• Title/Summary/Keyword: ceramic industry

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Investigation of Li Dopant as a Sintering Aid for ScSZ Electrolyte for IT-SOFC

  • Mori, Masashi;Liu, Yu;Ma, Shuhua;Hashimoto, Shin-ichi;Takei, Katsuhito
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.760-765
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    • 2008
  • In this study, the effects of small amounts (${\leq}3\;mol%$) of Li doping on the sintering characteristics and electrochemical performance of $(ZrO_2)_{0.89}(ScO_{1.5})_{0.1}(CeO_2)_{0.01}$ (ScSZ) were investigated. By adding 3 mol% lithium, the densification temperature of ScSZ was reduced from the conventional temperature of $1400^{\circ}C$ to $1200^{\circ}C$. It was found that Li doping also led to changes in the Zr:Sc ratio at the grain boundaries. Correspondingly, the dispersion of lithium zirconia at the grain boundaries accelerated the growth of ScSZ grains and increased the grain boundary resistance at temperatures below $450^{\circ}C$. At elevated temperatures of $450{\sim}750^{\circ}C$, the electrical conductivity of the ScSZ after doping remained almost unchanged under air and reducing atmospheres. These results suggest that the addition of lithium is promising for use in low temperature co-firing of ScSZ-based components for intermediate temperature solid oxide fuel cells.

Dielectric Properties of Complex Microstructure for High Strength LTCC Material (고강도 LTCC 소재을 위한 복합구조의 유전특성)

  • Kim, Jin-Ho;Hwang, Seong-Jin;Sung, Woo-Kyung;Kim, Hyung-Sun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.309-309
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    • 2007
  • The LTCCs (low-temperature co-fired ceramics) are very important for electronic industry to build smaller RF modules and to fulfill the necessity for miniaturization of devices in wireless communication industry. The dielectric materials with sintering temperature $T_{sint}$<$900^{\circ}C$ are required. In this study, we investigated with glass-ceramic composition, which was crystallized with two crystals. The microstructure, crystal phases, thermal and mechanical properties, and dielectric properties of the composites were investigated using FE-SEM, XRD, TG-DTA, 4-point bending strength test and LCR measurement. The starting temperature for densification of a sintered body was at $779{\sim}844^{\circ}C$ and the glass frits were formatted to the crystal phases, $CaAl_2Si_2O_8$(anorthite) and $CaMgSi_O_6$(diopside), at sintering temperature. The sintered bodies exhibited applicable dielectric properties, namely 6-9 for ${\varepsilon}_r$. The results suggest that the glass-ceramic composite would be potentially possible to application of low dielectric L TCC materials.

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Combustion Characterisitics of a Catalytic Combustorfor an Automotive Ceramic Gas Turbine (세라믹 가스 터빈용 촉매연소기의 연소특성)

  • Kim, Young-Il
    • Journal of the Korean Society of Industry Convergence
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    • v.1 no.2
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    • pp.49-54
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    • 1998
  • In the catalytic combustor, combustion characteristic and deterioration of catalysts were affected by non-uniformity of pre-mixed gas, Therefore, formation of uniform pre-mixed gas is one of important subjects. In this study, the effect of uniformity and non-uniformity of pre-mixed gas supplied to the catalyst was examined to clarify reaction acceleration and combustion characteristic of the catalytic combustion. It was clarified that static mixer or vaporizer tube length of about 150mm and weak swirl to a combustion air were effictive expedient to make uniform pre-mixed gas. And catalystic inlet temperature needs more than $600^{\circ}C$ with rich pre-mixed gas to active reaction.

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Nanocomposite Ni-CGO Synthesized by the Citric Method as a Substrate for Thin-film IT-SOFC

  • Wang, Zhenwei;Liu, Yu;Hashimoto, Shin-ichi;Mori, Masashi
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.782-787
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    • 2008
  • Ni-ceria cermets have been extensively investigated as candidates for the anode in intermediate-temperature solid oxide fuel cells. We have used the citric method to synthesize nanocomposite powders consisting of NiO (Ni metal content: $40{\sim}60%$ by volume) highly dispersed in $Ce_{0.9}Gd_{0.1}O_{1.95}$ (CGO). The microstructure characteristics and sintering behaviors of the nanocomposites were investigated. No impurity phases were observed and the shrinkage of these substrates matched well with that of a CGO electrolyte with a specific surface area of $11\;m^2/g$. Densification of the CGO electrolyte layer to $<5\;{\mu}m$ thickness was achieved by co-firing the laminated electrolyte with the porous NiO-CGO substrate at $1400^{\circ}C$ for 6 h.

Study on the Manufacture and Characteristics of Pitch-Based Activated Carbon Fibers Using Steam Activation (수증기 유량제어에 따른 피치계 활성탄소섬유 비표면적 특성에 대한 연구)

  • Hae-Reum Shin;Seung-Jun Yeo;Woo-Seung Noh;Man-Tae Kim
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.6_3
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    • pp.1333-1339
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    • 2023
  • To produce activated carbon fibers, the process is carried out through either physical activation method or chemical activation method. In this study, we present the results regarding the characteristics of activated carbon fibers manufactured under various conditions through the quantitative control of steam. The yield after activation indicates a decreasing trend with the increase in steam quantity and activation time. Additionally, specific surface area characteristics exhibit variations based on activation time and steam flow rate. The SEM analysis results reveal that higher steam flow rates lead to the presence of both mesopores and macropores on the surface of activated carbon fibers (ACF).

