• Journal of the Korea Institute of Building Construction
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• v.13 no.3
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• pp.253-262
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• 2013

The test on the mix of PVA fiber of low carbon inorganic composite as a cement substitute found it to be satisfactory in terms of flexibility and stiffness. The result of the evaluation of the properties of low carbon inorganic panel revealed that the absorptivity was low at 8 to 9%, which is lower than the KS value of 25%. Also, the test on non-combustibility and gas toxicity found that these factors satisfied the decision criteria. In the test on heavy metals discharges, Pb, Cd, Cr6+, Hg, and As were not detected. Regarding far-Infrared emissivity and formaldehyde emission, the substitute was found to be harmless to the human body. Therefore, if the issue of shrinkage, which is a disadvantage of inorganic composites, is addressed, it is judged that it is possible to develop a low carbon inorganic composite panel with better performance.

• The Journal of Advanced Prosthodontics
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• v.9 no.3
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• pp.217-223
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• 2017

PURPOSE. This study investigated the effects of silver nanoparticle (SN) loading into hydraulic calcium silicate-based Portland cement on its mechanical, antibacterial behavior and biocompatibility as a novel dental bone substitute. MATERIALS AND METHODS. Chemically reduced colloidal SN were combined with Portland cement (PC) by the concentrations of 0 (control), 1.0, 3.0, and 5.0 wt%. The physico-mechanical properties of silver-Portland cement nanocomposites (SPNC) were investigated through X-ray diffraction (XRD), setting time, compressive strength, solubility, and silver ion elution. Antimicrobial properties of SPNC were tested by agar diffusion against Streptococcus mutans and Streptococcus sobrinus. Cytotoxic evaluation for human gingival fibroblast (HGF) was performed by MTS assay. RESULTS. XRD certified that SN was successfully impregnated in PC. SPNC at above 3.0 wt% significantly reduced both initial and final setting times compared to control PC. No statistical differences of the compressive strength values were detected after SN loadings, and solubility rates of SPNC were below 3.0%, which are acceptable by ADA guidelines. Ag ion elutions from SPNC were confirmed with dose-dependence on the concentrations of SN added. SPNC of 5.0 wt% inhibited the growth of Streptococci, whereas no antimicrobial activity was shown in control PC. SPNC revealed no cytotoxic effects to HGF following ISO 10993 (cell viability > 70%). CONCLUSION. Addition of SN promoted the antibacterial activity and favored the bio-mechanical properties of PC; thus, SPNC could be a candidate for the futuristic dental biomaterial. For clinical warrant, further studies including the inhibitory mechanism, in vivo and long-term researches are still required.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.11a
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• pp.194-195
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• 2013

Recently, it is the tendency that the CO₂ gas generated in the manufacturing process is increased every year in case of the portland cement used in the most of constructions and civil engineering field. The method that uses the mineral admixtures as the cement substitute material in order to be more serious and as much as it occupies 7% of the global CO₂ gas outlet amount such as 1 ton produces the cement and it ejects the CO₂ gas of 0.4~1.0 ton, etc conclude this problem is examined. Therefore, PVA fiber was mixed into the inorganic binder recycling the blast furnace slag, which is the industrial byproduct with the purpose studying the Geo polymer which doesn't use the cement at all silica fume, red mud, and etc. In addition, the water curing temperature was differentiated and the strength characteristic of the curing body tried to be examined.

• Journal of Electrochemical Science and Technology
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• v.12 no.4
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• pp.440-452
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• 2021

Enhancement of durability and reduction of maintenance cost of concrete, with the implementation of various approaches, has always been a matter of concern to researchers. The integration of pozzolans as a substitute for cement into the concrete is one of the most desirable technique. Silica fume (SF) and colloidal nanosilica (CS) have received a great deal of interest from researchers with their significant performance in improving the durability of concrete. The synergistic role of the micro and nano-silica particles in improving the main characteristics of cemented materials needs to be investigated. This work aims to examine the utility of partial substitution of cement by SF and CS in binary and ternary blends in the improvement of the durability characteristics linked to resistance for electrochemical corrosion using electrical resistivity and half-cell potential analysis and chloride penetration trough rapid chloride penetration test. Furthermore, the effects of this silica mixture on the compressive strength of concrete under normal and aggressive environment have also been investigated. Based on the maximum compression strength of the concrete, the optimal cement substituent ratios have been obtained as 12% SF and 1.5% CS for binary blends. The optimal CS and SF combination mixing ratios has been obtained as 1.0% and 12% respectively for ternary blends. The ternary blends with substitution of cement by optimal percentage of CS and SF exhibited decreased rate for electrochemical corrosion. The strength and durability studies were found in consistence with the microstructural analysis signifying the beneficiary role of CS and SF in upgrading the performance of concrete.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.34 no.2
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• pp.66-72
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• 2024

