong-Jun;Kim, Hong Gi;Park, Edmond Changkyun;Park, Gun-Soo;Park, Daeui;Baek, Seung-Hwa;Park, Dongju;Lee, Jihye;Jeon, Sangeun;Kim, Seungtaek;Lee, Chang-Seop;Yoo, Hee Min;Kim, Seil
    • Journal of Microbiology and Biotechnology
    • /
    • v.31 no.3
    • /
    • pp.358-367
    • /
    • 2021
  • The World Health Organization (WHO) has declared the coronavirus disease 2019 (COVID-19) as an international health emergency. Current diagnostic tests are based on the reverse transcription-quantitative polymerase chain reaction (RT-qPCR) method, which is the gold standard test that involves the amplification of viral RNA. However, the RT-qPCR assay has limitations in terms of sensitivity and quantification. In this study, we tested both qPCR and droplet digital PCR (ddPCR) to detect low amounts of viral RNA. The cycle threshold (CT) of the viral RNA by RT-PCR significantly varied according to the sequences of the primer and probe sets with in vitro transcript (IVT) RNA or viral RNA as templates, whereas the copy number of the viral RNA by ddPCR was effectively quantified with IVT RNA, cultured viral RNA, and RNA from clinical samples. Furthermore, the clinical samples were assayed via both methods, and the sensitivity of the ddPCR was determined to be equal to or more than that of the RT-qPCR. However, the ddPCR assay is more suitable for determining the copy number of reference materials. These findings suggest that the qPCR assay with the ddPCR defined reference materials could be used as a highly sensitive and compatible diagnostic method for viral RNA detection.

Studies on the Variation of Physico-Chemical Characteristics During Storage and Frying (고추씨 기름의 저장 및 가열에 따른 이화학적 변화에 관한 연구)

  • Choi, Young-Jin;Ko, Young-Su
    • Korean journal of food and cookery science
    • /
    • v.6 no.2
    • /
    • pp.67-76
    • /
    • 1990
  • To observe the propability as the frying oil and oxidative stability of red pepper seed oil, some physico-chemical tests of the oil were examined during 21 days storage period at 5$^{\circ}C$, 15$^{\circ}C$ and 30$^{\circ}C$, and AOM value determined and after heating the oil at 180${\pm}$5$^{\circ}C$ for 40 hours with or without antioxidants. The analysis storage stability of red pepper seed oil showed that the quality of storage group at 5$^{\circ}C$ was almost as good as fresh oil, and the storage group at 30$^{\circ}C$ showed certain degree of rancidity. Change of physico-chemical characteristic during storage were so small so that storage stability of red pepper seed oil was found to be good. AOM stability of red pepper seed oil was 7 hours which is lower than other vegetable oil, but the degree of stability grew greatly after adding phenolic antioxidants, such on TBHQ or PG. As for the chemical change after heating continuously for 40 hours, acid value, peroxide value and refractive index increased, but iodine value decreased as the heating processed. The fatty acid composition also showed the remarkable reduction of linoleic acid. The addition of antioxidants resulted in the delay of oxidation, the degree of which was greater in TBHQ than in PG.

  • PDF

Setting-Up of a Fischer-Tropsch Catalyst Testing Apparatus (Fischer-Tropsch 觸媒試驗裝置의 試作)

  • Lee, Chai-Sung;Koh, Kwang-Gook
    • Journal of the Korean Chemical Society
    • /
    • v.5 no.1
    • /
    • pp.66-72
    • /
    • 1961
  • A small size Fischer-Tropsch Catalyst testing apparatus, designed for an operating pressure of 150 psig, was test fabricated from ordinary schedule 40 iron pipes. The operability of the apparatus was tested by charging the reactor tube with the Lurgi Fischer-Tropsch iron Catalyst and passing through it the water gas obtained by gasifying the Korean anthracite using steam and oxygen. With the kind of catalyst charged, the apparatus was proven to daily produce about 50c.c. of synthetic greasy product, water and water soluble compounds, by running at a temperature of $250^{\circ}C$ and at a space velocity of 180 volume of gas per volume of catalyst/hr. About 20 consecutive days of operation is claimed to be sufficient for gathering an enough amount of synthetic products for such ordinary tests as distillation analysis, density measurement, iodine value determination etc. This trial fabrication of apparatus may be the first case of its kind in Korea in that the work has been conducted out in much a pilot plant scheme rather than a routine laboratory way which depends on small glass ware apparatus.

