• 제목/요약/키워드: carbon density

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PAFC용 합금 촉매 제조 (Manufacture of Pt-transition Metal Alloy Catalyst for PAFC)

  • 김영우;이주성
    • 공업화학
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    • 제4권4호
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    • pp.692-700
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    • 1993
  • 카본 담체에 백금과 전이금속과의 합금 촉매를 제조하여 촉매의 부식성, 촉매능 및 단전지에서의 전극성능을 전기화학적으로 비교 검토하였다. 그리고 합금촉매의 분석은 XRD로 확인하였다. 본 연구에서 제조된 여러 가지 백금 합금 촉매 중 Pt-Mo/carbon, Pt-Fe-Co/carbon 및 Pt-Fe/carbon 촉매가 보다 우수한 산소 환원 전류밀도를 나타내었으나 Pt-Mo/carbon 촉매의 경우 초기 전극전류의 대부분이 촉매의 부식에 의한 전류임을 확인할 수 있었다. Pt/carbon촉매를 사용하였을 경우 나타난 전극의 전류밀도는 $120mA/cm^2$이었으나 Pt-Fe-Co/carbon 의 경우는 $200mA/cm^2$으로 순수 백금촉매보다 우수한 전극성능을 나타내었다.

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A New Model and Equation Derived From Surface Tension and Cohesive Energy Density of Coagulation Bath Solvents for Effective Precipitation Polymerization of Acrylonitrile

  • Zhou, You;Xue, Liwei;Yi, Kai;Zhang, Li;Ryu, Seung Kon;Jin, Ri Guang
    • Carbon letters
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    • 제13권3호
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    • pp.182-186
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    • 2012
  • A new model and resultant equation for the coagulation of acrylonitrile monomers in precipitation polymerization are suggested in consideration of the surface tension (${\gamma}$) and cohesive energy density ($E_{CED}$). The equation was proven to be quite favorable by considering figure fittings from known surface tensions and cohesive energy densities of certain organic solvents. The relationship between scale value of surface tension (${\gamma}$/M) and cohesive energy density of monomers can be obtained by changing the coagulation bath component for effective precipitation polymerization of acrylonitrile in wet spinning.

절연물의열화에 의한 변압기유의 가스분석 (Gas detection of transformer oil according to degradation characteristic of insulation material)

  • 황규현;서호준;이석우;이동희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.574-574
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    • 2005
  • To found out the degradation characteristic of transformer insulation, insulation material was depisited into transformer oil and heated. Due to the thermal stress which added to insulation, the density of carbon dioxide which included in transformer oil was mesured by using the gas density detection equipment of gas sensor and air circulation method. As a result, it didn't match with the transformer supervision standard. But it was found that as thermal stress increased, the density of carbon dioxide propertionally increased.

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Significant enhancement of critical current density by effective carbon-doping in MgB2 thin films

  • Ranot, Mahipal;Lee, O.Y.;Kang, W.N.
    • 한국초전도ㆍ저온공학회논문지
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    • 제15권2호
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    • pp.12-15
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    • 2013
  • The pure and carbon (C)-doped $MgB_2$ thin films were fabricated on $Al_2O_3$ (0001) substrates at a temperature of $650^{\circ}C$ by using hot-filament-assisted hybrid physical-chemical vapor deposition technique. The $T_c$ value for pure $MgB_2$ film is 38.5 K, while it is between 30 and 35 K for carbon-doped $MgB_2$ films. Expansion in c-axis lattice parameter was observed with increase in carbon doping concentration which is in contrast to carbon-doped $MgB_2$ single crystals. Significant enhancement in the critical current density was obtained for C-doped $MgB_2$ films as compared to the undoped $MgB_2$ film. This enhancement is most probably due to the incorporation of C into $MgB_2$ and the high density of grain boundaries, both help in the pinning of vortices and result in improved superconducting performance.

Assessment of Biomass and Carbon Stock in Sal (Shorea robusta Gaertn.) Forests under Two Management Regimes in Tripura, Northeast India

  • Banik, Biplab;Deb, Dipankar;Deb, Sourabh;Datta, B.K.
    • Journal of Forest and Environmental Science
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    • 제34권3호
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    • pp.209-223
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    • 2018
  • We investigated tree composition, stand characteristics, biomass allocation pattern and carbon storage variability in Sal forests (Shorea robusta Garten.) under two forest management regimes (Sal forest and Sal plantation) in Tripura, Northeast India. The results revealed higher species richness (29 species), stand density of $1060.00{\pm}11.12stems\;ha^{-1}$ and diversity index ($1.90{\pm}0.08$) in Sal forest. and lower species richness (4 species), stand density of $ 230.00{\pm}37.22stems\;ha^{-1}$ and diversity index ($0.38{\pm}0.15$) in Sal plantation. The total basal cover $33.02{\pm}4.87m^2ha^{-1}$) and dominance ($0.76{\pm}0.08$) were found higher in Sal plantation than the Sal forest ($22.53{\pm}0.38m^2ha^{-1}$ and $0.23{\pm}0.02$ respectively). The total vegetation carbon density was recorded higher in Sal plantation ($219.68{\pm}19.65Mg\;ha^{-1}$) than the Sal forest ($167.64{\pm}16.73Mg\;ha^{-1}$). The carbon density estimates acquired in this study suggest that Sal plantation in Tripura has the potentiality to store a large amount of atmospheric carbon inspite of a very low species diversity. However, Sal forests has also an impending sink of carbon due to presence of large number of young trees.

