• Composites Research
• /
• 제30권6호
• /
• pp.422-428
• /
• 2017

본 연구에서는 온도와 수분에 노출된 다중벽 탄소나노튜브가 함유된 나노복합재의 수분흡수거동, 인장특성, 열분석특성을 평가하였다. 이때 탄소나노튜브 함유량은 0 wt%, 1 wt%, 2 wt%를 고려하였으며 시편은 각각 $25^{\circ}C$와 $75^{\circ}C$의 침수조건에 600시간까지 노출시켰다. 연구결과에 따르면 수분흡수량은 노출시간이 길어지면 증가하지만 최대 수분흡수량과 600시간에서의 수분흡수량 차이는 일정하게 나타났다. 인장탄성계수는 노출시간이 길어지면 낮아지고 탄소나노튜브 함유량이 많고 노출온도가 높아지면 감소 정도는 크게 나타났다. 인장강도는 탄소나노튜브가 함유되지 않은 경우 노출시간이 길어지면 감소하지만 MWCNT 함유되면 MWCNT의 보강 효과로 인해 증가하는 양상이 나타났다. 저장탄성계수, 유리전이온도, $tan{\delta}$ 피크 크기는 노출시간이 길어지면 낮게 나타나며 높은 노출온도에 300시간 이상 노출되면 두 개의 피크를 갖는 $tan{\delta}$ 선도가 나타났다.

• 한국미생물·생명공학회지
• /
• 제41권1호
• /
• pp.52-59
• /
• 2013

The nutritional requirements for the maximum production of lipopeptides by Bacillus subtilis N7 (B. subtilis N7) were investigated and optimized using response surface methodology (RSM) under shake flask fermentation. A one-factor-at-a-time experimental setup was used to screen carbon and nitrogen sources. A Plackett-Burman design (PBD) was employed to screen the most critical variables for lipopeptides production amongst ten nutritional elements. The central composite experimental design (CCD) was finally adopted to elucidate the composition of the fermentation medium. Statistical analyses (analysis of variance, ANOVA) of the results showed that KCl, $MnSO_4$ and $FeSO_4{\cdot}6H_2O$ were important components and that their interactions were strong. Lipopeptide production was predicted to reach 709.87 mg/L after a 60 h incubation using an optimum fermentation medium composed of glucose 7.5 g/L, peanut oil 1.25 g/L, $MgSO_4$ 0.37 g/L, $KH_2PO_4$ 0.75 g/L, monosodium glutamate 6.75 g/L, yeast extract and $NH_4Cl$ (5:3 w/w) 10 g/L, KCl 0.16 g/L, $FeSO_4{\cdot}6H_2O$ 0.24 mg/L, $MnSO_4$ 0.76 mg/L, and an initial pH of 7.0. Lipopeptide production ($706.57{\pm}3.70$ mg/L) in the optimized medium confirmed the validity of the predicted model.

• Journal of Microbiology and Biotechnology
• /
• 제27권11호
• /
• pp.2010-2018
• /
• 2017

Mixotrophic microalgal growth gives a great premise for wastewater treatment based on photoautotrophic nutrient utilization and heterotrophic organic removal while producing renewable biomass. There remains a need for a control strategy to enrich them in a photobioreactor. This study performed a series of batch experiments using a mixotroph, Chlorella sorokiniana, to characterize optimal guidelines of mixotrophic growth based on a statistical design of the experiment. Using a central composite design, this study evaluated how temperature and light irradiance are associated with $CO_2$ capture and organic carbon respiration through biomass production and ammonia removal kinetics. By conducting regressions on the experimental data, response surfaces were created to suggest proper ranges of temperature and light irradiance that mixotrophs can beneficially use as two types of energy sources. The results identified that efficient mixotrophic metabolism of Chlorella sorokiniana for organics and inorganics occurs at the temperature of $30-40^{\circ}C$ and diurnal light condition of $150-200{\mu}mol\;E{\cdot}m^{-2}{\cdot}s^{-1}$. The optimal specific growth rate and ammonia removal rate were recorded as 0.51/d and 0.56/h on average, respectively, and the confirmation test verified that the organic removal rate was $105mg\;COD{\cdot}l^{-1}{\cdot}d^{-1}$. These results support the development of a viable option for sustainable treatment and effluent quality management of problematic livestock wastewater.

