• Composites Research
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• v.17 no.6
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• pp.37-43
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• 2004

To determine the effect of chain length and chemical structure of linear amine curing agents on thermal and mechanical properties, a standard bifunctional linear DGEBF epoxy resin was cured with EDA and HMDA having amine group at the both ends of main chain in a stoichiometrically equivalent ratio in condition of preliminary and post cure. From this work, the effect of linear amine curing agents on the thermal and mechanical properties is significantly influenced by numbers of carbon atoms of main chain. In contrast, the results show that the DCEBF/EDA system having two carbons had higher values in the thermal stability, density, shrinkage (%), grass transition temperature, tensile modulus and strength, flexural modulus and strength than the DGEBF/HMDA system having six carbons, whereas the DGEBF/EDA cure system had relatively low values in maximum ekothermic temperature, maximum conversion of epoxide, thermal expansion coefficient than the DGEBF/HDMA cure system. These findings indicate that the packing capability (rigid property) in the EDA structure affects the thermal and mechanical properties predominantly. It shows that flexural fracture properties have a close relation to flexural modulus and strength.

• Journal of Plant Biotechnology
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• v.7 no.1
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• pp.67-74
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• 2005

To overcome various disadvantages of conventional cul-ture vessels for micropropagation, a novel disposable vessel, the 'Vitron', made of a multi-layered $OTP^{(R)}$ film and supported by a polypropylene frame, was developed. The film possesses superior properties such as: high light transmittance, low water vapor transmittance and thermal stability and in particular, high gas-permeability. Single nodal explants, which were excised from the multiple shoots derived from shoot-tip culture, were cultured in Vitron and polycarbonate vessels on $3\%$ sugar-containing agar on MS medium and placed at 3000 ppm $CO_2$-enrichment at a low photosynthetic photon flux density (PPFD) ($45{\mu}mol\;m^{-2}\;s^{-1}$). The in vitro and ex vitro growth, and the net photosynthetic rate of in vitro and ex vitro plantlets were significantly enhanced in the Vitron compared to those cultured in a polycarbonate vessel. Explants that were cultured on the same MS medium under low PPFD at various $CO_2$ concentrations were also cultured at 3000 ppm $CO_2$- enrichment at various PPFD: 30, 45, 60, 75 and $90{\mu}mol\;m^{-2}\;s^{-1}$. The best in vitro and ex vitro growth obtained for 3000 ppm $CO_2$-enrichment at $75{\mu}mol\;m^{-2}\;s^{-1}$ PPFD. The novel Vitron vessel, when placed under the two conditions, may replace conventional culture vessels for the successful micropropagation of sweetpotato.

• Journal of the Korean Society for Precision Engineering
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• v.30 no.2
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• pp.137-142
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• 2013

The indiscriminate use of the fossil fuel has caused serious environmental pollutions such as the shortage of energy and global warming. Microalgae have being emphasized as $3^{rd}$ generation biomass which makes the carbon dioxide reduce effectively as well as produces the biofuel. Large scale production of microbial biomass by continuous culture is a quite challenging issue, because off-line optimization strategies of a microbial process utilizing a model-based scheme give rise to many difficult problems. In this paper, the static and simple control method which was able to be applied in time-variant growth environment and large scale of algae culture was studied. The significant disturbances in on-line measurement of cell density were reduced by Savitzky-Golay FIR smoothing filter. Dunaliella salina was cultivated continuously in a flat panel photobioreactor by the on-off control of the turbidostat process.

• Applied Chemistry for Engineering
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• v.24 no.5
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• pp.489-493
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• 2013

The most common carbonaceous anode materials of lithium ion batteries (natural graphite, artificial graphite, hard carbon, and mesocarbon microbeads) were utilized as an electrode in lithium ion capacitors. It could be able to enhance the energy density of capacitors due to the intercalation of lithium ion. In this work, the properties of capacitors using the symmetric electrode were measured by organizing coin cell typed capacitors. Also, we made other capacitors having pre-intercalated lithium ions at one side of the electrode. The results of electrochemical measurements for these capacitors show that the storage capacitance was appeared. In other words, if the migration of lithium ions is supplied continuously in the electrolytes, lithium ions can be diffused into the carbonaceous materials. And it results in the improvement of capacitance compared to only using symmetric carbonaceous electrodes. Also, we conducted the same measurement with graphene oxide having a the large specific area in the same condition. Herein, we recognized that the large specific area is extremely important for supercapacitors.

• Applied Chemistry for Engineering
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• v.24 no.4
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• pp.382-390
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• 2013

Foaming process of waste soda lime glasses by just chemical composition control of vitreous feed materials was investigated to find a novel and efficient recycling process. For the chemical composition control of feed materials, 10 wt. parts of $SiO_2$, 0.5 wt. parts of $Na_2SO_4$, 3.0 wt. parts of $B_2O_3$, and 0.3 wt. parts of carbon black as the foaming agent were mixed with 100 wt. parts of soda-lime vitreous feed powder. Proper conditions for foaming process in tunnel kiln are the foaming temperature of $830{\sim}850^{\circ}C$, the foaming time of 30~35 min, and the vitreous feed powder particle size of -325 mesh. Properties of foamed glass blocks obtained under these foaming conditions showed the density of $0.17{\sim}0.21g/cm^3$, thermal conductivity of $0.06{\pm}0.005kcal/h{\cdot}m{\cdot}^{\circ}C$, moisture absorption of 1.1~1.5%, and compressive strength of $20{\sim}30kgf/mm^2$.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.409-412
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• 2001