ENGINEERING CERAMICS의 평면연삭가공 특성에 관한 연구

  • 김호철;김원일;강재훈
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1992.10a
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    • pp.136-144
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    • 1992
  • Recently, Silicon Nitrde ceramic is regarded as the representative engineering ceramic with the excellent mechanical properties and many functions for mechanical components and parts among various kinds of ceramics in the mechanical industry. But, during the manufacturing of engineering ceramics, there is many volumetric shrinkage coupled with a distortion of the parts which is produced. Due to the requirement for high accuracy of size, form, and surface finish of the components, machining is needed surely. Nowdays, grinding with a resin bond type diamond wheels has been generally applied to machining of the engineering ceramics in the whole world because that it can be conveniently proceeded for workers to dress of tool and made with high reliability in producing factories among many bond type super-abrasive wheels yet. It is important task for attaining prescribed mechanical components with high reliability to observe the grinding mechanism of ceramics as like generation of cracks and chipping of material during process. Because they considerably effects on the strength characteristic of machined mechanical components. In this study, various surface grinding experiments using resin bond type diamond wheels are carried out for Silicon Nitride ceramic. Grinding mechanism of ceramics is observed experimentally and the relationship with various conditions is also attained. Form this experimental study, some useful machining data and information to determine proper machining condition for grinding of Silicon Nitride ceramic is obtained.

A study on the measurement of thermophysical properties of ceramic dielectric materials by unsteady square wave pulse heating method (非定常方形波 펄즈 加熱에 의한 세라믹 誘電體의 熱物性値 測定에 관한 硏究)

  • 차경옥
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.12 no.1
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    • pp.152-162
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    • 1988
  • In recent years, attention has been paid to the ceramic material next to metals and plastics due to its inherent characteristics, i.e., good hardness, resistance to heat and corrosion. Recently, various kinds of ceramic dielectrics have been developed for application in industry. It is of prime importance to know the thermophysical properties for wider use of these new materials. However, no extensive effort has been made for systematic measurement of the properties. In this paper, the dielectric constant of five different kinds of ceramic dielectrics ware measured. We call these samples as MgO.SiO$_{2}$, MgTiO$_{3}$, TiO$_{2}$, CaTiO$_{3}$, and BaTiO$_{3}$. Which are currently in commercial sue. The values of thermal dirrusivities, specific heats, and thermal conductivities of these ceramic dielectrics sere measured as a function of temperature ranging from room temperature to about 1300k.

The study on Ceramic Kilns for Common Qualities Based on the Sejongsillokjiriji -Focused on Woohari Kiln Site- (世宗實錄地理志에 나타난 中品磁器所에 관한 硏究 -于下理 窯址를 中心으로-)

  • Kim, Jong-Tae
    • Archives of design research
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    • v.17 no.4
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    • pp.307-318
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    • 2004
  • We could understand that Woohari oven place is the main place to create important ceramic from Sejongsillokjiriji through the research on the collected remains and books. It was very important founding to understand The history of Korean ceramic industry as well as the special feature of the valuable ceramic in Chosun Dynasty because this place is considered as the original place for center of creating valuable ceramic which called Gongseunghyun during the King, Sejong. Most of the unearthed pieces are containers for living. Specially, it shows clearly about this thought after we found a piece of a soup bowl which has the black letter "Seon". So Woorhar Kiln is an official place to manage food during the King, Sejong(1420') which took care of tribute for one of Sasunsa.

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Optimal Design of Ultrasonic Horn for Ultrasonic Drilling Processing of Ceramic Material (세라믹 소재 초음파 드릴링 가공을 위한 초음파 Horn의 최적 설계에 관한 연구)

  • Cha, Seung-hwan;Yang, Dong-ho;Lee, Sang-hyeop;Lee, Jong-Chan
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.9
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    • pp.1-11
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    • 2022
  • Recently, there has been continuous technological development in the semiconductor industry, and semiconductor manufacturing technologies are being advanced and highly integrated. For this reason, ceramic material having excellent heat resistance, wear resistance, and conductivity are used as components in semiconductor manufacturing. Among them, the probe card's space transformer is used as ceramic material to prevent electronic signal noise during the electrical die sorting of semiconductor function testing. However, implementing a bulk-type space transformer with a thickness of 5.6 mm or more is challenging, and thus it is produced in a structure with a stacked ceramic film. The stacked space transformer has low productivity because it is difficult to ensure hole clogging and a precise shape. In this research, an ultrasonic horn is designed to manufacture a bulk-type ceramic space transformer through ultrasonic drilling. Vibration characteristics were analyzed according to the ultrasonic horn, and the natural frequency was measured.