• Advances in nano research
• /
• 제12권4호
• /
• pp.345-352
• /
• 2022

In this paper, natural frequency curves are presented for three specific end supports considering distinct values of nonlocal parameter. The vibrational behavior of zigzag double walled carbon nanotubes is investigated using wave propagation with nonlocal effect. Frequency spectra of zigzag (12, 0) double walled carbon nanotubes have been analyzed with proposed model. Effects of nonlocal parameters have been fully investigated on the natural frequency against against variation of Poisson's ratio. A slow increase in frequencies against variation of Poisson's ratio also indicates insensitivity of it for suggested nonlocal model. Moreover, decrease in frequencies with increase in nonlocal parameter authenticates the applicability of nonlocal Love shell model. Also the frequency curves for C-F are lower throughout the computation than that of C-C curves.

• Computers and Concrete
• /
• 제32권3호
• /
• pp.303-311
• /
• 2023

An analysis of the Poisson's ratios influence of single walled carbon nanotubes (SWCNTs) based on Sander's shell theory is carried out. The effect of Poisson's ratio, boundary conditions and different armchairs SWCNTs is discussed and studied. The Galerkin's method is applied to get the eigen values in matrix form. The obtained results shows that, the decrease in ratios of Poisson, the frequency increases. Poisson's ratio directly measures the deformation in the material. A high Poisson's ratio denotes that the material exhibits large elastic deformation. Due to these deformation frequencies of carbon nanotubes increases. The frequency value increases with the increase of indices of single walled carbon nanotubes. The prescribe boundary conditions used are simply supported and clamped simply supported. The Timoshenko beam model is used to compare the results. The present method should serve as bench mark results for agreeing the results of other models, with slightly different value of the natural frequencies.

• 한국재료학회지
• /
• 제28권8호
• /
• pp.466-473
• /
• 2018

Nickel oxide(NiO) thin films, nanorods, and carbon nanotube(CNT)/NiO core-shell nanorod structures are fabricated by sputtering Nickel at different deposition time on alumina substrates or single wall carbon nanotube templates followed by oxidation treatments at different temperatures, 400 and $700^{\circ}C$. Structural analyses are carried out by scanning electron microscopy and x-ray diffraction. NiO thinfilm, nanorod and CNT/NiO core-shell nanorod structurals of the gas sensor structures are tested for detection of $H_2S$ gas. The NiO structures exhibit the highest response at $200^{\circ}C$ and high selectivity to $H_2S$ among other gases of NO, $NH_3$, $H_2$, CO, etc. The nanorod structures have a higher sensing performance than the thin films and carbon nanotube/NiO core-shell structures. The gold catalyst deposited on NiO nanorods further improve the sensing performance, particularly the recovery kinetics.

• 한국재료학회지
• /
• 제34권4호
• /
• pp.208-214
• /
• 2024

To fabricate intermetallic nanoparticles with high oxygen reduction reaction activity, a high-temperature heat treatment of 700 to 1,000 ℃ is required. This heat treatment provides energy sufficient to induce an atomic rearrangement inside the alloy nanoparticles, increasing the mobility of particles, making them structurally unstable and causing a sintering phenomenon where they agglomerate together naturally. These problems cannot be avoided using a typical heat treatment process that only controls the gas atmosphere and temperature. In this study, as a strategy to overcome the limitations of the existing heat treatment process for the fabrication of intermetallic nanoparticles, we propose an interesting approach, to design a catalyst material structure for heat treatment rather than the process itself. In particular, we introduce a technology that first creates an intermetallic compound structure through a primary high-temperature heat treatment using random alloy particles coated with a carbon shell, and then establishes catalytic active sites by etching the carbon shell using a secondary heat treatment process. By using a carbon shell as a template, nanoparticles with an intermetallic structure can be kept very small while effectively controlling the catalytically active area, thereby creating an optimal alloy catalyst structure for fuel cells.

• Advances in nano research
• /
• 제12권5호
• /
• pp.483-488
• /
• 2022

The present work is an attempt to study the vibration analysis of the single-walled carbon nanotubes (SWCNTs) under the effect of the surface irregularity using Donnell's model. The surface irregularity represented by the parabolic form. According to Donnell's model and three-dimensional elasticity theory, a novel governing equations and its solution are derived and matched with the case of no irregularity effects. To understand the reaction of the nanotube to the irregularity effects in terms of natural frequency, the numerical calculations are done. The results obtained could provide a better representation of the vibration behavior of an irregular single-walled carbon nanotube, where the aspect ratio (L/d) and surface irregularity all have a significant impact on the natural frequency of vibrating SWCNTs. Furthermore, the findings of surface irregularity effects on vibration SWCNT can be utilized to forecast and prevent the phenomena of resonance of single-walled carbon nanotubes.

