• Title/Summary/Keyword: carbon arc

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Study of Multi-Walled Carbon Nanotube Synthesis Using Liquid Nitrogen and Post-Process Filtration

  • Sornsuwit, Nuttaphong;Maaithong, Worawut
    • International Journal of Precision Engineering and Manufacturing
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    • v.9 no.3
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    • pp.18-21
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    • 2008
  • The study deals with the effects of parameters in the synthesis of carbon nanotubes in liquid nitrogen to find the most appropriate conditions such as electrical voltage and time that give carbon nanotubes with large volume and less proportion of impurity, which is a non-nanotubed carbon. The experiment employed the method of arc-discharge between graphite cathode and anode which are immersed in liquid nitrogen. The electrical DC current of 60A and 70A were applied with the time period ranging from 10 seconds to 25 seconds. It was found that the electrical current of 60A and 13 seconds arc-discharge time allowed the largest volume of carbon nanotubes generation. The longer time leads to more impurities around the carbon nanotubes. By the filtration of CNTs-suspended solution using 0.2 micrometers porous paper filter and the characterization using TEM, the carbon nanotubes synthesized in the study were approximately 25 layers multi-walled nanotubes with the average diameter of 18.2 nanometers.

A Study on the Wear Behavior of Tetrahedral Amorphous Carbon Coatings Based on Bending Angles of the Filtered Cathodic Vacuum Arc with Different Arc Discharge Currents (자장여과아크소스의 자장필터 꺾임 각도와 아크방전전류에 따라 증착된 ta-C 코팅의 마모 거동 연구)

  • Kim, Won-Seok;Kim, Songkil;Jang, Young-Jun;Kim, Jongkuk
    • Tribology and Lubricants
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    • v.38 no.3
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    • pp.101-108
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    • 2022
  • The structure and properties of tetrahedral amorphous carbon (ta-C) coatings depend on the main process parameters and bending angles of the magnetic field filter used in the filtered cathodic vacuum arc (FCVA). During the process, it is possible to effectively control the plasma flux of carbon ions incident on the substrate by controlling the arc discharge current, thereby influencing the mechanical properties of the coating film. Furthermore, we can control the size and amount of large particles mixed during carbon film formation while conforming with the bending angle of the mechanical filter mounted on the FCVA; therefore, it also influences the mechanical properties. In this study, we consider tribological characteristics for filtered bending angles of 45° and 90° as a function of arc discharge currents of 60 and 100 A, respectively. Experiment results indicate that the frictional behavior of the ta-C coating film is independent of the bending angle of the filter. However, its sliding wear behavior significantly changes according to the bending angle of the FCVA filter, unlike the effect of the discharge current. Further, upon changing the bending angle from 45° to 90°, abrasive wear gets accelerated, thereby changing the size and mixing amount of macro particles inside the coating film.

A Case Study of Chronic Plantar Pompholyx Including Steroids Side Effects (스테로이드제제 부작용을 동반한 만성 족부 한포진 치험 1례)

  • Kang, Da-Hae;Kim, Jung-Hyun;Lim, Hae-Won;Kim, Jee-Young;Kwon, Kang
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.24 no.1
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    • pp.181-191
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    • 2011
  • Backgrounds : Pompholyx is a distinctive reaction pattern presenting as symmetric vesicular hand and foot dermatitis. Other than acute symptoms like itching and vesicles, chronic changes with scaling, fissure and pain may follow. As patients are treated by steroid for a long period, it tends to present side effects after quitting steroid treatment. Objectives : This study was carried out to investigate the effect of carbon arc lamp therapy and oriental medical therapy that venesection therapy, ointments and herbal medicine on chronic plantar pompholyx including steroids side effects. Methods : We treated one case of chronic plantar pompholyx which had continued about 10 years, including steroids side effects with venesection therapy, carbon arc lamp therapy, ointments and herbal medicine. To evaluate the results of this treatment, we categorized symptoms into six items which are vesicles, itching, fissures, pain, erosions and scales. Results : Except mild itching, vesicles and scales in a small area, all the symptoms were subsided. Conclusions : It is considered that various kinds of oriental medical therapy including carbon arc lamp therapy could replace steroid therapy which has many side effects.