The high purity manganese oxides were made from the dust, generated in AOD process that produces a medium-low carbon ferromanganese and collected in the bag filter. Manganese oxide content in the dust was about 90%, and its phase was confirmed as Mn₃O₄. In the extraction of manganese, because of remaining amorphous MnO₂, the dust was reduced to MnO by roasting with charcoal. The pulp density of the reduced dust can control pH of the solution more than 4 and then Fe ion is precipitated to a ferric hydroxide. Because a ferric hydroxide co precipitates with Si ion etc, Fe, Si ion was removed f개m the solution. Heating made water to be volatized and nitrates was left in reactor Then nitrates were a liquid state and stirring was possible. Among the nitrates in reactor, only the manganese nitrate which have the lowest pyrolysis temperature pyrolyzed into β-MnO₂powder and NO₂(g) at the temperature less than 200℃. When the pyrolysis of manganese nitrate has been completed about 90%, injection of water stopped the pyrolysis. Nitrates of impurity dissolved and the spherical high purity β-MnO₂powders were obtained by filtering and washing. Mn₂O₃or Mn₃O₄ powder could be manufactured from β-MnO₂powder by controlling the heating temperature. Lastly, a manufactured manganese oxide particle has 99.97% purity.

• Applied Chemistry for Engineering
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• v.28 no.6
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• pp.714-719
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• 2017

The contaminated engine oil by fuel can intimidate driver safety due to vehicle problems such as engine abrasion, fire and sudden unintended acceleration. In this study, we investigate various functional properties of the engine oil contaminated with fuel. The test results indicated that the engine oil contaminated with fuel had relatively low values of the flash point, pour point, density, kinematic viscosity and cold cranking simulator. Furthermore, a four ball test suggested that the contaminated engine oil increased wear scar due to the poor lubricity. Moreover, SIMDIST (simulated distillation) using ASTM D2887 was applied to analyze fuel characteristics in an engine oil. The SIMDIST analysis result showed a lower carbon number, and the fuel was detected at an earlier retention time than that of using engine oil in chromatogram. Also, it is possible to quantitatively analyze for fuel contents in the engine oil. The SIMDIST method for the diagnosis of oil conditions can be used whether the fuel was involved or not, instead of analyzing other physical properties that require various analytical instruments, large volumes of oil samples, and long analysis time.

• Applied Chemistry for Engineering
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• v.30 no.6
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• pp.659-666
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• 2019

Proton exchange membrane fuel cells (PEMFCs) generate electricity by electrochemical reactions of hydrogen and oxygen. PEMFCs are expected to alternate electric power generator using fossil fuels with various advantages of high power density, low operating temperature, and environmental-friendly products. PEMFCs have widely been used in a number of applications such as fuel cell vehicles (FCVs) and stationary fuel cell systems. However, there are remaining technical issues, particularly the long-term durability of each part of fuel cells. Degradation of a carbon supported-platinum catalyst in the anode and cathode follows various mechanistic origins in different fuel cell operating conditions, and thus accelerated stress test (AST) is suggested to evaluate the durability of electrocatalyst. In this article, comparable protocols of the AST durability test are intensively explained.

• Journal of the Korean Wood Science and Technology
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• v.46 no.5
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• pp.527-540
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• 2018

In this study, the characteristics of the white charcoal from charcoal kilns made for both charcoal production and thermotherapy and from the traditional charcoal kiln were compared and examined. A charcoal kiln for thermotherapy as a secondary purpose was made to minimize environmental problems such as fine dust and harmful gas generated from sealed charcoal kiln in consideration of comfort and safety. White Charcoal produced from the charcoal kiln for both charcoal production and thermotherapy had higher ash and volatile matter and lower fixed carbon than that from the traditional charcoal kiln. The density of the white charcoal produced from the charcoal kiln for both charcoal production and thermotherapy was slightly higher than that of the traditional one, but the equilibrium moisture content and pH were not significantly different. The calorific value, refinement degree, hardness and anatomical structure were not different between the two. It was concluded that the white charcoal produced from the advanced charcoal kiln for thermotherapy as a secondary purpose meets the quality certification standards of Korea Forest Research Institute.

• KSBB Journal
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• v.11 no.1
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• pp.30-36
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• 1996

Based on fermentation data for cyclosporin A production, simple Monod kinetics was proposed for both immobilized and suspended cultures. Higher value of $\mu$mas and lower value of Km suggest better catalytic activity of the immobilized cells than the parallel suspended cells. Furthermore, lower Km value in the immobilized cell system indicates higher affinity of the immobilized cells for carbon substrate as compared with the suspended cells. For immobilized cell cultures, these parameters were also utilized for the estimation of effectiveness factor, an indicator for intraparticle mass transfer resistance. Based on simulation studies, optimum radius of celite beads was turned out $100 ~ 500{\mu}m$In this simulation work, we examined the influence of biosupport size and immobilized biomass density on diffusional resistance of substrate inside the bead matrix. In order to maintain uniformly distributed cell activities in biosupport, it was essential to determine optimum slze of particle, and then to estimate the most economic loaded biomass content.