• Title/Summary/Keyword: charge storage density

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Characterization of manganese oxide supercapacitors using carbon cloth (Carbon Cloth을 이용한 이산화망간 슈퍼커패시터 특성 연구)

  • Lee, Seung Jin;Kim, Chihoon;Ji, Taeksoo
    • Journal of Digital Contents Society
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    • v.18 no.6
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    • pp.1199-1205
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    • 2017
  • Global energy consumption is rapidly increasing yearly due to drastic industrial advances, requiring the development of new energy storage devices. For this reason, supercapacitors with fast charge-discharge, long life cycle and high power density is getting attention, and have been considered as one of the potential energy storage systems. In this research, we developed a supercapacitor that consists of amorphous manganese oxide($MnO_2$) electrodes deposited onto carbon cloth substrates using the hydrothermal method. The Fe-doped amorphous $MnO_2$ samples were characterized by X-ray diffraction(XRD), Energy Dispersive X-ray spectroscopy(EDX), as well as scanning electron microscopy(SEM). The electrochemical analysis of the prepared samples were performed using cyclic voltammetry and galvanostatic charge-discharge measurements in 1M $Na_2SO_4$ electrolyte. The test results demonstrate that the supercapacitor based on the Fe-doped amorphous $MnO_2$ electrodes has a specific capacitance as high as 163F/g at 1A/g current density, and good cycling stability of 87.34% capacitance retention up to 1000 cycles.

Thermo-piezoelectric $Si_3N_4$ cantilever array on n CMOS circuit for probe-based data storage using wafer-level transfer method (웨이퍼 본딩을 이용한 탐침형 정보 저장장치용 열-압전 켄틸레버 어레이)

  • Kim Young-Sik;Nam Hyo-Jin;Lee Caroline Sunyoung;Jin Won-Hyeog;Jang Seong.Soo;Cho Il-Joo;Bu Jong Uk
    • 정보저장시스템학회:학술대회논문집
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    • 2005.10a
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    • pp.22-25
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    • 2005
  • In this research, a wafar-level transfer method of cantilever array on a conventional CMOS circuit has been developed for high density probe-based data storage. The transferred cantilevers were silicon nitride ($Si_3N_4$) cantilevers integrated with poly silicon heaters and piezoelectric sensors, called thermo-piezoelectric $Si_3N_4$ cantilevers. In this process, we did not use a SOI wafer but a conventional p-type wafer for the fabrication of the thermo-piezoelectric $Si_3N_4$ cantilever arrays. Furthermore, we have developed a very simple transfer process, requiring only one step of cantilever transfer process for the integration of the CMOS wafer and cantilevers. Using this process, we have fabricated a single thermo-piezoelectric $Si_3N_4$ cantilever, and recorded 65nm data bits on a PMMA film and confirmed a charge signal at 5nm of cantilever deflection. And we have successfully applied this method to transfer 34 by 34 thermo-piezoelectric $Si_3N_4$ cantilever arrays on a CMOS wafer. We obtained reading signals from one of the cantilevers.

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Method of Minimizing ESS Capacity for Mitigating the Fluctuation of Wind Power Generation System (풍력발전의 출력 변동 저감을 위한 ESS 최소용량 산정기법)

  • Kim, Jae-Hong;Kang, Myeong-Seok;Kim, Eel-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.31 no.5
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    • pp.119-125
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    • 2011
  • In this paper, we have studied about minimizing the Energy Storage System (ESS) capacity for mitigating the fluctuation of Wind Turbine Generation System (WTGS) by using Electric Double Layer Capacitor (EDLC) and Battery Energy Storage System (BESS). In this case, they have some different characteristics: The EDLC has the ability of generating the output power at high frequency. Thus, it is able to reduce the fluctuation of WTGS in spite of high cost. The BESS, by using Li-Ion battery, takes the advantage of high energy density, however it is limited to use at low frequency response. To verify the effectiveness of the proposed method, simulations are carried out with the actual data of 2MW WTGS in case of worst fluctuation of WTGS is happened. By comparing simulation results, this method shows the excellent performance. Therefore, it is very useful for understanding and minimizing the ESS capacity for mitigating the fluctuation of WTGS.