Optimization of tetrahedral amorphous carbon (ta-C) film deposited with filtered cathodic vacuum arc through Taguchi robust design (다구찌 강건 설계를 통한 자장 여과 아크 소스로 증착된 사면체 비정질 탄소막의 최적화)

  • Kwak, Seung-Yun;Jang, Young-Jun;Ryu, Hojun;Kim, Jisoo;Kim, Jongkuk
    • Journal of the Korean institute of surface engineering
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    • v.54 no.2
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    • pp.53-61
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    • 2021
  • The properties of tetrahedral amorphous Carbon (ta-C) film can be determined by multiple parameters and comprehensive effects of those parameters during a deposition process with filtered cathodic vacuum arc (FCVA). In this study, Taguchi method was adopted to design the optimized FCVA deposition process of ta-C for improving deposition efficiency and mechanical properties of the deposited ta-C thin film. The influence and contribution of variables, such as arc current, substrate bias voltage, frequency, and duty cycle, on the properties of ta-C were investigated in terms of deposition efficiency and mechanical properties. It was revealed that the deposition rate was linearly increased following the increasing arc current (around 10 nm/min @ 60 A and 17 nm/min @ 100A). The hardness and ID/IG showed a correlation with substrate bias voltage (over 30 GPa @ 50 V and under 30 GPa @ 250 V). The scratch tests were conducted to specify the effect of each parameter on the resistance to plastic deformation of films. The analysis on variances showed that the arc current and substrate bias voltage were the most effective controlling parameters influencing properties of ta-C films. The optimized parameters were extracted for the target applications in various industrial fields.

Synthesis of Few-layer Graphene Film on a Ni Substrate by Using Filtered Vacuum Arc Source Method

  • Kim, Chang-Su;Seo, Ji-Hun;Gang, Jae-Uk;Kim, Do-Geun;Kim, Jong-Guk;Lee, Hyeong-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.157-157
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    • 2011
  • Graphene has generated significant interest in the recent years as a functional material for electronics, sensing, and energy applications due to its unique electrical, optical, and mechanical properties. Much of the considerable interest in graphene stems from results obtained for samples mechanically exfoliated from graphite. Practical applications, however, require reliable and well-controlled methods for fabrication of large area graphene films. Recently high quality graphene layers were fabricated using chemical vapor deposition (CVD) on nickel and copper with methane as the source of the carbon atoms. Here, we report a simple and efficient method to synthesize graphene layers using solid carbon source. Few-layer graphene films are grown using filtered vacuum arc source (FVAS) technique by evaporation of carbon atom on Ni catalytic metal and subsequent annealing of the samples at 800$^{\circ}$C. In our system, carbon atoms diffuse into the Ni metal layer at elevated temperatures followed by their segregation as graphene on the free surface during the cooling down step as the solubility of carbon in the metal decrease. For a given annealing condition and cooling rate, the number of graphene layers is easily controlled by changing the thickness of the initially evaporated amorphous carbon film. Based on the Raman analysis, the quality of graphene is comparable to other synthesis methods found in the literature, such as CVD and chemical methods.

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Effect of Pyrolysis Fuel Oil Based Carbon Coating onto CFX Cathode on High-rate Performance of Lithium Primary Batteries (불화탄소 전극의 열분해 연료유 기반 탄소 코팅이 리튬일차전지의 고율속 성능에 미치는 영향)

  • Sangyeop Lee;Naeun Ha;Seongjae Myeong;Chaehun Lim;Sei-Hyun Lee;Young-Seak Lee
    • Applied Chemistry for Engineering
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    • v.35 no.4
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    • pp.321-328
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    • 2024
  • The performance of carbon fluoride-based lithium primary batteries (Li/CFX) is limited due to poor rate capability resulting from the low conductivity of carbon fluoride, which is used as the active material. Therefore, in this study, we applied a carbon coating using pyrolysis fuel oil on carbon fluoride to overcome this limitation and considered its electrochemical performance. An amorphous carbon layer was formed on the surface of the carbon fluoride through carbon coating, and the surface physicochemical properties of the carbon fluoride were meticulously considered based on the heat treatment temperature. The advanced research chemical 1000 heat treated at 450 ℃ (ARC@C450) sample, which was commercial carbon fluoride heat-treated at 450 ℃, showed the largest increase in the concentration of sp2 carbon bonds (62%) and the highest formation of semi-ionic C-F bonds. Also, the primary battery using the ARC@C450 sample as a cathode active material exhibited stable discharge capability at the highest rate of 5 C (392 mAh/g), and the Rct value was reduced by 53% compared to the untreated sample. Therefore, we proposed pyrolysis fuel oil-based carbon coating as a method to overcome the low conductivity of carbon fluoride, and the carbon-coated carbon fluoride showed excellent rate performance, suggesting its potential application in high-power primary batteries.

