• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.23 no.1
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• pp.49-62
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• 2018

Net community production (NCP), defined as the difference between net primary production and respiration of heterotrophs, has been used as a measure of oceanic biological carbon pump. This paper summarizes the theoretical background and experimental methods for the estimation of NCP based on $O_2/Ar$ measurements ($O_2/Ar-NCP$). The high frequency measurements of $O_2/Ar-NCP$ (<1 min) is a significant enhancement over the conventional measures of biological pump, such as new production and export production. This paper also introduces some of important works as to the comparison between $O_2/Ar-NCP$ and other measures of biological pump, the distributions of $O_2/Ar-NCP$ in the oceans, and the correlation of $O_2/Ar-NCP$ with various oceanic parameters, including community structures.

• Applied Chemistry for Engineering
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• v.23 no.6
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• pp.583-587
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• 2012

Six kinds of new aminoalkyl phosphonic acid or aminoalkyl phosphinic acid derivatives with mono-dialkylamino, or di-dialkylamino functional groups in the molecule were synthesized and their smoke densities were tested. The aminoalkyl phposphonic acid or aminoalkyl phosphinic acid derivatives were synthesized with quantitative yields of 90~98.6% by one step reaction of the phosphorus acid or hypo phosphorous acid with amine and aldehyde. The smoke density was measured by the ASTM E 662 method. Values of the smoke density were obtained from 224.5 to 256.6. The smoke density of the compounds with two aminoalkyl structures decreased more than that of compounds with one aminoalkyl structure. In addition, there was no correlation between the smoke density and the number of carbon atoms in the alkyl group attached to the amino group.

• Structural Engineering and Mechanics
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• v.67 no.2
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• pp.207-217
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• 2018

In past years, numerous problems have vexed engineers with regard to buckling, corrosion, bending, and overloading in damaged steel structures. This article sets out to investigate the possible effects of carbon fiber reinforced polymer (CFRP) and steel plates for retrofitting deficient steel square hollow section (SHS) columns. The effects of axial loading, stiffness, axial displacement, the position and shape of deficient region on the length of steel SHS columns, and slenderness ratio are examined through a detailed parametric study. A total of 14 specimens was tested for failure under axial compression in a laboratory and simulated using finite element (FE) analysis based on a numerical approach. The results indicate that the application of CFRP sheets and steel plates also caused a reduction in stress in the damaged region and prevented or retarded local deformation around the deficiency. The findings showed that a deficiency leads to reduced load-carrying capacity of steel SHS columns and the retrofitting method is responsible for the increase in the load-bearing capacity of the steel columns. Finally, this research showed that the CFRP performed better than steel plates in compensating the axial force caused by the cross-section reduction due to the problems associated with the use of steel plates, such as in welding, increased weight, thermal stress around the welding location, and the possibility of creating another deficiency by welding.

• Steel and Composite Structures
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• v.34 no.2
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• pp.261-277
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• 2020

The main objective of this research paper is to consider vibration analysis of vacancy defected graphene sheet as a nonisotropic structure via molecular dynamic and continuum approaches. The influence of structural defects on the vibration of graphene sheets is considered by applying the mechanical properties of defected graphene sheets. Molecular dynamic simulations have been performed to estimate the mechanical properties of graphene as a nonisotropic structure with single- and double- vacancy defects using open source well-known software i.e., large-scale atomic/molecular massively parallel simulator (LAMMPS). The interactions between the carbon atoms are modelled using Adaptive Intermolecular Reactive Empirical Bond Order (AIREBO) potential. An isogeometric analysis (IGA) based upon non-uniform rational B-spline (NURBS) is employed for approximation of single-layered graphene sheets deflection field and the governing equations are derived using nonlocal elasticity theory. The dependence of small-scale effects, chirality and different defect types on vibrational characteristic of graphene sheets is investigated in this comprehensive research work. In addition, numerical results are validated and compared with those achieved using other analysis, where an excellent agreement is found. The interesting results indicate that increasing the number of missing atoms can lead to decrease the natural frequencies of graphene sheets. It is seen that the degree of the detrimental effects differ with defect type. The Young's and shear modulus of the graphene with SV defects are much smaller than graphene with DV defects. It is also observed that Single Vacancy (SV) clusters cause more reduction in the natural frequencies of SLGS than Double Vacancy (DV) clusters. The effectiveness and the accuracy of the present IGA approach have been demonstrated and it is shown that the IGA is efficient, robust and accurate in terms of nanoplate problems.

