• 제목/요약/키워드: carrier gas

검색결과 629건 처리시간 0.028초

Electronic and atomic structure control of epitaxial graphene

  • 안종렬
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.53-53
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    • 2010
  • Graphene comes into the spotlight as an emergent device material on account of its high carrier mobility reflecting its massless Dirac fermion behavior. Chemical technique to control reversibly the carrier concentration of semiconducting graphene for the achievement of a large-area graphene device has been strongly required. Here we show that the adsorptions of a metal and a molecule can manipulate the carrier concentration of single-layer graphene, epitaxially grown on SiC, which was directly observed using angle-resolve photoemission spectroscopy. These results will shed light on the researches for the very large scale integration of a graphene device. Furthermore, the carrier concentration changes can be applied to a highly sensitive gas sensor or a detector for an specific binding between an antigen and an antibody.

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Effect of Reduction Temperature on the Microstructure and Thermoelectric Properties of TAGS-85 Compounds

  • Madavali, Babu;Han, Seung-Tek;Shin, Dong-Won;Hong, Soon-Jik;Lee, Kap-Ho
    • 한국재료학회지
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    • 제27권8호
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    • pp.438-444
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    • 2017
  • In this work, the effects of hydrogen reduction on the microstructure and thermoelectric properties of $(GeTe)_{0.85}(AgSbTe_2)_{0.15}$ (TAGS-85) were studied by a combination of gas atomization and spark plasma sintering. The crystal structure and microstructure of TAGS-85 were characterized by X-ray diffraction(XRD) and scanning electron microscopy (SEM). The oxygen content of both powders and bulk samples were found to decrease with increasing reduction temperature. The grain size gradually increased with increasing reduction temperature due to adhesion of fine grains in a temperature range of 350 to $450^{\circ}C$. The electrical resistivity was found to increase with reduction temperature due to a decrease in carrier concentration. The Seebeck coefficient decreased with increasing reduction temperature and was in good agreement with the carrier concentration and carrier mobility. The maximum power factor, $3.3{\times}10^{-3}W/mK^2$, was measured for the non-reduction bulk TAGS-85 at $450^{\circ}C$.

Plasma nitridation of atomic layer deposition-Al2O3 by NH3 in PECVD

  • Cha, Ham cho rom;Cho, Young Joon;Chang, Hyo Sik
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.304.1-304.1
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    • 2016
  • We have investigated the effect of plasma nitridation of atomic layer deposited-Al2O3 films of monocrystalline Si wafers and the thermal properties of nitridated Al2O3 films. Nitridation was performed on Al2O3 to form aluminum oxynitride (AlON) using NH3 plasma treatment in a plasma-enhanced chemical vapor deposition and it was conducted at temperature of $400^{\circ}C$ with various plasma power condition. After nitridation, we performed firing and forming gas annealing (FGA). For each step, we have observed the minority carrier lifetime and the implied Voc by using quasi-Steady-State photoconductance (QSSPC). We confirmed a tendency to increase the minority carrier lifetime and the implied Voc after the nitridation. On the other hand, the minority carrier lifetime and the implied Voc was decreased after Firing and forming gas annealing (FGA). To get more information, we studied properties of the plasma treated Al2O3 films by using Secondary Ion Mass Spectroscopy (SIMS) and X-ray Photoelectron Spectroscopy (XPS).

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IMO C형 독립탱크의 설계치수 계산과정 및 평가방법에 대한 고찰 (Consideration for IMO Type C Independent Tank Rule Scantling Process and Evaluation Methods)

  • 허광현;강원식;박봉균
    • 대한조선학회 특별논문집
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    • 대한조선학회 2017년도 특별논문집
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    • pp.93-104
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    • 2017
  • IMO type C independent tank is one of the cargo containment system specified on IGC code. It is normally adopted for small and medium size liquefied gas carrier's cargo containment system and it can be applied to fuel tank of LNG fueled vessel. This study focuses on rule scantling process and evaluation methods in early design stage of type C independent tank. Actual design results of 22K LPG/Ammonia/VCM carrier's No.2 cargo tank are demonstrated. This paper presents the calculation methods of design acceleration and liquid height for internal design pressure as defined on IGC code. And this paper shows the applied results of classification rules about shell thickness requirement and buckling strength. Additionally this paper deals with evaluation methods of structural strength and cumulative fatigue damage using FE analysis.

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PIV와 CFD에 의한 LNG선박의 Hood room 환기특성에 관한 연구 (A Study on Ventilation Characteristics of LNG Carrier Hood room by PIV and CFD)

  • 조대환;김동찬;김만응;이영호
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2000년도 춘계학술대회논문집B
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    • pp.673-679
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    • 2000
  • LNG Carriers are currently known as sole commercial means of shipping natural gas on the sea. They are designed to proven dangerous explosion for shipping a lot of gas over long distance. In this study. In this study, a scaled model chamber was made to investigate ventilation characteristics of the hood room in LNG carrier. Experimental study was performed in model using visualization equipments with laser apparatus and image intensifier CCD camera gated by an AOM controller Twelve different kinds of measuring area were selected as experimental condition. Instant simultaneous velocity vectors at whole field were measured by using 2-D PIV system which software adopts two-frame grey-level cross correlation algorithm. To look into stagnation area of hood room for LNG carrier, a three-dimensional numerical simulation with standard ${\kappa}-{\varepsilon}$ model was carried out by using PHOENICS for three kinds of Reynolds number, $6.5{\times}10^3$, $9.7{\times}10^3\;and\;1.29{\times}10^4$, based on the cavity inlet velocity and cavity height. The flow pattern showed the large scale counter-clockwise forced-vortex rotated at center area, small eddies at each corner and stagnation area located at left-back upper side of model.

