• Title/Summary/Keyword: carbon nanotubes(CNT)

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A Study on Mechanical Properties of Carbon Nanotubes (탄소나노튜브의 기계적 물성에 관한 연구)

  • Nahm, Seung-Hoon;Kim, Dong-Kyun;Park, Jong-Seo;Kim, Am-Kee
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1059-1064
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    • 2003
  • This paper presents an overview of the mechanical properties of carbon nanotubes. The characteristics of carbon nanotubes were briefly introduced. We then present briefly the experimental techniques used to measure mechanical properties and the results obtained by other researchers. A carbon nanotube is too small to be pulled apart with standard tension devices. Manipulators should be used for mechanical testing. We introduced manipulation methods using nanomanipulators under field-emission scanning-electron microscope.

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Acid Treatments of Carbon Nanotubes and Their Application as Pt-Ru/CNT Anode Catalysts for Proton Exchange Membrane Fuel Cell

  • Kim, Min-Sik;Lim, Sin-Muk;Song, Min-Young;Cho, Hyun-Jin;Choi, Yun-Ho;Yu, Jong-Sung
    • Carbon letters
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    • v.11 no.4
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    • pp.336-342
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    • 2010
  • Different oxidation treatments on CNTs using diluted 4.0 M $H_2SO_4$ solution at room temperature and or at $90^{\circ}C$ reflux conditions were investigated to elucidate the physical and chemical changes occurring on the treated CNTs, which might have significant effects on their performance as catalyst supports in PEM fuel cells. Raman spectroscopy, X-ray diffraction and transmission electron microscope analyses were made for the acid treated CNTs to determine the particle size and distribution of the CNT-supported Pt-Ru nanoparticles. These CNT-supported Pt-based nanoparticles were then employed as anode catalysts in PEMFC to investigate their catalytic activity and single-cell performance towards $H_2$ oxidation. Based on PEMFC performance results, refluxed Pt-Ru/CNT catalysts prepared using CNTs treated at $90^{\circ}C$ for 0.5 h as anode have shown better catalytic activity and PEMFC polarization performance than those of the commercially available Pt-Ru/C catalyst from ETEK and other Pt-Ru/CNT catalysts developed using raw CNT, thus demonstrating the importance of acid treatment in improving and optimizing the surface properties of catalyst support.

Fluid flow dynamics in deformed carbon nanotubes with unaffected cross section

  • Rezaee, Mohammad;Yeganegi, Arian;Namvarpour, Mohammad;Ghassemi, Hojat
    • Advances in nano research
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    • v.12 no.3
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    • pp.253-261
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    • 2022
  • Numerical modelling of an integrated Carbon NanoTube (CNT) membrane is only achievable if probable deformations and realistic alterations from a perfect CNT membrane are taken into account. Considering the possible forms of CNTs, bending is one of the most probable deformations in these high aspect ratio nanostructures. Hence, investigation of effect associated with bent CNTs are of great interest. In the present study, molecular dynamics simulation is utilized to investigate fluid flow dynamics in deformed CNT membranes, specifically when the tube cross section is not affected. Bending in armchair (5,5) CNT was simulated using Tersoff potential, prior to flow rate investigation. Also, to study effect of inclined entry of the CNT to the membrane wall, argon flow through generated inclined CNT membranes is examined. The results show significant variation in both cases, which can be interpreted as counter-intuitive, since the cross section of the CNT was not deformed in either case. The distribution of fluid-fluid and fluid-wall interaction potential is investigated to explain the anomalous behavior of the flow rate versus bending angle.

A Study on the Applicability of CNT/Aluminum Nanocomposites to Automotive Parts (CNT강화 알루미늄 나노복합재의 자동차용 부품 적용성 연구)

  • Min, Byung Ho;Nam, Dong Hoon;Park, Hoon Mo;Lee, Kyung Moon;Lee, Jong Kook
    • Composites Research
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    • v.28 no.4
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    • pp.226-231
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    • 2015
  • Various characteristics(thermal expansion, microstructure, etc.) and mechanical properties of CNT-aluminum nano composites manufactured by volume production system were evaluated. Also, formability and durability were evaluated for potential applications in automotive parts, via compared with high-elasticity material (A390) and the current commercial product. As a result, this composite has excellent mechanical properties and formability, therefore, to verity its potential for application as light and high strength materials in automobile part.

Electrochemical Performance of Micro Sized Silicon/CNT/Carbon Composite as Anode Material for Lithium Ion Batteries (리튬이차전지용 음극활물질로서 Micro sized Silicon/CNT/Carbon 복합입자의 전기화학적 특성)

  • Shin, Min-Seon;Lee, Tae-Min;Lee, Sung-Man
    • Journal of the Korean Electrochemical Society
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    • v.22 no.3
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    • pp.112-121
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    • 2019
  • In this study, silicon / carbon nanotube / carbon composite particles with high capacity were fabricated by using micro-sized silicon particles and carbon nanotubes as an anode material for lithium ion batteries. The silicon / carbon nanotube / carbon composite particles were prepared by spray drying method to prepare spherical composite particles. The composite particles have the network structure of the carbon nanotubes around the silicon particles, in which the silicon particles and the carbon nanotubes are bonded by amorphous carbon. It appears that the volume expansion of silicon is effectively buffered and the electrical contact is maintained in the network structure of the composite particles during charge-discharge cycles.