고탄소계 Cr-Ti 합금강 레일재의 용접성에 관한 기초연구

  • 강계명;송진태
    • Journal of Welding and Joining
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    • v.8 no.1
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    • pp.54-61
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    • 1990
  • A pilot production is made to the high carbon Cr-Ti alloy rail steels with slight quantity of Cr & Ti added to the eutectoid carbon steel. As a part of weldability of these alloy steels, SH-CCT diagram for welding is first applied to the high carbon Cr-ti alloy rail steel with 0.1wt% Ti. The microstructure, which will be appeared at the HAZ of Enclosed-arc welding of this alloy rail seel, is a single phase of pearlite. As a result of this, it shows that the welding condition of Enclosed-arc welding applied to this alloy rail steel is a good condition.

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Strength Properties of the Concrete with Low Carbon Cement and Rapidly Cooled Electric Arc Furnace Oxidizing Slag (급냉 전기로 산화슬래그와 저탄소시멘트를 적용한 콘크리트의 강도특성)

  • Sun, Joung-Soo;Choi, Sun-Mi;Sung, Jong-Hyun;Bok, Young-Jae;Choi, Duck-jin;Kim, jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.11a
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    • pp.164-165
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    • 2013
  • This study is on the performance evaluation of concrete being used the CaMg based low carbon cement(LCC) as a binder and the rapidly cooled electric arc furnace oxidizing slag(EAF slag) as a fine aggregate. When using the sand as a fine aggregate, compressive strength of the concrete using LCC, as a binder, was reduced 9% comparing with that of OPC concrete. However, when using the EAF slag as a fine aggregate, the compressive strength was increased by 9%. We found that combination LCC and EAF slag contribute to the strength properties of concrete.

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Investigation of Amorphous Carbon Film Deposition by Molecular Dynamic Simulation (분자 동역학 전산모사에 의한 비정질 탄소 필름의 합성거동 연구)

  • 이승협;이승철;이규환;이광렬
    • Journal of the Korean Vacuum Society
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    • v.12 no.1
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    • pp.25-34
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    • 2003
  • Deposition behavior of hard amorphous carbon film was investigated by molecular dynamic simulation using Tersoff potential which was suggested for the interaction potential between carbon atoms. When high energy carbon atoms were collided on diamond (100) surface, dense amorphous carbon film could be obtained. Physical properties of the simulated carbon film were compared with those of the film deposited by filtered cathodic arc process. As in the experimental result, the most diamond-like film was obtained at an optimum kinetic energy of the incident carbon atoms. The optimum kinetic energy was 50 eV, which is comparable to the experimental observation. The simulated film was amorphous with short range order of diamond lattice. At the optimum kinetic energy condition, we found that significant amount of carbon atom were placed at a metastable site of distance 2.1 $\AA$. By melting and quenching simulation of diamond lattice, it was shown that this metastatic peak is Proportional to the quenching rate. These results show that the hard and dense diamond-like film could be obtained when the localized thermal spike due to the collision of high energy carbon atom can be effectively dissipated to the lattice.

Influence of Gas Metal Arc Welding Parameters on the Bead Properties in Automatic Cladding

  • TERNER, Mathieu;BAYARSAIKHAN, Tsend-Ayush;HONG, Hyun-Uk;LEE, Je-Hyun
    • Journal of Welding and Joining
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    • v.35 no.1
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    • pp.16-25
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    • 2017
  • Gas Metal Arc Welding is a widely used process in Industry due to its high productivity and potential to automation. The present study investigates the effects of the welding speed, arc voltage, welding current and shielding gas on the bead geometry for a low-carbon steel. The Response Surface Methodology (RSM) is used to choose an experimental design and perform test runs accordingly in order to produce mathematical models predicting the geometry, the hardness and the heat input of the bead as functions of the welding parameters. The direct and interaction effects of the four welding parameters are represented graphically and allow to determine an optimum set of welding parameters.