• Bulletin of the Korean Chemical Society
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• v.21 no.6
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• pp.588-594
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• 2000

Structural changes of an iron phthalocyanine (FePC) monolayer induced by adsorption and externally applied potential on high area carbon surface have been investigated in situ by iron K-edge X-ray absorption fine structure (XAFS) in 0.5 M $H_2S0_4.$ Fine structures shown in the X-ray absorption near edge structure (XANES) for microcrystalline FePC decreased upon adsorption and further diminished under electrochemical conditions. Fe(II)PC(-2) showed a 1s ${\rightarrow}$ 4p transition as poorly resolved shoulder to the main absorption edge rather than a distinct peak and a weak 1s ${\rightarrow}$ 3d transition. The absorption edge position measured at half maximum was shifted from 7121.8 eV for Fe(lI)PC(-2) to 7124.8 eV for $[Fe(III)PC(-2)]^+$ as well as the 1s ${\rightarrow}$ 3d pre-edge peak being slightly enhanced. However, essentially no absorption edge shift was observed by the 1-electron reduction of Fe(Il)PC(-2), indicating that the species formed is $[Fe(II)PC(-3)]^-$. Structural parameters were obtained by analyzing extended X-ray absorption fine structure (EXAFS) oscillations with theoretical phases and amplitudes calculated from FEFF 6.01 using multiple-scattering theory. When applied to the powder FePC, the average iron-to-phthalocyanine nitrogen distance, d(Fe-$N_p$) and the coordination number were found to be 1.933 $\AA$ and 3.2, respectively, and these values are the same, within experimental error, as those reported ( $1.927\AA$ and 4). Virtually no structural changes were found upon adsorption except for the increased Debye-Wailer factor of $0.005\AA^2$ from $0.003\AA^2.$ Oxidation of Fe(II)PC(-2) to $[Fe(III)PC(-2)]^+$ yielded an increased d(Fe-Np) (1 $.98\AA)$ and Debye-Wailer factor $(0.005\AA^2).$ The formation of $[Fe(II)PC(-3)]^-$, however, produced a shorter d(Fe-$N_p$) of $1.91\AA$ the same as that of crystalline FePC within experimental error, and about the same DebyeWaller $factor(0.006\AA^2)$.

• Ceramist
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• v.21 no.4
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• pp.388-405
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• 2018

In this paper, we review about current development of electrode materials for Li-ion batteries and catalysts for fuel cells. We scrutinized various electrode materials for cathode and anode in Li-ion batteries, which include the materials currently being used in the industry and candidates with high energy density. While layered, spinel, olivine, and rock-salt type inorganic electrode materials were introduced as the cathode materials, the Li metal, graphite, Li-alloying metal, and oxide compound have been discussed for the application to the anode materials. In the development of fuel cell catalysts, the catalyst structures classified according to the catalyst composition and surface structure, such as Pt-based metal nanoparticles, non-Pt catalysts, and carbon-based materials, were discussed in detail. Moreover, various support materials used to maximize the active surface area of fuel cell catalysts were explained. New electrode materials and catalysts with both high electrochemical performance and stability can be developed based on the thorough understanding of earlier studied electrode materials and catalysts.

