• Title/Summary/Keyword: carbon nanofiber

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Electrospun Polyacrylonitrile-Based Carbon Nanofibers and Their Hydrogen Storages

  • Kim Dong-Kyu;Park Sun Ho;Kim Byung Chul;Chin Byung Doo;Jo Seong Mu;Kim Dong Young
    • Macromolecular Research
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    • v.13 no.6
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    • pp.521-528
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    • 2005
  • Electrospun polyacrylonitrile (PAN) nanofibers were carbonized with or without iron (III) acetylacetonate to induce catalytic graphitization within the range of 900-1,500$^{circ}C$, resulting in ultrafine carbon fibers with a diameter of about 90-300 nm. Their structural properties and morphologies were investigated. The carbon nanofibers (CNF) prepared without a catalyst showed amorphous structures and very low surface areas of 22-31 $m^{2}$/g. The carbonization in the presence of the catalyst produced graphite nanofibers (GNF). The hydrogen storage capacities of these CNF and GNF materials were evaluated through the gravimetric method using magnetic suspension balance (MSB) at room temperature and 100 bar. The CNFs showed hydrogen storage capacities which increased in the range of 0.16-0.50 wt$\%$ with increasing carbonization temperature. The hydrogen storage capacities of the GNFs with low surface areas of 60-253 $m^{2}$/g were 0.14-1.01 wt$\%$. Micropore and mesopore, as calculated using the nitrogen gas adsorption-desorption isotherms, were not the effective pore for hydrogen storage.

Stretchable Strain Sensors Using 3D Printed Polymer Structures Coated with Graphene/Carbon Nanofiber Hybrids (그래핀/탄소나노섬유 코팅된 3D 프린팅 고분자 구조를 이용한 신축성 스트레인 센서)

  • Na, Seung Chan;Lee, Hyeon-Jong;Lim, TaeGyeong;Yun, Jeongmin;Suk, Ji Won
    • Composites Research
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    • v.35 no.4
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    • pp.283-287
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    • 2022
  • Stretchable strain sensors have been developed for potential future applications including wearable devices and health monitoring. For practical implementation of stretchable strain sensors, their stability and repeatability are one of the important aspects to be considered. In this work, we utilized 3D printed polymer structures having kirigami patterns to improve the stretchability and reduce the hysteresis. The polymer structures were coated with graphene/carbon nanofiber hybrids to make a robust electrical network. The stretchable strain sensors showed a high gauge of 36 at a strain of 32%. Because of the kirigami structures and the robust graphene/carbon nanofiber coating, the sensors also exhibited stable resistance responses at various strains ranging from 1% to 30%.

Electrochemical Characteristics of Supercapacitor Electrode Using MnO2 Electrodeposited Carbon Nanofiber Mats from Lignin-g-PAN Copolymer (이산화망간 전기증착 리그닌 기반 탄소나노섬유 매트를 이용한 슈퍼캐퍼시터용 전극소재의 전기·화학적 특성)

  • Kim, Seok Ju;Youe, Won-Jae;Kim, Yong Sik
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.5
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    • pp.750-759
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    • 2016
  • The $MnO_2$ electrodeposited on the surface of the carbon nanofiber mats ($MnO_2$-LCNFM) were prepared from electrospun lignin-g-PAN copolymer via heat treatments and subsequent $MnO_2$ electrodeposition method. The resulting $MnO_2$-LCNFM was evaluateed for its potential use in a supercapicitor electrode. The increase of $MnO_2$ electric deposition time was revealed to increase diameter of carbon nanofibers as well as $MnO_2$ content on the surface of carbon nanofiber mats as confirmed by scanning electon microscope (SEM) analysis. The electrochemical properties of $MnO_2$-LCNFM electrodes are evaluated through cyclic voltammetry test. It was shown that $MnO_2$-LCNFM electrode exhibited good electrochemical performance with specific capacitance of $168.0mF{\cdot}cm^{-2}$. The $MnO_2$-LCNFM supercapacitor successfully fabricated using the gel electrolyte ($H_3PO_4$/Polyvinyl alcohol) showed to have the capacitance efficiency of ~90%, and stable behavior during 1,000 charging/discharging cycles.

Damage analysis of carbon nanofiber modified flax fiber composite by acoustic emission

  • Li, Dongsheng;Shao, Junbo;Ou, Jinping;Wang, Yanlei
    • Smart Structures and Systems
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    • v.19 no.2
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    • pp.127-136
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    • 2017
  • Fiber reinforced polymer (FRP) has received widespread attention in the field of civil engineering because of its superior durability and corrosion resistance. This article presents the damage mechanisms of a novelty composite called carbon nanofiber modified flax fiber polymer (CNF-modified FFRP). The ability of acoustic emission (AE) to detect damage evolution for different configurations of specimens under uniaxial tension was examined, and some useful AE characteristic parameters were obtained. Test results shows that the mechanical properties of modified composites are associated with the CNF content and the evenness of CNF dispersed in the epoxy matrix. Various damage mechanisms was established by means of scanning electron microscope images. The fuzzy c-means clustering were proposed to classify AE events into groups representing different generation mechanisms. The classifiers are constructed using the traditional AE features -- six parameters from each burst. Amplitude and peak-frequency were selected as the best cluster-definition features from these AE parameters. After comprehensive comparison, a correlation between these AE events classes and the damage mechanisms observed was proposed.

