• Corrosion Science and Technology
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• 제15권5호
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• pp.245-252
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• 2016

The pipelines and equipments are degraded by flow-accelerated corrosion (FAC), and a large-scale test facility was constructed for simulate the FAC phenomena in secondary coolant environment of PWR type nuclear power plants. Using this facility, FAC test was performed on weld pipe (carbon steel and low alloy steel) at the conditions of high velocity flow (> 10 m/s). Wall thickness was measured by high temperature ultrasonic monitoring systems (four-channel buffer rod type and waveguide type) during test period and room temperature manual ultrasonic method before and after test period. This work deals with the complex effects of flow velocity on the wall thinning in weld pipe and the test results showed that the higher flow velocity induced different increasement of wall thinning rate for the carbon steel and low alloy steel pipe.

• Corrosion Science and Technology
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• 제21권3호
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• pp.209-220
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• 2022

Erosion-corrosion behaviors of Hadfield steel under a neutral aqueous environment with fine SiO₂ particles were examined and compared with those of conventional carbon steel. A range of electrochemical experiments (potentiodynamic polarization, linear polarization, and impedance), immersion test, and slurry pot test (i.e., erosion-corrosion test) were performed. Results showed that the Hadfield steel composed of austenitic matrix with (Fe,Mn)-based carbide had lower corrosion potential and higher corrosion current density than carbon steel with a typical ferrite/pearlite structure. In addition, pipe forming increased total corrosion rates (i.e., pure corrosion and erosion-enhanced corrosion rates). Nevertheless, the erosion-corrosion rate of Hadfield steel was much smaller. Morphological observation showed that local damage in the form of a crater by erosion-corrosion was more noticeable in carbon steel. The higher resistance of Hadfield steel to erosion-corrosion was attributed to its lower total erosion rates (i.e., pure erosion and corrosion-enhanced erosion rates) highly depending on surface hardness. This study suggests that Hadfield steel with higher resistances to flowing erosion-corrosion in an aqueous environment can be applied widely to various industrial fields.

• 상하수도학회지
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• 제22권3호
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• pp.379-387
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• 2008

The pH & alkalinity adjustment method by lime and carbon dioxide($CO_2$) for corrosion control in water distribution system was investigated to evaluate the corrosion characteristics of metal pipes, such as galvanized iron, copper, stainless steel, and carbon steel. When the pH in sand filtered and ozone+GAC treated water was increased with lime and $CO_2$ from 7.5 to 8.0, the concentration of residual chlorine decreased at higher pH and longer reaction time; the concentration of trihalomethane increased. The corrosion rate of coupons with corrosion control using lime and carbon dioxide was showed much smaller than those without corrosion control using pilot-scale simulated distribution system. The galvanized iron was corroded much faster than carbon steel, copper, and stainless steel. Especially, copper and stainless steel coupons were hardly corroded. The galvanized iron and carbon steel coupons with corrosion control were produced the corrosion products less than those without corrosion control by the results of environmental scanning electron microscope(ESEM) and energy dispersive x-ray spectroscopy(EDS) analyses. The galvanized iron coupon with pH and alkalinity adjustment by lime and carbon dioxide was detected about 30 percent of zinc, when the carbon steel was detected about 30 percent of calcium by calcium carbonate products formation. For the results of X-ray diffraction(XRD) analyses, the goethite(${\alpha}$-FeOOH) was identified as primary corrosion product of galvanized iron without corrosion control, while the Zinc oxide(ZnO) was found on corrosion products of galvanized iron coupon with corrosion control as the results of EDS analyses. However, the carbon steel corrosion products regardless of corrosion control were composed predominantly of maghemite(${\gamma}-Fe_2O_3$) and hematite(${\alpha}-Fe_2O_3$).

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2012년도 춘계학술대회 논문집
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• pp.723-724
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• 2012

• 대한기계학회논문집A
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• 제23권7호
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• pp.1147-1154
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• 1999

The objective of this paper is to evaluate the fracture resistance characteristics of SA508 CL.1a carbon steel, and their associated welds manufactured for primary coolant piping system of nuclear power plants. The effect of various parameters such as pipe size, welding method and chemical composition on the material properties were discussed. Test results showed that the offset of pipe size on tincture toughness was negligible, while the effect of welding method on fracture toughness was significant. In addition, Fracture toughness for carbon steel was influenced by silicon contents due to the different steel refining processes.

• 대한기계학회논문집A
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• 제22권1호
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• pp.227-237
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• 1998

In case the systems have radioactivity, toxic liquid or expensive fluid, and have to be performed repair work at one point of the system pipe, the formation of an internal ice plug by the removal of heat from the pipe is often consideredas a useful method. In this procedure, an annular jacket is placed around the pipe, and the jacket is then filled with liquid Nitrogen(-196.deg. C). Thermal analysis by the finite element method based on the laboratory experiments has been constructed. The result of the finite element analysis on the experimental model shows to be reasonable, and thus the finite element analysis for different pipe size, material and thickness has been performed to see if the ice plugging procedure in various applications can be safely performed without possibility of damage to the pipe. It has been confirmed that in carbon steel pipes the maximum stress is found around the boundary of the freezing jacket, and the stress increases as pipe thickness increases, but the maximum stress shows no consistency along the increment of the pipe diameter. The maximum stresses appear lower than yield stress in carbon steel. It has been also shown that in stainless steel pipes the maximum stresses are also found around the boundary of the freezing jacket, but almost the same value in spite of different pipe size an thickness, and the maximum stresses show slightly higher than the yield stress of the stainless steel.

