• Title/Summary/Keyword: carbon nanotubes(CNT)

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Synthesis and Microstructure of Single-Walled Carbon Nanotubes by Catalytic Chemical Vapor Deposition Method (촉매화학기상증착법에 의한 단일벽 탄소나노튜브의 합성과 미세구조)

  • Kim, Jong-Sik;Kim, Gwan-Ha;Kim, Chang-Il
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.7
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    • pp.359-363
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    • 2006
  • Single-walled carbon nanotubes (SWCNTs) with few defects and very small amount of amorphous carbon coating have been synthesized by catalytic decomposition of methane in $H_2$ over well-dispersed metal particles supported on MgO. The yield of SWCNTs was estimated to be 88.5% and the purities of SWCNTs thus obtained were more than 90%. Peak of the radial breathing mode in the Raman spectrum demonstrated that the diameters of synthesized CNTs are in the range 0.4-2.0 nm. Our results also indicated that MgO support materials are useful to a large-scale synthesis of high-quality SWCNTs. Increasing temperature could remarkably increase the yield and also improve the quality of SWCNTs from catalytic decomposition of methane. The morphologies and microstructures of the synthesized carbon materials were characterized by scanning electron microscopy (SEM), Thermogravimetric analysis (TGA), Raman spectroscopy, and X-ray diffraction (XRD).

In-situ TEM of Carbon Nanotube Field Emitters and Improvement of Electron Emission from Nanotube Films by Laser Treatment

  • Saito, Yahachi;Seko, Kazuyuki;Kinoshita, Jun-ichi;Ishida, Toshiyuki;Yotani, Junko;Kurachi, Hiroyuki;Uemura, Sashiro
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1081-1086
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    • 2005
  • Dynamic behavior of carbon nanotubes (CNTs) in an electric field is directly observed by in-situ transmission electron microscopy (TEM). The CNT field emitters examined by in-situ TEM are multiwalled, double-walled and single walled CNTs. Threshold fields for electron emission and sustainable emission currents depending on the structure of CNTs are presented, and degradation mechanism of the CNT field emitters is discussed. In addition to the microscopy studies on individual CNTs, our recent development in surface treatment of CNT layers grown by chemical vapor deposition, which brings about high density of emission current and high uniformity, is also presented.

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Fabrication and characterization of a carbon nanotube-based point electron source

  • Choi, Ha-Kyu;Kim, G.Y.;Song, Y.I.;Jeong, H.J.;Lim, S.C.;Lee, Y.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1536-1537
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    • 2005
  • We have made point electron sources using carbon nanotubes (CNTs). For the fabrication of point electron sources, CNTs were dispersed in a solution and attached on electrochemically etched W tips using electrophoresis. In our study, we have utilized various CNTs such as single-walled CNT (SWCNT), multiwalled CNT (MWCNT), and thin-MWCNT and threshold current, turn-on voltage, filed enhancement factor of each emitter have been studied upon a tube/bundle diameter and length. In addition, fieldemitted electron energy distribution of various CNT emitters is characterized.

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Improvement of thermal buckling response of FG-CNT reinforced composite beams with temperature-dependent material properties resting on elastic foundations

  • Bensaid, Ismail;Kerboua, Bachir
    • Advances in aircraft and spacecraft science
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    • v.6 no.3
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    • pp.207-223
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    • 2019
  • Current investigation deals with the thermal stability characteristics of carbon nanotube reinforced composite beams (CNTRC) on elastic foundation and subjected to external uniform temperature rise loading. The single-walled carbon nanotubes (SWCNTs) are supposed to have a distribution as being uniform or functionally graded form. The material properties of the matrix as well as reinforcements are presumed to be temperature dependent and evaluated through the extended rule of mixture which incorporates efficiency parameters to capture the size dependency of the nanocomposite properties. The governing differential equations are achieved based on the minimum total potential energy principle and Euler-Bernoulli beam model. The obtained results are checked with the available data in the literature. Numerical results are supplied to examine the effects of numerous parameters including length to thickness ratio, elastic foundations, temperature change, and nanotube volume fraction on the thermal stability behaviors of FG-CNT beams.

Recent Trends on Wide-Viewing-Angle LC Modes and New Trials on CNT-LC System

  • Lee, Seung-Hee;Lee, Young-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.101-104
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    • 2005
  • Recently, competition between LC modes for LC TVs becomes high. In this paper, status of each mode is briefly reviewed with commenting on its electro-optic characteristics and possible application fields. Further, to understand effects of carbon nanotubes (CNTs) dispersed in nematic liquid crystal on electro-optic characteristic and orientation of the LC, CNT-doped NLC cells are made and evaluated. The hysterisis studies of voltage-dependent capacitance show that the amount of residual dc is greatly reduced due to ion trapping by CNTS.

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Electrical Characteristics of Carbon Nanotubes by Plasma and Microwave Surface Treatments

  • Cho, Sang-Jin;Shrestha, Shankar Prasad;Lee, Soon-Bo;Boo, Jin-Hyo
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.905-907
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    • 2014
  • The plasma and microwave surface treatments of carbon nanotubes that loaded on plastic substrates were carried out with expecting a change of carbon nanotube dispersion by increasing treatment time. The microwave treatment process was undergone by commercial microwave oven (800 W). The electrical property was measured by hall measurement and resistance was increased by increasing $O_2$ flow rate of plasma, suggesting an improvement of carbon nanotube dispersion and a possibility of controlling the resistances of carbon nanotubes by plasma surface treatment. The resistance was increased in both polyethylene terephthalate and polyimide substrates by increasing $O_2$ flow rate. Resistance changes only slightly with different $O_2$ flow treatment in measure rho for all polyimide samples. Sheet resistance is lowest in polyimide substrate not due to high carbon nanotube loading but due to tendency to remain in elongated structure. $O_2$ or $N_2$ plasma treatments on both polyethylene terephthalate and polyimide substrates lead to increase in sheet resistance.