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Deep learning neural networks to decide whether to operate the 174K Liquefied Natural Gas Carrier's Gas Combustion Unit

  • Sungrok Kim;Qianfeng Lin;Jooyoung Son
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2022년도 추계학술대회
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    • pp.383-384
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    • 2022
  • Gas Combustion Unit (GCU) onboard liquefied natural gas carriers handles boil-off to stabilize tank pressure. There are many factors for LNG cargo operators to take into consideration to determine whether to use GCU or not. Gas consumption of main engine and re-liquefied gas through the Partial Re-Liquefaction System (PRS) are good examples of these factors. Human gas operators have decided the operation so far. In this paper, some deep learning neural network models were developed to provide human gas operators with a decision support system. The models consider various factors specially into GCU operation. A deep learning model with Sigmoid activation functions in input layer and hidden layers made the best performance among eight different deep learning models.

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PECVD의 주파수 조건에 따른 $SiN_x$막 증착 (The Silicon Nitride Films according to The Frequency Conditions of Plasma Enhanced Chemical Vapor Deposition)

  • 최정호;노시철;정종대;서화일
    • 반도체디스플레이기술학회지
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    • 제13권4호
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    • pp.21-25
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    • 2014
  • The silicon nitride ($SiN_x$) film for surface passivation and anti-reflection coating of crystalline silicon solar cell is very important and it is generally deposited by plasma enhanced chemical vapor deposition (PECVD). PECVD can be divided into low and high frequency method. In this paper, the $SiN_x$ film deposited by low and high frequency PECVD method was studied. First, to optimize the $SiN_x$ film deposited by low frequency PECVD method, the refractive index was measured by varying the process conditions like $SiH_4$, $NH_3$, $N_2$ gas rate, and RF power. When $SiH_4$ gas rate was increased and $NH_3$ gas rate was decreased, the refractive index was increased. The refractive index was also increased with RF power decline. Second, to compare the characteristics of the low and high frequency PECVD $SiN_x$ film, the refractive index was measured by varying $NH_3/SiH_4$ gas ratio and RF power and the minority carrier lifetime of before and after high temperature treatment process was also measured. The refractive index of both low and high frequency PECVD $SiN_x$ film was decreased with increase in $NH_3/SiH_4$ gas ratio and RF power. After high temperature treatment process, the minority carrier lifetime of both low and high frequency PECVD $SiN_x$ film was increased and increased degree was similar. The minority carrier lifetime of low frequency PECVD $SiN_x$ was increased from $11.03{\mu}m$ to $28.24{\mu}m$ and that of high frequency PECVD $SiN_x$ was increased from $11.60{\mu}m$ to $27.10{\mu}m$.

가스크로마토그라피에 의한 l-에페드린과 dl-메칠에페드린의 정량 (Gas chromatographic determination of l-ephedrine and dl-methylephedrine)

  • 윤용균
    • 약학회지
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    • 제16권1호
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    • pp.55-64
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    • 1972
  • The determination method of l-ephedrine and dl-methylephedrine by gas chromatography was developed, using reactive alkaline precolumn packed with celite 545 containing KOH. Symmetrical peaks were achieved under the condition, inlet temperature, $180^{\circ}C$-$230^{\circ}C$; column temperature, $180^{\circ}C$- $160^{\circ}C$; carrier gas flow rate, 30ml/minute. The peaks of the salts coincided with those of bases. When this method was applied to preparations, using d-dimethylaminobenzaldehyde as inner standard, good results were obtained. The relative retention times of l-ephedrine and dl-methylephedrine to p-dimethyl aminobenzaldehyde were 0.50 and 0.65 respectively.

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액화천연가스 운반선(LNGC)의 발전 추세 (A Developing Tendency of Liquefied Natural Gas Carriers)

  • 이동섭
    • 해양환경안전학회지
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    • 제15권3호
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    • pp.269-274
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    • 2009
  • LNGC(Liquefied Natural Gas Carrier)의 역사는 1959년 $5,000m^3$ 급 LNG선 "Methane Pioneer"호를 시작으로 1969년에는 $71,500m^3$ 급, 1973년에는 Moss Type의 최초 LNG운반선 "Norman Lady($87,600m^3$)호, 1980년대 $125,000m^3$ 급을 시작으로 1990년대를 거처 $135,000m^3$ 급, 2007년 $210,000m^3$급 그리고 2008년에는 $266,000m^3$ 급의 초대형 액화천연가스 운반선이 출현하였다. 또한 2006년 11월에는 기존 내 외연 기관이 아닌 발전기 기동으로 Propeller를 움직이는 DFDE(Duel Fuel Diesel Electric)엔진, 육상의 Storage Tank를 생략한 기화설비를 갖춘 LNG-RV(Re-gasification Vessel)와 주 기관은 Slow Diesel을 택하고, 운항 중 발생하는 BOG(Boil Off Gas)를 재액화시키는 설비를 갖춘 DRL(Diesel Re-Liquefaction)선박 및 해상 LNG 생산 저장시설인 LNG-FPSO(Floating Production and Storage Offshore), 그리 고 해상 LNG 인수기지 역할을 하는 LNG-FSRU(Floating Store and Re-gasification Unit) 등이 개발되었다. 이 논문에서는 LNG Project, 전 세계 에너지 시장과 LNGC의 발전 추세에 대하여 다루었다.

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