• 품질경영학회지
• /
• 제43권3호
• /
• pp.359-372
• /
• 2015

Purpose: Through studying the expert's and non-experts panel responses to the questions regarding the attributes of chemical-biological protection cloth quality in terms of the levels of customer demand and technical factors has been studied. We are applied to a QFD matrix with find out the relationship between the selective removal efficiency of chemical-biological cloth and the guidelines of technical approach. Methods: We fabricated several composite of ion-exchange resins with selectively permeable performance designed to facilities water vapor transport and selective adsorption of the harmful gases. With these materials, we characterized on the selectively permeable performance to identify ion-exchange resin with chemical-biological protective cloth. Results: Results showed that ion exchange materials possessed performance with selectively efficiencies as NH3, SOx, NOx and HCl gas. The selective adsorption amount of ammonia and hydrogen gases were $90-80{\mu}g/g$ with TRILITE SCR-BH sulfonated ion exchange resin. The PP non-woven/ion exchange resin adsorbent materials possessed performance with water vapor permeability were 1,100-1,350 g/m2/day, it's was two times high value compare with activated carbon. With these materials, we characterized selectively removal efficiency to identify new ion-exchange material with chemical-biological protective capability. Conclusion: This study shows that a QFD aids in deciding with of the adsorption parameters to optimized with chemical-biological protection cloth manufacturing.

• 환경위생공학
• /
• 제10권2호
• /
• pp.1-12
• /
• 1995

Under accelerated industrial developments environment pollution comes out to be very stirious. Especially the ions of heavy metal from wastewater, even if they are minimal, accumulated in ecology circle and do finally injury to human health. The general process for removal of heavy metals include coagulation and following sedimentation, ion -exchange and active carbon adsorption and sedimentation that applicate in popular, needs the expense of coagulant the additional treatment of sludge on the general process of coagulation and sedimentation. It is also a serious problem that the second pollution caused by coagulant. However chelating adsorption that uses natural chelating high- molecular compound has not pollution problem Among chelating high- molecules, the diminishing chitin that contained in crustaceans as crawfish and crab in our country with affluent water resources are easy to get. So it is advantageous to use this ubiquitous material for removing heavy metals because we could reuse natural resource. In this research, the author tested the effectiveness of the adsorption and removal of heavy metal ions by chitin and its derivatives. Chitin and cellulose became beads and used as flocculant, in this test. The results are as follows . First, bead showed higher removal ratio than powder in the comparative test on adsorbents such as chitin, chitosan and cellulose. Secondly, in the variety test by the kinds of adsorbent and time. chitosan bead and cellulose bead that showed the highest removal ratio. One hour need to remove the ions of heavy metal. Thirdly, the results of the adsorption degree test by pH revealed high removal ratio adsorption of chitin, cellulose and chitosan bead in alkalin condition but chitosan bead in acidic condition.

• 비파괴검사학회지
• /
• 제21권4호
• /
• pp.425-433
• /
• 2001

복합재료-금속 접착접합부가 사용 중 반복 하중을 받을 때 발생하는 피로 손상도를 음향초음파(acousto-ultrasonics; AU)법과 음향방출(acoustic emission; AE)법을 이용하여 평가하였다. 피로시험에는 단일겹치기(single-lap) 시험편을 사용하였으며, AU법을 통해 취득한 신호로부터 음향초음파변수(acousto-ultrasonic parameters; AUP)와 피로손상과의 상관관계 곡선을 얻고, AE법에서는 누적 AE events를 통한 피로손상과의 상관관계 곡선을 얻어, AU법과 AE법의 결과를 비교하였다. 이 곡선들은 피로손상에 의한 고분자기지 복합재료의 강성 저하$(E/E_0)$를 나타내는 곡선과 매우 유사하며, 이를 바탕으로 피로 손상도의 예측과 잔여 수명의 예측이 가능하다. 또한 피로 하중의 초기 단계와 피로손상의 누적에 의해 급격한 변화가 나타나는 단계의 파형 주파수 성분을 비교하여, 피로 파괴의 마지막 단계에서 나타나는 신호 중에는 본격적인 피로손상에 의해 발생하는 AE 신호 성분이 포함되어 있음을 확인할 수 있었다.

• 해양환경안전학회지
• /
• 제22권7호
• /
• pp.876-883
• /
• 2016

본 연구에서는 카누 선체 재료를 탄소섬유복합재료로 선정하였으며, 선형설계는 선박 설계 상용프로그램인 SOLIDWORKS를 이용하여 수행하였다. 카누의 유동해석은 상용프로그램인 STAR-CCM+를 이용하여 자유수면의 파형을 살펴보고 수치해석 결과를 통하여 저항성능을 확인하였다. 그 결과, 흘수가 0.09 m일 경우에 4 m/s 미만의 선속으로, 흘수가 0.24 m인 경우에는 2 m/s 미만으로 운항하면 안전하다고 판단되며, 두 명의 성인이 속도를 내는 데에도 무리가 없음을 확인하였다. 또한, 해석결과를 적용하고 CFRP를 이용하여, 기존의 재료보다 20 % 가볍게 제작된 카누에 대해서도 간략히 소개하였다.