Fabrication and characterization of graphite nanofiber reinforced aluminum matrix composites (탄소나노섬유 강화 알루미늄 복합재료의 제조 및 특성)

  • Jang J.H.;Oh K.H.;Han K.S.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.35-38
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    • 2004
  • Graphite nanofiber (GNF) and carbon nanotube (CNT) are novel fiber reinforcing materials which have outstanding physical and mechanical properties. Aluminum matrix composites reinforced graphite nanofiber were fabricated by conventional powder metallurgy (PM) method. The composites were prepared through ultrasonication, ball milling, and hot isostatic pressing. A uniform distribution of GNF in aluminum matrix could be obtained. To measure the mechanical properties of GNF-Al composites testings were done in indentation and compression. The compressive strength was enhanced according to reinforcing graphite nanofiber while the hardness was decreased. This study makes the high performance composites for future applications.

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Study on Lithium Extraction Using Cellulose Nanofiber ( 셀룰로오스 나노 섬유를 활용한 리튬 흡착 및 추출 연구)

  • Raeil Jeong;Jinsub Choi
    • Journal of the Korean institute of surface engineering
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    • v.57 no.1
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    • pp.31-37
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    • 2024
  • The surge in demand for lithium is primarily fueled by the expanding electric vehicle market, the necessity for renewable energy storage, and governmental initiatives aimed at achieving carbon neutrality. This study proposes a straightforward method for lithium extraction utilizing cellulose nanofiber (CNF) via a vacuum filtration process. This approach yields a porous CNF film, showcasing its potential utility as a lithium extractor and indicator. Given its abundance and eco-friendly characteristics, cellulose nanofiber (CNF) emerges as a material offering both economic and environmental advantages over traditional lithium extraction techniques. Hence, this research not only contributes to lithium recovery but also presents a sustainable solution to meet the growing demand for lithium in energy storage technologies.

Fabrication of Carbon Nanofiber/Graphite Electrodes for Lithium Ion Secondary Battery (리튬이온 2차전지용 탄소나노섬유/흑연 복합재 전극의 제조)

  • Kwon, kyong-Hee;Moon, Seung-Hwan;Kim, Myung-Chan;Oh, Se-Min;Kim, Myung-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.2
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    • pp.130-140
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    • 2003
  • In order to improve the lithium ion battery's performance, the carbon nanofibers were introduced to the anode electrode fabricated with natural graphite particles. The influence of structural adjustment of the particles by the introduction method of carbon nanofibers and the content of carbon nanofibers on the electrical property and charge/discharge characteristics of the electrode were investigated. The electrode fabricated with the mixture of 10 wt% of carbon nanofibers grown separately and 90 wt% of graphite particles showed an excellent discharge capacity of 400 mAh/g and the improved cycle performance. The improved performance could be explained by that the carbon nanofibers shortened and uniformly distributed on the surface of graphite particles by ball milling increased the stability for the intercalation/deintercalation of lithium ion and increased the electrical conductivity due to the closed packing between graphite particles.

CoMn Oxide/Carbon-nanofiber Composite Electrodes for Supercapacitors (코발트망간 산화물/탄소나노섬유 복합전극의 수퍼케폐시터 특성)

  • Kim, Yong-Il;Yoon, Yu-Il;Ko, Jang-Myoun
    • Journal of the Korean Ceramic Society
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    • v.45 no.8
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    • pp.493-496
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    • 2008
  • Composite electrodes consisting of $CoMnO_2$ and carbon nanofibers(vapor grown carbon nanofiber, VGCF) with high electrical conducivity($CoMnO_2$/VGCF) were prepared on a porous nickel foam substrate as a current collector and their supercapacitive properties were investigated using cyclic voltammetry in 1 M KOH aqueous solution. The $CoMnO_2$/VGCF electrode exhibited high specific capacitance value of 630 F/g at 5 mV/s and excellent capacitance retention of 95% after $10^4$ cycles, indicating that the used VGCF played the important roles in reducing the interfacial resistance in the composite electrode to improve supercapacitive performance.

Carbon-nanofiber Reinforced Copper Composites Prepared by Powder Metallurgy for Thermal Management of Electronic Devices

  • Weidmueller, H.;Weissgaerber, T.;Hutsch, T.;Huenert, R.;Schmitt, T.;Mauthner, K.;Schulz-Harder, J.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.844-845
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    • 2006
  • For microelectronic circuits, the main type of failure is thermal fatigue. Therefore, the search for matched coefficients of thermal expansion (CTE) of packaging materials in combination with a high thermal conductivity is the main task for developments of heat sink materials electronics, and good mechanical properties are also required. The aim of this work is to develop copper matrix composites reinforced with carbon nanofibers to meet these requirements. In this paper, a technology for obtaining a homogeneous mixture of copper and nanofibers will be presented and the microstructure and properties of consolidated samples will be discussed.

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