• 제목/요약/키워드: carbon content,

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Synthetic Properties of Fe/MgO Catalyst on Characteristics of Carbon Nanotubes Prepared by Catalytic Chemical Vapor Deposition

  • Jung, Sung-Sil;Lee, Dae-Yeol;Chung, Won-Sub;Park, Ik-Min
    • Carbon letters
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    • 제5권3호
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    • pp.133-141
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    • 2004
  • The synthetic behaviors of carbon nanotubes (CNTs) by Fe/MgO catalysts were investigated in 0~90 wt.% range of MgO mixture ratios by catalytic chemical vapor deposition (CCVD) process. The CNTs were synthesized with 40 minutes of synthetic time, and 923 K of synthetic temperature using 0.1 L/min of ethylene gas and 1.0 L/min of hydrogen gas as synthetic and carrier gas, respectively. As the increase of synthetic temperatures and times, the diameters of CNTs become thicker. The carbon yield showed in a parabolic curve as MgO content increased and the maximum carbon yield was obtained at 30 wt.% of MgO. There were no obvious changes in the diameters of CNTs respect to the change of MgO content. Fe/MgO CNTs showed good crystalinity by High Resolution Transmission Electron microscope (HR-TEM) analysis. The behaviors of Fe/MgO CNTs have a tendency of depending on synthetic time and temperature rather than MgO content.

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SEM과 AFM을 사용한 반도전 재료 내 카본블랙의 형태 및 분산성 측정 (Formation and Dispersion Measurement in Semiconducting Materials Using the SEM and AFM)

  • 이경용;양종석;남종철;최용성;박동하;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.236-237
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    • 2005
  • To measure surface roughness and smoothness of semiconducting materials in power cable, we have investigated the formation and growth process of carbon black showed by changing the content of carbon black. The specimens were primarily kneaded in material samples of pellet form for 5 minutes on rollers ranging between 70[$^{\circ}C$] and 100[$^{\circ}C$]. Then they were produced as sheets after pressing for 20 minutes at 180[$^{\circ}C$] with a pressure of 200[kg/cm]. The contents of conductive carbon black were the variable, and their contents were 20, 30 and 40[wt%], respectively. The surface roughness and smoothness of specimens were measured by SEM and AFM. From SEM experimental result, carbon black in specimens formed matrix as a particles. Also we showed growth process of carbon black according to an increment of the content of carbon black. From AFM experimental result, surface roughness of specimens decreased according to an increment of the content of carbon black.

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Quantitative Evaluation of Non-Carbon Content in the Single Wall Carbon Nanotube Soot using Thermogravimetric Analysis

  • Han, J.H.;An, K.H.;Lee, N.S.;Goak, J.C.;Jeong, M.S.;Choi, Y.C.;Oh, K.H.;Kim, K.K.;Lee, Y.H.
    • Carbon letters
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    • 제10권1호
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    • pp.5-8
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    • 2009
  • We measured the non-carbon content of single-walled carbon nanotubes (SWCNTs) in SWCNT soot using thermogravimetric analysis. The weight increased percentage by the oxidation of metal in the raw soot is well obtained by TGA graph which was confirmed with ICP-AES, XRD, and XPS. This work will be very useful for the purity precise evaluation of SWCNT with UN-vis-NIR spectroscopy.

영동지역 교목 3수종 생엽의 연소에 따른 탄소배출량 분석 (Analysis of Carbon Emissions from Combustion of Three Arbor in Youngdong Area)

  • 박영주;이해평
    • 한국안전학회지
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    • 제25권6호
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    • pp.210-215
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    • 2010
  • In this study, when the forest fire occurred, in order to estimate greenhouse gas emissions, tree glow in Gangwon Youndong area, Juglans mandshurica, Alnus japonica, Acer palmatum of carbon dioxide and carbon monoxide emissions were about. Water content were measured before the experiment, Juglans mandshurica 196.24%, Alnus japonica 169.17% Acer palmatum 210.10% moisture content showed a big difference, Living leaves of Acer palmatum were a lot of moisture. Also, 50g weight of carbon dioxide on the Juglans mandshurica 53.3644g, Alnus japonica 49.4256g, was released about Acer palmatum 51.3394g, Juglans mandshurica living leaves were the most carbon dioxide emissions. Carbon monoxide emissions result, About weight 50g Juglans mandshurica 1.5329g, Alnus japonica 1.7189g, 2.5002g about Acer palmatum was released, Acer palmatum living leaves were the most carbon monoxide emissions.