In this study, the applicability of CCMs (Carbondioxide conversion capture materials) manufactured by reacting carbon dioxide gas with DG (Desulfurization gypsum) as a cement substitute for secondary concrete products were evaluated and the basic physical properties of CCMs-mixed mortar and concrete specimens were measured to derive the optimal mixing ratio. The main chemical oxides of CCMs were CaO and SO₃, and the main crystalline phases were CaSO₄·2H₂O, Ca(OH)₂, CaCO₃, and CaSO₄. In addition, by the results of particle size analysis and heavy metal measurement, the applicability of CCMs as a cement substitute for secondary concrete products was confirmed. As a result of measuring the strength behavior using mortar and concrete specimens with CCMs, the compressive and flexural strength decreased as the mix ratio of CCMs increased, but requirements by the standards for interlocking blocks and retaining wall blocks, which are target products in this study, were satisfied up to the optimal mixing ratio of 10 wt.% substitution. Therefore, its applicability as a cement substitute for secondary concrete products was confirmed.

• Journal of Dental Rehabilitation and Applied Science
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• v.24 no.3
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• pp.311-316
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• 2008

Calcium phosphate cement (CPC) has been used as bone substitute successfully due to good biocompatibility and osteoconductivity. One of the important mechanical characteristics of CPC is flowablility, which can be evaluated by measuring rheological parameters. However, there have been few studies that measured rheological properties of CPC. The purpose of this study was to evaluate the rheological properties of CPC paste mixed with 2 kinds of setting solutions, 2% hydroxyprophyl methylcellulose (HPMC) and 35% polyacrylic acid (PAA). The CPC used was dicalcium phosphate dihydrate (DCPD). Rheological properties of CPC paste were measured using rheometer. The statistical analysis was carried out with Mann-whitney test with Bonferronis collection. CPC with both setting solutions showed shear thinning behavior. CPC with 2% HPMC showed signigicantly higher complex viscosity than CPC with 35% PAA(p<0.05).

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.675-680
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• 2002

This study was to operate a fitting production specific of concrete product for proper mixing discovery. Testing method was to operate slump, air content, compressive strength test. The standard was water-cement ratio 50% and weight substitution 0%, 10%, 20% by Fly-ash and using Silica-fume and HPMC(Hydroxy propyl methyl cellulos) by additive. The result of this study showed when add Fly-ash to Silica-Fume is better than HPMC.

• Journal of the Korea Institute of Building Construction
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• v.6 no.3 s.21
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• pp.59-66
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• 2006

This study aims to estimate strength approximate to actual concrete strength by presenting appropriate non-destructive strength estimation expression with admixtures such as fly ash, blast furnace slag and silica fume which are used as cement substitute and owing to theirs of cement owing to their equal conditions to blending characteristics of concrete used for domestic structures and their recyclable properties. As a result of comparing error rate of existing expressions and this estimation expression, error rate of this estimation is reduced compared to existing expressions and has higher reliability. When conventional concrete expression is applied to admixture concrete, error rate occurs and then this study suggests the following estimation expressions depending on types of admixture concrete.

• Structural Engineering and Mechanics
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• v.55 no.3
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• pp.675-686
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• 2015

The use of ground granulated blast furnace slag (GGBFS) from steel industries waste is showing perspective application in civil engineering as partial substitute to cement. Use of such waste conserves natural resources and minimizes the space required for landfill. The GGBFS used in the present work is of ultra fine size and hence serves as micro filler. In this paper strength and durability characteristics of ultra fine slag based high strength concrete (HSC) (with a characteristic compressive strength of 50 MPa) were studied. Cement was replaced with ultra fine slag in different percentages of 5, 10, and 15% to study the compressive strength, porosity, resistances against sulfate attack, sorptivity and chloride ion penetration. The experiments to study compressive strength were conducted for different ages of concrete such as 7, 28, 56, and 90 days. From the detailed investigations with 16 mix combinations, 10% ultra fine slag give better results in terms of strength and durability characteristics.

• Structural Engineering and Mechanics
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• v.61 no.2
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• pp.171-181
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• 2017

This paper summarizes the study on effect of ceramic waste powder as partial substitute to cement in binary blend and along with silica fume in ternary blend high strength concrete in normal and aggressive environments. Strength parameters such as compression & tension and durability indices such as corrosion measurement, deterioration, water absorption and porosity were studied. Ceramic waste powder was used in three different percentages namely 5, 10 and 15 with constant percentage of silica fume (1%) as substitutes to cement in ternary blend high strength concrete was investigated. After a detailed investigation, it was understood that concrete with 15% ceramic waste powder registered maximum performance. Increase of ceramic waste powder offered better resistance to deterioration of concrete.