• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.5
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• pp.222-228
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• 2019

In this study, we carried out the experiment to prepare lithium carbonate powder through gas-liquid reactions with a lithium-containing solution and $CO_2$ gas using lithium hydroxide, lithium chloride, and lithium sulfate. Thermodynamically, the carbonation reaction of a lithium-containing solution showed that aqueous reaction of lithium hydroxide occurs spontaneously, but aqueous reactions of lithium chloride and lithium sulfate does not occur spontaneously. In the case of lithium hydroxide solution, the recovery rate of lithium carbonate was 69.8 % at room temperature ($25^{\circ}C$), and increased to 89.4 % at $60^{\circ}C$. In the case of lithium chloride and lithium sulfate solution, lithium carbonate could be prepared using sodium hydroxide as an additive, but the recovery rates were 19.2 % and 16.7 %, respectively.

• Journal of the Korea Institute of Building Construction
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• v.19 no.5
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• pp.383-389
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• 2019

The supply of natural aggregate for concrete has been difficult, and the amount of construction waste has been continuously increasing. Therefore, the necessity of using recycled aggregate made of construction waste as aggregate is rised. Therefore, many studies on the characteristics of concrete using recycled aggregate have been made and positive studies have been reported mainly in recent studies. A study on the chlorides binding effect of the mortar with recycled coarse aggregate has been reported. However, due to the user's perception of waste, most of the recycled aggregate currently produced is used only for low value-added products. In order to improve the recognition of recycled aggregate and the user's perception of recycled aggregate concrete, long-term monitoring of the structure with 100% recycled aggregate was conducted to confirm the applicability of the recycled aggregate concrete.

• Applied Chemistry for Engineering
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• v.28 no.1
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• pp.101-111
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• 2017

Mineral carbonation is a technology in which carbonates are synthesized from minerals including serpentine and olivine, and industrial wastes such as slag and cement, of which all contain calcium or magnesium when reacted with carbon dioxide. This study aims to develop the mineral carbonation technology for commercialization, which can reduce environmental burden and process cost through the reduction of carbon dioxide using steel slag and the slag reuse after calcium extraction. Calcium extraction was conducted using NH4Cl solution for air-cooled slag and convert slag, and ${\geq}98%$ purity calcium carbonate was synthesized by reaction with calcium-extracted solution and carbon dioxide. And we conducted experimentally to minimize the quantity of by-product, the slag residue after calcium extraction, which has occupied large amount of weight ratio (about 80-90%) at the point of mineral carbonation process using slag. The slag residue was used to replace silica sand in the manufacture of cement panel, and physical properties including compressive strength and flexible strength of panel using the slag residue and normal cement panel, respectively, were analyzed. The calcium concentration in extraction solution was analyzed by inductively coupled plasma optical emission spectrometer (ICP-OES). Field-emission scanning electron microscope (FE-SEM) was also used to identify the surface morphology of calcium carbonate, and XRD was used to analyze the crystallinity and the quantitative analysis of calcium carbonate. In addition, the cement panel evaluation was carried out according to KS L ISO 679, and the compressive strength and flexural strength of the panels were measured.

• Journal of the Korean Ceramic Society
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• v.53 no.1
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• pp.18-23
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• 2016

The development of a binder system with a lower carbon footprint as an alternative to Portland cement has been intensely researched. In the present study, alkali-activated fly ash exposed to carbon dioxide at an early age was characterized in compressive strength tests and by MIP, XRD and FT-IR analyses. The compressive strength of carbonated specimens experienced a dramatic increase in comparison to uncarbonated specimens. The microstructural densification of the carbonated specimens was evidenced by MIP. The XRD pattern showed peaks assigned to nahcolite, indicating that the pH was lower in the carbonated specimens. Under the carbon dioxide-rich environment, the aluminosilicate gel reached a more Si-rich state, which improved the mechanical properties of the alkali-activated fly ash.

• Structural Monitoring and Maintenance
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• v.5 no.2
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• pp.313-323
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• 2018

The presence of water inside concrete structures is an essential condition for the deterioration of the structures. The free water in the concrete pores and micro-cracks is the culprit for the durability related problems, such as alkali-aggregate reaction, carbonation, freeze-thaw damage, and corrosion of steel reinforcement. To ensure the integrity and safe operation of the concrete structures, it is very important to monitor water seepage inside the concrete. This paper presents the experimental investigation of water seepage monitoring in a concrete slab using piezoelectric-based smart aggregates. In the experimental setup, an $800mm{\times}800mm{\times}100mm$ concrete slab was fabricated with 15 SAs distributed inside the slab. The water seepage process was monitored through interrogating the SA pairs. In each SA pair, one SA was used as actuator to emit harmonic sine wave, and the other was used as sensor to receive the transmitted stress wave. The amplitudes of the received signals were able to indicate the water seepage process inside the concrete slab.