A Carbon Nanotube Sample for the Fabrication of Nanotweezer (나노트위져 제작을 위한 탄소나노튜브 샘플)

  • Choi, Jai-Seong;Lee, Jun-Sok;Kang, Gyung-Soo;Kwak, Yoon-Keun;Kim, Soo-Hyun
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.997-1000
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    • 2004
  • This paper introduces our basic research about a carbon nanotube(CNT) sample for the fabrication of nanotweezer. We have made the nanotweezer through the physical adhesion of multi-walled carbon nanotubes(MWCNTs) on two sharp tungsten tips. Thereby we needed the CNT sample which is proper to this fabrication process. And we applied the dielectrophoretic methods to the fabrication of the CNT sample. During the basic experiment, we used a sharp edged electrode and a flat electrode as electrodes for dielectrophoresis and just a function generator as a voltage source for the generation of electric field.

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Fabrication and Characteristic Evaluation of Hybrid Carbon Nanotubes Reinforced SKD11 Cold Work Tool Steel (탄소나노튜브 강화 SKD11 냉간금형용 하이브리드 탄소나노소결체 제조 및 특성 평가)

  • Jung, Sung-Sil;Moon, Je-Se;Lee, Dae-Yeol;Youn, Kuk-Tae;Park, Chun-Dal;Song, Jae-Sun
    • Journal of Powder Materials
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    • v.20 no.4
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    • pp.291-296
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    • 2013
  • SKD11 (ASTM D2) tool steel is a versatile high-carbon, high-chromium, air-hardening tool steel that is characterized by a relatively high attainable hardness and numerous, large, chromium rich alloy carbide in the microstructure. SKD11 tool steel provides an effective combination of wear resistance and toughness, tool performance, price, and a wide variety of product forms. The CNTs was good additives to improve the mechanical properties of metal. In this study, 1, 3 vol% CNTs was dispersed in SKD11 matrix by mechanical alloying. The SKD11+ CNT hybrid nanocomposites were investigated by FE-SEM, particle size distribution, hardness and wear resistance. The CNT was well dispersed in the SKD11 matrix and the mechanical properties of the composite were improved by CNTs addition. It shows good feasibility as cold work die tool.

Etching Treatment of Vertically Aligned Carbon Nanotubes for the Application to Biosensor (바이오센서로의 응용을 위한 수직 배열된 탄소나노튜브의 식각처리)

  • Choi, Eun-Chang;Park, Yong-Seob;Choi, Won-Seok;Hong, Byung-You
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.7
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    • pp.594-598
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    • 2008
  • The metal catalyst particles which there is as impurities on a tip part of carbon nanotube (CNT) are not good to apply it to a nano-electronic device. It was very important the opening of CNT-tip to fix a target bio material and a material to accept in CNT in a biosensor, so we performed $HNO_3$ wet etching to remove the metal catalyst particle which there was on a tip part of CNT grown up in the study and observed the opened CNT-tip with etching time. We synthesized the CNTs using a HF-PECVD method and choses the CNT length of 700 nm for the application of nano-electronic device such as a biosensor etc.. We observed the opened CNT-tip with wet etching times of $HNO_3$ (10, 30, 60 min). From the results, we observed that the CNT-tip was opened with the increase of wet etching time lively. In case of CNTs etched during 60 min, we confirmed that there was not the ratio of Ni included in CNTsI as catalyst. Conclusively, in the case of CNT etched for 60 minutes, it is completely good for application of a biosensor and, in addition, the metal-free CNTs will contribute to the application of other nanoelectronic devices.

Electrical Properties and Self-poling Mechanism of CNT/PVDF Piezoelectric Composite Films Prepared by Spray Coating Method

  • Lee, Sunwoo;Jung, Nak-Chun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.256-256
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    • 2013
  • Carbon nanotubes (CNT) / polyvinylidene fluoride (PVDF) piezoelectric composite films for nanogenerator devices were fabricated by spray coating method. When the CNT/PVDF mixture solution passes through the spray nozzle with small diameter by the compressed nitrogen gas, electric charges are generated in the liquid by a triboelectric effect. Then randomly distributed ${\beta}$ phase PVDF film could be re-oriented by the electric field resulting from the accumulated electrical charges, and might be resulted in extremely one-directionally aligned ${\beta}$ phase PVDF film without additional electric field for poling. X-ray diffraction patterns were used to investigate crystal structure of the CNT/PVDF composite films. It was confirmed that they revealed extremely large portion of the ${\beta}$ phase PVDF crystalline in the film. Therefore we could obtain the poled CNT/PVDF piezoelectric composite films by the spray coating method without additional poling process. Charge accumulation and resulting electric field generation mechanism by spray coating method were shown in Fig. 1. The capacitance of the CNT/PVDF films increased by adding CNTs into the PVDF matrix, and finally saturated. However, the I-V curves didn't show any saturation effect in the CNT concentration range of 0~4 wt%. Therefore we can control the performance of the devices fabricated from the CNT/PVDF composite film by adjusting the current level resulted from the CNT concentration with the uniform capacitance value.

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