보강성 충전제가 첨가된 SBR/BR 블렌드의 가황특성에 관한 연구 (A Study on the Vulcanization Characteristics of SBR/BR Blends Containing Reinforcing Fillers)

  • 이석
    • Elastomers and Composites
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    • 제33권4호
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    • pp.274-280
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    • 1998
  • 가황반응에 대한 반응차수, 반응속도상수 및 활성화에너지, 가교결합에 의한 가교밀도 및 탄성상수를 동일한 가황시스템하에서 실리카와 카본블랙을 함유한 SBR/BR 블렌드에 대하여 조사하였다. 반응차수는 충전제 종류에 관계없이 1차 반응이었으며, 카본블랙이 첨가된 배합고무는 실리카가 첨가된 배합고무보다 반응속도가 빠르게 나타났다. 그러나 활성화에너지는 충전제 종류 및 고무 블렌드 조성에 관계없이 일정하게 나타났다. 가교밀도 및 탄성상수는 고무와 카본블랙간의 강한 상호작용으로 인해 카본블랙이 첨가된 조성물에서 높게 나타났다. 한편, 고무 블렌드중 부타디엔 고무 함량이 증가할수록 가교밀도 및 탄성상수는 감소하였다. 가황고무중 결합 황 함량 비교결과, 실리카가 첨가된 조성물중 일정한 결합 황 함량은 반응시작 후 20분 후에 나타났으나, 카본블랙이 첨가된 조성물은 10분 후에 나타났다. 또한 실리카가 첨가된 조성물은 카본블랙이 첨가된 조성물에 비해 반응 유도시간($t_2$) 및 최적 가황시간($t_{90}$)이 길게 나타났다.

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Preparation and Application of Functional Carbon Whisker Membrane for Separation Process

  • Bae, Sang-Dae;Son, Hee-Jong;Jung, Chul-Woo
    • 한국환경과학회지
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    • 제17권11호
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    • pp.1235-1241
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    • 2008
  • Membrane separation is extensively used for water/wastewater treatment because of its efficiency separation processes. However, particles in the feed water can deposit and accumulate on the membrane surface to created cake layer. As a consequence, the selectivity of the membrane and flux through the membrane are decreased, which is called fouling/blocking phenomenon. In order to solve fouling problem, we developed a novel membrane named Carbon Whisker Membrane (CWM) which contains vapor-grown carbon fibers/whiskers on the surface of the membrane and a layer of carbon film coated on the ceramic substrate. We firstly employed polymethyl methacrylate (PMMA) as a testing material to investigate the fouling mechanism. The results suggested that Carbon Whiskers on the surface of the membrane can prevent the directly contact between the membrane body and particles so that the fouling/blocking could not occurred easily compared to the membrane without carbon whiskers. We also researched the relationship with the diameter, density of carbon whisker on the membrane surface and total flux of solutions. Finally, we will be able to control the diameter and density of carbon whiskers on the membrane and existence of carbon whiskers on the membrane, it is important factor, might be prevent fouling/blocking in the water treatment.

탄소 니들펀칭 프리폼의 소재조성 및 공정변수에 따른 인장 특성평가와 제작 최적화 (Evaluation of the tensile properties and optimum condition of manufacturing of carbon needle punched perform by material composition and processing parameters)

  • 배준희;이재열;강태진;정관수
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2003년도 추계학술발표대회 논문집
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    • pp.63-66
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    • 2003
  • The effect of punching density and material composition on the tensile properties and optimum condition of manufacturing of carbon needle punched perform was studies. The interlaminar tensile strength were increased but the intralaminar tensile strength were decreased with increasing punching density. In the case of the performs composed of continuous oxi-PAN fabrics, there was a considerable improvement of the interlaminar and intralaminar tensile strength.

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전기분해 DLC 합성 (Fabrication of DLC Using Electrodeposition)

  • 이상헌;최용
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 제38회 하계학술대회
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    • pp.1265-1266
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    • 2007
  • Electro-deposition of carbon film on silicon substrate in methanol solution was carried out with various current density, solution temperature and electrode spacing between anode and cathode. The carbon films with smooth surface morphology and high electrical resistance were formed when the distance between electrode was relatively wider. The electrical resistance of the carbon films were independent of both current density and solution temperature.

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Carbon Storage and Uptake by Street Trees in Seoul

  • Jo, Hyun-Kil;Kim, Jin-Young;Park, Hye-Mi
    • Journal of Forest and Environmental Science
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    • 제34권2호
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    • pp.162-164
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    • 2018
  • This study quantified the carbon storage and uptake by street trees in Seoul and explored suitable planting and management strategies. A systematic sampling model was used to select 50 plots to survey the structures of street trees. The average density and cover of street trees were approximately 5.8 trees/$100m^2$ and 12.1%, respectively. Trees with a dbh of less than 30 cm accounted for about 66.3% of the total number of trees surveyed. The total carbon storage and uptake by the street trees were approximately 103,641 t and 10,992 t/yr, respectively. The total carbon uptake equaled the amount of annual carbon emissions from driving of about 11,000 cars. Street tree planting and management strategies were proposed to enhance carbon uptake. They included multi-layered and multi-aged planting, securing ground and space for plant growth, and avoiding excessive tree pruning.