• Proceedings of the SAREK Conference
• /
• 2006.06a
• /
• pp.58-63
• /
• 2006

In this study, performance of 2 pure hydrocarbons and 3 mixtures was measured in an attempt to substitute R22 under 3 different temperature conditions. The mixtures were composed of R1270(propylene), R290(propane) and R152a. They were tested in a refrigerating bench tester with a hermetic rotary compressor The test bench provided about 3.5 kW capacity and water and water/glycol mixture were employed as the secondary heat transfer fluids. All tests were conducted under the same external conditions resulting in the average saturation temperatures of $7^{\circ}C/45^{\circ}C$ and $-7^{\circ}C/41^{\circ}C$ and $-21^{\circ}C/28^{\circ}C$ in the evaporator and condenser, respectively. Test results show that the coefficient of performance (COP) of these refrigerants is up to 11.54% higher than that of R22 in all temperature conditions. Compressor discharge temperatures were reduced by $14{\sim}31^{\circ}C$ with these fluids. There was no problem with mineral oil since the mixtures were mainly composed of hydrocarbons. The amount of charge was reduced up to 58% as compared to R22. Overall, these fluids provide good performance with reasonable energy savings without any environmental problem and thus can be used as long term alternatives for residential air-conditioning and heat pumping application.

• Journal of the Korean Electrochemical Society
• /
• v.22 no.3
• /
• pp.122-127
• /
• 2019

In this study, we investigate the electrochemical performance of lithium terephthalate (LTA) battery using graphite coated metal current collector to overcome the disadvantages of organic batteries which is high interfacial resistance between current collector and electrode. The LTA anode material is synthesized by acid-based ion exchange reaction without impurities. The contact properties between stick-type LTA-based electrode and graphite coated current collector are estimated by the cross-section SEM and EIS. The graphite coated current collector significantly reduced the interfacial resistance of the LTA battery. The second discharge capacities of bare current collector LTA and graphite coated current collector LTA batteries are 107.6 mAh/g and 148.8 mAh/g at 0.1C, respectively. The graphite coated current collector LTA batteries show higher cycle life, higher discharge capacity, and higher rate-capability than bare LTA batteries.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.63 no.4
• /
• pp.455-460
• /
• 2014

South Korea's power consumption is increasing every year. For stable electric power supply, more generation facilities are needed. But it is not easy to build nuclear power generation facilities, so provision of renewable energy is thought of as the solution. For the system's stable management, practical use of energy storing system is needed. Currently, pumping up electric power station is considered most useful. In this study, we have calculated the least amount of energy storing device by considering the renewable energy, HVDC, and change in power for the appliance of ESS in Jeju system, according to The 6th Basic Plan for Long-term Electricity Supply and Demand. Also we have calculated the amount of the battery and about the load equalizing effect to use battery as power storing device. Finally, we have calculated the reduction of electricity generation and the reduction of $CO_2$ emission with this study.

• Journal of the Korean Electrochemical Society
• /
• v.13 no.4
• /
• pp.246-250
• /
• 2010

In this study, nano-crystallized $Al_2O_3$ was coated on the surface of $LiFePO_4$ powders via a novel dry coating method. The influence of coated $LiFePO_4$ upon electrochemical behavior was discussed. Surface morphology characterization was achieved by transmission electron microscopy (TEM), clearly showing nano-crystallized $Al_2O_3$ on $LiFePO_4$ surfaces. Furthermore, it revealed that the $Al_2O_3$-coated $LiFePO_4$ cathode exhibited a distinct surface morphology. It was also found that the $Al_2O_3$ coating reduces capacity fading especially at high charge/discharge rates. Results from the cyclic voltammogram measurements (2.5-4.2 V) showed a significant decrease in both interfacial resistance and cathode polarization. This behavior implies that $Al_2O_3$ can prevent structural change of $LiFePO_4$ or reaction with the electrolyte on cycling. In addition, the $Al_2O_3$ coated $LiFePO_4$ compound showed highly improved area-specific impedance (ASI), an important measure of battery performance. From the correlation between these characteristics of bare and coated $LiFePO_4$, the role of $Al_2O_3$ coating played on the electrochemical performance of $LiFePO_4$ was probed.

