• 제목/요약/키워드: carbon cycle

검색결과 1,023건 처리시간 0.033초

Interconnected meso/microporous carbon derived from pumpkin seeds as an efficient electrode material for supercapacitors

  • Gopiraman, Mayakrishnan;Saravanamoorthy, Somasundaram;Kim, Seung-Hyun;Chung, Ill-Min
    • Carbon letters
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    • 제24권
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    • pp.73-81
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    • 2017
  • Interconnected meso/microporous activated carbons were prepared from pumpkin seeds using a simple chemical activation method. The porous carbon materials were prepared at different temperatures (PS-600, PS-700, PS-800, and PS-900) and demonstrated huge surface areas ($645-2029m^2g^{-1}$) with excellent pore volumes ($0.27-1.30cm^3g^{-1}$). The well-condensed graphitic structure of the prepared activated carbon materials was confirmed by Raman and X-ray diffraction analyses. The presence of heteroatoms (O and N) in the carbon materials was confirmed by X-ray photoemission spectroscopy. High resolution transmission electron microscopic images and selected area diffraction patters further revealed the porous structure and amorphous nature of the prepared electrode materials. The resultant porous carbons (PS-600, PS-700, PS-800, and PS-900) were utilized as electrode material for supercapacitors. To our delight, the PS-900 demonstrated a maximum specific capacitance (Cs) of $303F\;g^{-1}$ in 1.0 M $H_2SO_4 $ at a scan rate of 5 mV. The electrochemical impedance spectra confirmed the poor electrical resistance of the electrode materials. Moreover, the stability of the PS-900 was found to be excellent (no significant change in the Cs even after 6000 cycles).

전기이중층 커패시터용 질소성 작용기를 이용한 개질 활성탄의 전기화학적 특성 (Electrochemical Characteristics of Reforming Activated Carbon with Nitrogenous Functional Group for Electric Double Layer Capacitor)

  • 양정진;최영주;김한주;육영재;박수길
    • 전기화학회지
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    • 제16권2호
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    • pp.65-69
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    • 2013
  • 전기이중층 커패시터용 활성탄의 정전 용량 향상을 위해 우레아를 이용해 활성탄 표면에 펩티드 결합을 유도하였다. 우레아 도입에 따른 활성탄은 소성과정을 거쳐 안정화되었으며, 전기화학적 특성을 순환전류 전압법을 이용하여 정전 용량을 관찰하고, 임피던스를 통해 저항 변화를 관찰하였으며, 충방전 평가를 통해 싸이클 성능을 관찰하였다. 결과적으로 질소성 작용기의 도입으로 정전 용량은 기존 탄소재에 비해 약 22.9%의 향상을 이루었으며, 저항 감소 및 우수한 싸이클 성능을 나타냄을 확인하였다.

The Partitioning of Organic Carbon Cycle in Coastal Sediments of Kwangyang Bay

  • Han, Myung-Woo;Lee, In-Ho;Kim, Kee-Hyun;Noh, Il
    • Journal of the korean society of oceanography
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    • 제32권3호
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    • pp.103-111
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    • 1997
  • Biogeochemical cycling of organic carbon is quantitatively partitioned in terms of 1) flux to the ocean bottom, 2) benthic utilization at or near the sediment-water interface, 3) remineralization and 4) burial within sediments, by making an independent determination for each component process from a single coastal site in Kwangyang Bay. The partitioning suggests that the benthic utilization at or near the sediment-water interface is the major mode of organic carbon cycling at the site. The benthic utilization takes 61.8% (441.6 gCm$^{-2}$ yr $^{-1}$) of the total near-bottem organic carbon flux, 714.6 gCm $^{-2}$yr$^{-1}$, and far exceeds the remineralization of organic carbon within the sediments which amounts only to 6% (41.24 gCm$^{-2}$yr$^{-1}$) of the total near-bottom flux. The residence time is about 1.6 years for the sedimentary metabolic organic carbon in the upper 45 cm. The dominant partitioning of the benthic utilization in the carbon budget suggests that most of labile organic carbons are consumed at or near the sediment-water interface and are left over to the sediment column by significantly diminished amounts.