  • PDF

Comparison of Physicochemical Properties of Korean and Australian Wheat Flours Used to Make Korean Salted Noodles

  • Kim, In-Sook;Binns, Colin;Yun, Hon;Quail, Ken;Lee, Chi-Ho
    • Food Science and Biotechnology
    • /
    • v.16 no.2
    • /
    • pp.275-280
    • /
    • 2007
  • The effect of using Korean wheat flour versus Australian wheat flour on noodle quality as a result of differing physical and chemical properties of the flours was investigated. The results provided appropriate technical information for selection of wheat varieties to produce high quality Korean salted noodles. Noodle quality was quantified based on measurement of the appearance and texture of noodles. When consumer preference tests were conducted, a firmer and more elastic texture was preferred for Korean white salted noodles, however, when appearance was included in the consumer tests, noodles made with Australian wheat were favored over Korean wheats. Korean flour was found to produce firmer and more elastic noodles, whereas Australian flour produced brighter, creamier colored noodles. In flour quality tests, Korean flours were found to have a higher setback viscosity and lower swelling power than Australian flour. Additionally, Korean flours had higher water absorption values. Protein content of flour was an important parameter affecting the firmness of Korean noodles, whereas setback viscosity and swelling power were the major determinants of elasticity. Overall, the important parameters for determination of the quality of Korean salted noodles were high setback viscosity, low swelling power, and high protein content.

Wind-Resistant Safety Reviews of Cable-Stayed Bridge by Wind Tunnel Tests (풍동실험을 통한 사장교의 내풍 안전성 검토)

  • Huh, Taik-Nyung
    • Journal of the Korean Society of Industry Convergence
    • /
    • v.23 no.4_2
    • /
    • pp.637-644
    • /
    • 2020
  • Because suicide accidents sometimes were happened in grand bridges over rivers or sea water recently, it will be necessary that prevention measures be made preparation in advance from now on. Additional safety facilities must be needed in addition to existing safety facilities in such a way as this prevention measure. In order to make cable-stayed bridge safe on wind for additional safety facilities, main girder models with added safety facilities for wind-tunnel tests was made, and wind tunnel experiments was carried out to measure aerodynamic force coefficients. Also, wind-resistant analyses of 3D cable-stayed bridge were performed on the basis of wind-tunnel test results. From the wind experiments, force coefficients of main girder with added safety facilities were assessed, and it is known that there are little possibility of galloping and rotation of steel main girder. Finally, from the wind resistant analyses, it was concluded that wind-resistant safety of cable-stayed bridge was secured on wind speed 60.6m/sec.

Component Analysis and Reproduction of a Brown Solid Cosmetic Excavated from Tomb of Princess Hwahyeop (화협옹주 출토 화장품(갈색 고체) 성분 분석 및 재현연구)

  • Lee, Chaehoon;You, Song-e;Lee, Hanhyoung;Kim, Hyoyun;Kim, Seongmi;Chung, Yongjae
    • Journal of Conservation Science
    • /
    • v.36 no.5
    • /
    • pp.430-439
    • /
    • 2020
  • This study focused on analyzing solid brown cosmetic residues that were excavated from the tomb of the Hwahyeop princess. The cosmetics had been buried in 1752 in Cheonghwa Baekja (small porcelain jars) within a Huigwakham (a stone box sealed with lime). A literature search and chemical analyses of the relics were conducted at the National Palace Museum of Korea. Based on the results of these analyses, raw materials and manufacturing methods for reproduction of the cosmetic were selected and then cream-form cosmetics were prepared. Aging tests using heat, ultraviolet (UV) radiation, and CO2 were carried out to emulate the deterioration of the excavated cosmetics. Further chemical analyses and functionality tests were performed to evaluate changes from the tests and the effect as a cosmetic. As heat aging progressed, among the reproduced cosmetics, the one which has a high proposition of oil showed a color difference value of 32; the oxidation of oils involved chemical changes in O-H and C=C groups. As the cosmetic cream deteriorated under UV aging, the pH value became acidic. The result of the functional coverage test of the reproduced cosmetic cream was lower than the standard coverage ratio of modern cosmetics.

A Study on Acceleration Aging Characteristics of B-KNO3 Igniter (B-KNO3 점화제의 가속 노화 특성 연구)

  • Paik, Jong Gyu;Ryu, Byung Tae;Kwon, Mira
    • Korean Chemical Engineering Research
    • /
    • v.52 no.2
    • /
    • pp.166-174
    • /
    • 2014
  • This research investigated the aging properties of the $B-KNO_3$ system as the igniter. The $B-KNO_3$ system showed the degradation in ignition properties depending on the method and period of storage. It should be found out the cause of the degradation to predict the reliability of the igniters. The changes of the properties by the degradation after aging tests were analyzed by microstructure analysis, XRD analysis and thermal analysis using DSC. It was found out that the lattice parameters of the $KNO_3$ as the oxidizer in the ignition system was changed into the JCPDS values as the aging time increased. Conclusively, the changes of the crystal structure of oxidizer affected the activation energy increasing as aging time increased.