• Journal of the Society of Naval Architects of Korea
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• v.47 no.5
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• pp.697-702
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• 2010

A WIG(Wing-In-Ground effect) craft flies close to the water surface by utilizing a cushion of relatively high pressurized air between its wing and water surface. This implies that when one designs such craft it is important to have lightweight structures with adequate strength to resist external loads with some margins. To investigate this requirement, this paper deals with the structural analysis of the bottom plate of small WIG craft having a design landing weight of 1.2-ton. As building materials for the WIG craft, pre-preg carbon/epoxy composites are considered. The strength information of the bottom plate is obtained using the first-ply-failure analysis in conjunction with a mid-plane symmetric laminated plate theory. As a result, the first-ply-failure location, load and deflection of the bottom plate are obtained. The calculated strength information is compared with the water reaction load for the bottom plate of seaplanes considered when they land on the water surface -the same fluid-structure interaction mechanism as that of WIG craft. In the calculation of seaplane water reaction load information, the rules shown in FAR(Federal Aviation Regulations) Part 25 are used. Through the comparison, the structural integrity of the bottom plate for the WIG craft is checked.

• Steel and Composite Structures
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• v.25 no.2
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• pp.141-155
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• 2017

This paper presents an investigation into the magneto-thermo-mechanical vibration and damping of a viscoelastic functionally graded-carbon nanotubes (FG-CNTs)-reinforced curved microbeam based on Timoshenko beam and strain gradient theories. The structure is surrounded by a viscoelastic medium which is simulated with spring, damper and shear elements. The effective temperature-dependent material properties of the CNTs-reinforced composite beam are obtained using the extended rule of mixture. The structure is assumed to be subjected to a longitudinal magnetic field. The governing equations of motion are derived using Hamilton's principle and solved by employing differential quadrature method (DQM). The effect of various parameter like volume percent and distribution type of CNTs, temperature change, magnetic field, boundary conditions, material length scale parameter, central angle, viscoelastic medium and structural damping on the vibration and damping behaviors of the nanocomposite curved microbeam is examined. The results show that with increasing volume percent of CNTs and considering magnetic field, material length scale parameter and viscoelastic medium, the frequency of the system increases and critically damped situation occurs at higher values of damper constant. In addition, the structure with FGX distribution type of CNTs has the highest stiffness. It is also observed that increasing temperature, structural damping and central angle of curved microbeam decreases the frequency of the system.

• Journal of Aerospace System Engineering
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• v.12 no.6
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• pp.32-40
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• 2018

An impact localization for a carbon fiber reinforced plastic (CFRP) composite plate was performed using the multiplexed fiber bragg grating (FBG) sensors and the error-outlier based impact localization algorithm. We found that the optimal impact localization with the maximum error of 31.82 mm and the averaged error of 6.31 mm are obtained when the error threshold (ET) and constant level (CL) are 0.3 nm and 110, respectively. Moreover, the detailed process of impact localization under certain optimal parameters and the relevant results were thoroughly investigated. We conclude that the multiplexed FBG sensors and the error-outlier based impact localization algorithm are suitable for an impact localization on composite structures, and expect that they can be utilized for various structural health monitoring (SHM) in the future.

• Steel and Composite Structures
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• v.30 no.3
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• pp.281-292
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• 2019

In this paper, analysis of critical fluid velocity and heat transfer in the nanocomposite pipes conveying nanofluid is presented. The pipe is reinforced by carbon nanotubes (CNTs) and the fluid is mixed by $AL_2O_3$ nanoparticles. The material properties of the nanocomposite pipe and nanofluid are considered temperature-dependent and the structure is subjected to magnetic field. The forces of fluid viscosity and turbulent pressure are obtained using momentum equations of fluid. Based on energy balance, the convection of inner and outer fluids, conduction of pipe and heat generation are considered. For mathematical modeling of the nanocomposite pipes, the first order shear deformation theory (FSDT) and energy method are used. Utilizing the Lagrange method, the coupled pipe-nanofluid motion equations are derived. Applying a semi-analytical method, the motion equations are solved for obtaining the critical fluid velocity and critical Reynolds and Nusselt numbers. The effects of CNTs volume percent, $AL_2O_3$ nanoparticles volume percent, length to radius ratio of the pipe and shell surface roughness were shown on the critical fluid velocity, critical Reynolds and Nusselt numbers. The results are validated with other published work which shows the accuracy of obtained results of this work. Numerical results indicate that for heat generation of $Q=10MW/m^3$, adding 6% $AL_2O_3$ nanoparticles to the fluid increases 20% the critical fluid velocity and 15% the Nusselt number which can be useful for heat exchangers.