Compensation of Power Fluctuations of PV Generation System by SMES Based on Interleaving Technique

  • Kim, Seung-Tak;Park, Jung-Wook
    • Journal of Electrical Engineering and Technology
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    • v.10 no.5
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    • pp.1983-1988
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    • 2015
  • This paper proposes the enhanced application of superconducting magnetic energy storage (SMES) for the effective compensation of power fluctuations based on the interleaving technique. With increases in demand for renewable energy based photovoltaic (PV) generation system, the output power fluctuations from PV generation system due to sudden changes in environmental conditions can cause serious problems such as grid voltage and frequency variations. To solve this problem, the SMES system is applied with its superior characteristics with respect to high power density, fast response for charge and discharge operations, system efficiency, etc. In particular, the compensation capability is effectively improved by the proposed interleaving technique based on its parallel structure. The dynamic performance of the system designed using the proposed method is evaluated with several case studies through time-domain simulations.

Flexible and Transparent Plastic Electrodes Composed of Reduced Graphene Oxide/Polyaniline Films for Supercapacitor Application

  • Sarker, Ashis K.;Hong, Jong-Dal
    • Bulletin of the Korean Chemical Society
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    • v.35 no.6
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    • pp.1799-1805
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    • 2014
  • In this article, we described about the preparation and electrochemical properties of a flexible energy storage system based on a plastic polyethylene terephthalate (PET) substrate. The PET treated with UV/ozone was fabricated with multilayer films composed of 30 polyaniline (PANi)/graphene oxide (GO) bilayers using layer-by-layer assembly of positively charged PANi and negatively charged GO. The conversion of GO to the reduced graphene oxide (RGO) in the multilayer film was achieved using hydroiodic acid vapor at $100^{\circ}C$, whereby PANi structure remained nearly unchanged except a little reduction of doping state. Cyclic voltammetry and charge/discharge curves of 30 PANi/RGO bilayers on PET substrate (shorten to PANi-$RGO_{30}$/PET) exhibited an excellent volumetric capacitance, good cycling stability, and rapid charge/discharge rates despite no use of any metal current collectors. The specific capacitance from charge/discharge curve of the PANi-$RGO_{30}$/PET electrode was found to be $529F/cm^3$ at a current density of $3A/cm^3$, which is one of the best values yet achieved among carbon-based materials including conducting polymers. Furthermore, the intrinsic electrical resistance of the PANi-$RGO_{30}$/PET electrodes varied within 20% range during 200 bending cycles at a fixed bend radius of 2.2 mm, indicating the increase in their flexibility by a factor of 225 compared with the ITO/PET electrode.

An Experimental Study on the Charging/Discharging Characteristics and Safety of Lithium-Ion Battery System for Submarine Propulsion (잠수함 추진용 리튬이온전지 충방전 특성 및 안전성 확보를 위한 실험적 연구)

  • Kim, Beomseog;Sohn, Seung hyun;Kang, Seokjoong
    • Journal of the Society of Naval Architects of Korea
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    • v.58 no.4
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    • pp.225-233
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    • 2021
  • Conventional submarine propulsion batteries have mainly used lead acid batteries, which have proved relatively safe, but in recent years, research on mounting lithium-ion batteries to improve the underwater operation capability of submarines is underway in advanced countries such as Japan. Korea has world-class technology in the development of electric vehicles and lithium-ion batteries for energy storage, but fire safety accidents continue to occur in electric vehicles and energy storage lithium-ion batteries. In order to mount the lithium-ion battery in a submarine, it is necessary to check the safety as well as whether the performance is improved compared to the lead acid battery. Through the charge/discharge experiment of this lithium-ion battery module unit, it was possible to measure how much performance was improved compared to the lead acid battery. Safety tests were conducted on the lithium-ion battery module assuming that it was mounted on a submarine, and it was confirmed that safety was secured when applied to a submarine. Since many modules are mounted on actual submarines, it has been confirmed that it can be applied to submarine systems by simulating charge/discharge characteristics through Hardware-in-the Loop(HILS). Through the results of this study, the application of lithium-ion batteries to submarines is expected to significantly improve the sustainability of underwater operations.

