• Title/Summary/Keyword: carbon/carbon composite

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A Study of Damage Sensing and Repairing Effect of CNT Nanocomposites (손상감지용 CNT 나노복합재료의 손상 감지능 및 보강효과 연구)

  • Kwon, Dong-Jun;Wang, Zuo-Jia;Choi, Jin-Young;Shin, Pyeong-Su;Park, Joung-Man
    • Composites Research
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    • v.27 no.6
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    • pp.219-224
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    • 2014
  • Nancomposites manufacture has been developed rapidly, because of reinforcing effects of CNT in terms of mechanical, electrical and thermal properties. In this study, 10 wt% CNT paste was fabricated with good dispersion state and easy processability. Damage sensing and reinforcing effect of CNT paste were investigated in nanocomposites. 10 wt% CNT paste exhibited better tensile and flexural properties than those of general 1 wt% CNT nanocomposites. To observe the healing effect of CNT paste, a crack was made artificially with 30wt% CF30wt%/PP composites, and the CNT paste was filled inside the crack. The damage sensing of CNT paste in CF30wt%/PP composites was investigated by electrical resistance measurement and mechanical tests. CNT paste exhibited good reinforcing effect in mechanical properties of CF30wt%/PP composites, and this reinforcing effect was getting better with larger cracks. The reason was because CNT paste had good interfacial adhesion with CF30wt%/PP composites to resist crack propagation. In electrical resistance measurement, there was a jump in electrical resistance signal at the adhesion interface. The jumping signal could be used to predict fracture of CF/PP composites. CNT nanocomposites for damage sensing had crack reducing effect and damage detection using electrical resistance method.

The Effect of Glass Fabric Separator Elongation on Electric Property in Structural Battery (유리섬유 분리막 인장으로 인한 구조전지의 전기적 물성 변화)

  • Shin, Jae-Sung;Park, Hyun-Wook;Park, Mi-Young;Kim, Chun-Gon;Kim, Soo-Hyun
    • Composites Research
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    • v.30 no.1
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    • pp.46-51
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    • 2017
  • Structural battery has been researched extensively to combine the functions of the battery and structure without gravimetric or volumetric increments compared to their individual components. The main idea is to employ carbon fabric as the reinforcement and electrode, glass fabric as the separator, and solid-state electrolyte which can transfer load. However, state-of-the-art solid-state electrolytes do not have sufficient load carrying functionality and exhibiting appropriate ion conductivity simultaneously. Therefore, in this research, a system which has both battery and load carrying capabilities using glass fabric separator and liquid electrolyte was devised and tested to investigate the potential and feasibility of this structural battery system and observe electric properties. It was observed that elongating separator decreased electrical behavior stability. A possible cause of this phenomenon was the elongated glass fabric separator inadequately preventing the penetration of small particles of the cathode material into the anode. This problem was verified additionally by using a commercial separator. The characteristic of the glass fabric and the interface between the electrode and glass fabric needed to be further studied for the realization of such a load carrying structural battery system.

Effect of Epoxy Mixed with Nafion Solution as an Anode Binder on the Performance of Microbial Fuel Cell (산화전극 결합제로서 나피온용액에 혼합된 에폭시가 미생물연료전지의 성능에 미치는 영향)

  • Song, Young-Chae;Kim, Dae-Seop;Woo, Jung-Hui
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.1
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    • pp.1-6
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    • 2014
  • The composite anodes of exfoliated graphite (EG) and multiwall carbon nanotube (MWCNT) were fabricated by using the binders with different content of epoxy in Nafion solution. The influence of the epoxy content in the anode binder on the performance of microbial fuel cell (MFC) was examined in a batch reactor. With the increase in the epoxy content in the anode binder, increase in physical binding force was observed, but at the same time an increase in the internal resistance of MFC was also observed. This was due to the increase in activation and ohmic resistance. For the anode binder without epoxy, the maximum power density was $1,892mW/m^2$, but a decrease in maximum power density was observed with the increase in the epoxy content in the anode binder. With the epoxy content of 50% in the anode binder, a decrease in the maximum power density to $1,425mW/m^2$ was observed, which about 75.3% of the anode binder without epoxy is. However, the material consisting of the same amount of epoxy and Nafion solution is a good alternative for anode binder in terms of durability and economics of MFC.

