• International Journal of Precision Engineering and Manufacturing-Green Technology
• /
• v.5 no.5
• /
• pp.637-642
• /
• 2018

The impact of the sintering process, especially in terms of sintering temperature and sintering aid concentration, on the ohmic transport and electrode performance of $(La_{0.80}Sr_{0.20})_{0.95}CoO_{3-{\delta}}$-gadolinia-doped ceria (LSCF-GDC) cathodes is studied. The ohmic and charge-transfer kinetics exhibit a highly coupled $Co_3O_4$ concentration dependency, showing the best performances at an optimum range of 4-5 wt%. This is ascribed to small grain sizes and improved connection between particles. The addition of $Co_3O_4$ was also found to have a dominant impact on charge-transfer kinetics in the LSCF-GDC composite layer and a moderate impact on the electronic transport in the current-collecting LSCF layer. Care should be taken to avoid a formation of excessive thermal stresses between layers when adding $Co_3O_4$.

• Applied Chemistry for Engineering
• /
• v.32 no.4
• /
• pp.385-392
• /
• 2021

In this study, impact of Co proportion and calcination temperature of ceria on the Co/CeO₂ was analyzed by comparing nitrogen monoxide oxidation performance of various catalysts and their physico-chemical properties. The structural properties of each catalyst were studied by XRD and BET analysis, and the surface crystal states of cobalt were proposed according to the surface density. Oxidation states of elements were observed through Raman and XPS analysis, and the relationship between typical oxidation states and nitrogen monoxide oxidation performance was designed. Through H₂-TPR, oxygen-transferring capacity due to changes in the characteristics of catalysts were identified, and activation sites (Co³⁺) for oxidation were suggested.

• Journal of Ceramic Processing Research
• /
• v.20 no.1
• /
• pp.18-23
• /
• 2019

Chemical looping combustion (CLC) is a promising carbon capture and storage (CCS) technology whose efficiency and cost primarily relies on the oxygen carrier materials used. In this paper, gadolinium-doped ceria (GDC, Ce0.9Gd0.1O1.95) was added as a promoter to improve the oxygen transfer rate of MgMnO3-δ oxygen carrier materials. Increasing GDC content significantly increased the oxygen transfer rate of MgMnO3-δ-GDC composites for the reduction reaction due to an increase in the surface adsorption of CH4 via oxygen vacancies formed on the surface of the GDC. On the other hand, the oxygen transfer rate for the oxidation reaction decreased linearly with increasing GDC content due to the oxygen storage ability of GDC. Adsorbed oxygen molecules preferentially insert themselves into oxygen vacancies of the GDC lattice rather than reacting with (Mg,Mn)O to form MgMnO3-δ during the oxidation reaction.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.32 no.2
• /
• pp.51-54
• /
• 2022

The physical properties of the noble metal current-collector used for fuel cells are greatly influenced by the material porosity. Therefore, increasing the porosity of the material studies has attracted much attention. One of the most representative strategies is to use porosity additives in sintering materials. The conventional porosity additive had a threedimensional structure of a spherical powder. In this study, porosity additive with 2-dimensional (2D) nanosheet was used to decrease the sintering density of Ag current-collector and its effect was confirmed. As a 2D layered structure material, 1 nm-thick RuO₂ nanosheets were used as porosity additives.

• Korean Journal of Materials Research
• /
• v.18 no.12
• /
• pp.660-663
• /
• 2008

Ni-GDC (gadolinia-doped ceria) composite powders, the anode material for the application of solid oxide fuel cells, were prepared by a solution reduction method using hydrazine. The distribution of Ni particles in the composite powders was homogeneous. The Ni-GDC powders were sintered at $1400^{\circ}C$ for 2 h and then reduced at $800^{\circ}C$ for 24 h in 3% $H_2$. The percolation limit of Ni of the sintered composite was 20 vol%, which was significantly lower than these values in the literature (30-35 vol%). The marked decrease of percolation limit is attributed to the small size of the Ni particles and the high degree of dispersion. The hydrazine method suggests a facile chemical route to prepare well-dispersed Ni-GDC composite powders.

• Proceedings of the KSME Conference
• /
• 2007.05b
• /
• pp.2021-2025
• /
• 2007

Performance of single cell at solid oxide fuel cell (SOFC) system is largely affected by electrocatalytic and thermal properties of cathode. Samarium-based perovskite oxide material is recently recognized as promising cathode material for intermediate temperature-operating SOFC due to its high electrocatalytic property. Perovskite structured $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$ and its composite material, $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}/Sm_{0.2}Ce_{0.8}O_{1.9}$ were investigated in terms of area specific resistance (ASR), thermal expansion coefficient (TEC), thermal cycling and long term performance. $Sm_{0.2}Ce_{0.8}O_{1.9}$ was used as electrolyte material. Electrochemical ac impedance spectroscopy (EIS) and dilatometer were used to measure the cathodic properties. Composite cathode ($Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$: $Sm_{0.2}Ce_{0.8}O_{1.9}$ = 6:4) showed a good ASR of 0.13${\Omega}$ $cm^2$ at 650$^{\circ}C$ and its TEC value was 12.3${\times}$10-6/K at 600$^{\circ}C$ which is similar to the value of ceria-based electrolyte of 11.9${\times}$10-6/K. Performance of composite cathode was maintained with no degradation even after 13 times thermal cycle test.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.402.1-402.1
• /
• 2016