• 대한조선학회지
• /
• 제25권4호
• /
• pp.58-68
• /
• 1988

$[0^{\circ}]_{8T},\;[90^{\circ}]_{8T},\;[+45^{\circ}]_{8T}$의 단축방향과 $[{\pm}15^{\circ}]_{2S},\;[{\pm}30^{\circ}]_{2S},\;[{\pm}45^{\circ}]2_{2S},\;[{\pm}60^{\circ}]_{2S},\;[{\pm}75^{\circ}]_{2S}$ Angle Ply 그리고 $0^{\circ},\;{\pm}45^{\circ},\;90^{\circ}$로 조합된 다방향 복합적층판의 기계적 성질에 대하여 스트레인 게이지를 이용하여 측정 수록하였다. 메트릭스의 특성이 잘 나타나는 $[10^{\circ}]$ Off-Axis와 $[{\pm}45^{\circ}]$ Angle Ply를 이용하여 전단탄성계수를 측정하였다. 복합재료 인장시험시 발생하는 Acoustic Emission 특성과 파괴거동을 비교 검토하고, 이것을 통하여 Acoustic Emission법의 유용성과 파손 메카니즘을 규명하고자 하였다.

• 한국재료학회지
• /
• 제25권6호
• /
• pp.279-287
• /
• 2015

In order to prepare anode materials for high power lithium ion secondary batteries, carbon composites were fabricated with a mixture of petroleum pitch and coke (PC) and a mixture of petroleum pitch, coke, and natural graphite (PC-NG). Although natural graphite has a good reversible capacity, it has disadvaantages of a sharp decrease in capacity during high rate charging and potential plateaus. This may cause difficulties in perceiving the capacity variations as a function of electrical potential. The coke anodes have advantages without potential plateaus and a high rate capability, but they have a low reversible capacity. With PC anode composites, the petroleum pitch/cokes mixture at 1:4 with heat treatment at $1000^{\circ}C$ (PC14-1000C) showed relatively high electrochemical properties. With PC-NG anode composites, the proper graphite contents were determined at 10~30 wt.%. The composites with a given content of natural graphite and remaining content of various petroleum pitch/cokes mixtures at 1:4~4:1 mass ratios were heated at $800{\sim}1200^{\circ}C$. By increasing the content of petroleum pitch, reversible capacity increased, but a high rate capability decreased. For a given composition of carbonaceous composite, the discharge rate capability improved but the reversible capacity decreased with an increase in heat treatment temperature. The carbonaceous composites fabricated with a mixture of 30 wt.% natural graphite and 70 wt.% petroleum pitch/cokes mixture at 1:4 mass ratio and heat treated at $1000^{\circ}C$ showed relatively high electrochemical properties, of which the reversible capacity, initial efficiency, discharge rate capability (retention of discharge capacity in 10 C/0.2 C), and charge capacity at 5 C were 330 mAh/g, 79 %, 80 %, and 60 mAh/g, respectively.

• 한국재료학회지
• /
• 제19권3호
• /
• pp.142-150
• /
• 2009

In this paper, non-treated ACF (Activated Carbon Fiber) /$TiO_2$ and Zn-treated ACF/$TiO_2$ were prepared. The prepared composites were characterized in terms of their structural crystallinity, elemental identification and photocatalytic activity. XRD patterns of the composites showed that the non-treated ACF/$TiO_2$ composite contained only typical single and clear anatase forms while the Zn-treated ACF/$TiO_2$ contained a mixed anatase and rutile phase with a unique ZnO peak. SEM results show that the titanium complex particles are uniformly distributed on and around the fiber and that the titanium complex particles are more regularly distributed on and around the ACF surfaces upon an increase of the $ZnCl_2$ concentration. These EDX spectra show the presence of peaks from the C, O and Ti elements. Moreover, peaks of the Zn element were observed in the Zn-treated ACF/$TiO_2$ composites. The prominent photocatalytic activity of the Zn-treated ACF/$TiO_2$ can be attributed to the three different effects of photo-degradation: doping, absorptivity by an electron transfer, and adsorptivity of porous ACFs between the Zn-$TiO_2$ and Zn-ACF.