• 제목/요약/키워드: cathodic protection

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A Study on the Characteristics of Cathodic Protection by Al-Alloy Sacrificial Anode in Marine Environment (해양환경중에서 A1-합금희생양극에 의한 음극방식특성)

  • 이연호
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.28 no.1
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    • pp.53-60
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    • 1992
  • In this study, cathodic protection experiment was carried out by Al-alloy sacrificial anode in marine environments which have specific resistance($\rho$) if 25~7000$\Omega$.cm and investigated protection potential, current density and loss rate of Al-alloy sacrificial anode. The main results resistance($\rho$) of 400$\Omega$.cm, the cathodic protection potential appears high about-720 mV(SCE). But below specific resistance($\rho$) of 300$\Omega$.cm, the cathodic protection potential appears low about-770 mV(SCE) and simultaneously, cathode is protected sufficiently. 2) The loss rate of Al-Alloy sacrificial anode became large with decreasing specific resistance and increasing the ratio(A sub(c)/A sub(a) of bared surface area of anode and cathode. 3) The loss rate of Al-alloy sacrificial anode(w) to the mean current density of anode(i) is as follows. w=ai+b (a, b : experimental constants)

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Cathodic Protection Behavior of Coastal Bridge Structure with Sacrificial Anode Cathodic Protection System (희생양극식 음극방식이 적용된 해안 교량 구조물의 방식거동)

  • Ha, Ji-Myung;Jin, Chung-Kuk;Jeong, Jin-A
    • Corrosion Science and Technology
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    • v.11 no.6
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    • pp.242-246
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    • 2012
  • This measurement represents the effectiveness of sacrificial anode cathodic protection (SACP) system in a coastal bridge structure. To verify the cathodic protection (CP) effect, the monitoring sensor (DMS-100) that could measure potential, corrosion rate, current, concrete resistivity, and temperature was embedded. The measurement conducted for three years after CP system was installed. Specifically, due to the fact that fresh water and sea water was repeated in the bridge structure, this bridge structure presented special CP behavior. Measurement factors were CP potential, CP current, concrete resistivity, and depolarization potential. In addition, visual inspection was also carried out. As a result of current and depolarization measurement, CP system was well activated in most piers.

Methods of Improving Operational Reliability of Oil Well Casing

  • Sergey A. Dolgikh;Irek I. Mukhamatdinov
    • Corrosion Science and Technology
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    • v.23 no.1
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    • pp.1-10
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    • 2024
  • Oil well casing leak is caused by contact of casing outer surface with formation electrolyte. It is usually associated with an aquifer with a high salt content or absence of a cement ring behind the casing. The only way to reduce external casing corrosion is through cathodic protection. Through cathodic polarization of casing structure, electron content in crystal lattice and electron density will increase, leading to a potential shift towards the cathodic region. At Tatneft enterprises, cathodic protection is carried out according to cluster and individual schemes. The main criterion for cathodic protection is the size of protective current. For a casing, the protective current is considered sufficient if measurements with a two-contact probe show that the electric current directed to the casing has eliminated all anode sites. To determine the value of required protective current, all methods are considered in this work. In addition, an analysis of all methods used to determine the minimum protective current of the casing is provided. Results show that the method of measuring potential drop along casing is one of the most reliable methods for determining the value of protective current.

A Study of Optimizing Cathodic Protection in Comparison of Design Methodologies

  • Choi, Young-Kwan;Choi, Sang-Yule;Shin, Myong-Chul
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.11
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    • pp.23-29
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    • 2010
  • The principal factor determining an optimum design method for cathodic protection is finding the protection current for preventing the corrosion of existing, already laid pipe. Some factors currently used to test designs include the sizes and lengths of pipes, soil resistivity, and the coating damage rate. We believe this method and current formulae are not optimum due to the uncertainty of determining the coating damage rate and the corrosion protection current's density. This paper analyzes the amount of protection current obtained by performing a temporary current test using data describing existing laid pipe. We then propose determining the corrosion protection current by using the temporary current test after modifying the formula. In addition, we suggest a way to choose optimized cathodic protection and the process of design by executing the design and taking account of such factors as a site condition of 34km-long non-protected water supply pipe lines (stages I and II) in ${\bigcirc}{\bigcirc}$ region, climate, interferences, and durability.

A Study on the Post-Weld Heat Treatment Effect Affecting Corrosion Behavior and Mechanical Property of Welding Part of RE36 Steel for Marine Structure (해양구조물용 RE36강 용접부의 부식거동 및 기계적 특성에 미치는 용접후 열처리 효과에 관한 연구)

  • 김성종;문경만
    • Journal of Welding and Joining
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    • v.19 no.1
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    • pp.65-74
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    • 2001
  • A study on the corrosion behavior in case of As-welded and PWHT temperature 55$0^{\circ}C$ of welding part of RE36 steel for marine structure was investigated with parameters such as micro-Vickers hardness, corrosion potential measurement of weld metal(WM), base metal(BM) and heat affected zone(HAZ), both Al anode generating current and Al anode weight loss quantity under sacrificial anode cathodic protection conditions. And also we carried out slow strain rate test(SSRT) in order to research both limiting cathodic polarization potential for hydrogen embrittlement and optimum cathodic protection potential as well as mechanical properties by post-weld heat treatment(PWHT) effect. Hardness of HAZ was the highest among three parts(WM, BM and HAZ) and the highest galvanic corrosion susceptibility was HAZ. And the optimum cathodic polarization potential showing the best mechanical properties by SSRT method was from -770mV to -875mV(SCE). In analysis of SEM fractography, applied cathodic potential from -770mV to -875mV(SCE) it appeared dimple pattern with ductile fracture while it showed transgranular pattern (Q. C : quasicleavage) under -900mV(SCE). However it is suggested that limiting cathodic polarization potential indicating hydrogen embrittlement was under -900mV(SCE).

