• Title/Summary/Keyword: carbon dioxide contents

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Effect of Carbonization Temperature on Carbon Dioxide Adsorption Behaviors of mesoporous carbon (중기공 탄소의 탄화온도에 따른 이산화탄소 흡착 거동)

  • Jang, Dong-Il;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.221.1-221.1
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    • 2011
  • In this study, we prepared the nitrogen-containing carbon spheres with mesopore processed by a facile polymerization-induced colloid aggregation method including carbonization in order to investigate the characterization and the effect on their carbon dioxide adsorption behaviors. The carbonization temperature was varied in the range of $600^{\circ}C$ to $900^{\circ}C$. The nitrogen contents of the mesoporous carbon sphere were characterized using XPS. The carbon dioxide adsorption capacities of the prepared mesoporous carbon sphere were determined by the amounts of carbon dioxide adsorptions at 298 K and 1.0 atm. The results showed that the prepared mesoporous carbons were highly effective for the carbon dioxide adsorption due to the increasing the affinity of the basic functionalities of adsorbent surface to acidic carbon dioxide. Maximum adsorption capacities of carbon dioxide at $25^{\circ}C$ were achieved up to 106 mg/g.

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Influence of Magnesium Oxide on Carbon Dioxide Adsorption Behaviors of Mesoporous Carbons (메조포어러스카본의 마그네슘 옥사이드의 처리에 따른 이산화탄소 흡착 거동)

  • Jang, Dong-Il;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.221.2-221.2
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    • 2011
  • In this study, we prepared the magnesium oxide decorated ordered mesoporous carbons processed by the reduction of magnesium oxide precursor on the CMK-3 surfaces in order to investigate the characterization and the effect on their carbon dioxide adsorption behaviors. The magnesium contents of the prepared samples were characterized using XPS. The textural properties of the prepared samples were investigated by $N_2$/77 K adsorption isotherms by BET equation. The carbon dioxide adsorption capacities of the prepared samples were investigated by the amounts of carbon dioxide adsorptions at 298 K and 1.0 atm. The results showed that the magnesium oxide on the CMK-3 surface enhanced interaction between carbon dioxide and adsorbents. Consequently, it was found that the magnesium oxide led to an increase in the carbon dioxide adsorption capacity of the CMK-3.

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Development of a Simulator for the Intermediate Storage Hub Selection Modeling and Visualization of Carbon Dioxide Transport Using a Pipeline (파이프라인을 이용한 이산화탄소 수송에서 중간 저장 허브 선정 모델링 및 시각화를 위한 시뮬레이터 개발)

  • Lee, Ji-Yong
    • The Journal of the Korea Contents Association
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    • v.16 no.12
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    • pp.373-382
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    • 2016
  • Carbon dioxide Capture and Storage/Sequestration (CCS) technology has attracted attention as an ideal method for most carbon dioxide reduction needs. When the collected carbon dioxide is transported to storage via pipelines, the direct transport is made if the storage is close, otherwise it can also be transported via an intermediate storage hub. Determining the number and the location of the intermediate storage hubs is an important problem. A decision-making algorithm using a mathematical model for solving the problem requires considerably more variables and constraints to describe the multi-objective decision, but the computational complexity of the problem increases and it also does not guarantee the optimality. This research proposes an algorithm to determine the location and the number of the intermediate storage hub and develop a simulator for the connection network of the carbon dioxide emission site. The simulator also provides the course of transportation of the carbon dioxide. As a case study, this model is applied to Korea.

Extraction of Indole Alkaloids from Catharanthus roseus by Using Supercritical Carbon Dioxide with Ethanol (초임계 이산화탄소와 에탄올을 이용한 일일초로부터 인들 알칼로이드의 추출에 관한 연구)

  • 송규민;박상우
    • KSBB Journal
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    • v.6 no.4
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    • pp.407-412
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    • 1991
  • The extraction of indole alkaloids from Catharanthus roseus using the supercritital carbon dioxide with ethanol was performed in various temperature and pressure conditions. The contents of vindoline in the extracts were determined by HPLC. In this study, the flow rate of cosolvent ehtanol was 20.4$\mu$l/min, about 3 wt.% of flow rate of supercritical carbon dioxide. However the effect of ethanol on the yield of extracted vindoline was not significant.