Preparation and Electrical Properties of $SrTiO_3$ Thin Films by Plasma Enhanced Metal Organic Chemical vapor Deposition (PE-MOCVD에 의한 $SrTiO_3$ 박막의 제조 및 전기적 특성에 관한 평가)

  • 김남경;윤순길
    • Journal of the Korean Ceramic Society
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    • v.33 no.2
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    • pp.177-182
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    • 1996
  • strontium titanate (SrTiO3) thin films deposited on Pt/MgO were prepared by Plasma Enhanced Metal Orgainc Chemical vapor Deposition (Pe-MOCVD). The crystallinity of SrTiO3 thin films increased with increasing depo-sition temperature and SrF2 second phase disappeared at 55$0^{\circ}C$ The films showed a dielectric constant of 177 and a dissipation factor of 0.0195 at 100 kHz. The variation of capacitance of the films with applied voltage was small showing paraelectric properties. The charge storage density and leakage current density were 40fC/${\mu}{\textrm}{m}$2 and 3.49$\times$10-7 A/cm2 at 0.25 MV/cm, respectively.

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Characteristics of nickel cobalt oxide (NiCo2O4) nanosheet electrodes prepared by hydrothermal synthesis and heat treatment (수열합성법으로 제조된 니켈코발트산화물(NiCo2O4) 나노시트 전극의 특성)

  • Lee, Seokhee;Cha, Hyunjin;Lee, Sangwoon;Kim, Juna;Park, Jeonghwan;Hwang, Donghyun;Son, Young Guk
    • Journal of the Korean institute of surface engineering
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    • v.55 no.1
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    • pp.32-37
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    • 2022
  • In a carbon-zero social atmospher, research is underway to reduce the use of fossil fuels. Interest in cleaner energy sources and their storage system is growing, and among them, research on effective energy storage is being actively conducted. Energy storage system(ESS) can be divided into secondary batteries, fuel cells, and capacitors, and the superiority of energy density of secondary batteries has a dominent influence on the ESS market. However, as problems with secondary batteries, charge/discharge speed, safety, and deterioration of electrodes are being highlighted. In this study, an electrode for supercapacitor with superior charge/discharge speed and specific capacitance is manufactured. The manufactured spinel nickel cobalt electrodes had specific capacitances of 1018.8 F/g, 690.8 F/g, and 475.1 F/g at 1 A/g in 1 M KOH electrolyte, and shows a performance retention rate of 77.48%, 63.30%, and 58.16% after 2000cycles at 7 A/g.

Electrochemical Characteristics of Hybrid Cell Consisting of Li Secondary Battery and Supercapacitor (리튬이차전지와 슈퍼커패시터로 구성된 하이브리드 셀의 전기화학적 특성)

  • KIM1, SANGGIL;GIL, BOMIN;HWANG, GABJIN;RYU, CHEOLHWI
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.1
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    • pp.43-48
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    • 2019
  • This study investigates the electrochemical characteristics of the hybrid cell that combined the advantageous characteristics of Li secondary battery and supercapacitor, high energy density and high power density, respectively. Electrochemical behaviors of the hybrid cell was characterized by charge/discharge, cycle and impedance tests. The hybrid cell using Li secondary battery and supercapacitor had better discharge capacity and cycle performance than that of using Li secondary battery only. Proper design of such a hybrid cell system is expected to result in substantial benefits to the well being of the Li secondary battery. The hybrid cell involving Li secondary battery for high energy density and supercapacitor for high power density may be the possible solution for future energy storage system.

Efficient cell design and fabrication of concentration-gradient composite electrodes for high-power and high-energy-density all-solid-state batteries

  • Kim, Ju Young;Kim, Jumi;Kang, Seok Hun;Shin, Dong Ok;Lee, Myeong Ju;Oh, Jimin;Lee, Young-Gi;Kim, Kwang Man
    • ETRI Journal
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    • v.42 no.1
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    • pp.129-137
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    • 2020
  • All-solid-state batteries are promising energy storage devices in which high-energy-density and superior safety can be obtained by efficient cell design and the use of nonflammable solid electrolytes, respectively. This paper presents a systematic study of experimental factors that affect the electrochemical performance of all-solid-state batteries. The morphological changes in composite electrodes fabricated using different mixing speeds are carefully observed, and the corresponding electrochemical performances are evaluated in symmetric cell and half-cell configurations. We also investigate the effect of the composite electrode thickness at different charge/discharge rates for the realization of all-solid-state batteries with high-energy-density. The results of this investigation confirm a consistent relationship between the cell capacity and the ionic resistance within the composite electrodes. Finally, a concentration-gradient composite electrode design is presented for enhanced power density in thick composite electrodes; it provides a promising route to improving the cell performance simply by composite electrode design.