• Journal of Energy Engineering
• /
• v.24 no.3
• /
• pp.74-81
• /
• 2015

Currently, the government is encouraging the introduction of energy storage system to reduce carbon emissions and peak power demand. The government is planning the cumulative capacity of ESS of 2GW in 2020. By utilizing charge and discharge of the ESS, it is possible to sell the surplus power to utility and electricity market. This paper suggests the model that economic feasibility of energy storage system for planning the construction of power generation facilities in 2035. Our results of simulation indicate the energy storage plan of utility for constructing renewable energy facilities is need to incentives from the government to encourage power utilities and expansion of ESS.

• Journal of the Korean Society for Heat Treatment
• /
• v.30 no.2
• /
• pp.61-66
• /
• 2017

$SnO_2$ was electrodeposited on nodule-type Cu foil at varing current density and electrodeposition time. Unlike the previous research results, when the anodic current is applied, the $SnO_2$ layer was not electrodeposited and the substrate is corroded. When the cathodic current was applied, the $SnO_2$ layer could be successfully deposited. At this time, the surface microstructure of the powdery type was observed, which showed similar crystallinity to amorphous and had a very large surface area. Crystallinity increased after low-temperature heat treatment at $250^{\circ}C$ or lower. As a result of evaluating the charge/discharge performances as an anode material for lithium ion battery, it was confirmed that the capacity of the heat treated $SnO_2$ was increased more than 2 times, but it still showed a limit point showing initial low coulombic efficiency and low cyclability. However, it was confirmed that the battery performances may be enhanced through optimizing the electrodeposition process and introducing post heat treatment.

• Journal of the Korean Applied Science and Technology
• /
• v.22 no.2
• /
• pp.142-150
• /
• 2005

The natural graphite particles A and heat-treated graphite particles B at $1800\;^{\circ}C$ after pitch-coating were used as the anode base materials for lithium ion secondary battery. In order to improve the performance of anode materials, the base anode materials were treated with various acids. With the acid treatments of 62% $HNO_3$ and 95% $H_2SO_4$ aqueous solution, the specific surface area and electrical conductivity of base anode materials were increased, and the initial charge-discharge capacity and cycle performance were improved due to the elimination of structural defects.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2001.07a
• /
• pp.713-716
• /
• 2001

In many papers, the electrochemical analysis of LiMn$_2$O$_4$shows the transition results of Mn$^{3+}$ ion. Charge ordering is accompanied by simultaneous orbital ordering due to the Jahn-Teller effect in Mnl$^{3+}$ ions. To analyze the cycle performance of LiMn$_{2-x}$Cu$_{x}$ O$_4$as the cathode of 4 V class lithium secondary batteries, XRD, TGA analysis were conducted. Although the cycle performance of the LiMn$_{2-x}$Cu$_{x}$ O$_4$was improved from pure LiMn$_2$O$_4$, the discharge capacity was significantly lower than LiCoO$_2$. In this paper, We study the Electrochemical characterization and enhanced stability of Cu-doped spinels in the LiMn$_{2-x}$Cu$_{x}$ O$_4$upon initial cycling.l cycling.

• Applied Chemistry for Engineering
• /
• v.8 no.4
• /
• pp.667-672
• /
• 1997

Thermal behavior of high capacity Nickel/Metal hybride battery in analyzed using the NISA software which is based on the three dimensional finite element method. Differential energy balance equation is used for the conduction heat transfer of the battery, while convective heat transfer equation is used for the interface between the battery and air. Heat generation rate and convective heat transfer coefficient are tested as variables to investigate thermal behavior, and the generalized equation for maximum temperature inside the battery is developed. The abrupt rise of the battery temperature due to the quick charge or discharge can be prevented from the use of metallic cooling fin. In addition, temperature augmentation of the battery is negligible when the low thermal conductive and thin insulating material is used outside of the battery case.

• Journal of the Korean Electrochemical Society
• /
• v.15 no.3
• /
• pp.160-164
• /
• 2012

The lead-acid batteries are the most often used in human life, because of their low cost, good reversibility and high potential but they have limit cycle ability with low capacitance. The main causes of this problem are forming recrystallization of $PbSO_4$ on electrodes surface during cycles which the recrystallization of $PbSO_4$ is known as sulfation. In this study, formation process of sulfation was investigated depending on charge and discharge cycle numbers. And we decomposed sulfation to renew cycle ability of lead-acid batteries. The renewed lead-acid batteries recovered to 84% compared to first capacity after 600 cycles.