• 제목/요약/키워드: carbon to nitrogen ratio

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바이오에탄올 SI 엔진에서 에탄올-가솔린 연료 혼합비율에 따른 희박연소 및 배기 특성 (Effect of Ethanol-gasoline Blending Ratio on Lean Combustion and Exhaust Emissions Characteristics in a SI Engine Fueled with Bioethanol)

  • 윤승현;김대성;이창식
    • 한국자동차공학회논문집
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    • 제19권1호
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    • pp.82-88
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    • 2011
  • Lean combustion and exhaust emission characteristics in a ethanol fueled spark-ignited engine according to ethanol-gasoline fuel blending ratio were investigated. The test engine was $1591cm^3$ and 10.5 of compression ratio SI engine with 4 cylinders. In addition, lambda sensor system was connected with universal ECU to control the lambda value which is varied from 1.0 to 1.5. The engine performance and lean combustion characteristics such as brake torque, cylinder pressure and rate of heat release were investigated according to ethanol-gasoline fuel blending ratio. Furthermore, the exhaust emissions such as carbon monoxide (CO), unburned hydrocarbon (HC), nitrogen oxides ($NO_x$) and carbon dioxide ($CO_2$) were measured by emission analyzers. The results showed that the brake torque, cylinder pressure and the stability of engine operation were increased as ethanol blending ratio is increased. Brake specific fuel consumption (BSFC) was increased in higher ethanol blending ratio while brake specific energy consumption (BSEC) was decreased in higher ethanol blending ratio. The exhaust emissions were decreased as ethanol blending ratio is increased under overall experimental conditions, however, some specific exhaust emission characteristics were mainly influenced by lambda value and ethanol-gasoline fuel blending ratio.

저 발열량 가스 연료의 화염거동 및 NOx 발생 특성에 관한 실험적 연구 (Experimental Study on the Flame Behavior and the NOx Emission Characteristics of Low Calorific Value Gas Fuel)

  • 김용철;이찬
    • 한국에너지공학회:학술대회논문집
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    • 한국에너지공학회 1999년도 춘계 학술발표회 논문집
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    • pp.89-93
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    • 1999
  • Experimental studies are conducted to investigate the flame stability and the thermal/fuel NOx formation characteristics of the low calorific value(LCV) gas fuel. Synthetic LCV fuel gas is produced through mixing carbon monoxide, hydrogen, nitrogen and ammonia on the basis that the thermal input of the syngas fuel into a burner is identical to that of natural gas, and then the syngas mixture is fed to and burnt with air on flat flame burner. Flame behaviors are observed to identify flame instability due to blow-off or flash-back when burning the LCV fuel gas at various equivalence ratio conditions. Measurements of NOx in combustion gas are made for comparing thermal and fuel NOx emissions from the LCV syngas combustion with those of the natural gas one, and for analyzing ammonia to NOx conversion mechanism. In addition, the nitrogen dilution of the LCV syngas is preliminarily attempted as a NOx reduction technique.

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곰보버섯 균사체 배양에 관한 연구 (A study on the Mycelial Growth of Morchella esculenta)

  • 신성의;차월석;이동병;정길록
    • 생명과학회지
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    • 제14권1호
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    • pp.126-130
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    • 2004
  • 곰보버섯(Morchella esculenta)은 맛과 영양이 풍부한 버섯으로 전 세계적으로 분포하는 버섯이다. 현재까지 우리나라에서 곰보버섯에 관한 체계적인 연구가 이루어지지 않은 상태에서 본 연구는 곰보버섯(자실체) 인공대량 생산방법 개발 및 심부배양을 통한 균사체 및 다당체 대량생산 공정개발을 위한 기초자료를 얻고자 shaking flask culture를 이용한 곰보버섯 균사체 배양특성에 관하여 조사하였다. 곰보버섯 균사체의 최적 배양온도는 $25^{\circ}C$이며, 최적 초기 pH는 6.5, 최적배지는 BG 이었다. BG 배지를 기본배지로 하여 영양 요구성 실험을 한 결과 최적탄소원은 fructose이고 최적농도는 5.0% (w/v)이며 질소원 선발 및 최적농도에서는 peptone과 NH$_4$Cl를 혼합하여 사용하였을 때 최대 균사체생육을 보였고, 상기의 두 질소원을 1:1의 무게비로 혼합하여 4.0% (w/v) 농도로 첨가하였을 때 최대 균사생육을 보였다.