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Applicability of DGCI (Dark Green Color Index) to Assess Potential Impacts of CO2 Leakage from the Geological Storage Site (이산화탄소 지중저장 시설의 잠재적 누출 판단을 위한 DGCI(Dark Green Color Index) 적용 가능성 평가)

  • Yoo, Sin Yee;Song, Yoon Jin;Oh, Hee Joo;Kim, You Jin;Yoo, Ga Young
    • Journal of Climate Change Research
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    • v.7 no.3
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    • pp.351-356
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    • 2016
  • The carbon capture and storage (CCS), which collects and stores carbon dioxide in a geological site, is a promising option to mitigate climate change. However, there is the possibility of carbon dioxide leakage from the soil in the steps of collecting, transporting, and storing. To ensure the feasibility of this technology, it is important to monitor the leakage of carbon dioxide and to assess the potential impacts. As plants are sensitive to the changes in carbon dioxide in the soil environment, we can utilize plant parameter to detect the carbon dioxide leakage. Currently, chlorophyll a content is a conventional index indicating the changes in plants, however, this method is labor intensive and it only utilizes a small portion of leaves. To overcome its limitations, a simple spectroscopic parameter, DGCI (dark green color index), was suggested as an easy and quick indicator. In this study, we compared the values of chlorophyll a contents with DGCI from the experiment investigating the impacts of high underground $CO_2$ on grape plants. Results suggest that DGCI had high correlation with chlorophyll a contents and it has high potential to be utilized as an easy indicator to monitor plants' responses to $CO_2$ treatment.

Physico-chemical Properties of leaf tobacco by expansion processes. (잎담배의 팽화방법에 따른 팽화율 및 내용성분 특성)

  • 김병구;김기환;정한주;이경구;이태호
    • Journal of the Korean Society of Tobacco Science
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    • v.18 no.1
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    • pp.76-84
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    • 1996
  • Flue-cured tobaccos(cv. NC82, grade AB3O-1) expanded by super steam, volatile organic solvents(tricuorofluoromethane, propane), carbon dioxide, nitrogen, and by freeze-drying were examined for their physico-chemical properties. The expanding rate by using the organic solvents or carbon dioxide at the impregnated pressure was 70% or more, whereas the rate by super steam and freeze-drying was 49.4 and 42.9%, respectively. The contents of total sugar, alkaloid and ether extracts of the expanded tobacco by organic solvents or carbondioxide were decreased to 27.6, 20% or more, and 13%, respectively, when compared to non-expanded one. The contents of citric acid of the tobacco expanded by using trichlorofluoromethane and carbon dioxide were increased to 19.1, 14.0%, respectively. Linoleic acid in the tobacco expanded by super steam or trichlorofluoromethane was also increased to 17.3%, but malonic acid in the tobacco expanded by super steam was 18.5% less than that in the non-expanded one. Nineteen essential oil among 22 assayed in this experiment were decreased in the expanded tobaccos. Key words : expanding method, tobacco, physico-chemical properties.

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The activation of PPAR-α and Wnt/β-catenin by Paeonia lactiflora root supercritical carbon dioxide extract

  • Kim, Bora
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.4
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    • pp.1136-1142
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    • 2019
  • The root of Paeonia lactiflora has been used in Chinese medicine. We conducted to check the comparative qualities of ethanol solvent extraction (PLE) and supercritical carbon dioxide extraction (PLS) of P. lactiflora root. PLE had higher antioxidant and polyphenol contents than PLS. But, PLS were significantly increased peroxisome proliferator-activated receptor (PPAR)-α. In addition, PLS inhibited the adipocyte differentiation of 3T3-L1 cells. When treated with the extract at a concentration of 100 ㎍/mL, the Wnt/β-catenin pathway reporter luciferase activity of HEK 293-TOP cells increased approximately by 3-folds compared to that of the untreated control group. These results indicate that P. lactiflora supercritical carbon dioxide extract may serve as a cosmeceutical for improving skin barrier function and the treatment of obesity.