The performance of solid oxide fuel cells (SOFCs) is directly related to the electrocatalytic activity of composite electrodes in which triple phase boundaries (TPBs) of metallic catalyst, oxygen ion conducting support, and gas should be three-dimensionally maximized. The distribution morphology of catalytic nanoparticle dispersed on external surfaces is of key importance for maximized TPBs. Herein in situ grown nickel nanoparticle onto the surface of fluorite oxide is demonstrated employing gadolium-nickel co-doped ceria ($Gd0.2-xNixCe0.8O2-{\delta}$, GNDC) by reductive annealing. GNDC powders were synthesized via a Pechini-type sol-gel process while maximum doping ratio of Ni into the cerium oxide was defined by X-ray diffraction. Subsequently, NiO-GNDC composite were screen printed on the both sides of yttrium-stabilized zirconia (YSZ) pellet to fabricate the symmetrical half cells. Electrochemical impedance spectroscopy (EIS) showed that the polarization resistance was decreased when it was compared to conventional Ni-GDC anode and this effect became greater at lower temperature. Ex situ microstructural analysis using scanning electron microscopy after the reductive annealing exhibited the exsolution of Ni nanoparticles on the fluorite phases. The influence of Ni contents in GNDC on polarization characteristics of anodes were examined by EIS under H2/H2O atmosphere. Finally, the addition of optimized GNDC into the anode functional layer (AFL) dramatically enhanced cell performance of anode-supported coin cells.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2013.02a
• /
• pp.130-131
• /
• 2013

Nanostructured oxides are widely used in heterogeneous catalysis where their catalytic properties are closely associated with the size and morphology at nanometer level. The effect of particle size has been well decumented in the past two decades, but the shape of the nanoparticles has rarely been concerned. Here we illustrate that the redox and acidic-basic properties of oxides are largely dependent on their shapes by taking $Co_3O_4$, $Fe_2O_3$, $CeO_2$ and $La_2O_3$ nanorods as typical examples. The catalytic activities of these rod-shaped oxides are mainly governed by the nature of the exposed crystal planes. For instance, the predominant presence of {110} planes which are rich in active $Co^{3+}$ on $Co_3O_4$ nanorods led to a much higher activity for CO oxidation than the nanoparticles that mainly exposed the {111} planes. The simultaneous exposure of iron and oxygen ions on the surface of $Fe_2O_3$ nanorods have significantly enhanced the adsorption and activation of NO and thereby promoted the efficiency of DeNOx process. Moreover, the exposed surface planes of these rod-shaped oxides mediated the reaction performance of the integrated metal-oxide catalysts. Au/$CeO_2$ catalysts exhibited outstanding stability under water-gas shift conditions owing to the strong bonding of gold particle on the $CeO_2$ nanorods where the formed gold-ceria interface was resistant towards sintering. Cu nanoparticles dispersed on $La_2O_3$ nanorods efficiently catalyzed transfer dehydrogenation of primary aliphatic alcohols based on the uniue role of the exposed {110} planes on the support. Morphology control at nanometer level allows preferential exposure of the catalytically active sites, providing a new stragegy for the design of highly efficient nanostructured catalysts.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.19 no.2
• /
• pp.145-152
• /
• 2006

The densification behavior and electrical conductivity of $Ce_{0.8}Gd_{0.2}O_{1.9}$ ceramics were investigated with the strontium gallate concentration ranging from 0 to $5\;mol\%$. Both the sintered density and grain size were found to increase rapidly up to $0.5\;mol\%$ $Sr_2Ga_2O_5$, and then to decrease with further addition. Dense $Ce_{0.8}Gd_{0.2}O_{1.9}$ ceramics with $97\%$ of the theoretical density could be obtained for $0.5\;mol\%$ $Sr_2Ga_2O_5$-added specimen sintered at $1250^{\circ}C$ for 5 h, whereas pure $Ce_{0.8}Gd_{0.2}O_{1.9}$ ceramics needed to be sintered at $1550^{\circ}C$ in order to obtain an equivalent theoretical density, Electrical conductivity was measured as a function of dopant content, over the temperature range of $350\;-\;600^{\circ}C$ in air. Total conductivity of $0.5\;mol\%$ $Sr_2Ga_2O_5$-added specimen showed the maximum conductivity of $2.37{\times}10^{-2}{{\Omega}-1}{\cdot}cm^{-1}$ at $500^{\circ}C$, The addition of strontium gallate was found to promote the sintering properties and electrical conductivities of $Gd_2O_3$-doped $CeO_2$.

• Transactions of the Korean hydrogen and new energy society
• /
• v.23 no.6
• /
• pp.640-646
• /
• 2012

The effect of Ce promotion over 1wt% $Pt/{\gamma}-Al_2O_3$ catalysts on the CO conversion and $CO_2$ selectivity was investigated in preferential CO oxidation (PrOx) to reduce the CO concentration less than 10 ppm in excess $H_2$ stream for polymer electrolyte membrane fuel cell (PEMFC). Ce-promoted 1wt% $Pt/{\gamma}-Al_2O_3$ catalysts were prepared by incipient wetness impregnation method and the loading amount of Pt was fixed at 1wt%. The content of Ce promoter which has excellent oxygen storage and transfer capability due to the redox property was adjusted from 0 to 1.5wt%. Ce-promoted 1wt% $Pt/{\gamma}-Al_2O_3$ catalysts exhibit high CO conversion and $CO_2$ selectivity at low temperatures below $150^{\circ}C$ due to the improvement of reducibility of surface PtOx species compared with the 1wt% $Pt/{\gamma}-Al_2O_3$ catalyst without Ce addition. When Ce content was more than 1wt%, the catalytic activity was decreased at over $160^{\circ}C$ in PrOx because of competitive $H_2$ oxidation. As a result, 0.5wt% Ce is optimal content not only to achieve high catalytic activity and good stability at low temperatures below $150^{\circ}C$ in the presence of $CO_2$ and $H_2O$ but also to minimize the $H_2$ oxidation at high temperatures.