Optimization of Production Yield for Neohesperidin by Response Surface Methodology (반응표면 분석법을 이용한 neohesperidin 생산 수율의 최적화)

  • Yang, Hee-Jong;Jeong, Seong-Yeop;Choi, Nack-Shick;Ahn, Keug-Hyun;Park, Chan-Sun;Yoon, Byoung-Dae;Ryu, Yeon-Woo;Ahn, Soon-Cheol;Kim, Min-Soo
    • Journal of Life Science
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    • v.20 no.11
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    • pp.1691-1696
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    • 2010
  • Neohesperidin is a natural new nutrition sweetener, widely existing in plants of dry citrus peel, which can be derived from extraction. Since the sweetness is 1,300-1,500 times greater than that of sugar, neohesperidin are widely used in fruit juices, wines, beverages, bakeries and pharmaceutical formulations, and are particularly suitable for consumption by diabetic patients. However, the yield of extraction from citrus peel waste is very low. In this study optimal yield conditions were determinedusing response surface methodology (RSM) in order to increase the neohesperidin extraction yield. The critical factors for maximum extraction yield were selected extraction pressure ($x_1$), extraction time ($x_2$), and concentration of ethanol ($x_3$). As a result, the extraction yield was improved when the extracting pressure increased. The extraction yield also increased in a time-dependent manner. When adding ethanol as an assistance solvent to the supercritical carbon dioxide, extraction yield was increased as more ethanol concentration was added. Finally, the extraction yield of neohesperidin was improved to about 162.22% compared to ethanol extraction as a conventional method.

Development of CFS Jacketing Retrofit Method for Rectangular High Strength Concrete Columns by Cross Sectional Shape Modification (4각형 고강도 콘크리트 기둥 단면 변형을 통한 CFS Jacketing 보강방법 개발)

  • Lee, Jong-Gil;Kim, Jang-Ho Jay;Park, Seok-Kyun;Kim, Jin-Keun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.6
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    • pp.153-161
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    • 2010
  • Numerous past studies have shown that safety and serviceability of many concrete infrastructures and buildings built in 1970's have far less strength capacities than their original intended design capacities, thereby requiring repair and strengthening. Currently, aged concrete structures are being repaired using various methods developed in the past. Unfortunately, these methods do not consider the specific conditions that these members are under, but they merely attach repairing materials on the external surface for random strength improvements. Therefore, in order to improve repair and strengthening methods by considering composite behavior between repairing material and structural member, enhanced construction methodologies are needed. Also, the enhanced repairing and strengthening methods must be able to be implemented on structural members constructed using high performance concrete to meet the present construction demand of building mammoth structures. Therefore, in this study, a repairing and strengthening method for retrofitting high strength concrete (HSC) columns that can effectively improve column performance is developed. A square HSC column's cross-sectional shape is converted to an octagonal shape by attaching precast members on the surface of the column. Then, the octagonal column surface is surface wrapped using Carbon Fiber Sheets (CFS). The method allows maximum usage of confinement effect from externally jacketing CFS to improve strength and ductility of repaired HSC columns. The research results are discussed in detail.

A Study on the Fire Risk of Car Interior Materials (자동차 내장재의 화재위험성에 관한 연구)

  • Lee, Hae-Pyeong;Kim, Young-Tak
    • Fire Science and Engineering
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    • v.24 no.2
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    • pp.82-88
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    • 2010
  • In this study, we have performed several tests for composite plastic materials to be applied on interior materials of a vehicle to identify their combustion characteristics using cone calorimeter, smoke density chamber and toxicity index chamber. We have prepared a total of 12 samples for 4 major parts of a vehicle wherein each major part has 3 different materials. The results of cone calorimeter test showed ignition time of PVC sheet and PVC leather were 2s. The 8 samples showed under less than 10s of ignition time. The sample comprising Nylon and PE had the biggest maximum heat release rate of 635 $kW/m^2$. The sample comprising Rubber showed the smallest maximum heat release rate but with the biggest total heat release. The results of smoke density chamber test showed the sample that is made up with Rubber had the biggest specific optical smoke density. The sample comprising PVC leather and PUR showed the biggest VOF4 which enables the initial smoke production. The results of toxicity index test showed that all samples contained carbon dioxide content exceeding its lethal concentration. The sample comprising PVC showed high content of hydrogen chloride and hydrogen bromide. The PVC sheet showed the biggest toxicity index calculated by using lethal concentration and test results. Toxicity index of all sample wes over 1.

Surface Modification of Microcrystalline Cellulose (MCC) Filler for CO2 Capture (CO2 흡착 충전제 제조를 위한 microcrystalline cellulose (MCC) 입자 표면개질연구)

  • Yang, Yeokyung;Park, Seonghwan;Kim, Hanna;Hwang, Ki-Seob;Ha, KiRyong
    • Korean Chemical Engineering Research
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    • v.55 no.1
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    • pp.60-67
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    • 2017
  • In this study, we performed surface modification of biodegradable microcrystalline cellulose (MCC) to use as a filler in polyethylene (PE) composite in food packaging application. We modified MCC surface with (3-trimethoxysilylpropyl)diethylenetriamine (TPDT) silane coupling agent, which has one primary amino group and two secondary amino groups per molecule, to introduce amino groups with a carbon dioxide adsorption capability in MCC. Effects of each of the reaction conditions such as amount of TPDT introduced, swelling time, reaction temperature, and reaction time on surface modification degree of MCC were investigated by changing a variety of above reaction conditions. The amount of TPDT grafted on MCC surface and formation of chemical bonds were confirmed by Fourier transform infrared spectroscopy (FT-IR), elemental analysis (EA), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA) and solid state $^{29}Si$ nuclear magnetic resonance (NMR) spectroscopy. We confirmed increase of grafted amount of TPDT on MCC with increasing reaction time, reaction temperature, and amount of introduced TPDT.