• Corrosion Science and Technology
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• 제16권6호
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• pp.305-316
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• 2017

Austenitic stainless steels have been widely used for various systems of nuclear power plants. Among these stainless steels, small pipes with diameter less than 14 inch have been produced in the form of seamless pipe. Annealing and cooling process during the manufacturing process can affect corrosion properties of seamless stainless steels. Therefore, 12 inch-diameter of as-received 304L stainless steel pipe was annealed and aged in this study. Intergranular corrosion resistance was evaluated by ASTM A262 Practice A, C, and E methods. The degree of sensitization was determined using a DL-EPR test. U-bend method in an autoclave was used to evaluate the SCC resistance in 0.01 M $Na_2S_4O_6$ or 40% NaOH solution at $340^{\circ}C$. As-received specimen showed relatively high degree of sensitization and intergranular corrosion rate. Carbon segregation was also observed near grain boundaries. Annealing treatment could give the dissolution of segregated carbon into the matrix. Aging treatment could induce segregation of carbon and finally form carbides. Microstructural analysis confirmed that high intergranular corrosion rate of the as-received seamless pipe was due to micro-galvanic corrosion between carbon segregation and grains.

• International Journal of Safety
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• 제6권2호
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• pp.1-7
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• 2007

In this study mechanical strength of A53B carbon steel was analyzed using several types of test specimens directly machined from oil recycling pipe experienced a failure due to hydrogen attack in chemical plants. High temperature hydrogen attack (HTHA) is the damage process of grain boundary facets due to a chemical reaction of carbides with hydrogen, thus forming cavities with high pressure methane gas. Driven by the methane gas pressure, the cavities grow on grain boundaries forming intergranular micro cracks. Microscopic optical examination, tensile test, Charpy impact test, hardness measurement, and small punch (SP) test were performed. Carbon content of the hydrogen attacked specimens was dramatically reduced compared with that of standard specification of A53B. Traces of decarburization and micro-cracks were observed by optical and scanning electron microscopy. Charpy impact energy in hydrogen attacked part of the pipe exhibited very low values due to the decarburization and micro fissure formation by HTHA, on the other hand, data tested from the sound part of the pipe showed high and scattered impact energy. Maximum reaction forces and ductility in SP test were decreased at hydrogen attacked part of the pipe compared with sound part of the pipe. Finite element analyses for SP test were performed to estimate tensile properties for untested part of the pipe in tensile test. And fracture toughness was calculated using an equivalent strain concept with SP test and finite element analysis results.

• 한국가스학회지
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• 제20권5호
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• pp.112-117
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• 2016

국내에서는 연료 가스 배관용 탄소강관으로 KS D 3631의 기준을 따르도록 되어있으며, 탄소강관이 지하에 매설되는 경우 부식을 방지하기 위해 강관에 합성수지로 피복을 한다. 피복은 부식 방지 조치를 하는 것으로 압축된 연료가스를 이송하는데 필요한 강도는 원관인 탄소강관이 그 역할을 수행한다. 따라서 탄소강관에 결함이 발생하였을 때, 그 결함에 따른 강도를 평가하는 것이 중요한데 국내에는 잔존강도를 평가하기 위한 방법이 부족하다. 결국 국외 기준인 DNV RP F101 또는 ASME B31G의 기준에 따라 잔존강도를 평가하는데, 그 결과가 국내 배관에 적용 타당성이 있는지 검증이 부족하며, 85% 이상의 결함에 대해서는 예측 할 수 없다. 따라서 본 연구에서는 KS D 3631의 배관을 이용하여 인위적 결함을 가공하여 잔존강도를 평가하기 위한 실험을 수행하였다. 그 결과 폭에 따라서 일정한 잔존강도의 차이를 보이며, 국내 연료 가스용 배관에는 DNV RP F101이 적합하다는 결론을 도출하였다. 본 연구의 결과는 결함 깊이가 큰 경우에 대한 결과와 타당한 국의 기준을 파악하기 위한 결과를 포함하고 있어, 배관의 잔존강도를 이용한 위험성 평가 등에 유용하게 활용될 것으로 기대한다.

• 상하수도학회지
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• 제37권4호
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• pp.203-214
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• 2023

In this study, the physical properties and fracture characteristics according to the tensile load are evaluated on the materials of the polymeric filler and carbon fiber-based composite sleeve technique. The polymeric filler and the composite sleeve technique are applied to areas where the pipe body thickness is reduced due to corrosion in large-diameter water pipes. First, the tensile strength of the polymeric filler was 161.48~240.43 kg_f/cm², and the tensile strength of the polyurea polymeric filler was relatively higher than that of the epoxy. However, the tensile strength of the polymeric filler is relatively very low compared to ductile cast iron pipes(4,300 kg_f/cm²<) or steel pipes(4,100 kg_f/cm²). Second, the tensile strength of glass fiber, which is mainly used in composite sleeves, is 3,887.0 kg_f/cm², and that of carbon fiber is up to 5,922.5 kg_f/cm². The tensile strengths of glass and carbon fiber are higher than ductile cast iron pipe or steel pipe. Third, when reinforcing the hemispherical simulated corrosion shape of the ductile cast iron pipe and the steel pipe with a polymeric filler, there was an effect of increasing the ultimate tensile load by 1.04 to 1.06 times, but the ultimate load was 37.7 to 53.7% compared to the ductile cast iron or steel specimen without corrosion damage. It was found that the effect on the reinforcement of the corrosion damaged part was insignificant. Fourth, the composite sleeve using carbon fiber showed an ultimate load of 1.10(0.61T, 1,821.0 kg_f) and 1.02(0.60T, 2,290.7 kg_f) times higher than the ductile cast iron pipe(1,657.83 kg_f) and steel pipe(2,236.8 kg_f), respectively. When using a composite sleeve such as fiber, the corrosion damage part of large-diameter water pipes can be reinforced with same level as the original pipe, and the supply stability can be secured through accident prevention.