Blowout of Rubber Vulcanizates: Influences of Cure Systems, Content of Carbon Black, and Organic Addities

  • 최성신;김익식
    • Bulletin of the Korean Chemical Society
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    • 제19권2호
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    • pp.174-178
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    • 1998
  • Blowout of NR and SBR vulcanizates was studied using a microwave oven. Rubber vulcanizates with different contents of carbon black (0, 30, 50, 70 phr) and various cure systems (conventional, semi-EV, and EV) were prepared. Unfilled rubber vulcanizates did not exploded by irradiation of microwave, while carbon black-filled ones exploded within 10 min. A blowout time of the carbon black-filled rubber vulcanizate decreases with an increase of the content of carbon black in the vulcanizate. A blowout temperature of the organic additive-extracted vulcanizate is higher than that of the not-extracted one, but the extracted vulcanizate blows out faster than the not-extracted one. A blowout temperature of the overcured vulcanizate is higher than that of the undercured one with the same cure system. Temperatures of unfilled SBR vulcanizates heated by the microwave irradiation are lower than those of unfilled NR ones. The carbon black-filled SBR vulcanizates blow out at higher temperatures than the carbon black-filled NR ones. Blowout times of the carbon black-filled SBR vulcanizates are longer than those of the carbon black-filled NR ones.

미연분 및 NOx배출 특성에 대한 고회분탄의 영향 연구 (Effect of High Ash Coal on Unburned Carbon and NOx Emission)

  • 김상인;이병화;임호;안기주;김만철;송주헌;전충환
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2012년도 제44회 KOSCO SYMPOSIUM 초록집
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    • pp.341-342
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    • 2012
  • The effect of high ash coal which has relatively high ash content and low combustibility on unburned carbon and NOx emission was experimentally investigated at several excess air ratio and particle size conditions of four coals containing different ash content in a drop tube furnace. Flue gas was measured by Gas analyzer in order to figure out unburned carbon characteristics. The results show that the higher content of ash makes the higher unburned carbon rate, subsequent changes in NOx emission characteristics was investigated.

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아공정 구상흑연주철의 Fading 거동에 미치는 탄소당량의 영향 (Effect of Carbon Equivalent on the Fading Behavior of Hypoeutectic Ductile Cast Iron)

  • 박헌범;박상준
    • 한국주조공학회지
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    • 제24권5호
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    • pp.290-294
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    • 2004
  • The effect of carbon equivalent on the fading behavior of hypoeutectic ductile cast iron was investigated. The carbon content was slightly increased right after graphite spheroidization treatment and remained almost constant with holding at $1,490^{\circ}C$ after 4 minute. The residual magnesium content was decreased slowly with holding. The empirical equation expressing the relationship between this and holding time was proposed ; $C=C_o-P{\times}t$. The proportionality constant, P, was inversely proportional to carbon content.