The Activation of PPAR-α and Wnt/β-catenin by Luffa cylindrica Supercritical Carbon Dioxide Extract

  • Kim, Bora
    • Natural Product Sciences
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    • v.25 no.4
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    • pp.341-347
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    • 2019
  • Luffa cylindrica (LC) is a very fast-growing climber and its fruit have been considered as agricultural wastes. We conducted to check the comparative qualities of ethanol solvent extraction (LCE) and supercritical carbon dioxide extraction (LCS) of L. cylindrica fruit and seed. LCS had higher antioxidant and polyphenol contents than LCE. LCS were significantly increased peroxisome proliferator-activated receptor (PPAR)-a and involucrin expression as epidermal differentiation marker in 3D skin equivalent model. LCS also showed antimicrobial activity against Staphylococcus aureus, a causative bacteria in atopic dermatitis. In addition, LCS inhibited the adipocyte differentiation of 3T3-L1 cells. When treated with the extract at a concentration of 100 ㎍/mL, the Wnt/β-catenin pathway reporter luciferase activity of HEK 293-TOP cells was increased approximately by 2-folds compared to that of the untreated control group. These results indicate that L. cylindrica supercritical carbon dioxide extract may serve as a cosmeceutical for improving skin barrier function and the treatment of obesity.

Efficiency Evaluation of Adsorbents for the Removal of VOC and NO2 in an Underground Subway Station

  • Son, Youn-Suk;Kang, Young-Hoon;Chung, Sang-Gwi;Park, Hyun-Ju;Kim, Jo-Chun
    • Asian Journal of Atmospheric Environment
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    • v.5 no.2
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    • pp.113-120
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    • 2011
  • Adsorbent combination studies have been carried out to remove nitrogen dioxide ($NO_2$) and volatile organic compounds (VOCs: BTEX) out of a subway environment characterized by high flow and low concentration. Optimal conditions for the high removal efficiency of the concerned target compounds were obtained through testing a series of control factors such as adsorbent sorts, thicknesses, and superficial velocity. It was found that the efficiencies increased as the specific surface area of activated carbon and its thickness increased, and external void fraction decreased. Furthermore, mixed activated carbon with granular and constructed contents was extensively tested to reduce pressure drop through the carbon bed. It was found that the performance of higher contents of granular activated carbon was better than that of higher contents of the constructed carbon. When the mixed carbon was applied to the subway ventilation system in order to eliminate $NO_2$ and VOC simultaneously, the removal efficiencies were found to be 75% and 85%, respectively.

Studies on the Volatile Fatty Acids and Carbon Dioxide Producted in Different Kimchis (김치의 휘발성(揮發性) 유기산(有機酸)과 이산화탄소에 관(關)한 연구(硏究))

  • Chyun, Jong-Hee;Lee, Hei-Soo
    • Korean Journal of Food Science and Technology
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    • v.8 no.2
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    • pp.90-94
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    • 1976
  • The amounts of volatile fatty acid and carbon dioxide of different salt Kimchis (1.02% NaCl, 3.16% NaCl) and Kimchis fermented at different temperature were determined. After the extraction of the acids with 80% ethanol it was steam-distillated. Identification and quantitative determination of individual acids were performed by gas chromatography and paper chromatography. Carbon dioxide contents were measured by microdiffusion method. Formic and acetic acid were found in four Kimchis. The acetic acid content of 1.02% NaCl Kimchi and Kimchi fermented at $4-5^{\circ}C$ were very high and their carbon dioxide contents were also high. Fifteen taste panels scored 1.02% NaCl Kimchi higher than 3.16% NaCl Kimchi and Kimchi fermented at $4-5^{\circ}C$ higher than Kimchi fermented at $20-22^{\circ}C$. It is assumed that large amounts of acetic acid and carbon dioxide make Kimchi flavorful.

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