• 공업화학
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• 제1권2호
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• pp.176-181
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• 1990

탄소섬유/알루미늄 복합 재료의 계면 전단 강도를 향상시키기 위하여 탄소섬유 표면을 $400-600^{\circ}C$의 온도 범위에서 황화수소 기체로 처리하였다. 처리 탄소섬유 표면의 변화를 주사 전자 현미경과 X-선 광전자 스펙트럼에 의해 관찰하고 분석하여 표면 처리 탄소섬유의 표면에 황 화합물이 존재하는 것을 확인하고, 표면처리 탄소섬유의 탄소 및 탄소의 함량 변화를 조사하였다. 탄소섬유 표면의 황화수소 기체 처리의 최적 온도는 $550^{\circ}C$였고, 처리 탄소섬유 표면의 황 화합물은 disulfide, $(S)_n$ 및 thiophene의 형태를 이루고 있었다. 처리 탄소섬유는 처리 온도 $400-600^{\circ}C$의 범위에서 5% 정도의 인장 강도 저하를 나타냈다.

• 접착 및 계면
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• 제21권2호
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• pp.51-57
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• 2020

최근 산업활동을 통해 배출되는 유해 오염물질 제거에 대한 관심이 증가하고 있다. 본 연구에서는 수증기 활성화 법을 이용하여 활성탄소섬유를 제조하고, 이의 유해가스 흡착 및 전기화학적 감응 특성을 분석하였다. 활성탄소섬유의 균일한 기공 구조, 활성 반응 면적 및 반응 위치를 조절하기 위하여, 활성화 온도(750-850 ℃) 및 활성화 시간(30-240 min)을 조절하였고, 다양한 활성화 조건을 통해 제조된 활성탄소섬유의 SO₂와 NO 가스 흡착 및 가스 센서를 통한 감응 특성을 분석하였다. 특히, 850 ℃에서 45 min동안 수증기 활성화 반응을 통해 제조된 활성탄소섬유가 가장 높은 비표면적(1,041.9 ㎡/g)과 기공 특성(0.42 ㎤/g)을 보였으며, 우수한 SO₂ (1.061 mg/g) 및 NO (1.210 mg/g) 가스 흡착 특성을 보였다.

• 한국염색가공학회지
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• 제33권4호
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• pp.280-287
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• 2021

Generating electricity by using water in many energy harvesting system is due to their simplicity, sustainability and eco-friendliness. Evaporation-driven moist-electric generators (EMEGs) are an emergent technology and show great potential for harvesting clean energy. In this study, we report a transpiration driven electro kinetic power generator (TEPG) that utilize capillary flow of water in an asymmetrically wetted cotton fabric coated with carbon black. When water droplets encounter this textile EMEG, the water flows spontaneously under capillary action without requiring an external power supply. First carbon black sonicated and dispersed well in three different solvent system such as dimethylformamide (DMF), sodiumdedecylbenzenesulfonate (SDBS-anionic surfactant) and cetyltrimethylammoniumbromide (CTAB-cationic surfactant). A knitted cotton/PET fabric was coated with carbon black by conventional pad method. Cotton/PET fabrics were immersed and stuttered well in these three different systems and then transferred to an autoclave at 120 ℃ for 15 minutes. Cotton/PET fabric treated with carbon black dispersed in DMF solvent generated maximum current up to 5 µA on a small piece of sample (2 µL/min of water can induce constant electric output for more than 286 hours). This study is high value for designing of electric generator to harvest clean energy constantly.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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• pp.188-191
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• 2002

3-D orthogonal woven carbon/Al composites were fabricated using a pressure infiltration casting method. Especially, to minimize geometrical deformation of fiber pattern and $Al_4C_3$ formation, the process parameters of the minimum pressurizing force, melting temperature, delay and holding time of molten aluminum pressurizing was optimized through the PC-controlled monitoring system. Resonant ultrasound spectroscopy (RUS) was utilized to measure the effective elastic constants of 3-D orthogonal woven carbon/Al composites. The CTE measurement was conducted using strain gages in a heating oven.

• Carbon letters
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• 제11권4호
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• pp.298-303
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• 2010

A method of functionalization of multi-walled carbon nanotube (MWNT) at room temperature using dry ozone gas is described. The resulting MWNT were characterized by Fourier transform infrared, x-ray photoelectron spectroscopy, and scanning electron microscopy. Combined to these analyses and solubility in liquids, it could be concluded that the dry ozone gas exposure introduces polar functional groups such as carboxylic groups to MWNT similar to acidic modification of MWNT. Particularly, the stable dispersion of MWNT in water after ozone treatment above a critical level could be obtained, implying potential bio-application. The hydrophilic functional groups on the MWNT introduced by ozone oxidation were helpful in improving the interaction with functional groups in PA6 such as $-NH_2$ and -CONH- resulting in improved mechanical properties.

• Journal of the Korean Wood Science and Technology
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• 제39권2호
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• pp.156-162
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• 2011

To evaluate the bonding performance of reinforced glulam, the textile type of glass fiber and aramid fiber, and the sheet type of glass fiber reinforced plastic (GFRP) and carbon fiber reinforced plastic (CFRP) were used as reinforcements. The reinforced glulam was manufactured by inserting reinforcement between the outmost and middle lamination of 5ply glulam. The types of adhesives used in this study were polyvinyl acetate resins (MPU500H, and MPU600H), polyurethane resin and resorcinol resin. The block shear strengths of the textile type in glass fiber reinforced glulam using MPU500H and resorcinol resin were higher than 7.1 N/$mm^2$, and these glulams passed the wood failure requirement of Korean standards (KS). In case of the sheet types, GFRP reinforced glulams using MPU500H, polyurethane resin and resorcinol resin, and CFRP reinforced glulams using MPU500H and polyurethane resin passed the requirement of KS. The textile type of glass fiber reinforced glulam using resorcinol resin after water and boiling water soaking passed the delamination requirement of KS. The only GFRP reinforced glulam using MPU500H after water soaking passed the delamination requirement of KS. We conclude that the bonding properties of adhesive according to reinforcements are one of the prime factors to determine the bonding performance of the reinforced glulam.