• Carbon letters
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• v.16 no.1
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• pp.62-66
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• 2015

In this study, carbonized fibers were prepared by using acidically cross-linked LDPE fibers. The surface morphologies of the carbonized fibers were observed by SEM. The effects of cross-linking process temperatures were studied using thermal analyses such as DSC and TGA. The melting and heating enthalpy of the fibers decreased as the cross-linking temperature increased. The cross-linked fibers had a carbonization yield of over 50%. From SEM results the highest yield of carbonized LDPE-based fibers was obtained by cross-linking at a sulfate temperature ($170^{\circ}C$). As a result, carbonation yield of the carbonized fibers was found to depend on the functions of the cross-linking ratio of the LDPE precursors.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.220.1-220.1
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• 2011

In recent years, the importance of Carbon Capture and Storage (hereafter CCS) is growing bigger and bigger. The development and commercialization of CCS technology are concerned for reducing carbon dioxide($CO_2$) emissions. For the most studies, the technology of $CO_2$ storage is known as the geological storage, ocean sequestration, mineral carbonation, industrial utilization, and so on. The geological storage is adjudged the most reasonable technology from economic and environmental aspects. Generally, the $CO_2$ geological storage is comprised of compression - transportation - drilling/injection - storage/management process. The critical problem is a leakage of $CO_2$ in all process. For resolving a leakage problem, it is necessary to predict and build a monitoring system. Those systems are proved safety of a leakage and received positive social perceptions of $CO_2$ geological storage. For those reasons, a risk assessment of $CO_2$ geological storage is required. A risk assessment is an estimated process of the possible effects when spilling $CO_2$. Although numerous studies of risk assessment have studied, it is incomplete to evaluate a risk and disaster quantitatively. The risk assessment will be developed for domestic application and safe $CO_2$ geological storage considering characteristics of Korea.

• Advances in concrete construction
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• v.5 no.6
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• pp.671-683
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• 2017

Commonly used concrete in general, consists of cement, fine aggregate, coarse aggregate and water. Natural river sand is the most commonly used material as fine aggregate in concrete. One of the important requirements of concrete is that it should be durable under certain conditions of exposure. The durability of concrete is defined as its ability to resist weathering action, chemical attack or any other process of deterioration. Durable concrete will retain its original form, quality and serviceability when exposed to its environment. Deterioration can occur in various forms such as alkali aggregate expansion, freeze-thaw expansion, salt scaling by de-icing salts, shrinkage, attack on the reinforcement due to carbonation, sulphate attack on exposure to ground water, sea water attack and corrosion caused by salts. Addition of admixtures may control these effects. In this paper, an attempt has been made to replace part of fine aggregate by tailing material and part of cement by fly ash to improve the durability of concrete. The various durability tests performed were chemical attack tests such as sulphate attack, chloride attack and acid attack test and water absorption test. The concrete blend with 35% Tailing Material (TM) in place of river sand and 20% Fly Ash (FA) in place of OPC, has exhibited higher durability characteristics.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.411-414
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• 2005

Concrete structure is recognized as the universal structuring material for its outstanding formability, economic efficiency, and strength development. However, as the ageing of field workers and the deficiency of skilled workers due to evasions from 3D business have recently become the major issues of the industry in Korea and as the materials are becoming more diversified and complicated for today's concrete structures are becoming higher, larger, and specialized, the need for practicality of construction work based on new technology and new method has greatly increased. In other words, the overall condition of today's construction business requires researches and developments on the self-compacting concrete for higher construction efficiency and quality improvements and the high-strength lightweight concrete for concrete weight reduction and reduction of area. Therefore experimental tests were performed as such compressive strength, dry shrinkage and carbonation of self-compacting concrete.

• Cement Symposium
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• s.49
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• pp.27-28
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• 2022

The cement industry emits a large amount of CO₂, and 60~65% of the CO₂ is generated from calcination of raw materials. So, the CO₂ from cement industry can be reduced by substituting decarbonated materials for limestone. In this study, the chemical composition and grindability of three types of steel slag were evaluated and the application of those materials will be examined for the production of low heat portland cement.