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Determination of Low-temperature Electrochemical Properties of Selected Cation-exchange Membranes for Cathodic Protection Analysis

  • Ko, Moon-Young;Kwon, Byeong-Min;Hong, Byung-Pyo;Byun, Hong-Sik
    • Korean Membrane Journal
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    • v.10 no.1
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    • pp.8-12
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    • 2008
  • The electrochemical properties of Nafion type membranes as a function of temperature to examine the key factors affecting the cathodic protection process at low temperatures was investigated in this study. Variable temperature experiments for AC impedance, DC resistance were conducted. The resistances of 3 Nafion membranes (N 324, N 450, N MAC) were measured in 30% KOH (aq) for a range of temperatures between $-30^{\circ}C$ and room temperature. Membrane resistance increases exponentially with decreasing temperature. This behaviour is most significant at operational temperatures below $0^{\circ}C$. These membranes are stable under the low temperature and caustic conditions of the heat exchange system, but they place a much higher restriction on the cathodic protection of the stainless heat exchange stack. N 450 has the lowest AC impedence and DC resistance at temperatures below $0^{\circ}C$ and consequently is most suitable membrane of the three, for low temperature applications.

Effect of Moisture on the Current Density for Optimized Cathodic Protection Condition in RC Structures (RC조 구조물의 최적 음극방식 조건 설정을 위한 함수율의 영향에 대한 평가)

  • Park, Dong-Cheon;Cho, Gyu-hwan;Ahn, Jae-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.05a
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    • pp.29-30
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    • 2013
  • Steel corrosion is the most serious problem in RC structures. Even though patch repair method is normally applied in repair system, the effectiveness is not enough. Cathodic protection in active repair method to deteriorated RC structures. FEM model was developed to simulate the optimized cathodic protection condition. Iro oxidation, hydrogen evolution and oxygen reduction were considered to expect current distribution. Moisture content in concrete which can affect the electrolyte conductivity was used as initial condition.

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Study on the Corrosionproofing in Concrete by Cathodic Protection (전위변화에 의한 콘크리트내의 철근방식에 관한 연구)

  • Lim, Seo-Hyung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.3 no.2
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    • pp.213-220
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    • 1999
  • The purpose of this study is to apply cathodic protection to reinforced concrete structure and provide fundamental data to prevent the corrosion. The theory of cathodic protection of steel in concrete is to apply sufficient direct current so that corroding anodes on the steel are prevented from discharging ions. Two methods are used to supply the external current. In one, the protected metal is the cathode by connecting it to a more active metal. In the second, an external direct current power source supplies the current. The first is the sacrificial-anode system and the second the impressed-current system. The study results showed that the corrosion of the reinforcing steel in concrete could be enormously decreased by using protective current. The sacrificial anode and concrete nave to be adhered closely each in order to prevent the corrosion of reinforcing steel.

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Determination of optimum protection potential for cathodic protection of offshore wind-turbine-tower steel substructure by using potentiostatic method (정전위법에 의한 해상풍력 타워 구조물용 강재의 음극방식을 위한 최적방식전위 결정)

  • Lee, Jung-Hyung;Jung, Kwang-hu;Park, Jae-Cheul;Kim, Seong-Jong
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.3
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    • pp.230-237
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    • 2017
  • In this study, electrochemical methods were used to determine the optimum protection potential of S355ML steel for the cathodic protection of offshore wind-turbine-tower substructures. The results of potentiodynamic polarization experiments indicated that the anodic polarization curve did not represent a passivation behavior, while under the cathodic polarization concentration, polarization was observed due to the reduction of dissolved oxygen, followed by activation polarization by hydrogen evolution as the potential shifted towards the active direction. The concentration polarization region was found to be located between approximately -0.72 V and -1.0 V, and this potential range is considered to be the potential range for cathodic protection using the impressed current cathodic protection method. The results of the potentiostatic experiments at various potentials revealed that varying current density tended to become stable with time. Surface characterization after the potentiostatic experiment for 1200 s, by using a scanning electron microscope and a 3D analysis microscope confirmed that corrosion damage occurred as a result of anodic dissolution under an anodic polarization potential range of 0 to -0.50 V, which corresponds to anodic polarization. Under potentials corresponding to cathodic polarization, however, a relatively intact surface was observed with the formation of calcareous deposits. As a result, the potential range between -0.8 V and -1.0 V, which corresponds to the concentration polarization region, was determined to be the optimum potential region for impressed current cathodic protection of S355ML steel.

A New Protection Strategy of Impressed Current Cathodic Protection for Ship

  • Oh, Jin-Seok;Kim, Jong-Do
    • Journal of Mechanical Science and Technology
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    • v.18 no.4
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    • pp.592-596
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    • 2004
  • Corrosion is never avoided in the use of materials with various environments. The underwater hull is normally protected against rusting by several coatings of anti-corrosive paint. The purpose of ICCP(Impressed Current Cathodic protection) system is to eliminate the rusting or corrosion, which occurs on metal immersed in seawater. The anode of ICCP system is controlled by an external DC source with converter. The function of anode is to conduct the protective current into seawater. The proposed algorithm includes the harmonic suppression control strategy and the optimum protection strategy and has tried to test the requirement current density for protection, the influence of voltage, the protection potential. This paper was studied the variation of potential and current density with environment factors, time and velocity, and the experimental results will be explained.