실리카와 카본블랙으로 보강된 SBR 고무 배합물의 특성에 보강제 조성비가 미치는 영향 (Influence of Filler Composition Ratio on Properties of Both Silica and Carbon Black-Filled Styrene-Butadiene Rubber Compounds)

  • 최성신
    • Elastomers and Composites
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    • 제36권1호
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    • pp.37-43
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    • 2001
  • 실리카와 카본블랙으로 보강된 SBR 배합물의 가황 특성과 bound rubber 함량 그리고 가황물의 물성에 보강제의 조성비가 미치는 영향을 연구하였다. 고무 배합물의 보강제 총 함량은 80.0 phr 이다. Bound rubber 함량은 실리카 함랑비가 증가할수록 증가하였고 점도 역시 증가하였는데, 특히 실리카 함량이 60.0 phr 이상일 때는 점도의 증가폭이 두드러지게 높아졌다. 가황시간은 실리카 함량이 증가할수록 느려졌고 가황 속도도 느려졌다. 실리카 함량비가 증가할수록 델타 토크가 증가함에도 불구하고 모둘러스는 감소하는 경향을 보였다. $60^{\circ}C$에서의 tan ${\delta}$ 값은 실리카 함량이 증가할수록 감소하였다.

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서울시 PM10 내의 수용성 유기탄소와 수분함량과의 상관성 분석 (The Relationship between the Estimated Water Content and Water Soluble Organic Carbon in PM10 at Seoul, Korea)

  • 이승하;김용표;이지이;이승묵
    • 한국대기환경학회지
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    • 제33권1호
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    • pp.64-74
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    • 2017
  • In this study, we have analyzed relationship between the measured Water Soluble Organic Carbon (WSOC) concentrations and the estimated aerosol water content of $PM_{10}$ (particulate matter with an aerodynamic diameter of less than or equal to $10{\mu}m$) for the period between September 2006 and August 2007 at Seoul, Korea. Water content of $PM_{10}$ was estimated by using a gas/particle equilibrium model, Simulating composition of Atmospheric Particles at Equilibrium 2 (SCAPE2). The WSOC concentrations showed low correlation with Elemental Carbon (EC), but Water Insoluble Organic Carbon (WISOC) were highly correlated with EC. It seemed that hydrophilic groups were produced by secondary formation rather than primary formation. As with the previous studies, WSOC showed good correlation with secondary ions ($NO_3{^-}$, $SO_4{^{2-}}$, $NH_4{^+}$), especially WSOC was highly correlated with $NO_3{^-}$ that is a secondary ion formed by photochemical oxidation from more local sources than $SO_4{^{2-}}$. No apparent correlation between the measured WSOC and estimated water content was observed. However, WSOC showed good correlation with estimated water content when it was assumed that relative humidity was higher than the deliquescence relative humidity of the system. In conclusion, WSOC is correlated with water content by hygroscopic ions and it is expected that nitrate play an important role among the water content and WSOC.

토양 흡착에 대한 유기탄소와 온도의 영향 (Influence of Organic Matter and Temperature on the Sorption of Volatile Organic Compounds on Soil)

  • 김희경
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 1998년도 공동 심포지엄 및 추계학술발표회
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    • pp.57-59
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    • 1998
  • The headspace method has been acknowledged as a cost-effective and convenient method to analyze volatile organic compounds(VOCs) in soil. The headspace analysis is based on equilibrium partitioning of VOCs among water, air and soil in a closed system. However, the headspace method cannot be applied to soils where most of the VOCs remain sorbed even at high temperature. In this study, it was investigated how the sorption characteristics of VOCs varied with soil with different organic carbon contents and temperature. This study showed that all the VOCs were volatilized, not sorved, only in the soil with 5% organic carbon at 45$^{\circ}C$ or higher. Some fraction of VOCs remained in soil with 8% organic carbon at $65^{\circ}C$ of higher. Most of the VOCs remained sorbed in soil with 12% organic content even at 95$^{\circ}C$. This result suggested that the headspace method can be applied only to soils with little organic carbon content (less than 5%). In this case, 45$^{\circ}C$ seems to be high enough to volatilize all the VOCs from soil. Large particles still showed a significant sorption capacity for VOCs from soil. Large Particles still showed a significant sorption capacity for VOCs despite of their low level of organic carbon content. It was also shown that the organic carbon sorption coefficients (Koc) of VOCs varied with soils with different organic carbon content. This suggests that not only the organic matter content of soil but also the property of the organic matter in soil influence the sorption of VOCs to soil.

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