• 전기화학회지
• /
• 제19권4호
• /
• pp.129-133
• /
• 2016

본 연구에서는 고분자와 탄소 물질을 복합화시켜 친환경의 유기 음극을 제조하였다. Poly(styrenesulfonate)(PSS)-carbon 복합 음극은 탄소 입자를 PSS이 둘러싸고 있는 core-shell 형태를 보이며 $524mAh\;g^{-1}$의 이론용량과 0.6 V 이하의 낮은 전압을 가진다. PSS-carbon 복합 음극은 0.1, 0.5, 1, 10C에서 각각 용량 $519.6mAh\;g^{-1}$, $461.2mAh\;g^{-1}$, $411.8mAh\;g^{-1}$, $315.9mAh\;g^{-1}$의 첫 번째 방전 용량을 가지면 30사이클까지 안정적인 주기 특성을 보여준다. Polystyrene 구조와 sulfonate 기능 기를 갖는 PSS와의 탄소 복합 전극은 유기 이차전지의 전기화학적 특성을 향상 시키기 적합한 음극활 물질로 여겨 진다.

• 공업화학
• /
• 제35권1호
• /
• pp.37-41
• /
• 2024

열대성 과일로 널리 재배되고 있는 코코넛(coconut)의 독특한 껍질(shell)은 과육 섭취 후 얻어지는 부산물로 활용 가치가 클 것으로 기대된다. 이 코코넛 껍질을 전도성 고분자와 혼합하여 복합소재를 간단한 방식으로 제조하고 섭씨 600도 정도의 상대적 저온에서 탄화하여 수득되는 소재의 전기화학적 특성 및 활용 가능성을 고찰하였다. 먼저, 외형적 요소를 주사전자현미경(scanning electron microscope, SEM)으로 관찰하였다. 탄소의 미세구조를 라만(Raman) 분광 분석을 통하여 추론하였다. 전기전도 가능성을 간단한 옴의 관계(Ohmic relation)를 통하여 확인하였다. 나아가, 탄화된 재료가 리튬 이차 전지의 음극(anode) 소재로 활용될 수 있는지 여부를 반쪽 전지(half-cell) 충방전(charge/discharge) 테스트를 통해 살펴보았으며, 최대 충전 용량은 약 750 mAh로 높게 나타났으나, 충전이 진행됨에 따라 빠른 감소를 보였다. 본 연구는 향후 목질계 폐기물의 활용에 대한 중요한 정보를 제공할 것이다.

• 한국환경과학회지
• /
• 제25권1호
• /
• pp.23-29
• /
• 2016

This study has conducted greenhouse gas emission reduction test as using Oyster-shells originated PCC paper filler compare to non-Oyster shells used PCC. This examination was estimated and calculated in accordance with both IPCC (Intergovernmental Panel on Climate Change) and World Business Council for Sustainable Development (WBSCD). The greenhouse gas emission reduction estimation result indicates that, when oyster shells are recycled and used as paper filler, it reduces $27.97tCO_2\;per\;100\;ton$ of oyster shells. It is greenhouse gas emission $44.27tCO_2$ from PCC production changed to carbon emission reduction when replaced with oyster shell. LNG greenhouse gas emission $16.3tCO_2$ in relation to the pre-treatment with oyster shell per 100 ton is also reflected. As a result, it is assumed that roughly $0.2797tCO_2/oyster\;shell{\cdot}ton$.

• 에너지공학
• /
• 제27권1호
• /
• pp.51-58
• /
• 2018

In this paper, we reported that the influence of advanced functional mineral filler calcium carbonate ($CaCO_3$) extracted from oyster shell waste, which are rich mineral sources of $CaCO_3$. Oyster Shells, available in abundance, have no eminent use and are commonly regarded as waste. Their improper disposal causes a significant level of environmental concern and also results in a waste of natural resources. Recycling shell waste could potentially eliminate the disposal problem, and also turn an otherwise useless waste into high value added products. Oyster shell waste calcination process to produce pure lime (CaO) which have good anti-microbial property for waste water treatment and then focuses on its current applications to treat the coffee waste and its effluents for biological treatment and utilization as a fertilizers.

• Steel and Composite Structures
• /
• 제34권4호
• /
• pp.599-613
• /
• 2020

In this article, free vibration attributes of double-walled carbon nanotubes based on nonlocal elastic shell model have been investigated. For this purpose, a nonlocal Flügge shell model is established to observe the small scale effect. The wave propagation is employed to frame the governing equations as eigenvalue system. The influence of nonlocal parameter subjected to different end supports has been overtly examined. A suitable choice of material properties and nonlocal parameter been focused to analyze the vibration characteristics. The new set of inner and outer tubes radii investigated in detail against aspect ratio and length. The dominance of boundary conditions via nonlocal parameter is shown graphically. The results generated furnish the evidence regarding applicability of nonlocal shell model and also verified by earlier published literature.