Ruminal pH pattern, fermentation characteristics and related bacteria in response to dietary live yeast (Saccharomyces cerevisiae) supplementation in beef cattle

  • Zhang, Xiangfei;Dong, Xianwen;Wanapat, Metha;Shah, Ali Mujtaba;Luo, Xiaolin;Peng, Quanhui;Kang, Kun;Hu, Rui;Guan, Jiuqiang;Wang, Zhisheng
    • Animal Bioscience
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    • 제35권2호
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    • pp.184-195
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    • 2022
  • Objective: In this study we aimed to evaluate the effect of dietary live yeast supplementation on ruminal pH pattern, fermentation characteristics and associated bacteria in beef cattle. Methods: This work comprised of in vitro and in vivo experiments. In vitro fermentation was conducted by incubating 0%, 0.05%, 0.075%, 0.1%, 0.125%, and 0.15% active dried yeast (Saccharomyces cerevisiae, ADY) with total mixed ration substrate to determine its dose effect. According to in vitro results, 0.1% ADY inclusion level was assigned in in vivo study for continuously monitoring ruminal fermentation characteristics and microbes. Six ruminally cannulated steers were randomly assigned to 2 treatments (Control and ADY supplementation) as two-period crossover design (30-day). Blood samples were harvested before-feeding and rumen fluid was sampled at 0, 3, 6, 9, and 12 h post-feeding on 30 d. Results: After 24 h in vitro fermentation, pH and gas production were increased at 0.1% ADY where ammonia nitrogen and microbial crude protein also displayed lowest and peak values, respectively. Acetate, butyrate and total volatile fatty acids concentrations heightened with increasing ADY doses and plateaued at high levels, while acetate to propionate ratio was decreased accordingly. In in vivo study, ruminal pH was increased with ADY supplementation that also elevated acetate and propionate. Conversely, ADY reduced lactate level by dampening Streptococcus bovis and inducing greater Selenomonas ruminantium and Megasphaera elsdenii populations involved in lactate utilization. The serum urea nitrogen decreased, whereas glucose, albumin and total protein concentrations were increased with ADY supplementation. Conclusion: The results demonstrated dietary ADY improved ruminal fermentation dose-dependently. The ruminal lactate reduction through modification of lactate metabolic bacteria could be an important reason for rumen pH stabilization induced by ADY. ADY supplementation offered a complementary probiotics strategy in improving gluconeogenesis and nitrogen metabolism of beef cattle, potentially resulted from optimized rumen pH and fermentation.

하수슬러지로부터 분리된 혐기세균에 의한 수소생산 최적화 (Optimization of Hydrogen Production Using the Mixed Microflora Isolated from Sewage Sludge)

  • 오유관;김미선
    • 한국수소및신에너지학회논문집
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    • 제19권1호
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    • pp.41-48
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    • 2008
  • Fermentative $H_2$ production was studied using microbial consortia isolated from heat-treated ($90{\circ}C$, 20 min) sewage sludge. Important parameters investigated were carbon(C) and nitrogen(N)-sources, C/N ratio, phosphate concentration, pH and temperature during anaerobic cultivation in serum bottles. Starch, ribose, sucrose and glucose were good C-sources for the culture growth and $H_2$ production. Yeast extract was better N-source than $(NH_4)_2SO_4$ or peptone when individually added to the synthetic media, however the combination of above three N-sources exhibited the additional effect for cell growth and $H_2$ evolution. Addition of 100 mM phosphate as a buffering agent prevented the rapid pH drop during the cultivation. The optimum initial pH for the cell growth was at 7.0, whereas $H_2$ production was observed at pH 5.5. Optimum temperature for the cell growth and $H_2$ production was $37{\circ}C$. Initial C/N ratio of 1.22 in the media using glucose and yeast extract as the C- and N-sources, respectively, showed the $H_2$ yield 1.0 mol $H_2$/mol glucose.