• Structural Engineering and Mechanics
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• 제33권4호
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• pp.429-446
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• 2009

Three-scale homogenization procedure is proposed in this paper to provide estimates of the effective thermal conductivities of porous carbon-carbon textile composites. On each scale - the level of fiber tow (micro-scale), the level of yarns (meso-scale) and the level of laminate (macro-scale) - a two step homogenization procedure based on the Mori-Tanaka averaging scheme is adopted. This involves evaluation of the effective properties first in the absence of pores. In the next step, an ellipsoidal pore is introduced into a new, generally orthotropic, matrix to make provision for the presence of crimp voids and transverse and delamination cracks resulting from the thermal transformation of a polymeric precursor into the carbon matrix. Other sources of imperfections also attributed to the manufacturing processes, including non-uniform texture of the reinforcements, are taken into consideration through the histograms of inclination angles measured along the fiber tow path together with a particular shape of the equivalent ellipsoidal inclusion proposed already in Sko ek (1998). The analysis shows that a reasonable agreement of the numerical predictions with experimental measurements can be achieved.

• 한국의류산업학회지
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• 제18권6호
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• pp.733-745
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• 2016

This paper provides a review of wearable textile strain sensors that can measure the deformation of the body surface according to the movements of the wearer. In previous studies, the requirements of textile strain sensors, materials and fabrication methods, as well as the principle of the strain sensing according to sensor structures were understood; furthermore, the factors that affect the sensing performance were critically reviewed and application studies were examined. Textile strain sensors should be able to show piezoresistive effects with consistent resistance-extension in response to the extensional deformations that are repeated when they are worn. Textile strain sensors with piezoresistivity are typically made using conductive yarn knit structures or carbon-based fillers or conducting polymer filler composite materials. For the accuracy and reliability of textile strain sensors, fabrication technologies that would minimize deformation hysteresis should be developed and processes to complement and analyze sensing results based on accurate understanding of the sensors' resistance-strain behavior are necessary. Since light-weighted, flexible, and highly elastic textile strain sensors can be worn by users without any inconvenience so that to enable the users to continuously collect data related to body movements, textile strain sensors are expected to become the core of human interface technologies with a wide range of applications in diverse areas.

• Carbon letters
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• 제12권1호
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• pp.31-38
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• 2011

This study experimentally investigated dicyclohexylammonium 2-cyanoacrylate (CA) as a potential comonomer for polyacrylonitrile (PAN) based carbon fiber precursors. The P(AN-CA) copolymers with different CA contents (0.19-0.78 mol% in the feed) were polymerized using solution polymerization with 2,2-azobis(isobutyronitrile) as an initiator. The chemical structure and composition of P(AN-CA) copolymers were determined by proton nuclear magnetic resonance and elemental analysis, and the copolymer composition was similar to the feeding ratio of the monomers. The effects of CA comonomer on the thermal properties of its copolymers were characterized differential scanning calorimetry (DSC) in nitrogen and air atmospheres. The DSC curves of P(AN-CA) under nitrogen atmosphere indicated that the initiation temperature for cyclization of nitrile groups was reduced to around $235^{\circ}C$. The heat release and the activation energy for cyclization reactions were decreased in comparison with those of PAN homopolymers. On the other hand, under air atmosphere, the P(AN-CA) with 0.78 mol% CA content showed that the initiation temperature of cyclization was significantly lowered to $160.1^{\circ}C$. The activation energy value showed 116 kJ/mol, that was smaller than that of the copolymers with 0.82 mol% of itaconic acids. The thermal stability of P(AN-CA), evidenced by thermogravimetric analyses in air atmosphere, was found higher than PAN homopolymer and similar to P(AN-IA) copolymers. Therefore, this study successfully demonstrated the great potential of P(AN-CA) copolymers as carbon fiber precursors, taking advantages of the temperature-lowering effects of CA comonomers and higher thermal stability of the CA copolymers for the stabilizing processes.

• 한국구조물진단유지관리공학회 논문집
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• 제24권4호
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• pp.81-90
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• 2020

기존 비보강 조적벽체의 내진 성능과 에너지 효율을 동시에 보강하기 위한 TCP 보강 공법을 개발하였다. TCP는 경량 모르타르 내 격자형 탄소섬유 시트와 모세관 튜브를 매립하여 일체로 타설한 패널로 조적벽체에 부착하여 탄소섬유 시트에 의한 내진보강과 모세관 튜브에 온수를 공급함으로써난방 또는 단열 등의 에너지 보강을 동시에 달성할수 있는 보강 공법이다. 본 연구에서는 TCP의 내진 보강 효과를 파악하기 위하여 TCP 보강 유무에 따른 조적 벽체를 대상으로 정적가력실험을 실시하였다. 실험 결과, TCP 보강에 의해 최대 강도 및 변위가 약 1.4배증가하였으며, 초기 강성과 에너지 흡수능력에 효과가 있음을 보였다. 또한, 손상에 따른 조적 벽체의 변형이 제어됨에 따라 취성 파괴를 예방할수 있을 것으로 판단된다.