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복합조직강의 연속어닐링과정에서 미세조직과 집합조직의 변화 (Change in Microstructure and Texture during Continuous-Annealing in Dual-Phase Steels)

  • 정우창
    • 열처리공학회지
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    • 제28권4호
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    • pp.171-180
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    • 2015
  • The variation in microstructure and texture during continuous annealing was examined in a series of 1.6% Mn-0.1% Cr-0.3% Mo-0.005% B steels with carbon contents in the range of 0.010 to 0.030%. It was found that microstructure of hot band consisted of ferrite and pearlite as a consequence of high coiling temperature, and eutectoid carbon content was between 0.011% and 0.016%. Martensite ranged in volume fraction from 1.5% to 4.0% when annealed at $820{\circ}C$ according to the typical continuous annealing cycle. The critical martensite content for the continuous yielding was about 4% from stress-strain curves. The continuous yielding was obtained in the 0.030% carbon steel and 0.010% to 0.020% carbon steels revealed some yield point elongation ranging from 0.8% to 2.2% in as-annealed conditions. Higher tensile strength in the higher carbon steel is due to both increase in the martensite volume fraction and ferrite grain refinement. Decreasing the carbon content to 0.01% strengthened the intensities of ${\gamma}$-fiber textures, resulting in the increase in the $r_m$ value, which was caused by the lower volume fraction of martensite. The higher carbon steels showed the lower $r_m$ value of about 1.0.

타이어 보강용 고 탄소강 미세 강선의 굽힘 피로 성질에 미치는 미세 조직의 영향 (The Effects of Microstrucutral Parameters on Bending Fatigue Properties of Heavily Drawn Pearlitic Steel Filaments used for Automotive Tires)

  • 양요셉;임승호;반덕영;박찬경
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2005년도 추계학술대회 논문집
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    • pp.193-197
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    • 2005
  • Influences of microstructure on high-cycle fatigue (HCF) limit of high carbon $(>0.7wt.\;\%)$ steel filaments used for tires have been investigated. A series of the fatigue tests was carried out depending on carbon content by using Hunter-type tester at a frequency of 60 Hz at a tension/compression stress of 900 to 1500 MPa. Microstructural changes of the filaments were identified in the lateral direction by using transmission electron microscopy (TEM). It was found that the mechanical properties, such as fatigue limit and tensile strength, were improved with increasing carbon content, which was mainly attributed to decreased lamellar spacing and cementite thickness. However, the fatigue ratio, which is defined as the ratio of the fatigue limit to the tensile strength, was reduced in a higher carbon range of 0.8 to $0.9\;wt.\%$, while the fatigue ratio was nearly constant in a lower carbon range of 0.7 to $0.8\;wt.\%$. Overall mechanical properties of the filaments, depending on carbon content, have been discussed in terms of the microstructural parameter change of lamellar spacing and cementite thickness. In addition, the variation of cementite morphology on the fatigue crack propagation of high carbon $(0.9wt.\;\%)$ filaments will be discussed.

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리튬이온 2차전지용 탄소나노섬유/흑연 복합재 전극의 제조 (Fabrication of Carbon Nanofiber/Graphite Electrodes for Lithium Ion Secondary Battery)

  • 권경희;문승환;김명찬;오세민;김명수
    • 한국응용과학기술학회지
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    • 제20권2호
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    • pp.130-140
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    • 2003
  • In order to improve the lithium ion battery's performance, the carbon nanofibers were introduced to the anode electrode fabricated with natural graphite particles. The influence of structural adjustment of the particles by the introduction method of carbon nanofibers and the content of carbon nanofibers on the electrical property and charge/discharge characteristics of the electrode were investigated. The electrode fabricated with the mixture of 10 wt% of carbon nanofibers grown separately and 90 wt% of graphite particles showed an excellent discharge capacity of 400 mAh/g and the improved cycle performance. The improved performance could be explained by that the carbon nanofibers shortened and uniformly distributed on the surface of graphite particles by ball milling increased the stability for the intercalation/deintercalation of lithium ion and increased the electrical conductivity due to the closed packing between graphite particles.