Biosurfactant 생산 효모 Rhodotorula sp. G-1의 분리 및 Biosurfactant 생산

  • 강상모;이철수;김영찬
    • 한국미생물·생명공학회지
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    • 제24권2호
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    • pp.185-190
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    • 1996
  • Some microorganisms including yeasts produce surface tension-decreasing biosurfactants. The strain G-1, the best producer of biosurfatants was isolated from the soil and identified as Rhodotorula sp., which was not discribed any report. The Rhodotorula sp. G-1 produced biosurfactant from vegetable oils, but failed to produce it from n-alkane or carbohydrate. Yeast extract was found to be more effective for the biosurfactant production as nitrogen source than any other inorganic nitrogen source. The composion of the optimal medium contained the following conponents: soybean oil 4%, glucose 2%, yeast extract 0.5%, KH$^{2}$PO$^{4}$ 0.1%, K$^{2}$HP0$^{4}$ 0.l%, MgSO$^{4}$ 5%, CaCl$^{2}$ 0.01%, NaCl 0.01%, pH 6.0. The surface tension activity was increased to 14% when, at first, the culture broth was fermented with only soybean oil as carbon sourse, and after 90 hours, feeded glucose, than that Of glucose and soybean oil added to it simultaneously. The maxium yield of the biosurfactant was about 15 g/l by after 90 hours, the feeding method of glucose.

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침지식 여과조를 이용한 합성 폐수의 탈질화 (Denitrification of Synthetic Wastewater in Submerged Biofilter)

  • 오승용;조재윤;김인배
    • 한국양식학회지
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    • 제10권3호
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    • pp.335-346
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    • 1997
  • 연구는 순환 여과식 어류 양식 시설에 일반적으로 이용되고 있는 선라이트 골판을 여과재료로 한 침지식 여과조의 적정 탈질 조건을 구명하기 위해 외부 탄소원으로 메탄올과 글루코스를 사용하여 수리학적 체류 시간 (hydraulic retention time, HRT)과 COD에 대한 NO 하(3) 상(-)-N 비율 변화에 따른 적정 탈질 조건을 알아보았다. 질산성 질소와 총무기질소(TIN)의 제거 효율은 HRT 4 시간보다는 8 시간이 좋았으며, 글루코스보다는 메탄올을 이용한 것이 좋았다(P<0.05). 최대 질산성 질소 제거는 글루코스의 경우 HRT 8 시간과 C : N 비율 4일 때 86.3%였고, 메탄올은 HRT 8시간과 C : N 비율 5일 때 97.8%, 6일 때 92.2%를 보여 C : N 비율 5가 가장 최적인 것으로 나타났다. 최대 총무기질소 제거 효율은 HRT 8 시간일 때 C : N 비율 5에서 글루코스는 71.5%, 메탄올은 96.9%을 보였다. 탈질화에 필수적인 혐기적 조건은 HRT 8 시간과 C : N 비율 5 이상이 되었을 때 이루어진 것으로 보아 적정 C : N 비율과 혐기적 조건이 이루어졌을 때의 최적의 탈질 효율을 보이는 것으로 나타났다.

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일본 서남부 가고시마 와카미코 해저 열수환경에서 형성된 2:1 점토광물 내 암모늄 거동 및 질소동위원소 특성 (Ammonium Behavior and Nitrogen Isotope Characteristics of 2:1 Clay Minerals from Submarine Hydrothermal System in the Wakamiko Crater of Kagoshima Bay, Southwestern Japan)

  • 조재국;토시로 야마나카;신동복
    • 자원환경지질
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    • 제54권1호
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    • pp.151-160
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    • 2021
  • 함암모늄 2:1 점토광물 내 암모늄 거동과 질소동위원소 특성을 살펴보기 위해 일본 남서부 해저 와카미코 화구(Wakamiko crater) 내 열수가 분출하는 두 지점에서 퇴적물 코어를 채취하여 스멕타이트로 대표되는 점토입자를 추출하였다. 점토입자 내 무기탄소 제거 후 순차적인 유기물 분해과정에서 감소하는 탄소-질소 비에 근거하여 무기질소 함량을 추정한 결과, 전질소에 대한 무기질소 비율은 SES 지점(Core#1093MG: av. 11.5%)에 비해 SWS 지점 (Core#1094MR: av. 18.2%)에서 높은 경향을 보였다. 후자에서 높은 광물 결정도를 보인 점은 상대적으로 진전된 광물화와 함께 교환성 암모늄이 비교환성 암모늄으로 전환된 결과로 해석된다. 단계적인 점토입자 내 교환성 암모늄의 제거과정에서 나타난 질소동위원소 조성 변화(SES 지점: Core#1093MG: -4.4 ~ +0.2 ‰, av. -2.4 ‰; SWS 지점: Core#1094MR: -0.7 ~ +3.0 ‰, av. +1.5 ‰)로부터 심부 마그마에서 비롯된 열류 및 열수에 의한 국부적인 온도변화는 함암모늄 2:1 점토광물의 형성에 관여한 유체 내 용존 암모늄과 암모니아 사이에서 질소동위원소 분별을 야기했을 것이다.