Fabrication and Mechanical Characteristics of Bulk Nickel/Carbon Nanotube Nanocomposites via the Electrical Explosion of Wire in Liquid and Spark Plasma Sintering Method

  • Minh, Thuyet-Nguyen;Hong, Hai-Nguyen;Kim, Won Joo;Kim, Ho Yoon;Kim, Jin-Chun
    • Journal of Powder Materials
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    • v.23 no.3
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    • pp.213-220
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    • 2016
  • In this study, bulk nickel-carbon nanotube (CNT) nanocomposites are synthesized by a novel method which includes a combination of ultrasonication, electrical explosion of wire in liquid and spark plasma sintering. The mechanical characteristics of the bulk Ni-CNT composites synthesized with CNT contents of 0.7, 1, 3 and 5 wt.% are investigated. X-ray diffraction, optical microscopy and field emission scanning electron microscopy techniques are used to observe the different phases, morphologies and structures of the composite powders as well as the sintered samples. The obtained results reveal that the as-synthesized composite exhibits substantial enhancement in the microhardness and values more than 140 HV are observed. However an empirical reinforcement limit of 3 wt.% is determined for the CNT content, beyond which, there is no significant improvement in the mechanical properties.

Improved Field Emission by Liquid Elastomer Modification of Screen-Printed CNT Film Morphology

  • Lee, Hyeon-Jae;Lee, Yang-Doo;Cho, Woo-Sung;Kim, Jai-Kyeong;Lee, Yun-Hi;Hwang, Sung-Woo;Ju, Byeong-Kwon
    • Journal of Information Display
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    • v.7 no.2
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    • pp.16-21
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    • 2006
  • The effect of improvement on the surface morphology of screen-printed carbon nanotube (CND) films was studied by using the optically clear poly-dimethylsiloxane (PDMS) elastomer for surface treatment. After the PDMS activation treatment was applied to the diode-type CNT cathode, the entangled carbon nanotube (CNT) bundles were broken up into individual free standing nanotubes to remarkably improve the field-emission characteristics over the as-deposited CNT film. Also, the cathode film morphology of a top gated triode-type structure can be treated by using the proposed surface treatment technique, which is a low-cost process, simple process. The relative uniform emission image showed high brightness with a high anode current. This result shows the possibility of using this technique for surface treatment of large-size field emission displays (FEDs) in the future.

Electrochemical Properties of Carbon Nano-tube as the Counter Electrode of Dye-sensitized solar cell (염료감응형 태양전지의 상대전극 재료로서 탄소나노튜브의 전기화학적 특성)

  • Kim, Hyun-Ju;Lee, Dong-Yun;Koo, Bo-Kun;Lee, Won-Jae;Song, Jae-Sung;Lee, Dae-Yeol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.10
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    • pp.1090-1094
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    • 2004
  • Studies on porous oxide electrode, dye and electrolyte for dye-sensitized solar cells have been intensively carried out until now. However, counter electrode have not been much studied so far. Accordingly, it is needed to investigate new counter electrode materials with superior catalyst property and to substitute for Pt electrode. In this case, carbon nano-tubes (CNTs) are one of alternatives for counter electrodes as following merits: low resistivity, excellent electron emission property, large surface area and low cost due to development of mass production technique. Such advantages gave us to select multiwalled CNTs (MWCNT) as counter electrode for dye-sensitized solar cell. Also, cyclic voltammetry and impedance spectroscopy were used to investigate electrochemical properties of both CNT electrode and Pt electrode. It was found that sheet resistance of CNT electrode was similar to that of Pt electrode, also, electrochemical properties of CNT electrode was superior to that of Pt electrode on the basis on the measurement of CV and impedance spectrum. It was found that CNT is likely to be a very promising electrode material for dye solar cells.

Material properties and machining performance of CNT and Graphene reinforced hybrid alumina composites for micro electrical discharge machining (탄소나노튜브와 그래핀 강화 하이브리드 알루미나 복합재료의 재료특성 및 마이크로방전가공 성능)

  • Sung, Jin-Woo;Kim, Nam-Kyung;Kang, Myung-Chang
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.6
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    • pp.3-9
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    • 2013
  • Aluminum Oxide($Al_2O_3$) ceramics are excellent candidates for such applications due to their outstanding mechanical, thermal, and tribological properties. However, they are difficult to machine using conventional mechanical methods. Carbon fillers, such as carbon nanotubes(CNT) and graphene nanoplatelets(GNP)can be dispersed in a ceramic matrix to improve the mechanical and electrical properties. In this study, CNT and Graphene reinforced hybrid ceramic composites were fabricated using the spark plasma sintering method at a temperature of $1,500^{\circ}C$, pressure of 40 MPa, and soaking time of 10min. Besides this, the material properties such as microstructure, crystal structure, hardness, and electrical conductivity were analyzed using FE-SEM, XRD, Vickers, and the 4-point probe method. A micro machining test was carried out to compare the effects of the material properties and the machining performance for CNT and Graphene reinforced ceramic composites.