DOI QR코드

DOI QR Code

Efficiency Evaluation of Adsorbents for the Removal of VOC and NO2 in an Underground Subway Station

  • Son, Youn-Suk (Department of Advanced Technology Fusion, Konkuk University) ;
  • Kang, Young-Hoon (Department of Environmental Engineering, Konkuk University) ;
  • Chung, Sang-Gwi (Department of Advanced Technology Fusion, Konkuk University) ;
  • Park, Hyun-Ju (Department of Advanced Technology Fusion, Konkuk University) ;
  • Kim, Jo-Chun (Department of Advanced Technology Fusion, Konkuk University)
  • Received : 2011.02.20
  • Accepted : 2011.05.04
  • Published : 2011.06.30

Abstract

Adsorbent combination studies have been carried out to remove nitrogen dioxide ($NO_2$) and volatile organic compounds (VOCs: BTEX) out of a subway environment characterized by high flow and low concentration. Optimal conditions for the high removal efficiency of the concerned target compounds were obtained through testing a series of control factors such as adsorbent sorts, thicknesses, and superficial velocity. It was found that the efficiencies increased as the specific surface area of activated carbon and its thickness increased, and external void fraction decreased. Furthermore, mixed activated carbon with granular and constructed contents was extensively tested to reduce pressure drop through the carbon bed. It was found that the performance of higher contents of granular activated carbon was better than that of higher contents of the constructed carbon. When the mixed carbon was applied to the subway ventilation system in order to eliminate $NO_2$ and VOC simultaneously, the removal efficiencies were found to be 75% and 85%, respectively.

Keywords

References

  1. Brosillon, S., Helenemanero, M., Oelfoussard, J. (2003) Mass transfer in VOC adsorption on zeolite: experimental and theoretical breakthrough curves. Environmental Science & Technology 35, 3571-3574.
  2. Burgess, J.E., Parsons, S.A., Stuetz, R.M. (2001) Developments in odor control and waste gas treatment biotechnology: a review. Biotechnology Advances 19, 35-63. https://doi.org/10.1016/S0734-9750(00)00058-6
  3. Chan, L.Y., Lau, W.L., Wang, X.M., Tang, J.H. (2003) Preliminary measurements of aromatic VOCs in public transportation modes in Guangzhou, China. Environment International 29, 429-435. https://doi.org/10.1016/S0160-4120(02)00189-7
  4. Chiang, Y., Chiang, P., Huang, C. (2001) Effect of pore structure and temperature on VOC adsorption on activated carbon. Carbon 39, 523-534. https://doi.org/10.1016/S0008-6223(00)00161-5
  5. Fukuyama, J. (2004) Odor pollution control for various odor emission sources in Japan, East Asia Workshop on Odor Measurement and Control Review, Office of Odor, Noise and Vibration. Environmental Management Bureau, Ministry of the Environment, Government of Japan, pp. 67-77.
  6. Gonzalez, J.D., Kim, M.R., Buonomo, E.L., Bonelli, P.R., Cukierman, A.L. (2008) Pyrolysis of biomass from sustainable energy plantation: Effect of mineral matter reduction on kinetics and charcoal pore structure. Energy sources part A- Recovery Utilization and Environmental Effects 30(9), 809-817. https://doi.org/10.1080/15567030600817878
  7. Haghighat, F., Lee, C.-S., Pant, B., Bolourani, G., Lakdawala, N., Bastani, A. (2008) Evaluation of various activated carbons for air cleaning-Towards design of immune and sustainable buildings. Atmospheric Environment 42, 8176-8184. https://doi.org/10.1016/j.atmosenv.2008.07.061
  8. Huang, M., Chou, C., Teng, H. (2002) Pore-size effects on activated-carbon capacities for volatile organic compound adsorption. AIChE Journal 48(8), 1804-1810. https://doi.org/10.1002/aic.690480820
  9. Johansson, C., Johansson, P. (2003) Particulate matter in the underground of Stockholm. Atmospheric Environment 37, 3-9.
  10. Kasaoka, S., Sakata, K., Tanaka, E., Naitoh, R. (1984) Design of molecular sieve carbon, studies on the adsorption of various dyes in the liquid phase. International Chemical Engineering 24, 734-742.
  11. Kim, K.Y., Kim, Y.S., Roh, Y.M., Lee, C.M., Kim, C.N. (2007) Spatial distribution of particulate matter ($PM_{10}$ and $PM_{2.5}$) in Seoul Metropolitan Subway station. Journal of Hazardous Materials 154(1-3), 440-443.
  12. Kingsley, M.L., Davidson, J.H. (2006) Adsorption of toluene onto activated carbons exposed to 100 ppb ozone. Carbon 44(3), 560-564. https://doi.org/10.1016/j.carbon.2005.08.002
  13. Lau, W.L., Chan, L.Y. (2003) Commuter exposure to aromatic VOCs in public transportation modes in Hong Kong. The Science of the Total Environment 308, 143-155. https://doi.org/10.1016/S0048-9697(02)00647-2
  14. Ma, X., Yang, D., Zhou, W., Zhang, C., Pan, X., Xu, L., Wu, M., Ma, J. (2008) Evaluation of activated carbon adsorbent for fuel cell cathode air filtration. Journal of Power Sources 175, 383-389. https://doi.org/10.1016/j.jpowsour.2007.08.116
  15. Schlegelmilch, M., Streese, J., Stegmann, R. (2005) Odor management and treatment technologies: An overview. Waste Management 25(9), 928-939. https://doi.org/10.1016/j.wasman.2005.07.006

Cited by

  1. in Tunnels vol.7, pp.1, 2013, https://doi.org/10.5572/ajae.2013.7.1.038
  2. Installation of platform screen doors and their impact on indoor air quality: Seoul subway trains vol.64, pp.9, 2014, https://doi.org/10.1080/10962247.2014.923350
  3. Chemical Properties and Source Profiles of Particulate Matter Collected on an Underground Subway Platform vol.9, pp.2, 2015, https://doi.org/10.5572/ajae.2015.9.2.165
  4. concentrations and their human health impacts in the metro subway system of Suzhou, China vol.19, pp.5, 2017, https://doi.org/10.1039/C6EM00655H
  5. Monitoring of polyaromatic hydrocarbons and volatile organic compounds in two major traffic tunnels in Seoul, Korea vol.33, pp.16, 2011, https://doi.org/10.1080/09593330.2012.655316
  6. Physicochemical Properties of Indoor Particulate Matter Collected on Subway Platforms in Japan vol.6, pp.2, 2012, https://doi.org/10.5572/ajae.2012.6.2.073
  7. Oddy Tests: Adding the Analytical Dimension vol.29, pp.1, 2011, https://doi.org/10.14351/0831-4985-29.1.22
  8. A review on activated carbon adsorption for volatile organic compounds (VOCs) vol.35, pp.5, 2011, https://doi.org/10.1515/revce-2017-0057
  9. Study on the subway environment induced by moving train using Gaussian distributed momentum source theory method vol.28, pp.8, 2011, https://doi.org/10.1177/1420326x18820473