마이크로파를 이용한 탈착시스템에서 개질화 된 활성탄의 흡.탈착 특성 (Adsorption and Desorption Characteristics of Toluene in Modified Activated Carbon Using Microwave Irradiation)

  • 김범준;최성우
    • 한국환경과학회지
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    • 제17권5호
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    • pp.493-500
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    • 2008
  • This paper describes the adsorption/desorpton efficiency of a modified activated carbon by irradiated microwave to treat toluene. By employing microwave energy, the regeneration time was considerably shortened compared with conventional thermal heating regeneration. New adsorbent called ACB (Activated Carbon-Bentonite) was prepared from powder activated carbon with mixing bentonite as a binder. Specific surface area, average pore size and total pore volume of ACB were calculated from the nitrogen adsorption/desorption isotherm. The surface of ACB was characterized with scanning electron microscope(SEM). The results showed that the specific surface area, total pore volume, average pore size of ABC was not influenced by regenerating cycle with microwave irradiation. Toluene was adsorbed onto ACB which desorbed by MW irradiation. Absorption capacity of ACB was 0.117 $g_{toluene}/g_{ACB}$. Desorption efficiency of toluene increased as higher microwave output was applied.

GC 연삭숫돌을 이용한 탄소섬유 에폭시 복합재료의 평면 연삭특성에 관한 연구 (A Study on the Plain Grinding Characteristics of Carbon Fiber Epoxy Composite with the GC Grinding Wheel)

  • 한흥삼
    • 한국생산제조학회지
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    • 제9권4호
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    • pp.34-47
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    • 2000
  • Since carbon fiber epoxy composite materials have excellent properties for structures due to their high specific strength, high specific modulus, high damping and low thermal expansion, the hollow shafts made of carbon fiber epoxy composites have been widely used for power transmission shafts for motor vehicles , spindles of machine tools, motor base, bearing mount for tool up and manufacturing. The molded composite machine elements are not usually accurate enough for mechanical machine elements, which require turning drilling , cutting and grinding. The experiment are surface grinding wheel GC60 to the carbon fiber epoxy composite specimen with respect to staking angle [0]nT , [45]nT, [90]nT on the CNC grinding machine. In this paper, the surface grinding characteristics of composite plate, which are surveyed experimentally and analytically with respect to the grinding force, surface roughness and wheel loading according to the variable depth of cut, wheel velocity and table feed rate are investigated.

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Studies on the Seasonal Variations of Plankton Organisms and Suspended Particulate Matter in the Coastal Area of Ko-Ri

  • Choe, Sang
    • 한국해양학회지
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    • 제7권2호
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    • pp.47-58
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    • 1972
  • Densities and composition of phytoplankton and zooplankton, concentrations of particulate organic carbon, particulate organic nitrogen, and particulate inorganic matter were determined in the coastal area of Ko-ri during one year. There are peaks of densities of plankton organisms in summer, autumn, and spring Concentrations of particulate organic carbon ranged from 35 to 3,785 mg/㎥ (averaging 868mg/㎥ ), particulate organic nitrogen ranged from 4.4 to 158mg/㎥ (averaging 45mg/㎥), inorganic suspended matter ranged from 0.6 to 11.6 mg/L (averaging 5.7mg/L), and the carbon-nitrogen ratios of the suspended matter were varied from 0.5 to 231(averaging 35), with each seasonal cycle. The phytoplankton density and particulate organic carbon were possitively correlated from March to November, negatively from December to February, and the zooplankton dinsity and particulate organic nitrogen were well correlated.

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장수명 공동주택의 친환경 요소기술 및 계획기법 체크리스트 구성에 관한 연구 (Study on the check list composition at Sustainable building strategies and Design methods of Long-life housing)

  • 한남수;이영
    • 한국주거학회논문집
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    • 제21권1호
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    • pp.103-112
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    • 2010
  • This Study is about the check-List composition for 'Low carbon green growth' of Long-life housing. That utilization for required the check-list composition at Sustainable building strategies and Design methods. That for long life housing, sustainable building strategies part of building construction and interior, the proper foundation for legislative system, maintenance methods with in building life cycle, sustainable and green architecture capability realization prepare for connection plan with 'Low carbon-green growth'. Extracting from elements of Architectural planing answer to basic concept of Low carbon-green growth and aimed at Low carbon scheme for energy saving, green growth scheme for environmental conservation as to each application purpose reconstitute by classify Check-list category about elements of Architectural planing. Through this architectural research deduce elements of architectural planing that can be research utilization with in Check-list composition.