Preparation of Aluminum Nitride Powders and Whiskers Using Aluminum(III) Salts as a Precursor

  • Jung, Woo-Sik;Chae, Seen-Ae
    • 한국세라믹학회지
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    • 제40권8호
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    • pp.720-724
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    • 2003
  • Aluminum nitride (AlN) powders were synthesized by using a mixture of an aluminum nitrate or sulfate salt and carbon (mole ratio of $Al^{3+}$ to carbon=L : 30). The AlN was obtained by calcining the mixture under a flow of nitrogen in the temperature range 1100-1$600^{\circ}C$ and then burning out the residual carbon. The process of conversion of the salt to AlN was monitored by XRD and $^{27}$ Al magic-angle spinning (MAS) NMR spectroscopy. The salt decomposed to ${\gamma}$-alumina and then converted to AlN without phase transition from ${\gamma}$-to-$\alpha$-alumina. $^{27}$ Al MAS NMR spectroscopy shows that the formation of AlN commenced at 110$0^{\circ}C$. AlN powders obtained from the sulfate salt were superior to those from the nitrate salt in terms of homogeneity and crystallinity. A very small amount of AlN whiskers was obtained by calcining a mixture of an aluminum sulfate salt and carbon at 115$0^{\circ}C$ for 40 h, and the growth of the whiskers is well explained by the particle-to-particle self-assembly mechanism.

Evaluating Soil Carbon Changes in Paddy Field based on Different Fraction of Soil Organic Matter

  • Seo, Myung-Chul;Cho, Hyeon-Suk;Kim, Jun-Hwan;Sang, Wan-Gyu;Shin, Pyeong;Lee, Geon Hwi
    • 한국토양비료학회지
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    • 제48권6호
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    • pp.736-743
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    • 2015
  • Organic matter plays important roles in soil ecosystem in terms of carbon and nitrogen cycles. Due to recent concerns on climate change, carbon sequestration in agricultural land has become one of the most interesting and debating issues. It is necessary to understand behavior of soil carbon for evaluating decomposition or sequestration of organic matter and analyzing potential carbon decomposition pattern about the kinds of organic matter sources to cope with well. In order to evaluate decomposition of soil carbon according to organic material during cultivating rice in paddy field, we treated organic material such as hairy vetch, rice straw, oil cake fertilizer, and manure compost at $50{\times}50{\times}20cm$ blocks made of wood board, and analyzed carbon contents of fulvic acid and humic acid fraction, and total carbon periodically in 2013 and 2014. Soil sampling was conducted on monthly basis. Four Kinds of organic matter were mixed with soil in treatment plots on 2 weeks before transplanting of rice. The treatment of animal compost showed the highest changes of total carbon, which showed $7.9gkg^{-1}$ in May 2013 to $11.6gkg^{-1}$ in October 2014. Fulvic acid fraction which is considered to easily decompose ranged from 1 to $2gkg^{-1}$. Humic acid fraction was changed between 1 to $3gkg^{-1}$ in all treatments until organic material had been applied in 2014. From May to August in the second year, the contents of humic acid fraction increased to about $4gkg^{-1}$. The average of humic fraction carbon at treatments of animal compost was recorded highest among treatments during two years, $2.1gkg^{-1}$. The treatment of animal compost has showed the lowest ratio of fulvic acid fraction, humic acid fraction compared with other treatments. The average ratio of fulvic fraction carbon in soil ranged from 16 to 20%, and humic fraction carbon ranged from 19 to 22%. In conclusion, animal compost including wood as bulking agent is superior in sequestrating carbon at agricultural land to other kinds of raw plant residue.