Development of Composite Sensing Technology Using Internet of Things (IoT) for LID Facility Management (LID 시설 관리를 위한 사물인터넷(IoT) 활용 복합 센싱 적용기술 개발)

  • Lee, Seungjae;Jeon, Minsu;Lee, Jungmin;Kim, Lee-Hyung
    • Journal of Wetlands Research
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    • v.22 no.4
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    • pp.312-320
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    • 2020
  • Various LIDs with natural water circulation function are applied to reduce urban environmental problems and environmental impact of development projects. However, excessive Infiltration and evaporation of LID facilities dry the LID internal soil, thus reducing plant and microbial activity and reducing environmental re duction ability. The purpose of this study was to develop a real-time measurement system with complex sensors to derive the management plan of LID facilities. The test of measurable sensors and Internet of Things (IoT) application was conducted in artificial wetlands shaped in acrylic boxes. The applied sensors were intended to be built at a low cost considering the distributed LID and were based on Arduino and Raspberry Pi, which are relatively inexpensive and commercialized. In addition, the goal was to develop complex sensor measurements to analyze the current state o f LID facilities and the effects of maintenance and abnormal weather conditions. Sensors are required to measure wind direction, wind speed, rainfall, carbon dioxide, Micro-dust, temperature and humidity, acidity, and location information in real time. Data collection devices, storage server programs, and operation programs for PC and mobile devices were developed to collect, transmit and check the results of measured data from applied sensors. The measurements obtained through each sensor are passed through the Wifi module to the management server and stored on the database server in real time. Analysis of the four-month measurement result values conducted in this study confirmed the stability and applicability of ICT technology application to LID facilities. Real-time measured values are found to be able to utilize big data to evaluate the functions of LID facilities and derive maintenance measures.

Impact Performance of 3D Orthogonal Composites by Automated Tape Placement Process (자동적층 공정에 의한 3차원 직교 섬유배열구조 복합재의 충격특성)

  • Song S-W;Lee C-H;Um M-K;Hwang B-S;Byun J-H
    • Composites Research
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    • v.18 no.3
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    • pp.38-46
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    • 2005
  • In order to characterize the outstanding performance of three-dimensional (3D) composites, the low velocity impact test has been carried out. 3D fiber structures have been achieved by using the automated tape placement (ATP) process and a stitching method. Materials for the ATP and the stitching process were carbon/epoxy prepreg tapes and Kevlar fibers, respectively. Two-dimensional composites with the same stacking sequence as 3D counterparts have also been fabricated for the comparison of damage tolerance. For the assessment of damage after the impact loading, specimens were subjected to C-Scan nondestructive inspection. Compression after impact (CAI) tests were conducted to evaluate residual compressive strength. The damage area of 3D composites was greatly reduced $(30-40\%)$ compared with that of 2D composites. Although the CAI strength did not show drastic improvement for 3D composites, the ratio of retained strength was $5-10\%$ higher than 2D samples. The effect of stitching on the impact performance was negligible above the energy level of 35 Joules.

Numerical Analysis of the Complex Permittivity of MWNT added Epoxy Depending on Agglomeration Size (에폭시 내부의 MWNT 응집 크기에 따른 복소유전율 변화의 해석적 관찰)

  • Shin, Jae-Hwan;Jang, Hong-Kyu;Choi, Won-Ho;Song, Tae-Hoon;Kim, Chun-Gon;Lee, Woo-Yong
    • Composites Research
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    • v.27 no.5
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    • pp.190-195
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    • 2014
  • This paper predicts the complex permittivity of MWNT added epoxy depending on agglomeration by numerical analysis. 1wt% MWNT added epoxy specimen is prepared using 3-roll-mill method and its complex permittivity is measured in X-band (8.2~12.4 GHz) using freespace measurement system. The analytic model is comprised of cube epoxy and perfect sphere agglomeration. The complex permittivity of the agglomeration model is predicted by complex permittivity mixing rule using the measured complex permittivity of epoxy and 1 wt% MWNT added epoxy. Commercial electromagnetic analysis software, CST, is used to obtain S-parameter of the analytic model and MATLAB code is used to calculate complex permittivity from the S-parameter. It is confirmed that the complex permittivity increases when the agglomeration size decreases.